• Title/Summary/Keyword: 자연기원

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Geochemical Study on the Naturally Originating Fluorine Distributed in the Area of Yongyudo and Sammokdo, Incheon (인천 용유도와 삼목도 지역 내 분포하는 자연기원 불소에 대한 지구화학적 연구)

  • Lee, Jong-Hwan;Jeong, Jong-Ok;Kim, Kun-Ki;Lee, Sang-Woo;Kim, Soon-Oh
    • Economic and Environmental Geology
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    • v.52 no.4
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    • pp.275-290
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    • 2019
  • Geochemical study was conducted to elucidate the origin of fluorine (F) distributed in the rocks within the four areas of Yongyudo and Sammokdo, Incheon, which have been used as the source area of land reclamation for the $3^{rd}$ and $4^{th}$ stage construction sites of the Incheon International Airport. The main geology of the study area is Triassic biotite granite. Fluorine is contained at high levels in biotite granite, mylonite, and dykes (andesite and, basaltic-andesite). Furthermore, the higher concentrations of fluorine in the biotite granite can be contributed to fluorite. The results of microscopic analyses reveal that the fluorite was mostly observed as small vienlets together with quartz. This features support that fluorite was naturally formed due to the secondary process of hydrothermal fluids. In addition, fluorine was investigated to be highly enriched in a large amount of mica within the veins. In the case of mylonite, a high levels of fluorine was contributed to a large amount of sericite. The sericites contained in the mylointe, differently to those of the biotite granite, filled the micro-fractures of quartz formed as a result of mylonitization and included small cataclastic quartz grains. This indicates that fluorine was naturally enriched due to the alteration of hydrothermal fluids filling fractured zones formed by mylonitization. Consequently, the results of petrological and mineralogical study confirm that the fluorine distributed in the rocks within the Yongyudo and Sammokdo originated naturally.

A Study on Environmental Damage due to Typhoons in Downstream Area of Abandoned Mine (태풍으로 인한 폐광산 하류 지역에서 환경피해 연구)

  • Cho, SungHyen;Lee, Dongguen;Lee, Goontaek;Kwon, Ohkyung;Kim, Tae Seung
    • Journal of the Korean earth science society
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    • v.43 no.1
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    • pp.119-127
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    • 2022
  • In recent years, the intensity of typhoons has increased due to climate change. It is presumed that the tailings and waste rock in the mining area harm the environment owing to flood damage. The Gangneung area has been affected by the largest typhoons in Korea, including No. 3,693 (1936), Rusa (2002), Maemi (2003), and Megi (2004). This study was based on a case in which high concentrations of arsenic were detected in the surroundings along a stream after floods caused by typhoons. Although the environmental damage-related law clarifies the responsibility of polluters, careful implementation is required in potential natural disaster areas. The pollutants from abandoned mines can be widely exposed due to typhoons as artificial causes may be mixed. To minimize the impact of natural disasters in these areas, it is necessary to improve and link relevant laws. This study is expected to help cope with mixed pollutants in downstream areas.

Characteristics of Nitrogen and Carbon Isotopes on Organic Matter and River Sediments of Toil Stream in Yeongju Dam Basin (영주댐 유역 토일천 유입 유기물 및 하천 퇴적물에 대한 질소와 탄소 동위원소 특성 연구)

  • Kang, Han;Song, Hye Won;Kim, Young Hun;Kim, Jeong Jin
    • Economic and Environmental Geology
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    • v.55 no.5
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    • pp.439-445
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    • 2022
  • Organic pollutants that contained in stream sediments have origins of mountain soil in natural and cattle manure in human activity. Nitrogen and carbon isotope analysis for mountain soil, cattle manure and stream sediment were performed for contribution evaluation of organic pollutants in Toil stream of Yeongju dam basin. Average carbon isotope ratio(δ13C) is -25.17‰, -22.34‰, and -26.39‰ for river sediments, cattle manure and mountain soil, respectively. Result of carbon isotope analysis suggests that river sediments are more affected by acid soils. Average value of the nitrogen isotope ratio (δ15N) is 9.46% for river sediment, 1.99% for mountain soil, and 19.53% for cattle manure. Result of nitrogen isotopic analysis show that contribution of cattle mature is slightly higher than that of mountain soil in Toil stream sediments.

