• Title/Summary/Keyword: 입자크기분포

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Characteristics of domestic coals and efficient control of coal dust (국내 석탄광 분진의 특성과 효율적 제어)

  • Kim, Soo Hong;Kwon, Jun Wook;Kim, Sun Myung;Kim, Yun kwang;Jang, Yun Ho
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.19 no.4
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    • pp.589-609
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    • 2017
  • This study carried out the density and energy dispersive X-ray spectroscopy and particle size analysis which are the physical characteristics of coal dust by collecting samples of coal dust in the five domestic mines to control the coal dust through ventilation in the workplace for coal mining in the country. This will contribute to a more comfortable working environment by understanding the physical characteristics of the coal dust which is derived from any hard coal produced domestically. In particular, the result of PSA analysis showed that the size of coal dust sample for this study ranged from $0.007{\sim}88.614{\mu}m$ were the particles less than $3.5{\mu}m$, the size range responsible for pneumoconiosis. To observe the flow of coal dust collected on the wind speed, the fallout of coal dust produced by the wind tunnel for the wind was measured and the particle size analysis of coal dust fallout was carried out. In addition, airborne dust is measured according to the mine velocity by using a multi-stage Anderson sampler in the mine where fine dust is generated in a large amount and the wind speed is found out to control the coal dust below $3.5{\mu}m$. In addition, natural ventilation pressure of A mine was calculated to prevent over design of the main fan.

Emulsion Polymerization of Vinyl acetate-Butyl acrylate Copolymer (유화 중합에 의한 비닐 아세테이트-부틸 아크릴레이트 공중합체의 합성 연구)

  • 설수덕;임종민
    • Polymer(Korea)
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    • v.28 no.2
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    • pp.135-142
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    • 2004
  • Poly(vinyl acetate) (PVAc) prepared by emulsion polymerization has broad applications for additives such as paint binder, adhesive for wood and paper due to its low glass transition temperature which help to plasticize substrate resins. Since emulsion polymerization has a disadvantage that surfactant and ionic initiator degrade properties of the product polymer, poly(vinyl acetate-co-butyl acrylate) (VVc-BA) was synthesized using potassium persulfate as catalyst and poly(vinyl alcohol) (PVA) as protective colloid to prevent the degradation. The copolymer latex product was internally plasticized and has enhanced colloid stability, adhesion, tensile strength and elongation. During VAc-BA emulsion polymerization, no coagulation and complete conversion occur with the reactant mixture of 0.7wt% potassium persulfate, 15wt% poly(vinyl alcohol) (PVA-217), and the balanced monomer that the weight ratio of vinyl acetate to butyl acrylate is 19. As the concentrations of PVA increase, the copolymerization becomes faster and polymer particles are more stable, resulting in enhanced mechanical stability of the VAc-BA copolymer. However, the size of the polymer particles decreases with increasing PVA contents. Properties of the VAc-BA copolymer, such as minimum film formation temperature, glass transition temperature, surface morphology, molecular weight and molecular weight distribution, tensile strength and elongation, were characterized using differential scanning calorimeter, transmission electron microscope and other instruments.

Polymerization of Ethylene over $Cp_2ZrCl_2$ Catalyst Supported on Montmorillonite (Montmorillonite에 담지된 $Cp_2ZrCl_2$ 촉매를 이용한 에틸렌 중합특성 연구)

  • Ahn, Sung-Hyun;Lee, Sung-Ho;Choi, Moo-Seok;Im, Jun-Seop;Sheikh, Rizwan;Cho, Deug-Hee;Park, Yeung-Ho
    • Applied Chemistry for Engineering
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    • v.24 no.1
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    • pp.55-61
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    • 2013
  • Heterogeneous metallocene catalysts supported on montmorillonite (MMT), [$Cp_2ZrCl_2$/MMT, $Cp_2ZrCl_2$/MAO/MMT, and $Cp_2ZrCl_2$ + MAO/MMT], were prepared with three different methods of immobilization and tested for ethylene polymerization. The heterogeneous catalysts immobilized on organo clay (30B-MMT) showed the higher metal loading and polymerization activity than those immobilized on natural clay $Na^+-MMT$. These results suggest that the hydroxyl groups of organo clay interlayers react with the MAO and catalyst through the chemical bond. The metallocene catalyst supported directly on MMT showed lower activity for ethylene polymerization compared to the homogeneous systems, while MMT/MAO/$Cp_2ZrCl_2$, catalysts treated with MAO before impregnation, showed a higher activity. The polymers obtained from MMT-supported catalysts have higher melting point, molecular weight and molecular weight distributions than those of homogeneous catalysts. The polymer particles with increasing significant size. Ethylene polymerization over 30B-MMT/MAO/$Cp_2ZrCl_2$ catalyst was also performed varying the process variables to optimize the process conditions.

