• Title/Summary/Keyword: 입자크기분포

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Characterization of Korean Sweet Potato Starches: Physicochemical, Pasting, and Digestion Properties (국내 육종 고구마 전분의 이화학 호화 및 소화 특성)

  • Baek, Hye Rim;Kim, Ha Ram;Kim, Kyung Mi;Kim, Jin Sook;Han, Gui Jung;Moon, Tae Wha
    • Korean Journal of Food Science and Technology
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    • v.46 no.2
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    • pp.135-142
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    • 2014
  • Physicochemical, pasting, and digestion properties of sweet potato starches from 11 Korean cultivars were investigated. Starch granules were variably oval, round, polygonal, spherical, and bell-shaped, and of 10.2-15.3 ${\mu}m$ in mean particle diameter. Amylose contents varied from 12.3 to 17.4%. A similar chain length distribution of amylopectin was found in each of the cultivars. The portion of $B_3$ correlated with the degree of amylose leaching. Thermal properties determined by differential scanning calorimetry showed high values of gelatinization temperatures in Shinyulmi and Jeungmi starches, but a relatively low value in Daeyumi starch. All starches exhibited a Ca-type diffraction pattern. Differing patterns were observed in swelling factors, depending on temperature. The contents of rapidly digestible starch, slowly digestible starch, and resistant starch ranged from 9.6-17.4, 31.4-45.6, and 35.7-62.8%, respectively. In Rapid Visco Analyser profiles, differences were observed in pasting parameters such as pasting temperature, peak viscosity, final viscosity, and breakdown.

Microhabitat Analysis of Endangered Species (I), Cobitis choiiwith Rapid Decreases of Population by Environmental Pollution for a Habitat Replacement (환경오염에 의해 급감하는 멸종위기 1급 어종인 미호종개의 대체 서식지 마련을 위한 미소서식지 분석)

  • Kim, Jiyoon;An, Kwangguk
    • Journal of Environmental Impact Assessment
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    • v.23 no.4
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    • pp.271-284
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    • 2014
  • The objectives of this research were to analyse the microhabitat of Cobitis choii which is designated as an endangered fish species (I) and national monument species in Korea (No. 454), and provide valuable information of suitable replacement habitat in the future for a conservation of the population with rapid decreases by environmental pollution. Sampling and microhabitat analysis in three streams such as Baekgok, Yugu and Gap Stream, known as one of the least habitats in Korea showed that the mean number of Cobitis choii observed was 2.6. This result indicated that the richness was too low, so the species conservation was very urgent. Optimal physical microhabitat of the population was determined as environmental conditions with > 60% sand with 1 mm particle size, optimal water depth of 20 - 60 cm in the habitats, and the optimal current velocity of < 0.4 m/s. Under the circumstances of the microhabitat, optimal water volume (discharge) was 0 - 2 m3/s in the each sectional analysis and this reach was mainly composed of the stream section with intermittant slow runs and pools. These microhabitats were largely disturbed by physical modifications of habitat and chemical pollutions due to direct influences of nutrient-rich water inputs from the urban area and intensive agricultural pollutants. For these reasons, optimal habitat replacement are required in the future for the conservation of the species.

Fabrication of Porous Alumina Ceramics by Spark Plasma Sintering (방전 플라즈마 소결법에 의한 다공성 알루미나 세라믹스의 제조)

  • Shin, Hyun-Cheol;Cho, Won-Seung;Shin, Seung-Yong;Kim, Jun-Gyu
    • Journal of the Korean Ceramic Society
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    • v.39 no.12
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    • pp.1183-1189
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    • 2002
  • In order to develope the porous alumina ceramics with high strength, the pore characteristics and compressive strength were investigated in terms of relation to the conditions of spark-plasma sintering and the contents of graphite as a pore precursor. Porous alumina bodies were successfully prepared by spark-plasma sintering and burning out graphite in air. High porous bodies were fabricated by sintering at 1000${\circ}C$ for 3 min under a pressure of 30 MPa, heating rate of 80${\circ}C$/min and on-off pulse type of 12:2. For example, alumina bodies prepared by the addition of 10∼30 vol% graphite showed high porosity of 50∼57%. Also, the open porosity increased with graphite content. The relationship between pore characteristics and graphite contents could be explained by percolation model depending on cluster number and size. Porous alumina bodies prepared by the addition of 10∼30 vol% graphite showed the high compressive strength of 55∼200 MPa. This great improvement in strength was considered to be mainly due to the spark-plasma discharges and the self-heating action between particles.

