• Title/Summary/Keyword: 인화점

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A Study on Fire and Explosion Accident Cause in Regenerated Thermal Oxidizer (축열식 소각로의 화재.폭발 사고원인 규명 연구)

  • Lee, Keun-Won;Ma, Byung-Chol;Hwang, Soon-Yong
    • Journal of the Korean Institute of Gas
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    • v.11 no.4
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    • pp.7-11
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    • 2007
  • There has been a report of fire and explosion accident in regenerated thermal oxidizer (RTO). This paper was to investigate accident causes of RTO in the resin re-treatment process. The experiments carried out physicochemical properties and thermal stability analyses by using flash point tester, flammable range apparatus, autoignition tester, GC/MSD and thermal screening unit. We inferred causes of fire and explosion from the regenerated thermal oxidizer to prevent an accident of its process.

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IMO 참석결과보고 - IMO 제17차 산적액체 및 가스전문위원회(BLG)

  • 선박안전기술공단
    • Journal of Korea Ship Safrty Technology Authority
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    • s.35
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    • pp.74-83
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    • 2013
  • ${\circ}$ 평형수 샘플링 및 분석지침의 시범기간 동안 지침의 표준화를 위해 개별기술에 대한 검증이 진행될 것이므로, 지침에 포함된 기술 및 국내 개발기술들의 검증을 위한 국내 연구 필요 ${\circ}$ 평형수장치의 운전 제한사항 검증 및 정보제공 등이 추가 요구되어 개정된 잠정기준에 따라 추가의 검증시험의 신속한 진행 필요 ${\circ}$ 선박 생물부착의 통제 및 관리를 위한 지침서 유효성 평가를 위한 성과측정의 정보 수집용 설문이 GISIS를 통해 이루어질 예정이므로, 정부 및 관련 산업단체에서 해당 설문에 참여하도록 협조 필요 ${\circ}$ 향후 가스 및 저인화점 연료를 사용하는 선박의 안전기준(IGF Code)이 아국 조선소에서 설계된 가스연료를 사용하는 선박에 적합하게 개발되도록 업계의 적극적인 참여 및 지원 필요

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Flash Points of Water+n-Propanol System Using Closed-Cup Measurement Apparatus (밀폐계 측정장치를 이용한 물-노말프로판올 계의 인화점)

  • Ha, Dong-Myeong;Choi, Yong-Chan;Lee, Sung-Jin
    • Journal of the Korean Society of Safety
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    • v.17 no.4
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    • pp.140-145
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    • 2002
  • The Flash Point is one of the most important combustible properties used to determine the potential for fire and explosion hazards of chemical materials. An accurate knowledge of the flash point is important in developing appropriate preventive and control measures in industrial fire protection. The lower flash points for the Water + n-Propanol systems were measured by using Pensky-Martens closed cup tester. The experimental data were compared with the values calculated by the laws of Raoult and van laar equation. The calculated values based on the van Laar equation were found to be better than those based on the Raoult's law.

A Study on the Flash Point Determination of Toluene-o-Xylene and Toluene-Methyl Ethyl Ketone Mixtures by Air-Blowing Method (유통법을 사용한 톨루엔과 o-크실렌 및 톨루엔과 메틸에틸케톤 혼합용제의 인화점 측정에 관한 연구)

  • 신열우;목연수;최일곤
    • Journal of the Korean Society of Safety
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    • v.10 no.2
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    • pp.92-96
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    • 1995
  • The flash point is generally used as a hazardous index of fire or explosion of a flammable liquid. In this study, the lower flash points and the upper flash points according to the composition of Toluene-o-Xylene and Toluene-Methyl Ethyl Ketone mixtures are determined by air-blowing method. As results, relations between the flash points and the compositions of mixtures ; (1) for Toluene-o-Xylene mixtures $T_{fL}$=25.23 $\alpha$ +5.34 $T_{fu}$=27.36 $\alpha$ +40.50 (2) for Toluene-Methyl Ethyl Keton mixtures $T_{fL}$=10.00 $\beta$-5.00 $T_{fu}$=16.91 $\beta$+20.45.

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Prediction of Upper Explosion Limits(UEL) by Measurement of Upper Flash Point Using Setaflash Apparatus for n-Alcohols (Setaflash 장치를 이용한 노말 알코올류의 상부인화점 측정에 의한 폭발상한계의 예측)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.25 no.2
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    • pp.35-40
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    • 2010
  • Explosion limit and flash point are the major combustion properties used to determine the fire and explosion hazards of the flammable substances. In this study, in order to predict upper explosion limits(UEL), the upper flash point of n-alcohols were measured under the VLE(vapor-liquid equilibrium) state by using Setaflash closed cup tester(ASTM D3278). The UELs calculated by Antoine equation using the experimental upper flash point are usually lower than the several reported UELs. From the given results, using the proposed experimental and predicted method, it is possible to research the upper explosion limits of the other flammable substances.