Elucidation of the Enrichment Mechanism of the Naturally Originating Fluorine Within the Eulwangsan, Yongyudo: Focusing on the Study of the Fault zone (용유도 을왕산 자연기원 불소의 부화기작 규명: 단층대 연구를 중심으로)

  • Lee, Jong-Hwan;Jeon, Ji-Hoon;Lee, Seung-Hyun;Kim, Soon-Oh
    • Korean Journal of Mineralogy and Petrology
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    • v.35 no.3
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    • pp.377-386
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    • 2022
  • In addition to anthropogenic origins, fluorine (F) is naturally enriched in rocks due to geological events, such as magma dissemination, hydrothermal alteration, mineralization, and fault activities. Generally, it has been well known that F is chiefly enriched in the region of igneous and metamorphic rocks, and biotite granite was mostly distributed in the study area. The F enrichment mechanism was not sufficiently elucidated in the previous studies, and the study on a fault zone was conducted to reveal it more precisely. The mineral composition of the fault zone was identical to that of the Eulwangsan biotite granite (EBG), but they were quantitatively different between the two areas. Compared with the EBG, the fault zone showed relatively higher contents of quartz and F-bearing minerals (fluorite, sericite) but lower contents of plagioclase and alkali feldspar. This difference was likely due to hydrothermal mineral alterations. The results of microscopic observations supported this, and the generation of F-bearing minerals by hydrothermal alterations was recognized in most samples. Accordingly, it might be interpreted that the mineralogical and petrological differences observed in the same-age biotite granite widely distributed in the Yongyudo was caused by the hydrothermal alterations due to small-scale geological events.

Application of Scanning Electron Microscopy (SEM) for Biotically Induced Microstructure Observation in Sedimentary Sample of Natural Condition (주사전자현미경 분석을 활용한 자연환경 퇴적시료의 생물기원구조 관찰)

  • Park, Hanbeom;Kim, Jinwook
    • Korean Journal of Mineralogy and Petrology
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    • v.33 no.3
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    • pp.165-173
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    • 2020
  • The activity of living microorganism directly or indirectly affects to the biomineralization in sediments and rocks that display the unique biotic structure. Minerals in the biotic structures showed unique properties and bypass the thermodynamic and kinetic barriers. Therefore, investigations on the biotically induced microstructure is essential to identify the new mineral formation mechanism by analyzing crystal structures and morphology at a nano-scale. The significant implication as well as advantages of using scanning electron microscopy to characterize the biotic structures were discussed in this paper for the examples of hydrothermal vent area microbial mat and deep-sea ferromanganese crust sample.

Characteristics of Natural and Experimental Fracture Propagation in Rocks (암석 내의 자연균열과 인공균열의 진행특성)

  • 백환조
    • The Journal of Engineering Geology
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    • v.7 no.1
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    • pp.53-62
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    • 1997
  • Fracture mechanics properties of rock materials can he applied to predict the distribution of natural fractures in rock masses, and also to assess the safety of rock slopes and underground structures. In this study, rock fracture toughness and other fracture rrechanics properties of sorne lithologies showing apparently rock-property-controlled distribution of natural fractures were measured. Propagation behaviors of natural and experirnental fractures were also characterized both qualitatively and quantitatively, in terns of the propagation types and sorne statistical parameters. It was concluded that the application of fracture mechanics theories to the ge6logic materials should be based on the geological background and evidences.

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A study on origin of fresh water in fresh and salt water interface (담·염수 경계면의 담수 기원에 관한 연구)

