• Polymer(Korea)
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• v.27 no.1
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• pp.69-74
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• 2003

In this study, we have investigated the adsorption properties for nitrate ion in ground water using mixed resin type hybrid ion exchange (HIXF) and fiber type ion exchanger. Their swelling ratio (4.45 g/g) and ion exchange capacities (2.45 meq/g) were higer than the swelling ratio of IEC and IXF. Adsorption yield increased for nitrate $NO_3^-$ and sulfate $SO_4^{2-}$ ions were optimal at the concentration ratios of nitrate and sulfate below 1.0 and the adsorption yields were 100% and 20%, respectively. On the other hand it was shown that the degree of adsorpted for nitrate to pH 3, but it was little changed in the other pH range. We found that the selective adsorption capacity for nitrate was the optimal the mixing ratios of resin and fibrous ion exchanger of below 0.5.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1995.05a
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• pp.100-105
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• 1995

Bulk glasses in the system $Na_2O$-CaO-$Al_2O_3$-$B_2O_3$-$SiO_2$ containing 20 to 30 mol% sod-ium hav been subjected to a sodium silver ion-exchange reaction for 0, 24, 36, 48 jr were analysed by electrical characterization Ion-exchanged glasses exhibit resistivity and activation energy values lower than those of the untreated ones. The electrical conductivity increase with sodium content and ion-exchanged time. In this experiment the electrical conductivity exhibit a maximum value of 1.78${\times}$10$^{-4}$S/cm at $200^{\circ}C$ which contains 30 mol% sodium and subjects ion-exchange reaction for 48hr.

• Journal of Radiation Protection and Research
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• v.13 no.2
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• pp.52-56
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• 1988

An ion-exchange method for the detection of radioactivity in water using ion-exchange resin in concentrating radioactive nuclides was compared with an evaporation method. The loss of the radioactive materials in the sample treated by the ion-exchange method was less by about 20% than that by the evaporation method. In addition, the evaporation method needed about 20 hours for evaporating one liter of the sample at $70^{\circ}C$, while the ion-exchange method spent 6 hours to adsorb and adsorb the same amount of the sample on the resin. Consequently, the ion-exchange method is more effective than the evaporation method for the treatment of the radioactively contaminated water and is especially suitable for detecting the low-level radioactivity in water.

• Proceedings of the Korean Vacuum Society Conference
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• 2015.08a
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• pp.100.1-100.1
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• 2015

중이온가속기에서 잔류기체 분자와 가속 이온의 충돌이 발생하면 이온빔 전류의 손실을 야기하는 직접적인 효과 외에 잔류 기체분자 중에서 전리된 이온들이 반발력에 의해 용기 벽에 부딪힐 때 표면에 흡착되어 있던 기체분자들을 충격탈리(stimulated desorption)시킨다. 더 심각한 경우는 산란된 고속 이온이 용기 벽과 충돌하면서 핵반응을 일으켜 방사화 시키거나 벽에서 다량의 기체를 방출시키는 것이다. 최악의 경우에는 고속이온의 에너지에 의해 용기벽이나 부품들이 열적인 손상을 입을 수도 있다. 현재 설계 및 연구개발이 진행중인 기초과학원(IBS) RISP (Rare Isotope Science Project)의 RAON 중이온가속기는 입사기에서 실험영역까지 각 부분의 진공도 조건이 일반적으로 10-8~10-9 mbar 대에 있어서 이온빔 전류의 손실이나 전리 이온들에 의한 충격탈리는 무시할 수도 있지만 고속이온의 기체방출 수율이 ~104 정도로 높은 것을 감안할 때 고속이온의 충격탈리에 의한 압력 증가가 감내할 수준인지 검토할 필요가 있다. 압력증가는 추가적인 손실을 유발하고 이것은 다시 압력을 상승시키는 진공 불안정성(vacuum instability)을 야기할 수 있다는 축면에서 조심하는 것이 좋다고 판단된다. 고속 중이온과 잔류기체 분자와의 충돌에서 이온이 손실되는 반응에는 쿨롬(coulomb) 산란과 전하교환(charge exchange)이 있는데 전자는 후자에 비해 일반적으로 1/10000 가까이 낮아서 무시할 수 있고, 전자 포획(electron capture) 또는 전자 손실(electron loss, 이온의 전리에 해당)로 대별되는 전하교환 반응이 이온 손실을 주도하는 것으로 알려져 있다. 이 연구에서는 다양한 전하교환 반응 단면적을 아우르는 비례칙(scaling law)을 사용하여 대표적인 중이온인 U33+ 및 U79+의 손실 및 잔류 기체의 전리율을 계산하고 충격탈리에 의한 표면방출 및 압력상승을 일차적으로 고려하여 진공도 조건의 타당성을 입증하려고 한다.

