• Title/Summary/Keyword: 이온 침투

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A Study on the Properties of Promoted High Durability Concrete Applied to Coastal Landfill Underground Structures (고내구성 콘크리트(PHDC)의 해안가 매립지 지하구조물의 현장적용 특성에 관한 연구)

  • Kim, Woo-Jae;Khil, Bae-Su;Kim, Do-Su;Kim, Sung-Su;Jung, Sang-Jin;Lee, Han-Seung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.153-154
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    • 2009
  • This study examined the field applicability of promoted high durability concrete (PHDC) developed for improving the chloride penetration resistance of coastal landfill underground structures. PHDC was found superior to conventional concrete containing slag in watertightness, crack resistance, and chloride penetration resistance required in coastal landfill underground structures. It was also more workable in field application, and easier to control the quality. This study investigated the strength development, crack resistance, and chloride penetration resistance of PHDC, and performed life evaluation of underground concrete structures of coastal landfill using the Life 365 program.

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An Experimental Stuty on Mass Concrete Durability & Hydration Heat Generation Characteristics according to Kinds of Cement & Form (시멘트 및 거푸집 종류에 따른 매스콘크리트의 내구성 및 수화발열특성에 관한 실험적 연구)

  • Kim, Kang-Min;Moon, Sang-Bong;Song, Yong-Soon;Kang, Suck-Hwa;Choi, Sam-Soon;Cho, Yong-Yeon
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.359-360
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    • 2009
  • This Study is performed Mock-up test accounting for height of placement to review behavior of mass concrete according to kinds of cement & form. First, we measured hydration heat and show a different hydration heat generation characteristics as compared with each other. And we measured mortar outflow, the strength of concrete core and standard specimens, concrete's ability to resist chloride ion penetration in order to durability estimation of concrete. This study was aims to improve quality of mass concrete under marine environment.

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Antimicrobial Coating Agent (항균 코팅제)

  • Ko, Jong-Sung
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.1
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    • pp.96-115
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    • 2013
  • This article describes the concept and the trend of antimicrobial coating agents, which will help to establish the direction of the research and development on antimicrobial coating agent. Antimicrobial agents are compounds that inhibit or kill microorganisms. They are classified into inorganic, metallic, low molecular weight organic, natural organic, and polymeric compounds. Antimicrobial coatings are applied to the surface of daily necessities, medical devices, industrial products, electrical appliances, fabrics, and interior building materials, etc. Conventional antibiotics penetrate microbes without damaging bacterial cell walls, leading to drug resistance which polymeric antimicrobials can prevent by disrupting cell walls. Most polymeric antimicrobials are focused on cationic polymers. Improvement in the selectivity and durability of antimicrobials and reduction of their toxicity will come true by more reasonable design of molecular structures and their combination in coating system.

An Evaluation on the Chloride Resistance of Concrete Footing at Coastal Area -Comparision of Performance in Korea Building Code(KBC)- (해안인접지역 기초 구조물콘크리트의 내염해 성능 평가 -건축구조기준과의 성능비교-)

  • Park, Yong-Kyu;Yoon, Gi-Won;Kim, Hyun-Woo;Kim, Yong-Ro;Song, Young-Chan
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.10a
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    • pp.148-149
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    • 2016
  • In this paper, the increase in chloride resistance of footing concrete at coastal area was evaluated by replacement of Mineral Admixture. In KBC 2009, the footing concrete's minimum specific concrete strength at coastal area is determined to 35MPa. However, this is criteria only based on the strength aspect. Thus, it is not considered to increase the chloride resistance by replacement of Mineral Admixture. According to the test results of chloride ions penetration resistance, 35MPa class concrete with OPC 100% shown inaccessible state. Low-strength (24~30MPa class) concretes with Mineral Admixture, however, presented better performances. In addition, chloride diffusion coefficient tests showed identical appearance. Therefore, the current KBC's chloride resistance criteria based on only concrete strength has to review for the reason it can cause many problems (ex. cost increases by growing concrete strength and the environmental issues by a lot of cement use).

