• Journal of the Korea Concrete Institute
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• v.21 no.6
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• pp.729-735
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• 2009

In this study, it is experimentally verified a feasibility of the wasted phosphogypsum ($CaSO_4/H_2O$) that is a byproduct from the phosphoric acid process of manufacturing fertilizers can be applied as an admixture in slag cement. For the test, phosphogypsum is modified as dihydrate, hemihydrate, type III anhydrite, and type II anhydrite, and then chemical characteristics and mechanical properties of various slag cements containing above mentioned gypsum materials were analyzed. The test results show that the gypsum made at high temperature has better quality with decrease of water-soluble phosphoric acid ($S-P_2O_5$) which has an effect on the quality of cement. And type II anhydrite shows superior quality in terms of drying shrinkage and the compressive strength of cement paste with hemihydrate at 56 days is higher than other gypsum material.

• Journal of the Korea institute for structural maintenance and inspection
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• v.14 no.3
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• pp.144-151
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• 2010

In this study, it is investigated the mechanical chemical properties of cement matrix using phosphogypsum and kaolin as a admixture for the substitutive materials to silica fume which is so expensive. For the test, phosphogypsum is modified as dihydrate, hemihydrate, type III anhydrite, and type II anhydrite, respectively and furnaced kaolin at $900^{\circ}C$ was also manufactured into meta kaolin by air cooling and water cooling method. The chemical characteristic and mechanical properties of various type of blended cements contained above mentioned gypsum and meta kaolin materials analyzed and compared with those characteristics of cement matrix with silica fume. From the test, the cement mixed meta kaolin made in water cooling has more excellent quality than other material.

• Journal of the Mineralogical Society of Korea
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• v.21 no.2
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• pp.193-200
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• 2008

We tried to evaporate and dry the moisture contained Flue gas desulfurization gypsum and phosphogypsum by using the microwave directly. In the result of the heating to the Flue gas desulfurization gypsum and phosphogypsum using 2.45 GHz microwave which was created by magnetron 700 W, 1,000 W and 1,700 W, respectively. According to the increasing the microwave output intensity from 700 W to 1,700 W, the evaporate time of moisture was shortened from 10 to 3 minutes. Gypsum were changed to calcium sulfate hemihydrate. However, ${\beta}$-calcium sulfate hemi-hydrate were not changed to anhydrite.

• Journal of the Korean Geotechnical Society
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• v.17 no.4
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• pp.331-339
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• 2001

인산석고(phosphogypsum)는 비료생산과정에서 발생되는 산업부산물로, 주요구성성분은 이수석고(CaSO$_4$.2$H_2O$)의 성분이 대부분이고 여기에 인(P$_2$O$_2$), 철(F)와 유기물질 등으로 이루어져 있다. 전 세계적으로 인산석고 발생량은 현재 1억8천만톤이고 향후 약 3억8천만톤 발생될 것으로 추정되며, 국내에는 약 157만톤이 발생되고 있다. 본 연구는 성토재료로 인산석고를 활용할 경우 이에 대한 물리적 환경적 특성을 분석하였다. 이를 위하여 인산석고와 화강토 혼합비율에 따른 입도분석, 비중시험, 다짐시험, CBR시험, pH시험 및 용출시험 등 일련의 실험을 실시하였다. 실험결과, 인산석고 혼합재료를 성토재료로 활용할 경우 환경적으로 유해한 영향이 적으며, 산업부산물의 자원화 차원에서 대체 성토재료로 활용이 가능한 것으로 나타났다.

• Cement Symposium
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• s.37
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• pp.111-116
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• 2010

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2001.05a
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• pp.453-456
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• 2001

• Proceedings of the Korean Nuclear Society Conference
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• 2001.05a
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• pp.424.2-424
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• 2001

• Proceedings of the Korean Nuclear Society Conference
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• 2002.10a
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• pp.361-361
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• 2002

• Proceedings of the Korea Concrete Institute Conference
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• 2010.05a
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• pp.263-264
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• 2010

In this study, respectively and furnaced kaolin at $900^{\circ}C$ was also manufactured into meta kaolin by air cooling and water cooling method. The chemical characteristic and mechanical properties of various type of blended cements contained above mentioned gypsum and meta kaolin materials analyzed and compared with those characteristics of cement matrix with silica fume. From the test, the cement mixed meta kaolin made in water cooling has more excellent quality than other material.

• Cement Symposium
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• no.32
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• pp.103-106
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• 2005

유해 중금속을 다량 함유하고 있는 산업폐기물의 고화 처리에 사용되는 칼슘설포알루미네이트(4CaO$\cdot$$3Al_2O_3$$\cdot$$SO_4$이후부터 CSA로 기입) 의 제조를 위해 철강부산물인 압연 슬러지를 활용하여 그 특성에 대해 조사하였다. 본 연구에서는 철강 부산물인 압연슬러지 외에 석회석 미분물, 인산부산 석고를 혼합하여 칼슘알루미네이트상을 합성하였다. 합성 결과 소성온도 1250$^{\circ}C$에서부터 CSA가 합성되었고, 이와 함께 칼슘실리케이트 (2CaO$\cdot$$SiO_2$)와 칼슘알루미노페라이트(4CaO$\cdot$$Al_2O_3$$\cdot$$Fe_2O_3$)도 함께 합성되었다. CSA 합성에 미치는 중금속 영향을 관찰한 결과 원료의 중금속이 CSA 합성 온도를 낮추는 효과가 있는 것으로 나타났다. CSA를 이용한 철강산업 폐기물의 중금속 고용 처리 연구에서도 본 실험에서 합성된 CSA가 폐기물의 중금속 고화 처리에 효과가 있는 것으로 나타났다.