온라인 협동조합의 공생마케팅 전략-웹기반 사진앨범협동조합 (주)와이드스쿨 사례-

  • 김창호
    • Distribution Business Review
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    • no.3
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    • pp.155-170
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    • 2003
  • 본 연구는 기본적으로 온라인과 오프라인의 통합마케팅을 절명하고 이에 관한 경험적 사례를 개발하기 위한 목적으로 진행되었다. 앨범서비스 영역의 공생적 기반 위에 전개되는 온 -오프라인의 경험적 사례를 개발하고 바람직한 마케팅방향 방향을 제시하였다. 본 연구는 문헌연구와 사례연구를 병행하여 연구를 진행하였다. 사례는 인터넷 기반의 앨범서비스를 제공하기 위한 (주)와이드스쿨이다. 온-오프라인의 협력적 통합마케팅의 전략을 전개하기 위해서는 무엇보다도 온 -오프라인의 뚜렷한 목표를 절정하고 성장방향에 대한 비전을 공유하고 나아가 온 -오프라인의 사명을 감당하는 것이다. 즉, 실천적으로는 \circled1 항상 고객 (customer)기반의 의사결정을 이루며 \circled2 철저한 협력적 돕는 경쟁(competition) 의식과 \circled3 구성원 자신의 일에 대한 자신감(confidence)을 지니고 \circled4 실천을 위한 용기(courage)를 가지고 \circled4 혁신하여 변화(change)를 선도하는 것이다. 온라인(on line)으로 표현되는 인터넷환경은 모든 영역에 변화를 요구하고 있다. 온라인에 관한 연구는 크게 온라인시장의 경쟁(competition)에 관한 연구와, 온라인 소비자(consumer)에 관한 연구 그리고 온라인 시장 참가기업(company)에 관한 연구로 구분된다(이석규 ; 2001). 이중 기업에 관한 연구의 중심에는 e-biz의 수익모텔에 관한 연구가 주류를 이루고 았다(David et al, 1999) 특히 오프라인기업의 경우 어떠한 형태방법으로 온라인 환경에 부응하며 기존의 마케팅활동과 연계할 것인가는 매우 중요한 문제다. 즉 기존의 오프라인기업이 온라인도구변화에 적응하고 이를 전략적으로 활용하기 위해서는 무엇보다도 오프라인과 온라인의 통합에 관한 형태와 전략 등을 명확히 이해하고 적용하는 것이 중요하다. 개수가 감소하는 것과는 상당히 다른 분포이다. 따라서 우리의 관측 결과는 2001년 사자자리 유성우의 극대 시간 전후 2시간에 적어도 0등급 이하의 밝은 유성이 상대적으로 많이 발생하였을 것으로 해석된다. 이런 밝은 유성의 빈도는 유성우 특성 연구에 중요한 의미를 가진다. 그러나 표준성만을 이용해 결정된 유성 등급은 유성의 지속 시간에 대한 불확실성과 전천 카메라 감응도의 비선형성에 의한 불확실성을 내포하고 있음을 지적해 둔다.umn chromatography)를 사용하였고 일련의 정제 과정을 통하여 배양액 중의 L-lactic acid 정제 수율은 약 85% 정도로 나타났으며 HPLC로 분석한 결과 99.7%의 순도를 확인할 수 있었다.경향을 나타내며 유입휫수와 $Dst_{min}$ 사이에는 높은 상관관계(0.83)가 있었다. 둘째, 주상기간 중 자기폭풍의 크기가 클수록 플럭스 비 ($f_{max}/f_{ave}$는 대체로 증가하는 경향을 나타냈다. 그리고 75~113keV 에너지 채널에서의 $Dst_{min}$ 값과 플럭스 비의 상관계수는 0.74로서 가장 높았으며 나머지 에너지 채널 역시 비교적 높은 상관관계를 나타냈다. 셋째, 주상기간 중 총 에너지 유입률 지수와 $Dst_{min}$ 사이에 높은 상관관계가 확인되었다. 특히 환전류를 구성하는 주요 입자의 에너지 영역(75~l13keV)에서 가장 높은(0.80) 상관계수를 기록했다. 넷째, 회복기 중에 일어나는 입자들의 유입은 자기폭풍의 지속시간을 연장시키는 경향을 보이며 큰 자기폭풍일수록 현저했다. 주상에서 관측된 이러한 특성은 서브스톰 확장기 활동이 자기폭풍의 발달과 밀접한 관계가 있음을 시사한다.se that were all low in two aspects, named "the Nonsignificant group".