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The Resistance of Penetrability and Diffusion of Chloride Ion in Blended Low Heat Type Cement Concrete (저발열형 시멘트 콘크리트의 염소이온 침투$\cdot$확산에 대한 저항성)

  • 문한영;신화철
    • Journal of the Korea Concrete Institute
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    • v.11 no.4
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    • pp.31-41
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    • 1999
  • Blended Low Heat type cement is ground granulated blast furnace slag and fly ash mixed ternary with ordinary portland cement. From the viewpoint of X-ray patterns of domestic LHC, the main components of cement such as $C_2$S, $C_3$A, $C_3$S are considerably reduced. Therefore the heat evolution of LHC paste is 42cal/g lower than of OPC paste. At early age, the compressive strength development of LHC concrete is delayed, but the slump loss ratio of fresh concrete is reduced more than 20% with elapsed time. The penetrability of LHC is lower than that of OPC by 1/7.8 with the penetrability of chloride ion into the concrete until the age of 120 days. And the PD Index value of LHC is 0.44$\times$10-6 $\textrm{cm}^2$/s, which indicates only 39.3% of OPC. From the Mercury Intrusion Porosimetry test of cement past, we know that the pore size of LHC is more dense than that of OPC by production of C-S-H.

Strength, Carbonation Resistance, and Chloride-Ion Penetrability of Cement Mortars Containing Catechol-Functionalized Chitosan Polymer (생체모방 폴리머의 구조 분석 및 폴리머 혼입율에 따른 시멘트 모르타르의 특성 변화)

  • Bang, Eun Ji;Choi, Se-Jin;Ko, Haye-Min
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.04a
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    • pp.253-254
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    • 2022
  • In this study, catechol-functionalized chitosan (Cat-Chit), a well-known bioinspired polymer that imitates the basic structures and functions of living organisms and biological materials in nature, was synthesized and combined with cement mortar in various proportions. The compressive strength, tensile strength, drying shrinkage, accelerated carbonation depth, and chloride-ion penetrability of these mixes were then evaluated. In the ultraviolet-visible spectra, a maximum absorption peak appeared at 280 nm, corresponding to catechol conjugation. The sample containing 7.5% Cat-Chit polymer in water (CPW) exhibited the highest compressive strength, and its 28-day compressive strength was ~20.2% higher than that of a control sample with no added polymer. The tensile strength of the samples containing 5% or more CPW was ~2.3-11.5% higher than that of the control sample. Additionally, all the Cat-Chit polymer mixtures exhibited lower carbonation depths than compared to the control sample. The total charge passing through the samples decreased as the amount of CPW increased. Thus, incorporating this polymer effectively improved the mechanical properties, carbonation resistance, and chloride-ion penetration resistance of cement mortar.

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A Study on Infiltration Process and Physicochemical Influence in the Unsaturated and the Saturated Zone of the Bottom Ashes from Thermal Power Plant (화력발전소 배출 바닥재의 불포화대와 포화대 침투과정과 물리화학적 영향에 대한 연구)

  • Park, Byeong-Hak;Joun, Won-Tak;Ha, Seoung-Wook;Kim, Yongcheol;Choi, Hanna
    • Economic and Environmental Geology
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    • v.55 no.1
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    • pp.97-109
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    • 2022
  • This study focused on the physicochemical effects of bottom ash dissolved precipitation on the soil and groundwater environment. The iced column and percolation experiments showed that most of the bottom ash particles were drained as the ash-dissolved solution, while the charcoal powder was filtered through the soil. Ion species of Al, As, Cu, Cd, Cr, Pb, Fe, Mn, Ca, K, Si, F, NO3, SO4 were analyzed from the eluates collected during the 24 h column test. In the charcoal powder eluates, a high concentration of K was detected at the beginning of the reaction, but it decreased with time. The concentrations of Al and Ca were observed to increase with time, although they existed in trace amount. In the bottom ash eluates, the concentrations of Ca and SO4 decreased by 30 mg·L-1 and 67 mg·L-1, respectively, over 24 h. It is regarded that the infiltration patterns of the bottom ash and biochar in the unsaturated zone were different owing to their particle sizes and solvent properties. It is expected that a significant amount of the bottom ash will mix with the precipitation and percolate below the water table, especially in the case of thin and highly permeable unsaturated zone. The biochar was filtered through the unsaturated zone. The biochar did not dissolve in the groundwater, although it reached the saturation zone. For these reasons, it is considered that the direct contamination by the bottom ash and biochar are unlikely to occur.

