• Title/Summary/Keyword: 이차 조건화

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Optimal Design of Linear Quadratic Regulator Restrict Maximum Responses of Building Structures Subject to Stochastic Excitation (확률적 가진입력을 받는 건축구조물의 최대응답 제한을 위한 선형이차안정기의 최적설계)

  • 박지훈;황재승;민경원
    • Journal of the Earthquake Engineering Society of Korea
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    • v.5 no.6
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    • pp.37-46
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    • 2001
  • In this research, a controller design method based on optimization is proposed that can satisfy constraints on maximum responses of building structures subject to around excitation modeled by partially stochastic process. The class of controllers to be optimized is restricted to LQR. Weighting matrix on controlled outputs is used as design variable. Objective function, constraint functions and their gradients are computed by the parameterization of control gain with Riccati matrix. Full state feedback controllers designed by proposed optimization method satisfy various design objectives and their necessary maximum control forces are computed for the production of actuator. LQG controllers composed of Kalman filter and LQR designed by proposed method perform well with little deterioration. So it is possible to design output feedback controllers satisfying constraints on various maximum responses of structures.

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Analyses on the Physical and Electrochemical Properties of Al2O3 Coated LiCoO2 (리튬이차전지용 양극 활물질(LiCoC2)의 표면처리의 특성 분석 및 전기화학적 특성 고찰)

  • Chang, Youn-Han;Choi, Sei-Young
    • Journal of the Korean Electrochemical Society
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    • v.10 no.3
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    • pp.184-189
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    • 2007
  • The importance of secondary battery industry is getting excited according to the development of battery industry as a high efficiency energy supplier of electronic machine of mobile information such as mobile phone, lap-top computer, PDA. It is rasing the interest about security of safety and high efficiency of cathode material for main part of secondary lithium battery. The cathode material which has been used like $LiCoO_2,\;LiMn_2O_4,\;LiNi_xCo_yMn_zO_2,\;LiNi_xCo_yM_zO_2$ (M=Al, Zr, Mg etc.,) the most typical material is $LiCoO_2$. But it is studying the development of substitute such as efficiency amelioration of $LiCoO_2$, thetiary element, olivine element because of the capacity of $LiCoO_2$, the matter of security; especially the betterment of efficiency, security research of safety has been actively processed in domestic and overseas about surface coating treatment of active cathode which is using oxide ($M_xO_3$). This study analyses side effect of battery according to increase of surface treatment, formation of precipitation for reagent condensation, non-reagent residue of oxide ($M_xO_3$) which is remains during the surface treatment of $LiCoO_2$; conducts study of new process, the consideration of the electrochemical property to improve oxide solution of mixing rate, mixture of surface treatment, dryness, calcinations conditionetc.

다중정현파 소음제어를 위한 능동소음제어 알고리듬

  • 이승만;류차희;윤대희
    • Journal of KSNVE
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    • v.5 no.4
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    • pp.453-460
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    • 1995
  • 본 논문에서는 정현파 소음을 제어하기 위한 filtered-x LMS에 바탕을 둔 새로운 적응 알고리듬을 제안하였다. 이러한 알고리듬은 두개의 연속적인 계수조정 식으로, 제어기의 계수를 조정한다. 서로 독립인 각 주파수별로 처리하기 때문에 빠른 수렴을 얻을 수 있다. 두번째식은 이차경로로 인한 위상지연을 추정한다. 정현 파 신호 주파수보다 4배 이상 빠른 표본화 주파수를 선택하여 추정된 위상지연 추정 값은 $2{\pi}f_0$만큼 오차를 나타내며, 이 값은 $\pi$2보다 작다. 정현파 신호의 주파수를 알면 이러한 오차는 $2{\pi}f_0$를 더함으로써 제거할 수 있다. 이러한 방법은 위상지연이 $\pi$2보다 큰 경우 수렴속도를 증가시킨다는 사실을 실험을 통하 여 알 수 있다. 추정된 위상지연은 제어기 계수값을 조정하는데 필요한 필터링된 참조신호를 발생시키믄데 사용된다. 참조신호의 위상지연이 각 주파수 성분별로 수행 되기 때문에, 콘볼루션 연산이 생략되어 계산량을 줄일 수 있다. 또한 연속적으로 위상지연을 추정하기 때문에 시변 상황에 적용이 가능하다. 조정식의 수렴조건을 유도하였다. 제안된 알고리듬은 제어기 계수를 추정하는데 바이어스가 없으며, 위상 지연추정을 위한 수렴상수의 최대허용치는 제어기계수에 대한 수렴상수에 반비례함을 이론적으로 분석을 통해 알 수 있다. 모의실험을 통하여 제안된 알고리듬이 filtered-x LMS 알고리듬에 바탕을 둔 다른 알고리듬보다 환경변화에 우수한 성능을 보임을 알 수 있다.

