• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.297-297
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• 2013

최근 각종 폴리머 및 강판과 같은 유연소재의 수요 증가로 인해 유연소재 표면의 전처리, 증착 및 기능성 부여를 위한 이온빔 또는 플라즈마 표면처리 기술이 세계적으로 활발히 연구개발 되고 있으며, 유연소재 표면처리 공정의 고속화 및 대면적화 기술이 요구되고 있다. 유연소재의 고속 및 대면적 표면처리 기술개발을 위해서는 Roll-to-Roll 공정에 적용 가능한 광폭 선형이온소스 기술 개발이 필요하다. 본 연구에서는 1.55 m급 광폭 Anode Layer 선형이온소스를 개발하였으며, 이온빔 인출 균일도 및 에너지 분포 특성을 평가하였다. 특히, 본 선형이온 소스 개발 시 시뮬레이션 연구를 통해 이온소소의 이온 인출 특성 및 내구성 향상을 위한 최적 구조를 설계하였다. 본 연구에서 개발한 선형이온소스는 최대 5 kV의 방전 전압 조건에서 평균 1.5 keV의 이온에너지를 가지는 Ar 이온빔이 1.55 m 폭에서 약 4.2%의 균일도를 보였다. 표면 처리 성능 평가시(Si wafer 기준) 소스와 기판과 거리 100 mm에서 에칭율은 15 nm/s였고, 이는 다른 표면처리 이온소스 대비 높은 효율을 나타냄을 확인할 수 있었다. 또한 4시간 이상 운전시에도 안정적인 인출 빔 전류 밀도를 확인하였으며, 소스 내부의 효율적인 냉각 구조로 인한 열손상은 발견되지 않았다.

• Journal of the Korean Institute of Telematics and Electronics T
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• v.35T no.2
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• pp.6-12
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• 1998

Thin film SOI(Silicon-on-insulator) device offer unique advantages such as reduction in short channel effects, improvement of subthreshold slope, higher mobility, latch-up free nature, and so on. But these devices exhibit floating-body effet such as current kink which inhibits the proper device operation. In this paper, the SOI NMOSFET with a T-type gate structure is proposed to solve the above problem. To simulate the proposed device with TSUPREM-4, the part of gate oxide was considered to be 30nm thicker than the normal gate oxide. The I-V characteristics were simulated with 2D MEDICI. Since part of gate oxide has different oxide thickness, the gate electric field strength is not same throughout the gate and hence the impact ionization current is reduced. The current kink effect will be reduced as the impact ionization current drop. The reduction of current kink effect for the proposed device structure were shown using MEDICI by the simulation of impact ionization current, I-V characteristics, and hole current distribution.

• Fire Science and Engineering
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• v.30 no.2
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• pp.114-122
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• 2016

This study is to analyze the explosion and fire risks due to high temperature and short circuit current of Lithium batteries. This study selected the typical types of Li-polymer batteries and Li-ion batteries as the test samples. The result of explosion risk assessment due to the high temperature showed that, while a Li-polymer battery had $170^{\circ}C$ explosion on average, a Li-ion battery had $187^{\circ}C$ explosion. The measurement result of temperature increase due to short circuit current revealed that, in case that protection circuit module (PCM) was normally working, there was little of temperature increase due to over-current limitation. However, in case that PCM was out of order, the temperature of a Li-polymer battery increased up to an average of $115.7^{\circ}C$ and the temperature of a Li-ion battery increased up to an average of $80.5^{\circ}C$, which showed the higher risks of fire and burn.

• Journal of the Korean Chemical Society
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• v.24 no.4
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• pp.295-301
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• 1980

The electrical conductivity of solid electrolyte $RbAg_4I_5$ single crystal was studied at various temperatures. The four-probe method was used in measuring the conductance with an ac signal imposed on the specimen. The ionic conductivity was $0.284 ohm^{-1} cm^{-1}\;at\;25^{\circ}C$, and the activation energy for $Ag^+$ ion migration was calulated to be 1.70 kcal/mole. These values agree well with those reported for polycrystalline samples. Reactions at $Ag/RbAg_4I_5$ interface were studied by cyclic voltammetry with a silver reference electrode. It was found that silver ion is reversibly reduced at silver surfaces below zero volt, and iodide was oxidized above +0.67 volt.The anodic current arising from the oxidation of the electrode was small in magnitude initially over a wide range of potential, but, after silver was cathodically deposited on the electrode, reversing the potential sweep to the anodic direction resulted in a sharp peak of anodic current.