A Petrological Study of Stones Used in the Three Storied Stone Pagoda of Bulguksa Temple (불국사 삼층석탑에 사용된 석재의 암석학적 연구)

  • Park, Sung-Chul;Moon, Sung Woo;Kim, Sa-Duk;Jwa, Yong-Joo
    • The Journal of the Petrological Society of Korea
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    • v.24 no.1
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    • pp.11-24
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    • 2015
  • In this study, the stone used for three storied pagoda of Bulguksa Temple, which is easy to access due to works for dismantle and restore will be analyzed on the basis of petrographic study, magnetic susceptibility, and ${\gamma}$-ray spectrometer, and identify petrographic characteristics. Also we will select candidate areas of fresh rock to change the stone used for three storied stone pagoda as from its provenance is presumed. According to the results of visual inspection, the stones used for the three storied stone pagoda are similar to the features of Namsan granite, which is distributed around Gyeongju-si, and when it comes to the section of the stupa finial, the features of all the parts from the stupa finial is similar to Namsan granite except for the section of Jeweled cover. On the other hand, the color, the composition, and the mineral size of the stones in the section from the part of jeweled cover are similar to Tohamsan granite. As a result of none-destruction inspection, it seems that the stones used for the three stories stone pagoda except for the section of jeweled cover are similar to the values for the magnetic susceptibility and the ${\gamma}$-ray spectrometer. On the other hand, Jeweled cover and the values of Tohamsan granite are alike. Namsan granite is appropriate in case that the stone used for three storied stone pagoda must be replaced to fresh rock because of damage by weathering. Meanwhile, Namsan granite is seperated from Yangsan fault. Due to this fact, Namsan granite appears to not only Mt. Namsan in Gyeongju, but also Dongcheon-dong, Gyeongju, and Huenggok-ri, Pohang. As a result, these two areas are suitable to the candidate area to change the stone used for three storied stone pagoda.

An Experimental Study on the Engineering Properties of Lightweight Aggregate Concrete (경량골재 콘크리트의 공학적 성질에 관한 실험적 연구)

  • ;R. N. Swanmy
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.39 no.1
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    • pp.75-82
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    • 1997
  • 건설기술과 산업의 발전에 따라 구조물은 대형화되어 가고, 건설공사의 급격한 팽창으로 골재 수용량이 급증함에 따라 천연골재자원은 점차 부족현상을 면치 못할 처지에 있다. 또한, 무리한 천연골재의 채취는 자연환경을 훼손시킬 뿐만 아니라 자연보호 측면에서도 심각한 공해문제로 대두되고 있어 공급량 부족현상은 날로 심화되고 있다. 이에 세계 몇몇 나라에세는 산업부산물을 이용한 골재 생산으로 공해예방과 폐기물 활용방법을 연구하고 있다. 산업부산물중 플라이 애쉬 생산량은 전 세계적으로 매년 약 2억여톤에 달하고 있으나 이중 일부만 활용되고 있는 실정이다. 이와같은 부산물을 활용하기 위한 일환으로 산업부산물인 PFA(Pulverized Fuel Ash)로 만든 인공경량골재의 년생산량이 영국은 600,000$m^3$, 미국은 300,000$m^3$이며, 매년 증가주세에 있다. 고성능 경량골재 콘크리트는 단위중량의 증가없이 내구성과 강도를 향상시켜 실용화 측면에서 경제적인 효과가 있으며, 플라이 애쉬로 만든 경량골재는 시멘트와의 친화력이나 접착면에서 우수한 것으로 알려져 있다. 본 시험에 사용한 골재는 플라이 애쉬로 만든 인공경량 조골재와 강모래이고, 결합제로서 프틀랜드 시멘트를 사용하였다. 부수적인 결합재로서는 플라이 애쉬, 슬래그, 실리카 흄을 사용하였으며, 고성능 경량골재 콘크리트를 개발코자 재령 28일과 180일의 압축강도가 각각 50MPa와 60MPa가 되도록 배합설계를 하였다. 본 연구에서는 플라이 애쉬, 슬래그, 시리카 흄과 같은 산업부산물을 혼입했을때 경량골재 콘크리트의 압축강도, 휨강도, 동탄성계수, 공극체적, 공극률, 단위중량, 공극 크기별 분포등의 변화를 실험적으로 구명하여 재반 구조용 콘크리트에 활용하기 위한 기초자료를 마련코저 한다.있어 특정한 발육단계의 난포 사망기전을 연구하기 어렵다. 또한 난포는 생체 내에서 다양한 호르몬을 동시에 분비하기 때문에 특정한 난소국부호르몬이 사망기전에 미치는 영향을 조사하기 힘든 점이 있다. 최근 들어 난포체외배양이 다양하게 개발되면서, 이러한 어려운 점을 극복할 수 있게 되었다. 본 논문은 각 발육단계의 난포를 절단해 체외배양하면서, apoptosis DNA 절단 현상을 이용하여 각종 난소국부 호르몬들이 난포발육단계별로 사망기전에 미치는 영향을 요약해 보였다. 난포는 발육하면서 점차 복잡한 호르몬 경로를 생존을 위해 필요로 한다. Prevulatory난포생존에 필요한 난소국부호르몬들은 early antral 단계의 난포에서는 그 미치는 영향이 감소되다가 preantral단계의 난포에서는 영향을 전혀 미치지 못했다. 단지 예외는 cGMP처리로써, 세포내 cGMP수준을 일정하게 유지시켜주는 것이 난포발육단계에 무관하게 생존에 중요한 인자로, 장래 연구는 난포 세포내의 cGMP수준을 조절하는 기작을 규명하는데 있을 것이다.인정되지 않았다. 7. 농지보전 처리구인 배수구와 초생수로구는 비처리구에 비해 낮은 침두 유출량과 낮은 토양유실량을 나타내었다.구보다 14% 절감되는 것으로 나타났다.작용하는 것으로 사료된다.된다.정량 분석한 결과이다. 시편의 조성은 33.6 at% U, 66.4 at% O의 결과를 얻었다. 산화물 핵연료의 표면 관찰 및 정량 분석 시험시 시편 표면을 전도성 물질로 증착시키지 않고, Silver Paint 에 시편을 접착하는 방법으로도 만족한 시험 결과를 얻을 수 있었다.째, 회복기 중에 일어나는 입자들의 유입은 자기폭풍의 지속시간을 연장시키는 경향을 보이며 큰 자기폭풍일수록 현저했다. 주상에서 관측된 이러한 특성은 서브스톰 확장기 활동이 자기폭풍의 발달과 밀접한 관계가