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식품 및 사료에서 발생하는 곰팡이독소의 독성 및 대사

  • Lee, Hui-Gwon;Hwang, Yeong-Hui;Kim, Min-Jeong;Kim, Mu-Gi;Lee, Seong-Eun;Lee, Hoe-Seon
    • Applied Biological Chemistry
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    • v.45 no.1
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    • pp.1-10
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    • 2002
  • 식품과 사료에서 곰팡이독소 오염은 세계적으로 중요한 문제이다. 곰팡이독소는 곰팡이의 이차대사산물로서 인축중독증을 야기하며 경제적인 손실을 초래한다. Aflatoxin, ergot alkaloid, fumonisin, ochratoxin, tremorgenic toxin, trichothecene 및 zearalenone 등이 식품과 사료에서 흘러 발생하는 곰팡이독소이다. 어떤 곰팡이는 하나 이상의 곰팡이독소를 생산하고, 또 어떤 곰팡이독소는 여러 종의 곰팡이에서 생성되기 때문에 여러 곰팡이독소가 함께 발견된다. 곰팡이독소의 발생에 영향을 끼치는 요인으로는 인위적으로 조절할 수 있는 보관과 환경적 조건도 포함된다. 기후와 같은 비본질적인 요인, 진균류의 계통 특이성 및 계통 변이와 같은 본질적인 요인 및 독소발생의 불안정성은 조절하기 어렵다. 곰팡이독소는 한 종의 동물에 있어서의 감수성과 종에 의존하며 인간에게 갖가지의 만성적 또는 급성적인 영향을 미친다. 그러나 반추동물은 곰팡이독소에 저항력을 가지고 있으며, 이는 반추동물의 위에 존재하는 미생물들이 곰팡이독소의 활성을 억제할 수 있기 때문이다. 곰팡이독소 피해의 경제적인 파급효과는 인축의 수명 단축, 축산물 생산감소, 오염된 식량과 사료의 처리 및 곰팡이독소의 문제점 해결을 위한 연구비용 등을 포함한다. 곰팡이독소 피해감소를 위한 국제적인 노력이 계속 진행되고 있지만 최근에 World Trade Organization이 발효되면서 동 식물이 지역간 자유로운 이동으로 곰팡이독소 피해 경감대책뿐만 아니라 피해측정이 어려워지고 있다.

Transformation of Long Waves Propagating over Trench (트렌치 위를 통과하는 장파의 변형)

  • Jung, Tae-Hwa;Suh, Kyung-Duck;Cho, Yong-Sik;Park, Sung-Hyun
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.19 no.3
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    • pp.228-236
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    • 2007
  • An analytical solution for long waves propagating over an asymmetric trench is derived. The water depth inside the trench varies in proportion to a power of distance from the center of the trench. The mild-slope equation, governing equation, is transformed into second order ordinary differential equation with variable coefficients by using the long wave assumption and then the analytical solution is obtained by using the power series technique. The analytical solution is confirmed by comparison with the numerical solution. After calculating the analytical solution under various conditions, the results are analyzed.

Reversed-Phase Ion-Interaction Chromatography of Aromatic Sulfonic and Carboxylic Acids (방향족 슬폰산 및 카르복시산의 역상 이온-상호작용 크로마토그래피)

  • Kang Sam-Woo;Oh Hae-Beom;Lee Seung-Seok
    • Journal of the Korean Chemical Society
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    • v.32 no.2
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    • pp.113-121
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    • 1988
  • The retention mechanism and separation of various aromatic sulfonic and carboxylic acids on reversed-phase liquid chromatographic column were studied in the mobile phase containing dodecyltrimethylammonium bromide (DTAB). The retention mechanism was found to be followed the ion-interaction model where the DTAB occupies a primary layer at the stationary phase while the sample anions and other co-anions in the system compete for forming the secondary layer. The capacity factors of samples were influenced by the several factors such as pH, concentration of various organic solvents, co-anions in the mobile phase and functional groups in sample molecules. Some mixtures of organic samples were attempted to separate under optimum condition.

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Design of Cylindrical Magnetic Gradient field for NMR-CT (NMR-CT에서 원통좌표계를 구현하는 경사자계의 고안)

  • 이대행;이순칠
    • Journal of the Korean Magnetics Society
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    • v.2 no.2
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    • pp.132-139
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    • 1992
  • We have designed a magnetic field gradient useful for cylindrical imaging in NMR-CT. The direc¬tion of the designed field is parallel to the axis and the gradient in the radial direction of cylindrical coordinate is monotonically increasing. The ratio of the gradient in the radial and axial direction is greater than 10 near the center of coordinate. This ratio depends on solenoid length, the number of reverse current turns at center, and the amount of the reverse current. We built a gradient coil based on the numerical simulation and tested the field generated by NMR-CT. The resulting image matches with the theoretical expectation within 10% error. Since the data acquisition time of 1-D imaging is significantly shorter than 2-D imaging, it becomes possible to image much more dynamic objects by the use of this gradient field.