Protection for sea-water intrusion by geophysical prospecting & GIS (해수침투 방지를 위한 물리검층과 GIS 활용방안)

  • Han Kyu-Eon;Yi Sang-Sun;Jeong Cha-Youn
    • 한국지구물리탐사학회:학술대회논문집
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    • 2000.09a
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    • pp.54-69
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    • 2000
  • There are groundwater trouble by high-salinity yield inducing sea-water intrusion in Cheju Island. It is used groundwater-GIS(Well-lnfo) in the maintenance and management of groundwater in Cheju Island to grasp groundwater trouble area and cause of high-salinity yield. For 16 wells certain to yield high-salinity, we logged specific electrical conductivity(EC) and tried to get hold of freshwater and saltwater relationship. As result of distribution of $Cl^-$ by depth, it is showed up groundwater trouble by high-salinity yield in the east coastal area and the partly north coastal area. The reason of high-salinity groundwater yield are low-groundwater level by the structure of geology and low-hydraulic gradient etc. There is necessity for management to development and use of groundwater in the high-salinity area, special management area.

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The Effect of Daucus carota L. Extracts on the Fluidity of Phospholid Liposomes (당근추출물이 인지질막 Liposome의 유동성에 미치는 영향)

  • 신미옥;배송자
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.30 no.4
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    • pp.646-650
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    • 2001
  • In this study, we investigated the thermotropic behavior of Daucus carota L. (DCS) extracts in phosphatidylcholine(PC) liposomes using high-sensitivity differential scanning calorimetry (nano-DSC). We used dipalmitoylphosphatidylcholine (DPPC) bilayers which made most stable liposomes among the other phosphatidylcholine. The sample DCS was extracted and fractionated to four different types, hexane(DCSMH), ethylacetate (DCSMEA), butanol (DCSMB) and aqueous(DCSMA) fractions. Compared to the other fractions of Daucus carota L., the DCSMH and DCSMEA fractions markedly affected the thermotropic properties of DPPC liposomes, broadened and shifted the thermograms of transition to lower temperatures. The incorporation of DCSMH and DCSMEA in DPPC liposomes were preferentially located in the hydrophobic core of DPPC bilayers, where it reduced the lipid packing orderness (cooperative unit) in the gel state compared to it in the liquid-crystalline state. These results suggest that the activities of the Daucus carota L. extracts to enhance the fluidity of the liposomal membrane have implication in their biological activities.

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Chloride Penetration Resistance of Ternary Blended Concrete and Discussion for Durability (삼성분계 혼합콘크리트의 염화물 침투 저항성 및 내구성에 대한 고찰)

  • Song, Ha-Won;Lee, Chang-Hong;Lee, Kewn-Chu;Kim, Jae-Hwan;Ann, Ki-Yong
    • Journal of the Korea Concrete Institute
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    • v.20 no.4
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    • pp.439-449
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    • 2008
  • Mineral admixtures are used to improve the quality of concrete and to develop sustainability of concrete structures. Supplementary cementitious materials (SCM), such as silica fume (SF), granulated blast furnace slag (GGBS) and pulverized fly ash (PFA), are gradually recognized as useful mineral admixture for producing high performance concrete. The study on ternary blended concrete utilizing mainly three major mineral admixtures is limited and the study on durability and chloride induced corrosion resistance of ternary blended concrete is very few. This study examines the durability characteristics of the ternary blended concrete composed of different amount of the SCM with ordinary Portland concrete and the study experimentally focuses on corrosion resistance evaluation of ternary blended concrete subjected to chloride attack. In this study, 50% replacement ratio of mineral admixture to OPC was used, while series of combination of $20{\sim}40%$ GGBS, $5{\sim}15%$ SF and $10{\sim}45%$ PFA binder were used for chloride corrosion resistance test. This study concerned the durability properties of the ternary blended concrete including the corrosion resistance, chloride binding, chloride transport and acid neutralization capacity. It was found that the ternary blended concrete utilizing the SCM densified the pore structures to lower the rate of chloride transport. Also, increased chloride binding and buffering to acid were observed for the ternary blended concrete with chlorides in cast.