• Membrane Journal
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• v.16 no.3
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• pp.167-181
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• 2006

Continuous Electrodeionization (CEDI) is a hybrid separation process of electrodialysis and ion exchange to produce high purity water under electric field. CEDI system is generally explained with two regimes, ionic removal and electroregeneration. The performance optimization and modification of stack configuration is required for the effective utilization and various applications of a CEDI system. Understanding on various system characterization method and ion transport equation is thus necessary to utilize the CEDI system more effectively. This article provides a general review of continuous electrodeionization, including the basic principles and current stage of technologies of a CEDI system.

• Proceedings of the KIEE Conference
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• 2007.10c
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• pp.185-188
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• 2007

본 논문에서는 수소이온교환막 연료전지의 퍼지 모델링 기법을 제안하였다. 수소이온교환막 연료전지는 가정용으로 공급이 적합한 연료전지로서 최근들어 많은 연구가 진행되고 있다. 연료전지 특성 모델은 이러한 연구에 중요한 역할을 하고 있으면 이 때문에 다양한 연료 전지 모델링 기법들이 제안되고 있다. 본 논문에서는 선형 행렬부등식 최적화기법을 기반 새로운 형태의 퍼지 모델링 기법이 제안되었다. 최종적으로 시뮬레이션을 통해 제안된 기법의 우수성을 확인하였다.

• Proceedings of the Optical Society of Korea Conference
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• 2000.08a
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• pp.160-161
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• 2000

BK7 glass 기판에 Ag$^{+}$-$Na^{+}$ 이온교환법을 이용하여 Y-분리기를 제작하였다. Y-분리기는 하나의 입력으로 입사되는 광파워를 두 개의 출력단으로 분리하거나 합하는 기능을 수행하는 가장 기본적인 소자로서 이온 교환법을 이용하여 0.2dB/cm 이하의 전송손실을 유지할 수 있다. 또한 MMI (multimode interference)가 갖는 파장에 의존적인 동작 특성과는 달리 사용 파장에 덜 의존적으로 광 신호를 분기시킬 수 있다$^{(1-3)}$ . (중략)

• Journal of the Korea Organic Resources Recycling Association
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• v.16 no.2
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• pp.38-46
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• 2008

Many researchers have reported that many biopolymers making up cell walls of the microorganisms display an ion-exchange property and play a major role in the sorption of the metal ions. Such polymers derived from microbial biomass are potentially useful as biosorbent materials for recovery various metal ions in industrial applications. although synthetic polymers such as ion-exchange resins and chelating resins have been widely used as commercial sorbents. In this study, valuable and commercial biopolymers for metal removal will be introduced.

• Journal of Radiation Protection and Research
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• v.27 no.1
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• pp.27-35
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• 2002

Characteristics of Amberlite IRN 77, a cation exchange resin, and the mechanisms of its adsorption equilibria with Co(II), Ni(II), Cr(III) and Fe(III) ions were investigated for the application of the demineralizing process in the primary coolant system of a pressurized water reactor (PWR). The optimum dosage of the resin for removal of the dissolved metal ions at $200mgL^{-1}$ was 0.6 g for 100 mL solution. Most of each metal ion was adsorbed onto the resin in an hour from the start of the reaction. Each metal adsorption onto the resin could be well represented by Langmuir isotherms. However, in the case of Fe(III) adsorption, continuous formation of Fe-oxide or -hydroxide and its subsequent precipitation inhibited the completion of the equilibrium between the metal and the adsorbent Cobalt(II) and Ni(II), which have an equivalent electrovalence, were adsorbed to the resin with a similar adsorption amount when they coexisted in the solution. However, Cr(III) added to the solution competitively replaced Co(II) and Ni(II) which were already adsorbed onto the resin, resulting in desorption of these metals into the solution. The result was likely due to a higher adsorption affinity of Cr(III) than Co(II) and Ni(II). This implies that the interactively competitive adsorption of multi-cations onto the resin should be fully considered for an efficient operation of the demineralizing ion exchange process in the primary coolant system.

• Nuclear Engineering and Technology
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• v.6 no.2
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• pp.97-111
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• 1974

The adsorption mechanism of Cs-137 in low level radioactive solution by vermiculite treated with Na ion is studied in order to investigate its effective utilization for the radioactive effluent treatment. The beneficial role of Na-vermiculite is that Na ion can induce the wider c-axis spacing in which Cs ion can be sorbed in vermiculite. Cation exchange capacity and distribution coefficient of cesium seems to be influenced by the variation of c-axis spacing of vermiculite. Comparative identification and detection with the characteristic analyses of X-ray diffraction and electron diffraction patterns, diffrential thermal analysis and electron microscopy of Na-, K- and Cs-vermiculite are studied for the phemomena of Cs adsorption by vermiculite. This importance of the utilization in terms of adsorption and fixation of cesium involving vermiculite is discussed. It is found that the Na-vermiculite is valuable outside charging material for high level radioactive liquid waste storage tank of underground to protect the pollution of the underground water.