• Title/Summary/Keyword: 이트리아

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Stability of $Pr_{6}O_{11}$-Based ZnO Varistors Doped with $Y_{2}O_{3}$ under d.c. Stresses ($Y_{2}O_{3}$가 첨가된 $Pr_{6}O_{11}$계 ZnO 바리스터의 d.c. 스트레스에 따른 안정성)

  • 윤한수;류정선;남춘우
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.551-554
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    • 2000
  • The stability of $Pr_6$$O_{11}$-based ZnO varistors doped with $Y_2$$O_3$ was investigated under various d.c. stresses. The varistors were sintered at $1350^{\circ}C$ for 1h in the addition range of 0.0 to 4.0 mol% $Y_2$$O_3$. The varistors doped with $Y_2$$O_3$ exhibited much higher nonlinearity than that without $Y_2$$O_3$. In Particular, the varistors containing 0.5 mol% $Y_2$$O_3$ showed very excellent V-I characteristics, which the nonlinear exponent was 51.19 and the leakage current was 1.32 $\mu\textrm{A}$. And these varistors also showed an excellent stability, which the variation rate of the varistor voltage and the nonlinear exponent were -0.80% and -2.17%, respectively, under 4th d.c. stress, such as (0.80 $V_ {1mA}$/$90^{\circ}C$/12h)+(0.85 $V_{1mA}$/$115^{\circ}C$/12h)+(0.90 $V_{1mA}$/$120^{\circ}C$/12h)+(0.95 $V_{1mA}$/$125^{\circ}C$/12h). Consequently, since $Pr_ 6$$O_{11}$-based ZnO varistors doped with 0.5 mol% $Y_2$$O_3$ have an excellent stability as well as good nonlinearity, it is expected to be usefully used to develop the superior varistors in future.

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Transformability and Phase Transformation Behaviors of Metastable Tetragonal Phase in 2Y-TZP Powder. (2Y-TZP 분말내 준안정 정방정상 입자의 전이도 및 상전이거동)

  • Kim, Hwan;Lee, Jong-Kook
    • Korean Journal of Materials Research
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    • v.2 no.5
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    • pp.320-329
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    • 1992
  • In 2Y-TZP powders calcined at temperature range of 80$0^{\circ}C$0 to 150$0^{\circ}C$, the effect of stabilization and the transformability of tetragonal phase on the tetragonal to monoclinic transformation have been investigated. The transformability of tetragonal phase in calcined powders shows maximum at the calcination temperature of 130$0^{\circ}C$. This result is explained by a combined effect of the increase of particle size and of constrained force among the particles with increasing the calcination temperature. The amount of transformed monoclinic phase with calcination temperature after quenching in liquid nitrogen, stress induction and isothermal aging at 25$0^{\circ}C$is also explained by the transformability of tetragonal phase determined by the sum of particle size effect and constraint effect.

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Analysis of Attrition Rate of 50μm Size Y2O3 Stabilized Zirconia Beads with Different Microstructure and Test Conditions (50μm급 이트리아 안정화 지르코니아 비드의 미세구조 및 마모 조건에 따른 마모율 분석)

  • Kim, Jung-Hwan;Yoon, Sae-Jung;Hahn, Byung-Dong;Ahn, Cheol-Woo;Yoon, Woon-Ha;Choi, Jong-Jin
    • Korean Journal of Materials Research
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    • v.29 no.4
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    • pp.233-240
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    • 2019
  • This study analyzes the mechanical properties, including the attrition rate, of $50{\mu}m$ size yttria-stabilized zirconia (YSZ) beads with different microstructures and high-energy milling conditions. The yttria distribution in the grain and grain-boundary of the fully sintered beads relates closely to Vickers hardness and the attrition rate of the YSZ beads. Grain size, fractured surfaces, and yttrium distribution are analyzed by electronic microscopes. For standardization and a reliable comparison of the attrition rate of zirconia beads with different conditions, Zr content in milled ceramic powder is analyzed and calculated by X-ray Fluorescence Spectrometer(XRF) instead of directly measuring the weight change of milled YSZ beads. The beads with small grain sizes sintered at lower temperature exhibit a higher Vickers hardness and lower attrition rate. The attrition rate of $50{\mu}m$ YSZ beads is measured and compared with the various materials properties of ceramic powders used for high-energy milling. The attrition rate of beads appears to be closely related to the Vickers hardness of ceramic materials used for milling, and demonstrates more than a 10 times higher attrition rate with Alumina(Hv ~1650) powder than $BaTiO_3$ powder (Hv ~315).

