• Title/Summary/Keyword: 이온성 인

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Thermal analysis and estimation of high power 18650 lithium ion battery under varying current condition (고출력 18650 리튬이온 배터리의 가변전류 열해석 및 추정)

  • Kang, Taewoo;Yoo, Kisoo;Lee, Pyeong-Yeon;Kim, Jonghoon
    • Proceedings of the KIPE Conference
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    • 2019.07a
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    • pp.424-425
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    • 2019
  • 본 논문은 1차 RC 등가회로를 이용하여 리튬이온 배터리의 저항성 발열인 비가역 발열의 파라미터를 제시하였다. 발열 추정을 위해 1 C-rate에서 HPPC(Hybrid Pulse Power Characterization) 실험을 통하여 비가역 발열의 파라미터인 SOC 5%별 내부 저항을 추출하였다. 추출된 SOC 5%별 저항을 이용하여 1C-rate에서 3C-rate로 변화하는 조건에서 열 추정 성능을 확인하였다. 높은 C-rate로 방전 전류가 변화하는 상황에서 발열 시뮬레이션과 실험값을 비교하였으며, 1C-rate의 HPPC 실험에서 얻어진 내부 저항이 부하의 변동에 따른 리튬이온 배터리의 발열 추정 파라미터로써 사용될 수 있음을 검증하였다.

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Electro-electrodialysis Using the Radiation-treated Cation Exchange Membrane by Accelerated Electron Radiation to Concentrate HI from HIx Solution (전자선 가속기에 의해 방사선 처리한 양이온교환막을 이용한 전해-전기투석에 의한 HIx용액으로부터 HI의 농축)

  • Hwang, Gab-Jin;Kim, Jeong-Keun;Lee, Sang-Ho;Choi, Ho-Sang
    • Membrane Journal
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    • v.17 no.4
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    • pp.338-344
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    • 2007
  • Electro-electrodialysis of hydriodic acid with HI molality of ca. 9.5 $mol/kg-H_2O$ was examined in the presence of iodine using a commercial cation exchange membrane, CMB, as a separator. For the increase of the selectivity of proton permeation, the membrane was radiation-treated by accelerated electron radiation. The membrane properties (area resistance, ion exchange capacity, water content) of the radiation-treated membranes were measured. The area resistance in 2 $mol/dm^3$ KCl solution, ion exchange capacity and water content of the radiation-treated membranes at each dose rate dad almost the same value as that of the non-treated membrane (original of CMB membrane). Electro-electrodialysis of hydriodic acid with HI molality of ca. 9.5 $mol/kg-H_2O$ was examined at $75^{\circ}C$ with 9.6 $A/dm^2$. The radiation-treated cation exchange membrane by accelerated electron radiation had higher selectivity of the proton permeation by cross-linking structure of polymer than that of the non-treated membrane.

The PWM Control Which used Microprocessor for Intensity Control of Acid Ion Water (산성이온수 농도제어를 위한 Microprocessor를 이용한 PWM 제어)

  • Kwon, Yunjung;Nam, Sangyep
    • Journal of the Institute of Electronics and Information Engineers
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    • v.50 no.7
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    • pp.269-274
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    • 2013
  • We are used with the alkaline ion water which an application field does to object for drinking water compare with the alkaline ion water which asked ion acid electrolysis so as to be very different. This is used with sterilization disinfection use by residual chlorine in case of strong acidity according to ph intensity, and in case of middle acidity use by washing and face washing, and mix with meal materials in case of weak acidity widely usable in cooking. Acid ion water generates as we electrolyze water. Chlorine gas and sodium hydroxide etc. was generated at electrolysis process, and we have toward sterilizing power. Derelicts such as chlorine, phosphorus, sulfur etc. are gathered from a negative ion, and we make acid ion water to + electrode direction in electrolysis. We used a diaphragm in order to disconnect too acid water and alkaline water. We implemented so that the acid water which it came down to three kinds of PWM voltage to PWM (pulse width modulation) control, and implementation method of ph intensity change authorized ph intensity between weak acidity to electrode in strong acidity as we used Microprocessor, and intensity was adjusted successively by PWM control was generated.