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Effect of Cross-flow Velocity and TMP on Membrane Fouling in Thermophilic Anaerobic Membrane Bioreactor Treating Food Waste Leachate (음식물 침출수를 처리하는 막결합 고온혐기성 소화시스템에서 교차여과와 막간압력이 파울링에 미치는 영향)

  • Kim, Young-O;Jun, Duk-Woo;Yoon, Seong-Kyu;Chang, Chung-Hee;Bae, Jae-Ho;Yoo, Kwan-Sun;Kim, Jeong-Hwan
    • Membrane Journal
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    • v.21 no.4
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    • pp.360-366
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    • 2011
  • The effect of cross-flow velocity and transmembrane pressure (TMP) on membrane fouling was observed from pilot-scale operation of thermophilic anaerobic membrane bioreactor (AnMBR) treating food waste leachate. It was found that fouling rate was reduced significantly as cross-flow velocity increased at constant TMP mode of operation while this effectiveness was more pronounced at lower TMP. Higher TMP resulted in less permeable fouling layer possibly due to compressibility of foulant material on membrane surface. Particle sizes of membrane concentrate ranged from 10 to $100{\mu}m$, implying that shear-induced diffusion enhance back transport of these particle sizes away from the membrane effectively. From the continuous operation of AnMBR, it was confirmed that shear rate played an important role in the reduction of membrane fouling. Membrane autopsy works at the end of operation of AnMBR showed clearly that both organic and inorganic fouling were significant on membrane surface. Surface shear by cross-flow velocity was expected to be less effective to remove irreversible fouling which can be mainly caused by the adsorption of organic colloidal materials into membrane pores.

Characterization of Heavy Metals Including Mercury and Fine Particulate Emitted from a Circulating Fluidized Bed Power Plant Firing Anthracite Coals (무연탄 순환유동층 발전소로부터 배출되는 수은을 포함한 중금속 및 미세분진의 배출 특성)

  • Kim, Jeong-Hun;Yoo, Jong-Ik;Seo, Yong-Chil
    • Korean Chemical Engineering Research
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    • v.48 no.2
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    • pp.268-274
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    • 2010
  • Emission of heavy metals as hazardous air pollutants has been focused with tightening regulatory limits due to their hazardousness. Measurements and characteristic investigations of heavy metals emitted from a commercial power plant burning anthracite coal have been carried out. The plant consists of a circulating fluidized bed combustor, a cyclone, a boiler and an electrostatic precipitator(ESP) in series. Dust and gaseous samples were collected to measure main heavy metals including gaseous mercury before ESP and at stack. Dust emissions as total particulate matter (TPM), PM-10 and PM-2.5 at inlet of ESP were very high with 23,274, 9,555 and $7,790mg/Sm^3$, respectively, as expected, which is much higher than those from pulverized coal power plants. However TPM at stack was less than $0.16mg/Sm^3$, due to high dust removal efficiency by ESP. Similarly heavy metals emission showed high collection efficiency across ESP. From particle size distribution and metal enrichment in sizes, several metal concentrations could be correlated with particle size showing more enrichment in smaller particles. Mercury unlike other solid metals behaved differently by emitting as gaseous state due to high volatility. Removal of mercury was quite less than other metals due to it's volatility, which was 68% only. Across ESP, speciation change of mercury from elemental to oxidized was clearly shown so that elemental mercury was half of total mercury at stack unlike other coal power plants which equipped wet a scrubber.

Characteristics of Shear Strength and Consolidation Behavior of Soft Ground according to Stage Fill (단계성토에 따른 연약지반의 전단강도 및 압밀거동 특성)

  • Bang, Seongtaek
    • Journal of the Korean GEO-environmental Society
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    • v.21 no.7
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    • pp.17-26
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    • 2020
  • The soft ground in the southwest coastal area composed of marine clay is greatly influenced by sediment composition, particle size distribution, particle shape, adsorption ions and pore water characteristics, tide and temperature. In addition, the geotechnical properties are very complex due to stress history, change in pore water, dissolution process and gas formation. In this study, the physical and mechanical properties of the soft ground were evaluated through field tests and laboratory tests to investigate the strength increase characteristics according to consolidation on the soft ground in the southwest coast. In addition, in order to understand the consolidation behavior of soft ground such as subsidence, pore water pressure, horizontal displacement of soil by embankment load, measuring instruments such as pore water pressuremeter, settlement gauge, inclinometer and differential settlement gauge was installed, and a piezocon penetration test was carried out step by step to confirm the increase in shear strength of the ground. Through this, it was confirmed that the shear strength of the ground is increased according to the stages of filling. In addition, by evaluating the properties of consolidation behavior, strength increase and consolidation prediction by empirical methods and theories were compared to analyze the characteristics of strength increase rate and consolidation behavior in consideration of regional characteristics.

