• Title/Summary/Keyword: 이온저장

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Ionic Liquids as a SO2 Absorption Media (이온성액체 기반 SO2 흡수제 개발 동향)

  • Choi, Ji-Shik;Johari, Suzaimi;Lee, Sang-Deuk;Lee, Hyun-Joo
    • Clean Technology
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    • v.18 no.1
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    • pp.22-30
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    • 2012
  • Separation of $SO_2$ from the flue gases of fossil fuel power plants are important issue because of its strong environmental impact. Industrially, $SO_2$ is being removed with a slurry of limestone, lime or aqueous caustic soda. However, these scrubbing processes possess several drawbacks such as the generation of huge amount of wastewater and the production of metal salts. Recently, ionic liquids have gained increasing interest as an absorbent for acid gas, $CO_2$ and $SO_2$. In this review, we have introduced the recent progress of ionic liquids as a $SO_2$ absorbent.

A Study on the Rainwater Quality Monitoring and the Improvement, Collection and Storage System (빗물 집수 및 저장 시스템 개선과 수질 분석 모니터링)

  • Kim, Chul-Kyung
    • Clean Technology
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    • v.17 no.4
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    • pp.353-362
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    • 2011
  • In our nature, the utilization of rainwater is essential for healthy water recirculation. This is one of the solutions of the increment of impermeability surface according to the development of new cities; this study of the improvement of rainwater quality has been carried on through the improvement of collecting and restoring system of rainwater. The southwestern region of Daejeon City, the rainwater coefficient of run off was 0.40 and this number had computed to 0.59 after the development. After filtration of rainwater, the heavy metal (Cu, As, Cr, Fe, Mn) contents level were lower than underground water. Moreover, collected rainwater showed better quality than underground water in following criteria; hardness, permanganate consumption quality, chloride, evaporation residue, sulfates and nitrate nitrogen. This water quality met the gray water quality standards. The rainwater quality was still suitable to use as bathroom flushing and gardening after 100 days of storage. This study proved that modification (installation of cover with gutter to existing rainwater collection system, proper filtering, and installation of underground storage tank) of collection system could improve quality of water and maintain this approximately 100 days.

Trends in safety improvement technologies for an electric propulsion system of eco-friendly ships (친환경 선박용 전기추진시스템 안전성 향상 기술개발 동향)

  • Kim, Sehwan;Choi, Gilsu;Lee, Jae Suk
    • Journal of IKEEE
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    • v.25 no.3
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    • pp.556-564
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    • 2021
  • This paper presents trends of safety improvement technologies for an electric propulsion system of eco-friendly ships. As an effort to reduce a green house effect, demands for eco-friendly ships have been increased. An energy storage system (ESS) is one of key systems in an eco-friendly ship and a lithium-ion battery generally used in an ESS system due to its high power density and efficiency. However, a lithium-ion battery is considered as one of reasons for ESS fire hazard. Since a fire extinguishing facility is especially limited in the ocean, safety issue in an eco-friendly ship is important. In this paper, recent safety improvement technologies for traction motors, ESS batteries and structures for eco-friendly ships are presented.

Stabilization Performance Evaluation of Filter(pH) Using Ionic Water Generator (이온수기 필터(pH)의 안정화 성능평가)

  • Nam, Sangyep;Kwon, Yunjung
    • Journal of the Institute of Electronics and Information Engineers
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    • v.52 no.3
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    • pp.199-205
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    • 2015
  • This study is about ionic water generator filter Recently, a lot of people feel deep interest in health and drinking water. And there are various types of water. Ionic water generator is a system with special function, and can be classified as a medical device and should be manufactured after approval from the Food and Drug Administration. Basically ionized water is different from the packaged and stored water. When the tap water or ground water passes through the various filters of ionic water generator, it turns to the purified water of pH7 ~ 7.5 and we can electrolyze that water into anion and cation by diaphragm. And in negative electrode side, we can get alkaline water with calcium ($Ca^+$), potassium ($K^+$), magnesium ($Mg^+$), sodium ($Na^+$) for body. In general, we can change pH value from 5 to 9 of ionizer by controlling the level of electrolysis voltage in the ionizer. In general, 1stage (pH8), 2stage (pH8.5), 3stage (pH9), 4stage (pH9.5) are used as the alkaline ionized water, -1Stage (pH6.0), -2 stage (pH5.0) are used as the acidic water. But in early stage, the water that passed through filter was weakly alkaline water and that was problem. Therefore, when filter condition is stable, the pH and ORP value of water is different with the early one. the initial setting pH value of the ionizer was confirmed that changes significantly. In order to resolve this problem we need to wash filter for some period time and neutralize by acidification treatment of the filter.