A Hybrid Method of Storing XML Data Using RDBMS (RDBMS를 이용한 XML 데이터의 혼합형 저장 기법)

  • Jeon, Chan-Hoon;Kang, Hyun-Chul
    • The Journal of Society for e-Business Studies
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    • v.14 no.1
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    • pp.57-79
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    • 2009
  • As the Web-based e-Business prevails, the volume of XML data on the Web is getting larger than ever. Although much research has been done on decomposing and storing XML data in RDB, which is now the most popular storage for XML, and on processing XML queries through their SQL counterparts, little attention was paid to how to alleviate the burden of storing massive volume of XML data. In this paper, we propose a hybrid method of storing XML data in RDB, whereby the unit of storage could be an XML subtree as well as an XML node. The part of XML data whose nodes were separately stored could be reformed into an XML subtree for storing when it gets rarely queried or less valuable for reference as time goes by. With this method, we designed and implemented a hybrid XML storage and query processing system, comparing it with the conventional system where an XML node is the only unit of storage. Through experiments, we compared storage efficiency and query processing performance, validating the effectiveness of our proposed system.

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Redox Characteristics of Cobalt Oxide based Oxygen Carriers for Chemical-Looping Combustion (Chemical-looping combustion을 위한 cobalt oxide계 산소운반체의 산화 환원특성)

  • Lee, J.B.;Park, C.S.;Choi, S.I.;Song, Y.W.;Yang, H.S.;Kim, Y.H.
    • Journal of Hydrogen and New Energy
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    • v.15 no.1
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    • pp.46-53
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    • 2004
  • Redox characteristics of cobalt oxide-based oxygen carriers were tested for chemical-looping combustion. Cobalt oxide was chosen as active metal oxide and $CoAl_2O_4$ was compared with YSZ(yttria-stabilized zirconia) as a binder. Cobalt oxide/$CoAl_2O_4$ was prepared by sol-gel method. Hydrogen fuel was reacted with metal oxide and then the reduced metal was successively oxidized by air. The effects of reaction temperature were measured and the regenerabilies during 10 cycles were examined by a TGA. In regenerability of cobalt oxide/YSZ and cobalt oxide/$CoAl_2O_4$, after they showed above 90% conversion in first reduction, they were stabilized in about 70-75% conversion. From reaction rate constant obtained, the activation energies of cobalt oxide/YSZ in oxidation and reduction were 51.47kJ/mol and 7.71kJ/mol respectively.

Short Aramid Fiber Reinforced Polyethylene and Epoxy Composity- I. Studies on the Curing Acceleration of Epoxy/Amine System by Differential Scanning Calorimeter (Aramid단섬유보강 고기능폴리에틸렌 및 에폭시 복합재료 제조- I.DSC에 의한 에폭시/아민계의 경화 촉진 연구)

  • Ha, Chan Sik;Lim, Seung Ha;Kim, Byung Kyu;Chin, Young Jo;Cho, Won Jei
    • Applied Chemistry for Engineering
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    • v.3 no.1
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    • pp.111-118
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    • 1992
  • The curing acceleration of epoxy/amine system was investigated by using differential scanning calorimeter(DSC), The epoxy, diglycidylether of bisphenol A (DGEBA) was cured with methylene dianiline (MDA) with or without accelerators. Two kinds of accelerators were tested for the study ; tris(dimethylaminomethyl)phenol (DMP - 30) and 3 - (3,4 - dichlorophenyl)-1, 1-dimethylurea (DIURON). Heats of reaction and glass transition temperatures ($T_g$) of the cured epoxy system were analyzed by DSC along with the estimation of activation energy by the dynamic DSC studies. It was found that DMP - 30 is more effective accelerator than DIURON which showed faster curing and lower activation energy.

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Factors Affecting Distribution and Dispersal of Pomacea canaliculata in South Korea (왕우렁이(Pomacea canaliculata)의 국내 분포와 확산 특성 및 영향 요인 분석)

  • Lee, Dae-Seong;Park, Young-Seuk
    • Korean Journal of Ecology and Environment
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    • v.53 no.2
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    • pp.185-194
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    • 2020
  • Pomacea canaliculate (channeled apple snail; CAS), which is one of the world's worst alien invasive species, is widely distributed in Korea, and raised ecological and economic problems. In this study, we surveyed the distribution and dispersal characteristics of CAS in Korea, and analyzed the effects of environmental and anthropogenic (or social) factors on their distribution and dispersal. We considered various events related to CAS such as changes of policy including promotion of agriculture using CAS and enactment of biological diversity conservation law. Our results showed that human activities strongly influenced to the distribution and dispersal of CAS in Korea. Distribution of CAS seemed to relate with environment-friendly agriculture considering environmental conditions of CAS habitats. And dispersal characteristics of CAS were significantly correlated with social factors such as cultivation area and rate of organic products, production CAS on inland fishery.

