• Economic and Environmental Geology
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• v.53 no.4
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• pp.347-362
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• 2020

Iron (hydro)oxides in aqueous environments are primarily formed due to mining activities, and they are known to be typical colloidal particles disturbing surrounding environments. Among them, hematites are widespread in surface environments, and their behavior is controlled by diverse factors in aqueous environments. This study was conducted to elucidate the effect of environmental factors, such as ionic composition and strength, pH, and natural organic matter (NOM) on the behavior of colloidal hematite particles. In particular, two analytical methods, such as dynamic light scattering (DLS) and single-particle ICP-MS (spICP-MS), were compared to quantify and characterize the behavior of colloidal hematites. According to the variation of ionic composition and strength, the aggregation/dispersion characteristics of the hematite particles were affected as a result of the change in the thickness of the diffuse double layer as well as the total force of electrostatic repulsion and van der Walls attraction. Besides, the more dispersed the particles were, the farther away the aqueous pH was from their point of zero charge (PZC). The results indicate that the electrostatic and steric (structural) stabilization of the particles was enhanced by the functional groups of the natural organic matter, such as carboxyl and phenolic, as the NOM coated the surface of colloidal hematite particles in aqueous environments. Furthermore, such coating effects seemed to increase with decreasing molar mass of NOM. On the contrary, these stabilization (dispersion) effects of NOM were much more diminished by divalent cations such as Ca²⁺ than monovalent ones (Na⁺), and it could be attributed to the fact that the former acted as bridges much more strongly between the NOM-coated hematite particles than the latter because of the relatively larger ionic potential of the former. Consequently, it was quantitatively confirmed that the behavior of colloidal hematites in aqueous environments was significantly affected by diverse factors, such as ionic composition and strength, pH, and NOM. Among them, the NOM seemed to be the primary and dominant one controlling the behavior of hematite colloids. Meanwhile, the results of the comparative study on DLS and spICPMS suggest that the analyses combining both methods are likely to improve the effectiveness on the quantitative characterization of colloidal behavior in aqueous environments because they showed different strengths: the main advantage of the DLS method is the speed and ease of the operation, while the outstanding merit of the spICP-MS are to consider the shape of particles and the type of aggregation.

• Applied Chemistry for Engineering
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• v.20 no.3
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• pp.313-316
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• 2009

Synthesis of porous $CeO_2$ particles was investigated using various ionic liquids (ILs) as an effective template. The pore structure and crystalline phase of $CeO_2$ particles was affected significantly by the composition of ionic liquids. The strength of the hydrogen bonds on the anion part of ionic liquid was an essential factor to form the pore architecture of $CeO_2$ particles. Moreover, the length of alkyl group on the cation part of ionic liquid determined the pore size and surface area of $CeO_2$ particles. Among the ionic liquids, it was found that 1-Buthyl-3-methylimidazolium hexafluorophosphate ([Bmim][PF6]) was the most effective ionic liquid to synthesize the porous $CeO_2$ particle.

• Journal of the Korean Chemical Society
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• v.42 no.2
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• pp.197-202
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• 1998

1-(2-Pyridylazo)-2-Naphthol (PAN) has been widely used as a spectrophotometric reagent and metallochromic indicator for many metal ions. In this work, the chelate reagent of PAN was used as mobile phase additive for the separation of metal ions by reversed phase chromatography. Metal ions could be detected by monitoring the effluent at 570 nm with spectrophotometric detector. In order to investigate retention behaviors of the metal ions, the chromatograms and capacity factors were obtained as the variation of pH, ionic strength and composition of organic modifier in mobile phase. Under the obtained optimum conditions, the mixtures of Fe(III), Ni(II), Cu(II), Zn(II) and Co(II) could be separated successfully and the calibration curves under the recommended conditions showed an excellent linearity. The detection limits(S/N) were feasible at the nanogram level.