Mineral extraction from by-products of brown rice using electrodialysis and production of mineral salt containing lower sodium (전기투석을 이용한 현미부산물로부터의 미네랄성분 추출 및 나트륨감량형 미네랄 소금 제조)

  • No, Nam-Doo;Park, Eun-Jung;Kim, Mi-Lim
    • Food Science and Preservation
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    • v.22 no.6
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    • pp.859-866
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    • 2015
  • The purpose of this study was to develop a supplemental healthy food that can help prevent high blood pressure-related diseases caused due to the excessive consumption of sodium in salt. This was achieved by using ion-displacement techniques to produce mineral salt with lower sodium content by using fermented brown rice by-products rich in minerals. Mineral salt containing 2019.2 mg/100 g of potassium, 678.5 mg/100 g of magnesium, 48.7 mg/100 g of calcium, and 19.5 mg/100 g of sodium was obtained by fermenting brown rice by-products to create a culture medium for the mineral salt. Mineral salt containing 1769.7 mg/100 g of potassium, 573.6 mg/100 g of magnesium, 35.3 mg/100 g of calcium, and 19.5 mg/100 g of sodium was obtained by filtering and refining the by-product extract of fermented brown rice. The results showed that when the stream velocity of the instrument used for electrolysis was 200 mL/min and the current and the concentration of the reactive liquid in the purified water chamber were higher, the effect of electrolysis was greater. Ion hot water extraction of the fermented brown rice by-products improved by up to 95% and was collected as purified water within 90 min of the reaction time. Chloride ions with pH 7.4 were produced by mixing sodium hydroxide in a purified saline water chamber with electro-analyzed water. The salt produced in this study contained low sodium, 5.7~30%, as compared to 40% sodium content of the normal salt.

High Energy Density Germanium Anodes for Next Generation Lithium Ion Batteries (다음세대 리튬이온 배터리용 고에너지 밀도 게르마늄 음극)

  • Ocon, Joey D.;Lee, Jae Kwang;Lee, Jaeyoung
    • Applied Chemistry for Engineering
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    • v.25 no.1
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    • pp.1-13
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    • 2014
  • Lithium ion batteries (LIBs) are the state-of-the-art technology among electrochemical energy storage and conversion cells, and are still considered the most attractive class of battery in the future due to their high specific energy density, high efficiency, and long cycle life. Rapid development of power-hungry commercial electronics and large-scale energy storage applications (e.g. off-peak electrical energy storage), however, requires novel anode materials that have higher energy densities to replace conventional graphite electrodes. Germanium (Ge) and silicon (Si) are thought to be ideal prospect candidates for next generation LIB anodes due to their extremely high theoretical energy capacities. For instance, Ge offers relatively lower volume change during cycling, better Li insertion/extraction kinetics, and higher electronic conductivity than Si. In this focused review, we briefly describe the basic concepts of LIBs and then look at the characteristics of ideal anode materials that can provide greatly improved electrochemical performance, including high capacity, better cycling behavior, and rate capability. We then discuss how, in the future, Ge anode materials (Ge and Ge oxides, Ge-carbon composites, and other Ge-based composites) could increase the capacity of today's Li batteries. In recent years, considerable efforts have been made to fulfill the requirements of excellent anode materials, especially using these materials at the nanoscale. This article shall serve as a handy reference, as well as starting point, for future research related to high capacity LIB anodes, especially based on semiconductor Ge and Si.

Studies on the Sorption and Fixation of Cesium by Vermiculite (II)

  • Lee, Sang-Hoon
    • Nuclear Engineering and Technology
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    • v.6 no.2
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    • pp.97-111
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    • 1974
  • The adsorption mechanism of Cs-137 in low level radioactive solution by vermiculite treated with Na ion is studied in order to investigate its effective utilization for the radioactive effluent treatment. The beneficial role of Na-vermiculite is that Na ion can induce the wider c-axis spacing in which Cs ion can be sorbed in vermiculite. Cation exchange capacity and distribution coefficient of cesium seems to be influenced by the variation of c-axis spacing of vermiculite. Comparative identification and detection with the characteristic analyses of X-ray diffraction and electron diffraction patterns, diffrential thermal analysis and electron microscopy of Na-, K- and Cs-vermiculite are studied for the phemomena of Cs adsorption by vermiculite. This importance of the utilization in terms of adsorption and fixation of cesium involving vermiculite is discussed. It is found that the Na-vermiculite is valuable outside charging material for high level radioactive liquid waste storage tank of underground to protect the pollution of the underground water.

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Analysis of Water Purification Capability of the Spent Fuel Storage Pool Using Consolidated Fuel Storage in Uljin 1&2 (조밀화 핵연료 집합체 저장에 의한 울진 1&2호기의 사용후 핵연료 저장조 정화능력 해석)

  • Lim, Chae-Joon;Park, Goon-Cherl;Chung, Chang-Hyun
    • Nuclear Engineering and Technology
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    • v.22 no.2
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    • pp.83-94
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    • 1990
  • The radioactivity in the spent fuel storage pool is calculated to ensure to maintain its concentration below the permissible limit, when the storage capacity of Uljin nuclear power plant unit 1&2 is extended from 9/3 to 32/3 core using consolidated fuels in maximum density rack (MDR). For this evalulation, two models to calculate the spent fuel pool activities on the continuous and intermittent operating its purification system are developed and these results compared, The results of above two cases show that the current water purification system can not guarantee the radioactivity concentration below the design limit, 5$\times$10$^{-4}$ $\mu$Ci/ml, for the extention to 32/3 core. Therefore, it has been concluded that a modification of the current purification system is necessary to extend the spent fuel storage capacity with the above method. The alternative way suggested in this study is to increase the number of cation bed demineralizers.