• Journal of the Korean Electrochemical Society
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• v.3 no.3
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• pp.152-156
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• 2000

The effect of cupric ion concentration on the throwing power has been studied in the electrodeposition of Cu on the porous reticular electrodes with the electrolytes of $CuSO_4\;and\;H_2SO_4$. Sulfuric acid electrolytes with lower concentration of $CuSO_4$ improved throwing power in electrodeposition of copper not only due to higher cathodic polarizability but also due to higher conductivity of the electrolytes. The increase in conductivity of the electrolytes at low concentration of $CuSO_4$ could be also illustrated by the decrease in viscosity of the electrolytes. It was found that both the throwing power and the limiting current density should be taken into account in the electrodeposition of Cu on the reticular electrodes. According to the experimental results, the electrolyte of 0.2M $CuSO_4$ and 0.5M $H_2SO_4$ was found to be the most appropriate condition at the current density of $10mA/cm^2$.

• The Journal of Natural Sciences
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• v.7
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• pp.37-46
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• 1995

Electrochemical behavior of $Ln^{3+},$-ALC complexes($Gd^{3+},$ $Tb^{3+},$ $Dy^{3+},$ $Ho^{3+},$ $Er^{3+},$ $Yb^{3+}$ and $Lu^{3+}$-alizarin complex-one) has been investgated by d.c polarography, differential pulse polarography and cyclic voltammetry. The reduction mechanism of ALC comes to the conclusion that the two electron make one step of reversible processes, and that there is few adsorption in the electrode reaction. The new complex is made from one lanthanide ion and one ALC. This complex is proven to make an adsorptive complex wave, by the experiments of differential pulse polarography and cyclic voltammetry. The reduction potential of complex wave($P_2$)turns up more negatively than ligand wave($P_1$) does. Linear calibration curves of the decreasing P1 and increasing $P_2$ is obtained when the lanthanide concentration varys from $2.5X10^5$M to $1X10^4M$.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.297-297
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• 2010

KSTAR 토카막의 두번째 실험 캠페인 동안 고속파 전자가열 (FWEH)을 위한 ICRF 고주파입사 실험을 실시하였다. 토로이달 자기장은 2 T, 플라즈마 전류는 200-300 kA, 주반경은 1.8 m, 부반경은 0.5 m의 원형 플라즈마가 가열 대상이 되었으며, 네개의 ICRF 안테나 전류띠 가운데 중심부의 두개의 전류띠를 최대 300 kW로 구동하기 위한 운전 주파수는 44.2 MHz가 선택 되었다. 이 주파수는 플라즈마의 모든 영역에서 이온 사이클로트론 공명을 일으키지 않으므로 플라즈마에 흡수되는 대부분의 출력은 전자에게 전달될 것으로 기대되었다. 낮은 고주파-플라즈마 결합으로 인하여 전송선의 최대 고주파 전압이 허용치를 초과하기 때문에 비교적 낮은 최대 출력만이 허용 되었으나, ECE에 의해 관측된 전자의 온도는 국지적으로 최대 150 % 까지 증가하는 것을 확인 할 수 있었다. 낮은 고주파-플라즈마 결합의 첫번째 원인은 FWEH의 효율이 이온을 가열할 때 보다 상대적으로 낮기 때문이다. 플라즈마 내에 이온 사이클로트론 공명층이 형성되면 높은 효율로 고주파를 입사 할 수 있다는 것은 잘 알려진 사실이다. 또다른 원인은 D 형상의 플라즈마에 맞도록 만들어진 안테나와, 원형 플라즈마간의 부조화로 인하여 고속파 차단층이 (Fast Wave Cutt-off Layer) 평균적으로 넓게 형성되기 때문이다. 플라즈마 외곽에 반드시 존재하는 낮은 플라즈마 밀도의 고속파 차단층 내부에서, 중심부로 향하는 고주파의 진폭은 지수함수로 감쇠하므로 가능하면 플라즈마 밀도를 높여 차단층 자체의 폭을 줄이거나, 안테나 전류띠를 플라즈마에 바짝 접근시켜야만 한다. 고주파 진단 장치로는 송출기의 출력과 반사파 측정 장치, 공명루프의 전압 측정 장치가 있는데, 이것들을 이용하여 안테나에 전달되는 출력 및 고주파-플라즈마 결합 효율을 나타내는 플라즈마에 대한 고주파 부하 저항을 구할 수 있다. 측정 결과, 부하 저항의 최소값은 진공시 또는 ICRF만의 방전시의 값 0.25 Ohm 보다 큰 0.5 Ohm을 나타냈으며, 최대값은 플라즈마의 상태에 따라 1 Ohm에서 2 Ohm 사이에서 매우 빠르게 요동하는 것을 확인했다. Mm 파 반사계의 측정에 의하면 플라즈마 언저리의 위치가 약 3 cm 정도의 크기로 요동하는 것으로 나타났는데, 부하 저항과 언저리 위치의 파형이 정확하게 일치하지 않지만 유사한 경향성을 가진 것으로 보인다. 따라서 플라즈마 언저리 위치의 제어를 통하여 가열 효율을 높게 유지할 수 있음을 알 수 있다. 본 발표에서는 실험의 소개와 함께 부하 저항의 관점에서 가열 효율을 높일 방안을 토론하도록 한다.