• Proceedings of the Korean Vacuum Society Conference
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• 1999.07a
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• pp.231-231
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• 1999

PDP(Plasma Display Panel)는 21세기 디스플레이 시장을 대체할 차세대 디스플레이 장치로서 넓은 시야각, 얇고, 가볍고, 메모리기능이 있다는 여러 가지 장점들을 가지고 있지만 현재 고휘도, 고효율, 저소비전력 등의 문제점들을 해결하여야 한다. 이러한 문제점들의 해결을 위해서는 명확한 미세방전 PDP 플라즈마에 대한 정확한 진단 및 해석이 필요하다. 따라서 본 연구에서는 미세 면방전 AC-PDP 플라즈마의 기초 변수들 (플라즈마 밀도 & 온도, 플라즈마 뜬 전위, 플라즈마 전위 등의 측정을 통해 고휘도, 고효율 PDP를 위한 최적의 방전환경을 알아내는 데 있다. 일반적으로 전자의 밀도는 방전전류에 비례하는 관계를 보인다. 전류에 대해 방전전압이 일정하다면 전자밀도가 커짐에 따라서 휘도는 포화되며 상대적으로 휘도와 전류의 비로 표시되는 발광효율은 감소하게 된다. 반면 전자밀도가 상당히 작다면 휘도는 전자밀도에 비례하고 효율은 최대값을 보인다. 따라서 미세구조 PDP에서 휘도와 발광효율, 양쪽에 부합하는 최적의 방전환경을 플라즈마 전자밀도와 온도의 측정을 통해서 해석하는 것이 필요하다. 본 실험에서는 방전기체의 종류와 Ne+Xe 방전기체의 조성비에 따른 플라즈마 밀도, 온도의 공간적인 분포특성을 진단하기 위해서 초미세 랑뮈에 탐침(지름: 수 $mu extrm{m}$)을 제작하였다. 제작된 초미세 탐침을 컴퓨터로 제어되는 스텝핑모터를 장착한 정밀 X, Y, Z stage에 부착하여서 수 $\mu\textrm{m}$간격의 탐침 삽입위치에 따라서 미세면방전 AC-PDP의 플라즈마 밀도 및 온도분포 특성을 진단하였다. PDP 방전공간에 초미세 랑뮈에 탐침을 삽입해서 -200~+200V의 바이어스 전압을 가해준다. 음의 바이어스 전압구간에서 이온 포화전류를 얻어내어 여기서 플라즈마 이온 밀도를 측정하고 양의 바이어스 전압구간에서 플라즈마 전자온도를 측정하면 미세면방전 AC-PDP 플라즈마의 기초 진단이 가능하다.

• Proceedings of the Korean Vacuum Society Conference
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• 2015.08a
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• pp.88.2-88.2
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• 2015

최근 CIGS 박막태양전지에 대한 저가/고효율화에 대한 연구가 심도있게 진행되는 상황에서 태양전지를 구성하고 있는 요소박막에 대한 기능향상 또한 chalcophyrite 구조를 개선하기 위한 실험에 대하여 연구가 많이 진행되고 있다. 전자빔 조사방식은 플라즈마에서 발생되는 이온과 전자 클러스터 중에 전자를 그리드로 선택하여 조사할수 있는 방식으로 가속전압, 인가시간에 따라 샘플에 인가받는 에너지세기의 양을 조절할수 있다. 결정화를 위한 전자빔 조사와 표면구조 개선을 위한 공정조건은 서로 상이한데, CIGS를 구성하는 박막태양전지의 구성박막인 Mo, CIGS, ZnO에 대한 전자빔 조사 변수로서 가속전압을 1.5~5.0 keV로 조사시간은 300 sec이내로 했을때의 각 구성박막의 조성적, 광학적, 전기적, 구조적 특성변화를 관찰하였고, 이에 대한 태양전지 소자로서의 특성을 발표한다. 결론적으로 전자빔 조사는 아주 빠른 시간 이내에 표면을 modify할수 있으며, 가해지는 전자빔의 운동에너지와 매칭이 되는 공정조건 구현 및 탐색을 통해 소결, 결정화까지도 가능한 아주 유용한 방법으로 간주될수 있다.

• Analytical Science and Technology
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• v.24 no.1
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• pp.15-23
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• 2011

An accurate mass and isotope ratio were determined using a gas chromatography/time of flight mass spectrometer in CI positive mode for the identification of unknown metabolites. High mass tune was used to improve the ion intensity of $[M+H]^+$. Chromatographic resolution and dynamic range enhancement were performed to obtain more reliable accurate masses and correct isotope abundance ratios. Average absolute errors of mass and isotope ratios for 24 reference metabolite -TMS (trimethylsilyl) derivatives were 6.8 ppm, 1.5% of (M+1/M ratio) and 1.7% of (M+2/M ratio), respectively. The correct formulas of twenty one compound were retrieved within top-2 hit from the heuristic algorithm for elemental composition using each accurate mass and isotope abundance ratio.