Management System of Invasive Alien Species Threating Biodiversity in Korea and Suggestions for the Improvement (국내 생물다양성 위협 외래생물의 관리제도 및 개선방향)

  • Kim, Dong Eon
    • Journal of Environmental Impact Assessment
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    • v.27 no.1
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    • pp.33-55
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    • 2018
  • It has been noted that the main cause of biodiversity loss is influx of alien species. Specifically, habitats destruction, economic loss, and human injury are increasing due to invasive alien species. There were 2,167 alien species in Korea. 21 alien species of extraterrestrials including Lycorma delicatula, Solenopsis invicta, Myocastor coypus, and Spartina alterniflora at high risk through ecological risk assessment, are designated as invasive alien species. Alert species, which may have negative impact on ecosystems when they are introduced into the country, are assigned to 127 species through the ecosystem risk evaluation. To list such alien species to prevent invasion of alien species in advance, and to minimize damage caused by imported alien species, a national level management system called the Conservation and Use of Biological deversity Act was established, but there is a lack of a systematic management system in accordance with degree of risk. There is also a risk assessment chart should be developed thatreflects ecological characteristics of each taxon and evaluation criteria in predicting the risk.

Prediction of Tensile Strength of Wet Sand (II) : Validation (습윤 모래에서 인장강도의 예측 (II) : 검증)

  • Kim, Tae-Hyung
    • Journal of the Korean Geotechnical Society
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    • v.24 no.6
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    • pp.37-44
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    • 2008
  • At low normal stress levels, tensile strength of sand characteristically varies with either saturation or suction of soil in an up-and-down manner with a peak tensile strength that can occur at any degree of saturation. A theory that accurately predicts tensile strength of wet sand was presented in the previous study. In this study, the results of uniaxial tensile, suction-saturation and direct shear tests obtained from three sands (Esperance sand from Seattle, Washington, clean sand from Perth, Australia, and Ottawa sand) are used to validate the proposed theory. The closed form expression of the proposed theory can predict well the experimental data obtained from these sands in terms of the variation patterns of tensile strength over the entire saturation regimes, the magnitude of the tensile strength, its peak value, and the corresponding degree of saturation when the peak strength occurs.

Review of Copper Trihydroxychloride, a Green Pigment Composed of Copper and Chlorine (구리와 염소 주성분 녹색 안료 코퍼 트리하이드록시클로라이드(Copper Trihydroxychloride)에 대한 고찰)

  • Oh, Joonsuk;Lee, Saerom;Hwang, Minyoung
    • Korean Journal of Heritage: History & Science
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    • v.53 no.2
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    • pp.64-87
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    • 2020
  • Copper trihydroxychloride (atacamite, botallackite, paratacamite, etc.), the first green pigment used in Mogao Grotto's mural paintings of China, has been known as "copper green", "green salt", and "salt green", etc. and has been used as an important green pigment with malachite. At first, the natural mineral atacamite was employed, but after the Five Dynasties (907~960 CE), synthetic copper trihydroxychloride was primarily used. In Chinese literature, copper green, green salt, and salt green are recorded as being made via reaction with copper powder, Gwangmyeongyeom (natural sodium chloride), and Yosa (natural ammonium chloride), and the prepared material was analyzed to be copper trihydroxychloride. Copper trihydroxychloride pigment was not found in paintings prior to the Joseon Dynasty (1392~1910 CE) in Korea. In analysis of the green pigments used in paintings and the architectural paintworks in the Joseon Dynasty, copper trihydroxychloride was also shown to have been used as an important green pigment with malachite (Seokrok). In particular, the proportion of copper trihydroxychloride use was high in Buddhist paintings, shamanic paintings, and dancheongs (decorative coloring on wooden buildings). Some of these turned out to be synthetic copper trihydroxychloride, but it is unclear whether the rest of them are synthetic or natural pigments due to a lack of analyzed data. From literature and painting analyses, the pigment name of copper trihydroxychloride in the Joseon Dynasty turns out to be Hayeob, a dark green pigment. It is believed to have first been prepared by learning from China in the early Joseon period (early 15th century) and its use continued until the late 19th century with imported Chinese pigment. Round or oval particles with a dark core of copper trihydroxychloride which were used in Chinese literature were similar to the synthetic copper trihydroxychloride pigments used in the Joseon Dynasty and Chinese paintings. Therefore, the synthetic copper trihydroxychloride pigments of Korea and China are believed to have been prepared in a similar way.