• Title/Summary/Keyword: 이온강도

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The Strength Estimation of Precast Concrete Products by the Chloride Ion Penetration Test (염소이온 투과시험에 의한 콘크리트 제품의 강도 추정)

  • 장문기
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.41 no.6
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    • pp.82-89
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    • 1999
  • This paper present the strength estimation of precast concrete products by chloride ion penetration method. The relation between the strength of precast concrete product and the ion passing charge is linear and a numerical model of FCK =515.96-0.201Q is prposed. The results showe good agreement at about 9.0% error ration with the estimated model results for real precast concrete product.

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Material Characteristics of High-Strength Concrete Incorporating High Replacement Level of Blast-Furnace Slag (고로슬래그를 다량 함유한 고강도 콘크리트의 재료적 특성)

  • Lee, Hoi-Keun;Jung, Jae-Hong;Kim, Han-Joon;Lee, Seung-Hoon
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.291-292
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    • 2010
  • In this study, high-strength concrete mixtures were made with blast-furnace slag of 50% and 70% replacement level to evaluate material properties including compressive strength development, adiabatic temperature rise, autogenous shrinkage and chloride-ion migration coefficient. Test results showed that the use of high percentage blast-furnace slag in high-strength concrete can reduce heat of hydration and chloride-ion migration coefficient, result in control thermal cracking and improve durability performance especially under high corrosive environment.

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Ionic Equilibria in $ZnSO_4-Na_2SO_4-H_2SO_4-NaOH-H_2O$ System ($ZnSO_4-Na_2SO_4-H_2SO_4-NaOH-H_2O$계의 이온 평형)

  • 이만승;박현주;나춘기
    • Resources Recycling
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    • v.11 no.1
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    • pp.19-25
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    • 2002
  • For $ZnSO_4$-$Na_2$$SO_4$-$H_2$ $SO_4$-$NaOH-H_2$O system, pH of solutions with different electrolyte concentrations was measured at $25^{\circ}C$ and ionic equilibria were analyzed by using K-value method. Activity of water and activity coefficients of solutes were calculated by Pitzer equation. The equilibrium concentration and activity coefficients of solutes were calculated from initial experimental conditions. At high ionic strength of 4m, the pH values calculated were in good agreement with those measured. In the experimental ranges of ionic strength of solution from 3.5 to 4.3 m, the mean activity coefcient of $ZnSO_4$calculated agreed well with those obtained from literature.

Preparation and Properties of Heterogeneous Cation Exchange Membrane for Recovery of Ammonium Ion from Waste Water (폐수중 암모늄 이온 회수를 위한 불균질 양이온교환막의 제조 및 특성)

  • Jeong, Boo-Young;Song, Sang-Hun;Baek, Ki-Wan;Cho, In-Hee;Hwang, Taek-Sung
    • Polymer(Korea)
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    • v.30 no.6
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    • pp.486-491
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    • 2006
  • Heterogeneous membranes were prepared by compression molding for the recovery of ammonium ion from waste water. Degree of sulfonation for sulfonated ion exchange resin increased with increasing amount of chlorosulfonic acid. It was 3.32 meq/g at 10 vol%. The tensile strength and elongation of the heterogeneous membrane was decreased with increasing contents of ion exchange resin. The tensile strength for LLDPE matrix membrane was the highest and also the elongation for EVA matrix membranes were the highest. The water content of heterogeneous membrane was increased with increasing contents of ion exchange resin. The maximum value of transport number for PE matrix membrane was 0.973. The electrical resistance of LLDPE matrix membrane was the lowest. It was value of $10.36{\Omega}/cm^2$ at 70 wt% resins.

The Configuration and Polyelectrolyte Behavior of Carboxymethyl Chitin in Low Concentration Solution (저농도 용액에서의 Carboxymethyl Chitin의 사슬배좌와 전해질 거동)

  • PARK Seong-Min;LEE Keun-Tae;KIM Sang-Moo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.28 no.4
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    • pp.451-456
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    • 1995
  • To elucidate the intrinsic rheological properties of carboxymethyl chitin (CM-chitin) from the shell of red snow cyab (Chinonecetes japonicus), the configuration and polyelectrolyte behavior of CM-chitin in low concentration solution were investigated. Unperturbed dimensions were ranged from $127{\AA}\;to\;113{\AA}$ as root mean square end-to-end distance$(r_0)$, $52{\AA}$ to $46{\AA}$ as radius of gyration$(S_0)$. The intramolecular expansion tarter(a) was not varied with molecular weight and was 2.1. And effective bond length $(b_0)$ was $14.5{\AA}$. In perturbed condition, Flory constant was $2.35\times10^{21}$. When ionic strength were 0.02 and 1.0, intrinsic viscosity were 1.95dl/g and 1,06 dl/g, respectively. These results suggested that CM-chitin is a polyelectrolyte in aqueous media. At infinite ionic strength, intrinsic viscosity was 0.91dl/g. The intrinsic stiffness of CM-chitin backbone was estimated by evaluating the stiffness parameter (B) as 0.11 and agreed well with the results of k-carrageenan.

