• Title/Summary/Keyword: 자연점화

Search Result 34, Processing Time 0.025 seconds

Relationship between Autoigniton Temperature(AIT) and Ignition Delay Time for Acids (산(Acid)류의 자연발화온도와 방화지연시간의 관계)

  • 하동명
    • Fire Science and Engineering
    • /
    • v.18 no.2
    • /
    • pp.27-33
    • /
    • 2004
  • An accurate knowledge of the AIT(Autoignition temperatures) of chemicals is important in developing appropriate prevention and control measures in industrial fire protection. The AITs describe the minimum temperature to which a substance must be heated, without the application of a flame or spark, which will cause that substance to ignite. The measurement AITs are dependent upon many factors. namely initial temperature. pressure, volume, fuel/air stoichiometry. catalyst material, concentration of vapor, ignition delay time. This study measured the AITs of acids from ignition delay time by using ASTM E659-78 apparatus which was produced in the year 1994. The experiment AITs were a good agreement with the calculated AITs by the proposed equations with a few A.A.P.E.(average absolute percent error) and A.A.D.(average absolute deviation).

Effects of Catalytic Reaction and Natural Convection on the Hot Surface Ignition of Methane-Air Mixtures (메탄-공기 예혼합기의 열면점화에 미치는 촉매반응 및 자연대류의 영향)

  • Kim, H.M.;Jurng, J.S.
    • Journal of the Korean Society of Combustion
    • /
    • v.2 no.1
    • /
    • pp.29-38
    • /
    • 1997
  • In this study, the experimental and numerical investigations of the ignition of methane-air mixtures by a electrically heated wire have been carried out. In order to define the initial condition and make the analysis simple, the following control unit was developed; which heats the wire to the setting temperature in a very short time, and maintains the wire temperature constant until ignition. Experiments with the feedback control have been performed using nickel and platinum wires in normal gravity and microgravity. From experimental results, ignition temperatures in normal gravity are higher than those in microgravity, however, the dependences of ignition temperature on equivalence ratio are not affected by natural convection. Numerical calculations, including catalytic reaction for platinum, have been performed to analyze the experimental results in microgravity. Numerical results show that reactants near platinum wire are consumed by catalytic reaction, therefore, the higher temperature is needed to ignite the mixture with platinum wire.

  • PDF

The study on Coal Spontaneous Ignition Prevention using Safety Materials of Food and Cosmetics (식품과 화장품의 안전 소재를 이용한 석탄 자연발화 억제에 대한 연구)

  • Jun, Soo-Man;Kim, Young-Hee
    • Journal of the Korean Applied Science and Technology
    • /
    • v.39 no.2
    • /
    • pp.368-376
    • /
    • 2022
  • Spontaneous ignition occurs in industrial sites or anywhere in our lives, and is a phenomenon in which a substance ignites itself without an ignition source in the atmosphere. As the rate of chemical reaction increases, the heat generated increases, and the risk of spontaneous ignition increases. In this study, safe raw materials used for food and cosmetics were mixed to prepare coal spontaneous ignition prevention agents specifically among various spontaneous ignition phenomena. The effect of suppressing spontaneous combustion of coal was confirmed through lab and field tests with low-calorie, low-grade coal from Indonesia. As a result of the outdoor field test, the ignition prevention agent manufactured in this study compared with the control group(Fire after 90 days) showed excellent ignition inhibitors for more than 120 days. In addition, CO concentration control was confirmed by comparing the concentration of carbon monoxide for 50 days at the indoor coal yard. It was confirmed that the results were better than the comparative group coal and the existing anti-firing method. In addition, the possibility of coal fire prevention agents for indoor coal farms will be applied from 2024 was confirmed by studying the environment and safety of workers' working environments through official test such as soil and water quality test, MSDS of coal fire prevention agents in consideration of working workers, water quality, and eye irritation tests.