The Measurement of Lower Flash Points For Binary Mixtures (이성분계 혼합물의 하부인화점 측정)

  • Ha, Dong-Myeong;Lee, Sungjin
    • Journal of the Korean Society of Safety
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    • v.28 no.1
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    • pp.35-39
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    • 2013
  • The flash point is an important indicator of the flammability of a chemical. In this study, the flash points for the n-propanol+n-butanol and n-propanol+acetic acid systems were measured by Tag open-cup apparatus. The experimental data were compared with the values calculated by the Raoult's law and optimization method based on van Laar and UNIQUAC equations. The calculated values by optimization method were found to be better than those based on the Raoult's law.

Flash Point of p-xylene and Epoxy Resins Mixtures (파라크실렌과 에폭시수지 혼합물의 인화점에 관한 연구)

  • 윤희승;강민호;하동명;정국삼
    • Journal of the Korean Society of Safety
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    • v.15 no.3
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    • pp.78-82
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    • 2000
  • The flash point is an important property and hazardous index of a flammable liquid. The flash points are used by virtually all the environmental, health, and safety organizations in both government and industry to classify flammable liquids for safety and transportation regulations. The basics of all flash points behavior are concerned with the vapor pressure and explosive limits. The flash points of pure components and the mixture of solvents can be calculated with the use of the laws of Raoult, Dalton and Le Chatelier. In this paper, experimentally determined lower flash points of a p-xylene and epoxy resin system were compared with the calculated values by using Raoults law. Calculated lower flash points were in reasonable agreement with the observed values.

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Prediction of Upper Explosion Limits(UEL) by Measurement of Upper Flash Points for n-Alkanes and Aromatic Compounds (노말알칸류와 방향족탄화수소류의 상부인화점 측정에 의한 폭발상한계의 예측)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.26 no.4
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    • pp.59-64
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    • 2011
  • Explosion limit and flash point are the major combustion properties used to determine the fire and explosion hazards of the flammable substances. In this study, in order to predict upper explosion limits(UELs), the upper flash point of n-alkanes and aromatic compounds were measured under the VLE(vapor-liquid equilibrium) state by using Setaflash closed cup tester(ASTM D3278). The UELs calculated by Antoine equation and chemical stoichiometric coefficient tusing the experimental upper flash point were compared with the several reported UELs. From the given results, using the proposed experimental and predicted method, it is possible to research the upper explosion limits of the other flammable substances.

The Measurement and Calculation of the Lower Flash Points using of Binary Systems Using Cleveland Open Cup Tester (클리브랜드 개방식 장치를 이용한 이성분계 하부인화점 측정 및 계산)

  • Lee, Sung-Jin;Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.23 no.5
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    • pp.67-72
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    • 2008
  • The lower flash points for the flammable binary systems, 2-propanol+formic acid and 2-propanol+n-butyric acid, were measured by Cleveland open cup tester. The optimization method using van Laar equation and the Raoult's law were used to estimate the lower flash points and were compared with experimentally-derived data. The calculated values based on the optimization method were found to be better than those based on the Raoult's law.

A Study on the Assessment of Hazardous Properties of Flammable liquids (인화성액체의 위험성평가에 관한 연구)

  • Lee, Bong-Woo;Park, Chul-Woo;Song, Haak;Kim, Hak-Jin
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2009.04a
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    • pp.276-285
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    • 2009
  • 화학물질의 분류 및 표시의 국제표준화시스템(GHS)을 조기에 구축하고 국내에 사용하는 화학물질을 보다 안전하게 제조, 저장 및 운송하기 위하여 위험물안전관리법과 GHS시험 방법으로 다양한 인화성액체 시험을 실시하여 이들의 결과에 대한 연관성을 도출하고, 국내 실정에 적합한 국제표준화 시험방법을 선택가능방식(Building Block Approach)으로 제시하고자 한다. 위험물의 80%를 차지하는 인화성액체의 분류에 필요한 시험은 인화점이 가장 중요한 요소지만, 도료류와 같은 혼합물은 가연성액체량과 GHS-연소지속성에 따라 위험물/비위험물로 분류될 수 있다. 도료류는 두 시험의 분류결과가 대부분 비슷하게 나타나 GHS-연소지속성시험을 선택가능방식을 통해 우리나라에 적합하게 도입하는 것이 바람직 할 것으로 보인다.

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