• Title/Summary/Keyword: 입자 생성

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Toughness Improvement of Unsaturated Polyester Mortars Blended with Polyurethane Liquid Rubber (폴리우레탄 액상고무를 혼합한 불포화 폴리에스테르 모르타르의 인성 증진효과)

  • 최영준;박준철;박정민;김화중
    • Journal of the Korea Concrete Institute
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    • v.14 no.3
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    • pp.283-290
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    • 2002
  • Generally polymer mortar and concrete using unsaturated polyester resin has high strengths and good chemical resistance. However it also has high brittleness and because of this reason, it is not used for the purpose that demands high resistance to impact. The purpose of this study is to improve the brittleness of unsaturated polyester mortar(UPE mortar) which could be used for the flooring material with recycled aggregates and UPE. Polyurethane liquid rubber(PU) and recycled aggregates were used to complement the brittleness and to recycle the resources respectively. The characteristics of mortar were investigated according to the molecular weight and substitution rate of PU. As the molecular weight and PU substitution rate were increased, the viscosity was increased, working life became fast and curing shrinkage was reduced. Compressive and flexural strengths were also reduced but tile brittleness was improved. Therefore, it is seemed that the improved WE mortar could be obtained by using polyurethane liquid rubber with the polyol of molecular weight 2000, 3000.

Mechanical Properties of Partially Stabilized $\alpha$-Sialon Synthesized from Kimcheon Quartzite (김천규석으로부터 제조한 부분안정화 $\alpha$-Sialon의 기계적 물성)

  • 서원선;조덕호;이홍림
    • Journal of the Korean Ceramic Society
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    • v.25 no.2
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    • pp.143-153
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    • 1988
  • In order to synthesize the partially stabilized $\alpha$-Sialon, A1N and Y2O3 were added to synthesized $\alpha$-Si3N4. The phase composition, mechanical properties, micro structure, etc, of the synthesized $\alpha$-Sialon were investigated. Partially stabilized $\alpha$-Sialon ceramics could be synthesized from the composition which was a little deviated from x=0.4, x=0.6 composition along the Si3N4.0.1Y2O3:0.9AlN tie line at 1750-180$0^{\circ}C$ for 2 hrs in N2 atmosphere. It is assumed that A1N is more closely related than Y2O3 to the formation of $\alpha$-Sialon, and that A1N is more easily dissolved into $\alpha$-structure than into $\beta$-structure. In Ya2O3-rich phase mechanical properties were observed to be poor because of formation of mellilite, grain growth, and thermal decomposition of $\alpha$-Sialon. The maximum values of M.O.R, KIC and hardness are 723 MPa, 4.5MN/㎥/2 and 19.3 GPa, respectively, and they were observed for the $\alpha$-Sialon ceramics sintered at 178$0^{\circ}C$.

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Heat treatment induced morphological changes of $Ca^{++}$ implanted single crystal $Al_2O_3$ ($Ca^{++}$를 implant한 단결정 $Al_2O_3$에서 열처리에 의한 형태학적 변화)

  • 김배연
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.3
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    • pp.327-333
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    • 1999
  • Controlled Ca impurity implanted inner crack-like pore in the high purity alumina bi-crystal had been created by micro-fabrication technique, which includes ion implantation, photo-lithography, Ar ion milling, and hot press. The morphological change and the growth od crystals formed by heat treatment in Ca doped high purity single crystal alumina, were observed using optical microscopy. The dot was developed and hexagon like crystal appeared on inner surface of crack-like pore after heat treatment. Bar type crystals, probably CaO . $6Al_2O_3$, were observed on the inner surface of 100ppm Ca implanted specimen after 1 hour heat treatment at $1,500^{\circ}C$, but this bar type crystal disappeared after 1 hour heat treatment at $1,600^{\circ}C$. This disappearance means that there should be little increase of Ca solubility limit to alumina and/or changes of diffusion coefficient of Ca in alumina around this temperature.