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Preparation and Effect of Eudragit E100 Microcapsules Containing Grapefruit Seed Extract on Kimchi (자몽씨 추출물을 함유한 Eudragit E100 미세캡슐의 제조 및 김치에 대한 영향)

  • 김한수;정성기;조성환;구재관;이승철
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.32 no.8
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    • pp.1239-1244
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    • 2003
  • Microcapsules were prepared by coacervation method using acetone/liquid paraffin system to control the ripening of kimchi. Eudragit E100, which was soluble at below pH 5.0 in aqueous solution, was used to make microcapsules to be sensitive to acidity of kimchi. The microcapsules with Eudragit E100 containing grapefruit seed extract (GFSE) showed the highest yield of 92.13%, the size of microcapsules was decreasing as increasing the amount of aluminium stearate, a dispersing agent. Morphology of the microcapsules determined by scanning electron microscopy showed spherical forms. GFSE, encapsulated antimicrobial agents, was quickly released at acidic buffer (pH 4,5,6) within 1 storage day. However, 70% of encapsulated GFSE in Eudragit E100 microcapsules was continuously released at pH 7 till 3 days, and it was sustained till 9 days. Characteristics of kimchi containing microcapsules of GFSE were analysed with ripening period. Decease of pH in kimchi was retarded with the added GFSE microcapsules till 2 days of fermentation, but GFSE did not affect pH in kimchi after 3 days. Total numbers of microorganisms and lactic acid microorganisms in kimchi were decreased with increasing the amount of the added GFSE microcapsules, however, the effect of controlled released GFSE from pH sensitive Eudragit E100 microcapsules was hard to detect. These results suggest the possibility of pH sensitive microcapsules for high qualify of kimchi.

Crystalline Growth Properties of Diamond Thin Film Prepared by MPCVD

  • Park Soo-Gil;Kim Gyu-Sik;Einaga Yasuaki;Fujishima Akira
    • Journal of the Korean Electrochemical Society
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    • v.3 no.4
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    • pp.200-203
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    • 2000
  • Boron doped conducting diamond thin films were grown on Si substrate by microwave plasma chemical vapor deposition from a gaseous feed of hydrogen, acetone/methanol and solid boron. The doping level of boron was ca. $10^2ppm\;(B/C)$. The Si substrate was tilted ca. $10^{\circ}$ to make Si substrate, which have different height and temperature. Experimental results showed that different crystalline of diamond thin films were made by different temperature of Si substrate. There appeared $3\~4$ steps of different crystalline morphology of diamond. To characterize the boron-doped diamond thin film, Raman spectroscopy was used for identification of crystallinity. To survey surface morphology, microscope was used. Grain size was changed gradually by different temperature due to different height. The Raman spectrum of film exhibited a sharp peak at $1334cm^{-1}$, which is characteristic of crystalline diamond. The lower position of diamond film position, the more non-diamond component peak appeared near $1550 cm^{-1}$.