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Charge/discharge Capacity of Natural Graphite Anode According to the Charge/discharge Rate in Lithium Secondary Batteries (리튬 이차전지의 음극재료인 천연흑연의 충방전 속도에 따른 충방전 용량)

  • Ryu Ji Heon;Oh Eun Young;Oh Seung M.
    • Journal of the Korean Electrochemical Society
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    • v.7 no.1
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    • pp.32-37
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    • 2004
  • The charge/discharge capacity of natural graphite anode in lithium secondary batteries was examined as a function of charge/discharge rate. When the natural graphite anode was galvanostatically cycled in the range of 0.0-2.0V $(vs.\;Li/Li^+)$, the charging capacity decreased with an increase in the charging rate, which is caused by an earlier approach to the charging cut-off (0.0 V) before the complete charging that is in turn caused by an ever-increasing overpotential at higher rates. Even if the overpotential of discharging reaction also increased at higher discharge rates, the discharging reaction took place in the range of 0.0-0.3 V that is far below the discharge cut-off (2.0 V). As a result, the discharge capacity was not affected by the discharge rate because all the lithium ions once intercalated are fully discharged even at high current condition. As the overpotential of lithium deposition reaction also increased at high current condition, the charge capacity of natural graphite could be enlarged by lowering the charging cut-off voltage below 0.0 V, There is, however, a limitation for the lowering of cut-off voltage because the resistance for lithium deposition is smaller than that of lithium intercalation into graphite. When the charge cut-off voltage was lowered down to -0.04 V under IC condition, lithium ions were inserted into graphite without lithium deposition such that the discharge capacity could be raised up to $11\%$.

High-purity Lithium Carbonate Manufacturing Technology from the Secondary Battery Recycling Waste using D2EHPA + TBP Solvent (이차전지 폐액으로부터 D2EHPA + TBP solvent를 활용한 탄산리튬 제조기술)

  • Dipak Sen;Hee-Yul Yang;Se-Chul Hong
    • Resources Recycling
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    • v.32 no.1
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    • pp.21-32
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    • 2023
  • Because the application of lithium has gradually increased for the production of lithium ion batteries (LIBs), more research studies about recycling using solvent extraction (SX) should focus on Li+ recovery from the waste solution obtained after the removal of the valuable metals nickel, cobalt and manganese (NCM). The raffinate obtained after the removal of NCM metal contains lithium ions and other impurities such as Na ions. In this study, we optimized a selective SX system using di-(2-ethylhexyl) phosphoric acid (D2EHPA) as the extractant and tri-n-butyl phosphate (TBP) as a modifier in kerosene for the recovery of lithium from a waste solution containing lithium and a high concentration of sodium (Li+ = 0.5 ~ 1 wt%, Na+ = 3 ~6.5 wt%). The extraction of lithium was tested in different solvent compositions and the most effective extraction occurred in the solution composed of 20% D2EHPA + 20% TBP + and 60% kerosene. In this SX system with added NaOH for saponification, more than 95% lithium was selectively extracted in four extraction steps using an organic to aqueous ratio of 5:1 and an equilibrium pH of 4 ~ 4.5. Additionally, most of the Na+ (92% by weight) remained in the raffinate. The extracted lithium is stripped using 8 wt% HCl to yield pure lithium chloride with negligible Na content. The lithium chloride is subsequently treated with high purity ammonium bicarbonate to afford lithium carbonate powder. Finally the lithium carbonate is washed with an adequate amount of water to remove trace amounts of sodium resulting in highly pure lithium carbonate powder (purity > 99.2%).

How is the inner contour of objects encoded in visual working memory: evidence from holes (물체 내부 윤곽선의 시각 작업기억 표상: 구멍이 있는 물체를 중심으로)

  • Kim, Sung-Ho
    • Korean Journal of Cognitive Science
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    • v.27 no.3
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    • pp.355-376
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    • 2016
  • We used holes defined by color similarity (Experiment 1) and binocular disparity (Experiment 2) to study how the inner contour of an object (i.e., boundary of a hole in it) is encoded in visual working memory. Many studies in VWM have shown that an object's boundary properties can be integrated with its surface properties via their shared spatial location, yielding an object-based encoding benefit. However, encoding of the hole contours has rarely been tested. We presented objects (squares or circles) containing a bar under a change detection paradigm, and relevant features to be remembered were the color of objects and the orientation of bars (or holes). If the contour of a hole belongs to the surrounding object rather than to the hole itself, the object-based feature binding hypothesis predicts that the shape of it can be integrated with color of an outer object, via their shared spatial location. Thus, in the hole display, change detection performance was expected to better than in the conjunction display where orientation and color features to be remembered were assigned to different parts of a conjunction object, and comparable to that in a single bar display where both orientation and color were assigned into a single bar. However, the results revealed that performance in the hole display did not differ from that in the conjunction display. This suggests that the shape of holes is not automatically encoded together with the surface properties of the outer object via object-based feature binding, but encoded independently from the surrounding object.