• Title/Summary/Keyword: 이온강도

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The Study on the Strengthening of $Li_2O-AI_2O_3-SiO_2$ Glass-Ceramics by Ion Exchange (LAS계 결정화유리의 화학적강화에 관한 연구)

  • Jang, Pil-Sun;Gang, Won-Ho
    • Korean Journal of Materials Research
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    • v.6 no.4
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    • pp.364-371
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    • 1996
  • 본 연구는 이온교환에 의한 Li2O-AI2O3 계 결정화유리의 강화에 관한 연구이다. 모유리의 이온교환 전후의 강도를 비교하였으며, 결정화유리의 결정화전후에 이온교환에 따르는 강도를 상호 비교하였다. 그 결과 모유리의 Na+이온교환에 따른 최대 강도값은 45$0^{\circ}C$-3hr의 열처리 조건하에서 최고 6배(60Kg/mm2)의 강도값을 나타내었으며, 결정화후 이온교환에 따른 강도증가는 45$0^{\circ}C$-1hr의 열처리 조건하에서 최고 10배의 강도증대효과를 보였다. 한편 과도한 이온교환 열처리조건하에서는 응력이완현상을 나타냄을 알 수 있었다.

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Oxidation of Endocrine Disrupting Chemicals Using Sodium Persulfate (과황산나트륨을 이용한 내분비계장애물질 산화제거)

  • Lim, Chan Soo;Yun, Yeo Bog;Kim, Do Gun;Ko, Seok Oh
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.33 no.2
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    • pp.609-617
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    • 2013
  • The objective of this study was to evaluate the oxidation method to remove endocrine disrupting chemicals in reverse osmosis(RO) retentate for the reuse of wastewater effluent. Oxidation of organic pollutants was induced by the persulfate catalyzed by Fe(II). Affecting factors such as initial pH and ionic strength on the Fe(II) catalyzed persulfate oxidation were evaluated. $17{\alpha}$-ethynylestradiol (EE2) degradation efficiency decreased as pH and ionic strength increased. However, the efficiency increased as chloride ion concentration increased due to the influence of radical transfer.

Functionality of Extracted Proteins by Additives and Ionic Strength (첨가제의 종류와 이온강도에 따라 추출되는 육단백질의 기능적 특성)

  • Rhee, Min-Suk;Lee, Jun-Sup;Koh, Kyung-Chul;Kim, Young-Kyo;Kim, Byoung-Chul
    • Korean Journal of Food Science and Technology
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    • v.30 no.1
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    • pp.69-76
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    • 1998
  • This study was investigated to determine the effect of additives and ionic strength on the functionality of extracted proteins in preblends in order to use less additive in restructured meat products. Preblends contained the combinations of sodium chloride (NaCl; 0, 4.5, 9.0%), sodium tripolyphosphate (STPP; 0, 2.5, 5.0%), and tetrasodium pyrophosphate (PP; 0, 2.44, 4.88%). The pH values increased linearly with increasing STPP and PP concentrations (p<0.01). In the equivalent ionic strengths, PP was more effective than STPP in increasing pH. Phosphate ions were more effective on total extractable protein (used 1 M NaCl buffer) than chloride ion at equivalent ionic strengths. Solubility was decreased by adding NaCl and increasing total extractable proteins. Meat sulfhydryl contents were high with increasing total extractable proteins. When protein extracts were heated at $65^{\circ}C$, 7 min, meat sulfhydryl contents decreased and surface hydrophobicity increased (p<0.01). However, all protein extracts showed no differences in SDS-PAGE pattern. In conclusion, PP is more effective than STPP in order to use less additive but there was no linear relationship between functionnal improvement and ionic strength.