Performance evaluation on characteristic length variation of $H_2O_2$/Kerosene bipropellant rocket engine (특성길이 변화에 따른 $H_2O_2$/Kerosene 이원추진제 로켓 엔진의 성능평가)

  • Jo, Sung-Kwon;Jang, Dong-Wuk;Kim, Jong-Hak;Yoon, Ho-Sung;Kwon, Se-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
    • /
    • 2010.11a
    • /
    • pp.55-62
    • /
    • 2010
  • In addition to the previous study for development of a 1,200 N-class bipropellant rocket engine with concentrated hydrogen peroxide, the effect of characteristic length and thrust measurement were experimentally evaluated. Tests with characteristic lengths of 0.95, 1.07, and 1.20 m were performed and $C^*$ and Isp efficiencies were increased as increasing characteristic length. The maximum $C^*$ and Isp efficiencies were 98.4% and 93.1% respectively. Based on the evaluation of the designed engine, the optimized characteristic length was proposed in using the engine adapted decomposed hydrogen peroxide and the engine performance at vacuum-level was evaluated using thrust and Isp efficiency at the designed equivalence ratio. As a result, 218.4 s at sea-level, 253.3 s at vacuum-level, and vacuum thrust of 1035.3 N can be estimated.

  • PDF

Performance Evaluation on Characteristic Length Variation of $H_2O_2$/Kerosene Bipropellant Rocket Engine (특성길이 변화에 따른 $H_2O_2$/Kerosene 이원추진제 로켓 엔진의 성능평가)

  • Jo, Sung-Kwon;Jang, Dong-Wuk;Kim, Jong-Hak;Yoon, Ho-Sung;Kwon, Se-Jin
    • Journal of the Korean Society of Propulsion Engineers
    • /
    • v.15 no.3
    • /
    • pp.1-8
    • /
    • 2011
  • In addition to the previous study for development of a 1,200 N-class bipropellant rocket engine with concentrated hydrogen peroxide, the effect of characteristic length and thrust measurement were experimentally evaluated. Tests with characteristic lengths of 0.95, 1.07, and 1.20 m were performed and $C^*$ and Isp efficiencies were increased as increasing characteristic length. The maximum $C^*$ and Isp efficiencies were 98.4% and 93.1% respectively. Based on the evaluation of the designed engine, the optimized characteristic length was proposed in using the engine adapted decomposed hydrogen peroxide and the engine performance at vacuum-level was evaluated using thrust and Isp efficiency at the designed equivalence ratio. As a result, 218.4 s at sea-level, 253.3 s at vacuum-level, and vacuum thrust of 1035.3 N can be estimated.

Thermal Analysis for Solid Rocket Motor exposed to Fast Cook Off (급속가열 상황에 있는 고체 추진기관에 대한 열해석)

  • Doh, Young-Dae;Yoo, Ji-Chang;Kim, Chang-Kee;Lee, Do-Hyung;Ham, Hee-Cheol
    • Proceedings of the Korean Society of Propulsion Engineers Conference
    • /
    • 2009.05a
    • /
    • pp.196-199
    • /
    • 2009
  • The most important thing is to analyze the Fast Cook Off problem of the solid motor case exposed to direct flame is a heat transfer analysis. Heat causes degradation and ignition of the propellant. To archive an acceptable reaction level in Fast Cook Off, the rocket motor case generally must fail structurally prior to propellant ignition. We investigate the responses of the solid motor case exposed to Fast Cook Off by using finite element method for the thermal analysis.

  • PDF

Change in Biodiversity and Community Structures in Agricultural Fields depending on Different Farming Methods (농법 차이에 따른 농경지 생태계의 생물 다양성 및 군집 구조의 변화)

  • Kim, Hoon;Kim, Kyo-Jin;Sun, Yan;Jo, Young-Ju;Kim, Tae-Yeon;Moon, Myung-Jin
    • Korean Journal of Organic Agriculture
    • /
    • v.26 no.4
    • /
    • pp.687-706
    • /
    • 2018
  • Organic agriculture is well known to be not only affecting the physical and chemical status of the soil but also closely connected to the biodiversity through complex community structure and ecological interactions. Current study monitored and analyzed the invertebrate biodiversity of organic and conventional paddy fields and upland fields from April, 2017 to August, 2017. Total of 680 species (with 14,371 individuals) were confirmed - more number of species were identified at the organic agriculture practicing fields. According to the various indices analysis, organic paddy field showed about 40% higher diversity index, while organic upland field showed about 10% higher diversity index. Richness index at organic paddy field was 60% higher compared to conventional paddy field, while organic upland field showed 40% higher value. Dominance and evenness index at conventional agriculture practicing fields were low, which possibly indicate at least partial dominance phenomenon. Hemipteran, dipteran and aranean species showed highest diversity in all fields, while dipteran, hemipteran, aranean and coleopteran species had highest diversity in conventional agriculture practicing fields.