  • Kim, Byung-Woo;Choi, Ilhwan;Baek, Keon-Ha;Ryu, Kyongsik;Lee, Sang-Wuk
    • Proceedings of the Korea Water Resources Association Conference
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    • 2019.05a
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    • pp.217-217
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    • 2019
  • 해안과 하천이 위치해 있는 낙동강하구의 담 염수 경계면 추적 연구에서 담 염수 경계면의 담수기원특성을 분석하기 위해서는 담 염수 경계면을 이루는 담수의 기원이 하천 혹은 지하수 인지를 규명하는 것이 매우 중요하다. 담 염수 경계면에 있는 담수는 일반적으로 하천과 지하수에 의한 것으로, 낙동강하구 일원을 대상으로 지하수공 내 해수침투 여부 파악을 위해 화학적(유기물) 분석을 실시하였다. 이와 아울러 낙동강하구 일원에서 담 염수 경계면에서 채취한 수질시료의 담수기원을 분석하기 위하여 K-water연구원 수질안전센터에 지하수공 7개지점(BH-1~7호공)의 심도별 물시료 2~4개지점(총 23개 지점), 하천(1개 지점), 해수 및 해안유출수(각 1개 지점)를 포함한 26개 시료를 LC-OCD(Liquid Chromatography-Organic Carbon Detector)로 분석하였다. LC-OCD 분석결과 특성은 기본적으로 유기물질이 물에서 유래한 aquagenic 혹은 토양층에서 유래한 pedogenic 유기물질 인지에 달려있다. 댐 또는 하천에서 pedogenic 유기물의 농도는 일반적으로 유역분지의 수문 또는 수리지질학적 경로에 의존한다. pedogenic 유기물들은 주로 상대적으로 작은 분자량을 갖는 친수성, 높은 사슬밀도 및 내화성 분자특성을 갖는 펄빅산으로 구성된다. aquagenic 유기물질은 수생 식물성 생물이나 플랑크톤의 분해 산물로서 세포벽에서 유래된 peptidoglycans와 고분자량의 polysaccharides 등을 포함한다(Chio & Jung, 2008; Buffle, 1988). 담 염수 경계면 추적을 위한 7개 관측공의 심도별 수질시료는 하천, 해수, 그리고 해안유출수의 용존유기탄소를 분석하기 위하여 LC-OCD로 정밀분석하였다. 그 결과, humic, 휴믹물질의 산화물질인 building blocks, 생물고분자 물질(bio-polymers), neutrals, acids로 분석되었으며, 일반적인 자연유기물질의 기원은 pedogenic과 aquagenic 유기물질로 분류된다. IHSS 표준물질 분석 등을 통한 SUVA 값으로부터 자연유기물질의 기원정보를 제공하는 HS-Diagram으로 도시한 결과, 2018년 11월 2일 조사한 26개의 원수시료 전체는 pedogenic fulvic acid〉aquagenic fulvic acid으로 하천의 기원이 우세한 것으로 분석되었다. BH-1호공과 BH-6호공의 특정 1개구간 GL.-6m를 제외한 모든 구간에서 aquagenic FA의 지하수 기원으로 분석되었으며, 나머지 지하수공(BH-2, 3, 4, 5, 7)과 하천 및 해안유출수는 유역분지 수문학적 경로인 pedogenic FA의 하천 기원의 담수인 것으로 분석된다.

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Origin of Fluorine Contained in Rocks within the Eulwangsan, Yongyudo (용유도 을왕산에 분포하는 암석 내 불소 기원)

  • Lee, Jong-Hwan;Jeong, Jong-Ok;Kim, Kun-Ki;Lee, Sang-Woo;Kim, Soon-Oh
    • Economic and Environmental Geology
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    • v.51 no.6
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    • pp.521-529
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    • 2018
  • This study was conducted to investigate the natural origin of fluorine contained in the rocks within the Eulwangsan area via petrological and mineralogical analyses. The main geology of the Yongyudo Eulwangsan area is Triassic biotite granite. Biotite granite and mylonite are the major rock types containing fluorine at high levels (up to 1,700 and 2,400 mg/kg for biotite granite and mylonite, respectively). In the case of the biotite granite, a high concentration of fluorine can be contributed to fluorite, and the results of microscopic analyses show that the fluorite was observed as small veinlets filling cleavages and micro-fractures within alkali-feldspars and plagioclases, or observed together with quartz in ore veins, indicating the secondary formation of fluorite by hydrothermal fluids. In mylonite, on the other hand, a high fluorine concentration is attributable to sericite. Microscopic analyses revealed that the boundary between sericite and surrounding quartz was not clear, the sericite occurred filling the micro-fractures of quartz and encapsulating small quartz cataclasts. These results indicate that the sericite was also formed as a result of hydrothermal alteration. Consequently, it is speculated that the high fluorine level in the rocks of the Eulwangsan area of Yongyudo is of natural origin due to hydrothermal processes.