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Numerical Analysis of High-Order Harmonic Generation in Alkalic Metal Ions (알칼리 금속 이온에서의 고차고조파발생에 대한 수치해석)

  • 김규욱;김용평
    • Korean Journal of Optics and Photonics
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    • v.6 no.1
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    • pp.39-44
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    • 1995
  • 3차원 .delta.-potential을 가진 원자 모델을 이용하여 Nd:YAG(1064nm), Ti:sapphire(806nm), 색소(616nm), XeCl(308nm) 레이저를 기본파로 하고, 1차 이온화된 K/sup +/, Na/sup +/, Li/sup +/ 등의 알칼리 금속 이온을 비선형 매질로 할 때 고차고조파 분포를 수치적으로 해석하였다. 계산 결과 고차고조파 발생에서 특징적으로 나타나는 plateau는 비선형 매질의 이온화 에너지가 클수록, 기본파의 파장이 길수록 높은 차수에서 폭넓게 나타나고, 그 강도는 감소한다.

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Optical properties of Rare-Earth-Implanted GaN Epilayer (희토류 원소를 이온주입법으로 도핑한 GaN 박막의 광전이 특성)

  • Kim, Yong-Min
    • Journal of the Korean Vacuum Society
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    • v.16 no.3
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    • pp.210-214
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    • 2007
  • We have studied optical transitions of Gd-implanted GaN epilayers. Photoluminescence transition intensity at 590 nm at T=5 K diminishes and its center position moves to short avelength (blue shift) with increasing temperature up to 200 K. Above T=200 K, the transition intensity increases with increasing temperature while the center position remains the same. We believe that such anomalous optical transition behavior is due to the effect of rare-element in the semiconductor host material and lattice imperfection which was occurred during the implantation process well as.

Prediction of Organic Acid Chromatogram in High Performance Ion Chromatography (고성능 이온 크로마토그래피에서 유기산의 크로마토그램 예측 연구)

  • 원혜진;한선호;박양순;조기수;김인호
    • KSBB Journal
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    • v.15 no.1
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    • pp.60-65
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    • 2000
  • In order to predict the chromatogram for organic acid in ion chromatography, Langmuir isotherm parameters were obtained by Retention Time Method (RTM) and moment method. Ion chromatography analysis for formic acid was performed and compared with theoretically predicted profiles under isocratic condition. Band profiles were estimated with the equilibrium-dispersive model of chromatography using a PDEsolver Macsyma . The relationship between the characteristics of chromatogram and the variable operating condition in chromatography such as the flow rate, ionic strength and injection volume was studied. Satisfactory agreement was observed between the experimental and the estimated chromatograms with parameters obtained form the moment method.

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Effect of pH and ionic strength on the removal of radionuclide by Na-mica (pH와 이온강도가 나트륨-운모를 이용한 방사성 핵종 흡착제거에 미치는 영향)

  • Seol, Bitna;Cho, Yunchul
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.1
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    • pp.83-89
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    • 2014
  • The aim of this study is to investigate the sorption/ion exchange of radioactive nuclides such as $Cs^+$ and $Sr^{2+}$ by synthetic Na-micas. In order to prepare Na-micas, two natural micas (phlogopite and biotite) were used as precursor materials. XRD, SEM, and EDS analyses were used to examine material characterization of synthetic Na-micas. Analyses of materials revealed that Na-micas were successfully obtained from natrual micas by K removal treatment. On the other hand, single solute (Cs or Sr) and bi-solute (Cs/Sr) sorption experiments were carried out to determine sorption capacity of Na-micas for Cs and Sr under different pH and ionic strength conditions. Uptake of Cs and Sr by micas in bi-solute system was lower than in single-solute system. Additionally, Langmuir and Langmuir competitive models were applied to describe sorption isotherm of Na-micas. bi-solute system was well described by Langmuir competitive models. For the results obtained in this study, Na-micas could be promising sorbents to treat multi-radioactive species from water and groundwater.

The Chloride Ion Diffusion Characteristics of High Performance Lightweight Concrete Using Metakaolin (메타카올린을 사용한 고성능 경량 콘크리트의 염소이온 확산 특성)

  • Lee, Changsoo;Kim, Youngook;Nam, Changsik
    • Journal of the Society of Disaster Information
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    • v.7 no.1
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    • pp.21-31
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    • 2011
  • The objectives of this study is replaced Silicafume with Metakaolin that is used to lightweight concrete to better performance. So, this study made high-performance lightweight concrete using Metakaolin and characteristics of the fundamental properties and chloride ion diffusion. Consequently, it is compressive strength and chloride ion penetration resistance is lower than lightweight concrete using Silicafume, the performance of compressive strength contrast Silicafume is about 88 to 95%. Also, this study got a content result because the chloride ion penetration resistance showed the performance in around 80 to 90%. As a result, this study insist that replacement ratio of Metakaolin is suitable for 10 to 15%.Silicafume and Metakaolin have similar characteristics. In addition, it is similar to the performance of alternative materials is possible.