An Experimental Study on the Spontaneous Ignition of Flaxseed Oil and Olive Oil Adsorbed on Towels (타올에 흡착된 아마인유와 올리브유의 자연발화에 대한 실험적 연구)

  • Kim, Kyoung-Su;Choi, Yu-Jung;Choi, Jae-Wook
    • Journal of the Society of Disaster Information
    • /
    • v.18 no.2
    • /
    • pp.324-332
    • /
    • 2022
  • Purpose: In order to conduct a spontaneous ignition test in which a fire occurs in the absence of an ignition source due to the oil adsorbed on the towel. A phenomenon in which spontaneous ignition occurs when adsorbed to fibers using flaxseed oil, which is drying oil and olive oil, which is non-drying oil, is tested through an experiment. Method: After placing the sample container in the experimental device, observe the change in the central temperature of the sample, and when the central temperature rises above the set temperature and a fire occurs, it is judged as "ignition", and the experiment is stopped after checking the maximum value of the central temperature of the sample,When the central temperature of the sample was maintained similar to the set temperature, it was judged as "non-ignition" and the experiment was stopped. Result: In the towels with adsorbed flaxseed oil, the temperature in the sample container increased rapidly and combustion occurred in sheets 5, 10, and 15. Olive oil is a non-drying oil, does not ignite because it is difficult to dry because carbon is a single bond and it is difficult to bond with oxygen. Conclusion: It was confirmed that the more the amount of towel adsorbed to the drying oil, flaxseed oil, the longer the time to reach the set temperature and the occurrence of ignition.

Characterization of Algal-Bacterial Ecological Interaction and Nutrients Removal Under Municipal Wastewater Condition (실제 하수조건에서 조류-세균 복합군집의 생태적 상호작용 및 영양염류 제거 특성 규명)

  • Lee, Jang-Ho;Park, Joon-Hong
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.33 no.5
    • /
    • pp.314-324
    • /
    • 2011
  • Algal biomass cultivated by wastewater is potentially useful resource for biodiesel production. However, little is known about algal nutrient metabolism and microbial interaction with bacteria under real municipal wastewater condition. In this work, we characterized nitrogen and phosphorus removals of municipal wastewater by a representative wastewater-growing algal population. Ankistrodesmus gracilis SAG 278-2, and analyzed its ecological interaction with wastewater bacterial communities. Compared to wastewater sludge itself, algal-bacterial co-culture improved nutrient removal. According to bacterial community analysis with 16S rRNA genes, a selective and dominant growth of a Unclassified Alcaligenaceae population resulted from algal growth in the algal-bacterial co-culture. The selectively stimulated bacterial population is phylogenetically close to Alcaligenes faecalis subsp. 5659-H, which is known to be co-present interact with algae in aquatic environment. These findings suggest that algal growth/metabolism may have effects on selection of a specific bacterial population in algal-bacterial co-cultures that can efficiently remove nutrients from municipal wastewater.

Flammability and Thermal Stabilities of Heat Transfer Oils (열매체유의 인화성과 열안정성)

  • Lee, Keun-Won;Lee, Jung-Suk;Choi, Yi-Rac
    • Journal of the Korean Institute of Gas
    • /
    • v.15 no.2
    • /
    • pp.82-87
    • /
    • 2011
  • Heat transfer oils are used in applications such as heating systems of chemical plant, refinery heat exchange systems, gas plant process, injection molding systems, and pulp and paper processing. These oils are extremely stable and resistance to thermal and oxidative degradation. In the event of a spill or accidental release of heat transfer oils, it can be ignite easily when there is an ignition source. This paper discusses the flammability and thermal stabilities of new and used oils. The flammability of the oils are assessed by measuring changes in flash point and auto ignition temperature. The thermal stability of oils are evaluated by the thermal screening unit ($TS^u$) and the differential scanning calorimeter (DSC). From the experimental results, it is suggested to give fire hazard characteristics to safe precautions for the proper use and treatment of heat transfer oils.