Effects of Metal Ion Mole Ratio and Calcination Temperatures on Magnetic Properties and Microstructure of Ba2Co2Fe12O22 Powders Synthesized by Solid State Reaction (고상반응법으로 제조된 Ba2Co2Fe12O22분말의 자기적 성질과 미세구조에 미치는 금속이온몰비와 열처리 온도의 영향)

  • Cho, Kwang-Muk;Nam, In-Tak
    • Journal of the Korean Magnetics Society
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    • v.19 no.6
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    • pp.216-221
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    • 2009
  • Y-type barium ferrite $Ba_2Co_2Fe_{12}O_{22}$ was synthesized by a solid state reaction method. Effects of metal ion mole ratio and calcination temperatures on magnetic properties and microstructures of the synthesized powders were investigated. Phase analysis and microstructure observation were performed with a XRD (X-ray diffractometer) and a FESEM (field effect scanning electron microscope), respectively. Magnetic properties of the powders were measured with a VSM (vibrating sample magnetometer). Single phase Y-type was synthesized when metal ion mole fraction $Fe^{3+}:\;Ba^{2+}:\;Co^{2+}$ was 6 : 1 : 1 and calcination temperature was $1050\;{^{\circ}C}$. High saturation magnetization value of 39.1 emu/g was obtained when metal ion mole fraction $Fe^{3+}:\;Ba^{2+}:\;Co^{2+}$ was 8 : 1 : 1 and calcination temperature was $1200\;{^{\circ}C}$.

Effects of Drinking Ion Water on Performance, Egg Quality and Blood Biochemical Composition of Laying Hens under High Temperature Conditions (고온환경에서 이온수의 급수가 산란계의 생산성, 계란 품질 및 혈액성상에 미치는 영향)

  • Lim, Chun Ik;Rana, Md Masud;Li, Hong Long;Cho, Tae Hyun;Ryu, Kyeong Seon
    • Korean Journal of Poultry Science
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    • v.47 no.3
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    • pp.121-126
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    • 2020
  • This study was conducted to investigate the effect of drinking ion water on the performance, egg quality, and serum biochemical properties of laying hens in a high-temperature environment. A total of 180 laying hens with equal egg production rates were randomly divided into three treatments with five replicates. Treatments were applied from 24 to 27 weeks of age and included the supply of ion water (IW), tap water (TW), and cold water (CW). The results showed that the egg production rate, egg weight, and feed intake of hens were significantly (P<0.01) improved in the IW group compared with those in the TW group but did not differ from those in the CW group. Egg quality parameters such as albumen height, Haugh unit, and eggshell thickness were found to be higher in the IW than in the TW group (P<0.05); however, no significant differences were observed in comparison with the CW group. Serum Ca and P concentrations tended to increase (P<0.10) in the IW group, and serum high-density lipoprotein cholesterol and albumin levels were greater (P<0.05) in response to IW than those to TW. This study provides evidence that the supply of IW can relieve the high-temperature stress during the summer. In particular, because the improved effects of the IW were confirmed to be similar to those of CW, it shows potential as a method to manage the drinking water of hens in the summer season along with the supply of CW.

Synthesis of Biodiesel from Soybean Oil Using Lewis Acidic Ionic Liquids Containing Metal Chloride Salts (금속염화물을 첨가한 루이스산 이온성 액체 촉매를 이용한 대두유로부터 바이오디젤 합성)

  • Choi, Jae Hyung;Park, Yong Beom;Lee, Suk Hee;Cheon, Jae Kee;Choi, Jae Wook;Woo, Hee Chul
    • Korean Chemical Engineering Research
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    • v.48 no.5
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    • pp.643-648
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    • 2010
  • Production of biodiesel from soybean oil catalyzed by Lewis acidic ionic liquids(ILs) containing metal chloride salts was investigated in this study. Metal chloride salts, such as $SnCl_2$, $ZnCl_2$, $AlCl_3$, $FeCl_3$ and CuCl, were screened for oil transesterification in the range of 363-423 K. Among these metal chlorides, tin chloride showed particularly high catalytic property for the oil transesterification. Similarly, among these Lewis acidic ionic liquid catalysts, $[Me_3NC_2H_4OH]Cl-2SnCl_2$ resulted in a high fatty acid methyl esters(FAMEs) content of 91.1% under the following reaction conditions: 403 K, 14 h, and a molar ratio of 1:12:0.9 (oil:methanol:catalyst). Unlike the pure tin chloride catalysts, Lewis acidic ILs containing tin chloride $[Me_3NC_2H_4OH]Cl-2SnCl_2$ catalyst could be recycled up to five times without any significant loss of activity by separating from the FAMEs with simple decantation. The Lewis acidity and high moisture-stability of this catalyst appeared to be responsible for the excellent catalytic performance. The effects of reaction time and the molar ratio of methanol/catalyst to oil on the FAMEs production were also studied in this work.