Manufacturing Techniques and Provenance of Earthen Wares in Daecheonri Prehistory Site of Okcheon County, Korea (옥천 대천리 유적지 토기의 제작기법 및 원료산지 분석)

  • Lee, Hyo-Min;Yang, Dong-Yun;Gu, Ja-Jin;Kim, Ju-Yong;Han, Chang-Gyun;Choe, Seok-Won
    • The Korean Journal of Quaternary Research
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    • v.18 no.1 s.22
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    • pp.1-20
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    • 2004
  • A geoscientific research was performed on 12 samples of comb-pattern potteries which were excavated at Daecheonri neolithic site, Korea. The texture and compositions of 12 potteries and surrounding metrix of soil and rocks were compared with the help of petrographic microscope, XRD and REE data. As to the manufacturing techniques thick potteries are caused by the amount and number of coarse grains which are assumed to be added shards when their distributional pattern are considered. DC1, DC3, DC 7 and DC11 samples have clearly oriented textures, and the orientation of vesicles in DC3 and DC11 samples arranged in the same direction with those on the pottery surface. This indicates the use potter's wheel technique in manufacturing potteries. Burning temperature is assumed over $800^{/circ}C$, particularly under reduction environment. As to the source, raw materials of pottery matrix are derived from the bottom of excavation site, or in an extracted outcrop of the northwestern foothill from site, while the shard materials are very similar with those extracted from sandy loams near sites. Finally any use pattern of pottery may control the pottery thickness, shard addition, and matrix selection.

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Preliminary Research of the Sedimentary Environment in Bupyeng Reservoir Region, Soyang Lake in Chuncheon - Focus on Sentinel-2 Satellite Images and in-situ data - (춘천시 소양호 상류 부평지구의 퇴적환경에 대한 선행연구 - 현장조사와 위성영상자료를 중심으로 -)

  • Kim, GeonYoung;Kim, Dain;Kim, TaeHun;Lee, JinHo;Jang, YoSep;Choi, HyunJin;Shim, WonJae;Park, SungJae;Lee, Chang-Wook
    • Korean Journal of Remote Sensing
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    • v.34 no.6_1
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    • pp.1119-1130
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    • 2018
  • Soyang Lake has been contributing to economic growth by preventing flood damage in the metropolitan area, the water level in the middle to upper flow of lake has been greatly decreased due to the drought in 2015. In order to restore the existing flow rate, Bupyungbo has been built in Bupyeong-ri, Shin Nam-myeon, Inje-gun to cause artificial changes on the sedimentary environment of Bupyeong freshwater region. Therefore, this study intends to confirm the changes of sedimentary environment since Bupyeongbo has been utilized. For this study, we used the Sentinel-2 satellite image data periodically to measure the dimension of water according to the volume of water kept near Bupyung district and analyzed the particle size and the percentage of water content of the sediments through field study. The Sentnel-2 satellite images showed us how the water surface has been changed and that during the period from September 2017 to October 2018, the minimum and maximum area of water surface was observed in June 2018 and in January 2018, respectively. In addition, we find that the smaller being the particle size, the higher having the water content and that there is higher the correlation between the water content and the grain size of the sediment layer. Hereafter, if we will acquire the drone images at Bupyung district, we expect that we will be able to measure the distribution of sediments in the same area according to different time periods and observe various kinds of sediment through field work.

Evaluation of Water Quality Change by Membrane Damage to Pretreatment Process on SDI in Wastewater Reuse (하수재이용에서 전처리 막 손상에 의한 수질변화가 SDI에 미치는 영향평가)

  • Lee, Min Soo;Seo, Dongjoo;Lee, Yong-Soo;Chung, Kun Yong
    • Membrane Journal
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    • v.32 no.4
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    • pp.253-263
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    • 2022
  • This study suggests a guideline for designing unit process of wastewater reuse in terms of a maintenance of the process based on critical parameters to draw a high quality performance of RO unit. Defining the parameters was done by applying membrane integrity test (MIT) in pretreatment process utilizing lab-scale MF. SDI is utilized for judging whether permeate is suitable to RO unit. However, result said TOC concentration matching with particle count analysis is better for judging the permeate condition. When membrane test pressure (Ptest) was measured to derive log removal value in PDT, virgin state of membrane fiber was used to measure dynamic contact angle utilizing surface tension of the membrane fiber. Actually, foulant affects to the state of membrane surface, and it decreases the Ptest value along with time elapsed. Consequently, LRVDIT is also affected by Ptest value. Thus, sensitivity of direct integrity test descends with result of Ptest value change, so Ptest value should be considered not the virgin state of the membrane but its current state. Overall, this study focuses on defining design parameters suitable to MF pretreatment for RO process in wastewater reuse by assessing its impact. Therefore, utilities can acknowledge that the membrane surface condition must be considered when users conduct the direct integrity test so that Ptest and other relative parameter used to calculate LRVDIT are adequately measured.