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Carbonation Treatment of EAF Slag for Using Aggregate of Concrete (EAF-Slag의 콘크리트용(用) 골재(骨材)로의 활용(活用)을 위한 탄산화(炭酸化) 처리(處理) 연구(硏究))

  • Yoo, Kwang-Suk;Ahn, Ji-Whan;Lee, Kyung-Hoon
    • Resources Recycling
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    • v.18 no.3
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    • pp.36-41
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    • 2009
  • The objectives of this study are focusing on the issue with efficiently recycling for EAF slag as construction material such as an aggregate of concrete. This study can be classified mainly into two categories: the first section is the carbonation treatment of Electric Arc Furnace(EAF)-slag for obtaining soundness as using aggregate of concrete. And the second section is the application of carbonated EAF-slag on the mortar test to evaluate the stability and mechanical property, which is compressive strength, according to the replacement of EAF-slag on the mortar. It was known that pH of EAF-Slagle according to carbonation time decreases drastically to 7 within several sec of carbonation, and a calcite is formed on the surface of EAF slag. The formation of calcite during the carbonation process of EAF slag lead to fill at pore in the texture of EAF-Slag surface, and than the porosity of EAF-slag decreases with carbonation process. In the mortar test, compressive strength, according to the replacement of EAF-Slag to sand on the mortar, the compressive strength of mortar increased as the 50% replacement ratio of EAF slag for sand was above 10% higher than that of reference mortar according to 50% replacement of EAF slag.

Kinetic Study of Synthesis of Aluminum Nitride Using Carbon Reduction and Subsequent Nitridation Method (탄소환원질화법에 의한 AlN 합성의 속도론적 연구)

  • Park, Hyungkyu;Choi, Youngyoon;Nam, Chulwoo
    • Resources Recycling
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    • v.26 no.3
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    • pp.39-46
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    • 2017
  • AlN powder was prepared by carbon reduction and subsequent nitridation method through lab- scale experiments. AlN powder was synthesized using the mixture of high purity $Al_2O_3$ powder and carbon black at $1,600{\sim}1,700^{\circ}C$ for 0.5~6 hours under nitrogen atmosphere (flow rate of nitrogen gas: $4.7{\times}10^{-6}{\sim}20{\times}10^{-6}m^3/sec$) with variation of charged height of the mixture powder. Experimental results showed that size of the synthesized particles grows with increasing of temperature. The reaction activation energy was calculated as 382 kJ/mol at the temperature range, and it was considered that chemical reaction is the rate determining step. Content of oxygen and nitrogen of the prpared samples were 0.71~0.96 wt% and 30.7~35.1 wt%. The results was similar with those of the commercial AlN product.

Vortex Flow Analisys around the Floating Body with Vertical Plate (연속부착된 수직평판을 갖는 부유구조물 주위의 와유동 해석)

  • Kim, Ho;Lee, Gyoung-Woo;Cho, Dae-Hwan;Gim, Ok-Sok
    • Proceedings of KOSOMES biannual meeting
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    • 2007.05a
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    • pp.161-168
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    • 2007
  • In this paper, the floating body with double barriers is introduced with a study on the flow patterns and characteristics in around the floating body by using 2 frame p article tracking method. This paper introduce an analisys method to predict the characteristics of flow around the neighbording fields of Floating Body with double barriers in order to investigate a high performance model. Flow visualization has conducted in a circulating water channel by a high speed camera and etc. Flow phenomena according to velocity distribution and flow separation around the floating body with double barriers were obtained by two-dimensional PIV system.

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An Investigation on the Technical Background for Carbon-14 Monitoring in Radioactive Effluents (원자력시설의 Carbon-14 방사성유출물에 대한 감시배경의 조사)