A Study on the Reduction of COD, Total Phosphorus and Nitrogen in Wastewater by Electrolysis and HClO Treatment (전기화학처리와 HClO 처리를 통한 폐수중 COD, 총인, 총질소의 저감에 대한 연구)

  • Kim, Tae Kyeong;Song, Ju Yeong
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.3
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    • pp.436-442
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    • 2017
  • This study was conducted to develop a wastewater treatment system to remove organic matter, nitrate nitrogen, and phosphate ion in synthetic wastewater. COD was removed almost 100% by the oxidation reaction of HClO and nitrate nitrogen was reduced to ammonia by electrolysis treatment, but ammonia was reoxidized into nitrate nitrogen by HClO treatment. Ammonia was removed almost 100% by heating evaporation and no ammonia was reoxidized into nitrate by HClO treatment. Phosphate ion could be removed by precipitation treatment by forming metal complex according to pH. Through electrolysis treatment and HClO treatment, removal efficiencies of COD 99.5%, nitrogen 97.3% and phosphorus 91.5% were obtained.

Coagulation of Synthetic Reactive Dye Wastewater by Cyanoguanidine-formaldehyde Resin (Cyanoguanidine-formaldehyde Resin에 의한 반응성 염료 응집 특성)

  • Nah, In Wook;Jin, Yang Oh;Hwang, Kyung Yub
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.12
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    • pp.2135-2139
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    • 2000
  • The coagulation of anionic colloidal particles by the cyanoguanidine(CG)-formaldehyde resin has been reported to be caused by an electrostatic interaction of the diaminomethylene urea (DU) cation with an anionic surface charge of particles. In this research, 100~500 nm sized cationic cyanoguanidine-formaldehyde resin was synthesized to coagulate anionic dye wastewater, and the results showed that the less pH of aqueous cyanoguanidine-formaldehyde resin solution was, the higher Zeta potential of that was. In case of coagulating 0.4 g/L reactive dye by cyanoguanidine-formaldehyde resin at pH 3, 5, 7, 9, and 11, COD removal and the percent decolorization of synthetic dye wastewater at pH 3 are higher than those of other pH conditions. The COD removal and the percent decolorization of synthetic dye wastewater were 74% and 90% at 400 ppm, pH 3.

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Diffusion Characteristics of Chloride ion under Single and Combined Attacks in Concrete Structures (콘크리트 구조물의 단일 및 복합열화 환경하에서의 염소이온 확산특성)

  • 오병환;강의영;인광진;이성규;서정문
    • Journal of the Korea Concrete Institute
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    • v.14 no.5
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    • pp.708-717
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    • 2002
  • Durability is a major concern in the design and construction of concrete structures which are located in the sea environments. In particular, the combined action of chlorides, sulfates, and carbonation nay influence greatly the deterioration behavior of concrete structures. The purpose of the present study is to explore the diffusion characteristics of chloride ions in concrete structures under combined deterioration conditions. The present test results indicate that the chloride penetration into concrete structures is more pronounced under combined attacks of chlorides, sulfates and carbonation. The diffusion coefficients and surface chloride contents were found to increase under combined multiple deterioration conditions. The present study provides quantitatively the penetration and diffusion characteristics of chloride ions in concrete structures under various deterioration conditions. The results of present study may be efficiently used for the realistic design of concrete structures under combined deterioration conditions.

A Study on the Tungstate-Sensing Electrodes (Tungstate Ion 감응 전극에 관한 연구)

  • Gwon-Shik Ihn;Jung-hwa Lee;R. P. Buck
    • Journal of the Korean Chemical Society
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    • v.27 no.2
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    • pp.111-116
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    • 1983
  • Three component $Ag_2S-PbS-PbWO_4$ electrodes have been prepared and evaluated for sensitivity to tungstate. The 51.71 : 16.64 : 31.65(w/w%) composition is superior in terms of potentiometric response, stability, rapidity of response and reproducibility. Testing was done over the concentration range $10^{-1}~10^{-4}M WO_4^{2-}$ in $0.1F-NH_4Ac-NH_4OH$ buffer at pH 8.00 with constant ionic strength. The quality of response is similar to that of corresponding phosphate-sensing electrode. Many common ions interfere.

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