• Proceedings of the Optical Society of Korea Conference
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• 2003.07a
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• pp.34-35
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• 2003

광통신 분야에서 광신호의 장거리 전송에 따른 세기 감소를 보강하기 위해 쓰이는 광섬유증폭기는 현재 1.3 $\mu\textrm{m}$ 대역, 1.45 $\mu\textrm{m}$ 대역 및 1.5 $\mu\textrm{m}$ 대역에서 작동하는 희토류 이온 첨가 광섬유 광증폭기가 개발되어 쓰이고 있다. 한편 ETRI에서는 기존 광통신에 쓰이는 광 증폭기에 추가해 더 넓은 파장대를 광통신에 쓸 수 있도록 하는 새로운 파장대역의 광 증폭기 구현을 가능케하고 나아가 광통신 용량을 기존보다 휠씬 더 큰 10 Tbps급 이상으로 늘이기 위해 1.6 $\mu\textrm{m}$ 파장대인 U 밴드대 광증폭기용 광섬유인 Pr 첨가 셀레나이드 유리 조성의 신소재를 개발하였는데, 본 연구에서는 Ge-Sb-Ga-Se 계열의 Pr 첨가 셀레나이드 유리의 굴절률을 분광타원 법 (spectroscopic ellipsometry)을 사용하여 결정하였다. (중략)

• Applied Chemistry for Engineering
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• v.10 no.6
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• pp.822-827
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• 1999

The specific capacitance characteristics which were of the electric double layer capacitors(ELDC) made of phenol based activated carbon fiber(ACF) electrodes and organic electrolytes has been investigated with respect to different specific surface area of electrodes and different kinds of organic electrolytes. Throughout charge-discharge cell tests, it has been found that larger surface area and larger pore diameter of electrodes contribute to increase the specific capacitance. Binary mixture of organic solvent with propylene cabonate(PC) and tetrahydrofuran(THF) for 1 M-$LiClO_4$ electrolyte has a higher specific capacitance than single solvent of PC or mixed solvent with PC and diethyl cabonate(DEC). Also, even though 1 M-tetraethylamonium perchlorate(TEAPC) of organic electrolyte shows higher specific capacitance, it has longer charge time because of its lower ion mobility.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.7 no.1
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• pp.6-17
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• 1997

Lithium niobate single crystals with various [Li]/[Nb] ratios were grown by the Czochralski method from melts having compositions varing between 48.6 ~ 58.0 mol % $Li_2O$. A vapor transport equilibration technique has been used to improve the homogeneity and adjust the [Li]/[Nb] ratio in small $LiNbO_3$ single crystals grown by the Czochralski method. When equilibrated with a Li-rich powder (65 mol%$Li_2O$), containing a mixture of $LiNbO_3$ and $Li_3NbO_4$, crystals of nearly stoichiometric composition can be obtained. This was established by studying the composition dependence of the following properties; lineshape, intensity and linewidth for the electron paramagnetic resonance (EPR) of $Fe^{3+}$ energy of the fundamental absorption edge and $OH^-$ absorption spectra.

• Journal of the Korean Society of Radiology
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• v.9 no.1
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• pp.39-45
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• 2015

$La_2W_3O_{12}:Eu^{3+}$ phosphors were prepared by solid state reaction method. The crystal structure was characterized by XRD pattern and ICSD card (78180). Luminescence properties of $La_2W_3O_{12}:Eu^{3+}$ are investigated by optical and laser-excitation spectroscopy in which emission and excitation spectra and time-resolved spectra are measured. The 1 mol % $Eu^{3+}$-doped $La_2W_3O_{12}$ phosphor exhibits broad excitation band peaking at 286 nm due to the ligand-to-metal charge transfer transition. The excitation lines due to the $^7F_0{\rightarrow}{^5D_4},{^5D_4},{^5L_6},{^5G_4},{^5D_3},{^5D_2}$ transitions of $Eu^{3+}$ are observed in the wavelength region 350-500 nm. The strong line emission is observed at 618 nm corresponding to the due to the $^5D_0{\rightarrow}^7F_2$ transition. The lifetime of 618 nm emission decreases with increasing temperature as 7 K ($114{\mu}s$), 100 K ($94{\mu}s$), 200 K ($10{\mu}s$) and 300 K ($0.5{\mu}s$).