  • Kim, Hee-Geun;Kong, Tae-Young;Jeong, Woo-Tae;Kim, Seok-Tae
    • Journal of Radiation Protection and Research
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    • v.34 no.4
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    • pp.195-200
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    • 2009
  • effluents to the environment. The activity of carbon-14, one of the radioactive effluents, in the environment is already high level and its effect on radiation exposure to the public and the environment is insignificant; thus, NPPs did not perform the carbon-14 monitoring in effluents in the past. By the way, effluents of noble gas and particulate radioactive materials originated from nuclear fuels has been continuously reduced due to both the advancement of manufacturing and integrity technology for nuclear fuels and the improvement of operation methods of NPPs. Futhermore, the portion of dose assessment by tritium and carbon-14 to the public has been relatively increased because the lower limit of detection for low-energy beta sources, such as tritium and carbon-14, is low due to the advancement of radiation detection technology. In this paper, the technical background for carbon-14 monitoring in nuclear facilities was investigated using United States technical reports and papers. This paper also reviews whether carbon-14 monitoring is necessary or not based on the investigated documents.

Influences of Magnetization Reversal and Magnetic Interaction on Coercivity of Sr-Ferrite Particles with Different Sizes (크기가 다른 Sr-Ferrite 입자의 자화 역전과 자기 상호작용이 보자력에 미치는 영향)

  • Kim, Hyeon Soo;Jeong, Soon Young;Kim, Kyung Min;Kwon, Hae-Woong
    • Journal of the Korean Magnetics Society
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    • v.27 no.1
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    • pp.23-29
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    • 2017
  • In this study, the influences of magnetization reversal and magnetic interaction on the coercivity of Sr-ferrite particles with different sizes were investigated through various magnetic measurements. The shape of the initial magnetization curve and the magnetic field dependence of the coercive force indicate that the magnetization reversal changes from domain nucleation to wall pinning as the particle size decreases. On the other hand, the Henkel plot, interaction field factor and ${\Delta}M(H)$ obtained from the DCD and IRM curves show that the strength of the dipolar interaction is increased with increasing the particle size. Therefore, it can be concluded that coercivity is closely related to magnetic interaction as well as magnetization reversal mechanism.

On Flow Charactistics around Special Rudders by PIV Measurement; Flapped and Water-blowing Rudder (PIV 계측에 의한 특수타 주위의 유동특성에 대하여; 플랩러더와 물분사러더)

  • Gim, Oxoc
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.23 no.2
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    • pp.200-207
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    • 2017
  • The purpose in having a control surface on ships is to control the motion of the ship. The control surface may be composed entirely of a single movable surface or of a combination of fixed and movable portions. A control surface has one sole function to perform in meeting its purpose, and that is to develop a control force in consequence of its orientation and movement relative to the water. The forces and moments generated as a result of this rotation and angle of attack then determine the manoeuvring characteristics of the ship. In this paper, two-dimensional flow characteristics of a flapped rudder and a water-blowing control rudder were accomplished respectively by PIV method in a circulating water channel. Model test has been carried out with different angles of attack of main foil (NACA 0012) and flap's deflection angles to predict the performance of the flapped rudder and the water-blowing control rudder. The 2-frame particle tracking method has been used to obtain the velocity distribution in the flow field. $Re{\fallingdotseq}3.0{\times}10^4$ has been used during the whole experiments and measured results have been compared with each other.

Improvement of Wettability and Removal of Skin Layer on Ar-Plasma-Treated Polypropylene Blend Surface (폴리프로필렌 복합소재의 아르곤 플라즈마 처리로 표면층 제거와 젖음성 향상)

  • Weon, Jong-Il;Lee, Sun-Yong
    • Polymer(Korea)
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    • v.36 no.4
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    • pp.461-469
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    • 2012
  • The surface modification and characterization of Ar-plasma treated polypropylene (PP) blend are investigated using x-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and contact angle measurement. An increase in Ar-plasma treatment time leads to an increase in wettability, oxygen containing polar functional groups, the amount of talc, and surface roughness on the PP blend surface. A careful observation using SEM indicates that there exists a skin layer consisting of only PP component. The difference in viscosity between PP and rubber particles facilities the formation of skin layer. However, it is found that an increase in Ar-plasma treatment time helps to decrease the thickness of skin layer. Additional methodologies for the elimination of skin layer during injection molding are also discussed. The surface modification and morphological alteration induced by Ar-plasma treatment provides a hydrophilic state, followed by the improvement in wettability, on the PP blend surface.