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PE 첨가에 의한 방사성폐수지 아스팔트고화체의 특성연구

  • 김태국;손종식;김길정;안섬진;정인하
    • Proceedings of the Korean Nuclear Society Conference
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    • 1998.05b
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    • pp.385-390
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    • 1998
  • 방사성 페이온교환수지 아스팔트고화체를 처분장 등지에서 장기간 저장시 안전성 확보를 위하여 물리적 강도가 높고 고화체내에서 방사성핵종의 침출저항성 및 처리시 감용의 효과가 우수한 고화체 연구가 필요하게 되었다. 실험에 사용된 이온교환수지는 입상형 양이온 교환수지를 대상으로 하였으며 고화매질로서는 도로포장용으로 생산되는 직류아스팔트 60/70을 사용하였다. 고화보조제는 방사성 고체패기물 포장시 사용되어 폐기물로 발생되는 페폴리에틸렌(폐PE) 필름을 사용하였다. 실험결과 고화체의 형태안정성은 PE 함유량이 10 wt% 이상일 때 고화체 형태를 그대로 유지할 수 있으며 압축강도는 414 kPa(60 psi) 이상을 나타내었다. 최적의 운전조건은 이온교환수지, PE 함유량이 건조기준으로 각각 30~50 wt%, 10~25 wt% 이며, 고화온도는 170~20$0^{\circ}C$이다. 고화체의 침출특성은 확산 (diffusion) 으로 해석이 가능하며, 유효확산계수(De)는 Cs, Co의 경우 각각 1.621$\times$$10^{-7}$, 1.186$\times$$10^{-9}$ $\textrm{cm}^2$/day로 나타나고, Leachablity index는 각각 11.7, 13.8로 미국 원자력위원회 (NRC)가 요구하는 기준값 6보다 훨씬 높게 나타났다.

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Characterization of a TSV sputtering equipment by numerical modeling (수치 모델을 이용한 TSV 스퍼터링 장비의 특성 해석)

  • Ju, Jeong-Hun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.46-46
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    • 2018
  • 메모리 소자의 수요가 데스크톱 컴퓨터의 정체와 모바일 기기의 폭발적인 증가로 NAND flash 메모리의 고집적화로 이어져서 3차원 집적 기술의 고도화가 중요한 요소가 되고 있다. 1 mm 정도의 얇은 웨이퍼 상에 만들어지는 메모리 소자는 실제 두께는 몇 마이크로미터 되지 않는다. 수직방향으로 여러 장의 웨이퍼를 연결하면 폭 방향으로 이미 거의 한계에 도달해있는 크기 축소(shrinking) 기술에 의지 하지 않고서도 메모리 소자의 용량을 증대 시킬 수 있다. CPU, AP등의 논리 연산 소자의 경우에는 발열 문제로 3D stacking 기술의 구현이 쉽지 않지만 메모리 소자의 경우에는 저 전력화를 통해서 실용화가 시작되었다. 스마트폰, 휴대용 보조 저장 매체(USB memory, SSD)등에 수 십 GB의 용량이 보편적인 현재, FEOL, BEOL 기술을 모두 가지고 있는 국내의 반도체 소자 업체들은 자연스럽게 TSV 기술과 이에 필요한 장비의 개발에 관심을 가지게 되었다. 특히 이 중 TSV용 스퍼터링 장치는 transistor의 main contact 공정에 전 세계 시장의 90% 이상을 점유하고 있는 글로벌 업체의 경우에도 완전히 만족스러운 장비를 공급하지는 못하고 있는 상태여서 연구 개발의 적절한 시기이다. 기본 개념은 일반적인 마그네트론 스퍼터링이 중성 입자를 타겟 표면에서 발생시키는데 이를 다시 추가적인 전력 공급으로 전자 - 중성 충돌로 인한 이온화 과정을 추가하고 여기서 발생된 타겟 이온들을 웨이퍼의 표면에 최대한 수직 방향으로 입사시키려는 노력이 핵심이다. 본 발표에서는 고전력 이온화 스퍼터링 시스템의 자기장 해석, 냉각 효율 해석, 멀티 모듈 회전 자석 음극에 대한 동역학적 분석 결과를 발표한다. 그림1에는 이중 회전 모듈에 대한 다물체 동역학 해석을 Adams s/w package로 해석하기 위하여 작성한 모델이고 그림2는 180도 회전한 서브 모듈의 위상이 음극 냉각에 미치는 효과를 CFD-ACE+로 유동 해석한 결과를 나타내고 있다.

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