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레이저 변수가 마그네슘 원자의 다광자 이온화에 미치는 영향 연구

  • 김달우
    • Proceedings of the Optical Society of Korea Conference
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    • 1990.02a
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    • pp.185-189
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    • 1990
  • 고강도 레이저 장에서 마그네슘 원자의 다광자 이온화에 미치는 레이저 parameter의 영향을 Time-of-Flight spectrometer를 사용하여 분광학적 방법으로 연구하였다. 진공 챔버 속에서 파장 532nm와 1064nm인 레이저 펄스를 강도 1010-13W/'$ extrm{cm}^2$ 범위내에서 변화시키며 마그네슘 원자와 반응시켜서 Mg+ 및 Mg2+ 이온을 생성시켰으며 레이저의 파장, 강도 및 편광에 따른 광전자 스펙트럼을 구하였다. 또한, 전자 두 개를 방출하고 생성된 Mg2+ 이온의 발생 기구에 대하여 논하였다.

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무기 및 유기 응집제를 이용한 수중 휴믹산의 플럭특성

  • Heo, Mi-Ran;Lee, Min-Gyu;Gam, Sang-Gyu
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2005.11a
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    • pp.137-140
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    • 2005
  • Alum과 PDDA에 대하여 각각 휴믹산의 플럭 형성-파괴-재형성을 관찰 한 결과 sweep flocculation에 의해 휴믹 플럭을 형성하는 alum은 플럭의 파괴 및 재형성은 비가역적이이나 유기응집제인 PDDA 플럭의 파괴는 가역적이라는 것을 알 수 있었다. 그리고 플럭 강도지수 측정으로부터 PDDA는 alum보다 높은 강도를 가지는 것을 알 수 있었다. 그리고 플럭강도에 미치는 이온강도의 영향을 살펴 보면 alum은 플록강도에 미치는 영향이 거의 없었지만 유기응집제인 PDDA는 플럭 강도가 크게 감소함을 알 수 있었다.

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Adhesion and Release of Bacteria in Quartz and Iron-coated Sands: Effect of Ionic Strength (석영 및 철피복 모래에서 박테리아 부착.탈착: 이온강도의 영향)

  • Lee, Chang-Gu;Park, Seong-Jik;Kim, Hyon-Chong;Han, Yong-Un;Park, Jeong-Ann;Kim, Song-Bae
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.4
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    • pp.287-293
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    • 2009
  • This study investigated the influence of ionic strength on the adhesion and release of bacteria (Escherichia coli, Bacillus subtilis, and Staphylococcus aureus) in quartz and iron-coated sands using column experiments. Results show that the mass recovery remained constant (E. coli = 13.7${\pm}$0.5%, B. subtilis = 9.8${\pm}$1.3%, S. aureus = 13.0${\pm}$2.1%) in iron-coated sand while it decreased from 80.7 to 45.3% (S. aureus) in quartz sand with increasing ionic concentrations from 1 to 100 mM. As the ionic concentrations of leaching solution was lowered from 100 to 0.1 mM, average 39.1% of bacterial detachment was quantified from quartz sand, but no bacterial release was observed in iron-coated sand. The phenomenon observed in iron-coated sand can be attributed to the inner-sphere complexes between bacteria and coated sand, which have minimal effect from ionic strength. This study improves our knowledge regarding the bacterial interaction with surface-modified porous media.

A Study on the Stability of the Ca-Bentonite Colloids Using a Dynamic Light Scattering Method (동적광산란 방법을 이용한 칼슘벤토나이트 콜로이드의 안정성에 대한 연구)

  • Baik Min-Hoon;Park Jong-Hoon;Cho Won-Jin
    • Journal of Soil and Groundwater Environment
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    • v.11 no.3
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    • pp.12-19
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    • 2006
  • In this study, the stability of Ca-bentonite colloids from Gyeongju area was studied by investigating the changes in the size of the bentonite colloids using a dynamic light scattering method depending on the geochemical conditions such as pH and ionic strength. Kinetic and equilibrium coagulation behavior of the bentonite colloids was investigated by changing the pH and ionic strength of the bentonite suspensions. The results showed that the stability of the bentonite colloids strongly depended upon contact time, pH, and ionic strength. It was also shown that the bentonite colloids were unstable at higher ionic strength greater than 0.01 M $NaClO_4$ at whole pH values considered. In addition, the stability ratio Wand the critical coagulation concentration (CCC) were also calculated using the data from the kinetic coagulation experiments. The stability ratio W was decreased as the ionic strength increased and varied with pH depending on the ionic strength. The CCC of the Ca-bentonite colloids was about 0.05 M $NaClO_4$ around pH 7.