• Analytical Science and Technology
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• v.12 no.1
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• pp.40-46
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• 1999

Zn-Ni alloy electrodeposition on steel has been examined by means of X-ray diffraction and scanning electron microscopy. The effect of current density, $Ni^{2+}$ ion concentration, and $Cl^-$ ion concentration on the structure as well as morphology of the electrodeposit have been studied. The Ni content of the electrodeposit increased with decreasing current density in the range studied in this work. The Ni content of the electrodeposit also increased with increasing $Ni^{2+}$ ion and $Cl^-$ ion concentrations. The structure change of the electrodeposit was closely related to the Ni content. In fact, the mixture phase of ${\eta}$ and ${\gamma}$ was found below 10 wt.% of Ni while the ${\gamma}$ phase only was observed above 10 wt.% of Ni. In addition, the lattice parameter, a, of then phase structure increased and the lattice parameter, c, of it decreased as the Ni content of the electrodeposit increased. The morphology of the electrodeposit varied from the plate-like shape to the fine granular shape depending upon the change in composition and structure of the electrodeposit.

• Journal of the Korean Chemical Society
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• v.18 no.4
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• pp.244-250
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• 1974

The mechanisms of the electrode reaction of chlorate ion were investigated, using Pt-electrode, by means of the technique of galvanostatic double pulses. For double current pulses (a cathodic pulse followed by an anodic pulse), the mechanism of the electrode reaction of chlorate ion over a current density range from 20 ma/cm2 to 25 ma/cm2 was suggested as the following: $CIO_3^-\;{\longrightarrow^{I}_{n_{1c}}\;CIO_2^-\;{\longrightarrow^{II}_{n_{2a}}\;CIO^-\;{\longrightarrow^{I'}_{n_{1a}}\;CIO_2^-\;{\longrightarrow^{II'}_{n_{2a}}\;CIO_4^-$ For a higher current density from 40 ma/cm2, it was suggested as the following: $CIO_3^-\;{\longrightarrow^{III}_{n_c}}\;CIO^-\;{\longrightarrow^{I'}_{n_{1a}}\;CIO_2^-\;{\longrightarrow^{II'}_{n_{2a}}\;CIO_4^-$ or $CIO_3^-\;{\longrightarrow_{n_c}}\;CIO^-\;{\longrightarrow_{n_a}}\;CIO_4^-$

• Journal of Korean Society of Environmental Engineers
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• v.28 no.6
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• pp.640-647
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• 2006

It is difficult to treat wastewater involved in heavy metal in electroplating industry. Recently, many industries adopt the clean technology to prevent production of pollutant in the process or reuse after the appropriate pollutant treatment. In this study, we estimate the ability of recovery of nickel and the efficiency using lab-scale ion exchange and electrodialysis process with electroplating industry wastewater. In the ion exchange experiments with 5 types of resin, the result showed that S 1467(gel-type strong acidic cation exchange resin) has the highest exchange capacity. And it showed that the 4 N HCl has the highest in regeneration efficiency and maximum concentration in the regeneration experiments with various kinds md concentration of the regenerant. During the electrodialysis experiments, we varied the current density, the concentration of electrode rinse solution, the flow rate of concentrate and electrode rinse solution in order to find the optimum operating condition. As a result, we obtained $250A/m^2$ of current density, 2 N $H_2SO_4$ of concentration of electrode rinse solution, 30 mL/min of flow rate of concentrate and electrode rinse solution as the best operating conditions. We performed the scale-up experiments on the basis of ion exchange and electrodialysis experiments. And we obtained the experimental result that exchange capacity of S 1467 was 1.88 eq/L resin, and regeneration efficiency was 93.7% in the ion exchange scale-up experiment, we also got the result that concentration and dilution efficiency increased, and current efficiency kept constant in the scale-up experiments.