The Effect of NH3 Concentration during Co-precipitation of Precursors from Leachate of Lithium-ion Battery Positive Electrode Active Materials (리튬이차전지 양극활물질의 암모니아 침출액에서 공침법에 의한 활물질 전구체의 합성에 대한 암모니아 농도의 영향)

  • Park, Sanghyuk;Ku, Heesuk;Lee, Kyoung-Joon;Song, Jun Ho;Kim, Sookyung;Sohn, Jeongsoo;Kwon, Kyungjung
    • Resources Recycling
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    • v.24 no.6
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    • pp.9-16
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    • 2015
  • In a recycling scheme of spent lithium ion batteries, a co-precipitation process for the re-synthesis of precursor is essential after the leaching of lithium ion battery scraps. In this study, the effect of ammonia as impurity during the co-precipitation process was investigated in order to re-synthesize a precursor of Ni-rich cathode active material $LiNi_{0.6}Co_{0.2}Mn_{0.2}O_2$ (NCM 622). As ammonia concentration increases from 1 M (the optimum condition for synthesis of the precursors based on 2 M of metal salt solution) to 4 M, the composition of obtained precursors deviates from the designed composition, most notably for Ni. The Ni co-precipitation efficiency gradually decreases from 100% to 87% when the concentration of ammonia solution increases from 1 M to 4 M. Meanwhile, the morphological properties of the obtained precursors such as sphericity, homogeneity and size distribution of particles were also investigated.

Change of Science Teachers' Perceptions About the Atmosphere Composition of Molecules with Different Masses (서로 다른 질량을 가진 분자들로 이루어진 대기의 조성에 대한 과학교사들의 인식 변화)

  • Yoo, Seunggyun;Paik, Seoung-Hey
    • Journal of the Korean Chemical Society
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    • v.62 no.4
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    • pp.288-298
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    • 2018
  • In this study, we surveyed pre- and post-perceptions of fourteen science teachers related to the atmosphere composition of molecules with different masses by the developed test. As a result of the test, the teachers were classified into two types of thoughts; One of them is considered the atmosphere to be a homogeneous solution, and the other is a thought that the composition ratio of the atmosphere was not homogeneous considering the different weights of particles. The two types were reclassified into three categories; one of them is considering large gravity effect, another is considering small gravity effect, and the other is considering medium scale gravity effect. Total six types of thoughts were found from the pre-test. After introducing crosscutting concepts which are related to the composition of atmosphere. The teachers discussed the phenomena with the molecular motion by weights of atoms and temperature, the homogeneity of the solution of air in chemistry domain. They also discussed with the relationship between mass and gravity and distance in physics domain. And the discussion included distribution of the atmosphere, convection phenomena, etc. After the discussion, the teachers changed their pre-conceptions to post-concoctions considering combined perspectives of gravity, mass, temperature, altitude etc. Through these changes, we are able to confirm the importance of crosscutting concepts covered in various disciplines. In the integrated science, we should help teachers to provide students with these types of thinking in order to form a coherent world-view and to carry out inquiry thinking as an intellectual tool.

The Effect of Hydrogen Reduction Treatment on Properties of Ba-ferrite (환원처리가 Ba-ferrite의 물성에 미치는 영향)

  • 홍양기;정홍식;김현준
    • Journal of the Korean Magnetics Society
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    • v.7 no.1
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    • pp.25-30
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    • 1997
  • Physical and magnetic behaviors of reduced Co-Zn-Ti-Sn substituted Ba-ferrite particles with hydrogen are different from those of reduced-pure Ba-ferrite particles. The coercivity of substituted Ba-feffite particles shows a peaking effect with the reduction temperature ranging from 250 to 520 $^{\circ}C$, while the coercivity of pure Ba-ferrite decreases monotonically. The reduction process of substituted Ba-ferrite has been found to be devided into three steps. At the first and second steps, the magneto-plumbite structure maintained. When the reduced-substituted Ba-ferrite particles are reoxidized, the coercivity is reversible at the first step but irreversible at the second step. During the third step of reduction process above 410 $^{\circ}C$. The magneto plumbite structure was collapsed with formation of $\alpha$-Fe and $BaFeO_{3-x}$ phases and consequently the coercivity distribution is broaden and the coercivity irreversible. The coercivity and saturation magnetization decreases and increases up to 130 emu/g respectively. In this study, it is found that the substituted elements prevent the magneto-plumbite structure from collapse during the reduction process and furthermore migrate from the magnetic sites of $2a+4f_{IV}$, 2b, and 12k to $4f_{VI}$ and 12k'. An increase in the coercivity before the collapse of magneto-plumbite structure is attributed to the migration of cations in hexagonal Ba-ferrite structure.

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