The Statistical Hypothesis Verification to Influence of Addition of Metakaolin and Silica Fume on Compressive Strength and Chloride Ion Penetration of High Strength Concrete (메타카올린 및 실리카퓸의 혼입이 고강도 콘크리트의 압축강도와 염소이온 투과에 미치는 영향에 관한 통계적 가설검증)

  • Min, Jeong Wook
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.15 no.1
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    • pp.215-225
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    • 2011
  • Metakaolin is a dehydroxylated form of the clay mineral kaolinite. Rocks that are rich in kaolinite are known as china clay or kaolin, traditionally used in the manufacture of porcelain. The particle size of metakaolin is smaller than cement particles, but not as fine as silica fume. This paper investigates the effect of the concrete containing metakaolin as a mineral admixture on the compressive strength and resistance properties to chloride ion penetration. In this study, the experiment was carried out to investigate and analyze the influence of replacement ratio of metakaolin and micro silica fume on the compressive strength and chlorine ion penetration resistance of concrete. All levels were water/binder ratio 30%, replacement ratio of metakaolin and silica fume were 0, 5, 10, 15, 20% respectively. The compressive strength of concrete using metakaolin tends to increase, as the replacement ratio increases but the chlorine ion penetration resistance was not so as lager as silica fume concrete. Therefore, the optimum mixing ratio of metakaoline to satisfy a properties of compressive strength and chlorine ion penetration resistance was was approximately10%.

이온교환에 의한 유리의 내마모성 향상

  • 조성재;방건웅;문한규
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1989.11a
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    • pp.69-72
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    • 1989
  • 구형의 압자를 유리평판 위에 올려 놓고 미끄럼 시험을 할 때 하중이 임계치보다 크면 유리평판 표면에 소위 "semi-circular cone-crack(SCCC)"들이 형성된다. 그리고 이 SCCC형성에 필요한 임계하중은 유리의 강도에 의하여 결정된다. 한편 소석회 유리에서 크기가 작은 이온인 $Na^+$를 큰 이온인 $K^+$로 대치시켜주는 경우 시편표면에 잔류압축응력이 생성되어 강도가 크게 증가한다. 따라서 유리의 내마모성도 이온교환을 하면 크게 향상될 것임을 예측할 수 있다. 본 연구의 목적은 이 예측을 실험적으로 확인하는 것이다. 확인하는 것이다.

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Quality Assurance of Air Kerma Strength for Ir-192 High Dose Rate Source (Ir-192 고선량률 선원에 대한 공기커마강도의 품질보증)

  • Kim, Jong-Eon;Yoon, Chun-Sil;Kim, Sung-Hyun
    • Journal of radiological science and technology
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    • v.30 no.2
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    • pp.147-151
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    • 2007
  • AAPM TG43 report has recommended to measure air kerma strength with the strength of source. Main purpose of this study is to verify the accuracy of air kerma strength provided by manufacturer. Materials for this study were MAX-4001 Electrometer, HDR 1000 Plus of the corporation of standard imaging, and 6 french bronchial Applicator with 1000 mm. we measured ionization current in 10-90 mm range from the bottom of the central axis of chamber. The reference point of calibration displayed by the maximum ionization current in the ionization current curve was measured, and air kerma strength was computed from the maximum ionization current. we acquired 50 mm distance to correspond with the maximum ionization current in the ionization current curve. Its distance has perfectly fitted to the source reference point of calibration certificate of UW-ADCL. Air kerma strength computed value has measured about 0.5% more than calibration value provided by manufacturer. Air kerma strength of calibration certificate provided by manufacturer has acquired reliable results. This study shows that considering the move error of dwell position of source and the dead space length in well-type chamber is a good way to get an accurate result.

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