• Title/Summary/Keyword: 이산화탄소 포집

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Systems Engineering-based Approach In Developing Concept Design Of Carbon Capture System (이산화탄소 포집 시스템 개념설계 개발을 위한 시스템 엔지니어링 기반 접근방법)

  • Lee, Chang Hwan;Hong, Dae Geun;Yoon, Su Chul;Suh, Suk-Hwna;Sur, Hwal Won
    • Journal of the Korean Society of Systems Engineering
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    • v.9 no.2
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    • pp.23-36
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    • 2013
  • Plant industry is one of technology-intensive and most prosperous industries in Korea because of its recent prosperity and promising outlook in export. However, no Korean EPC company has yet been well prepared in lifting their capacity sufficient enough to get the upstream conceptual or basic design and engineering orders for sizable plant projects which are known as the more value-added. If systems engineering, a methodology which developed complex systems such as airplanes and has been justified its effectiveness in Defense and NASA projects, can be integrated with plant engineering which should be developed and applied based on the requirements of so many stakeholders, conditions, lifecycle concepts, and constraints of the projects, huge synergic effect is expected particularly in developing a specific upstream design, which is a conceptual or basic design. The notion of integration with each other between systems engineering and plant engineering can be really the crux of EPC's success in any plant projects. This paper suggests an approach showing a methodology how to dig out, analyze, evaluate, verify and implement the stakeholders' requirements into a plant design in conceptual phase using the theory and skills of systems engineering. ISO/IEC 15288 well known systems engineering standards is used. Carbon capture system is used for a case study, for it is an emerging technology in reducing emissions of carbon dioxide causing global warming from flue gas after combustion. Here systems engineering was proven to play a substantial role in enhancing the capability of designers in developing a conceptual design of whole plant or certain part of crucial plant systems.

Properties of carbonated green construction materials by changes in processing conditions (공정조건 변화에 따른 탄산화 녹색건자재의 물성)

  • Kim, Yootaek
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.3
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    • pp.152-160
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    • 2013
  • The purpose of this study is to enhance the mechanical strength of specimens containing fly ash from fluidized bed type boiler, which the recycling rate will be eventually increased. Specimens containing fly ash in a certain portion were made and aged for 3, 14, and 28 days. Specimens were carbonated under the supercritical condition at $40^{\circ}C$. The carbonation process under the supercritical condition was performed to enhance the mechanical property of specimens by filling the voids and cracks existing inside cement specimen with $CaCO_3$ reactants. The additional aging effect after the supercritical carbonation process on mechanical strength of specimens was also investigated by comparing the compressive strength with and without 7 day extra aging. Under the supercritical condition and additional 7 day aging specimens were very effective for enhancement of mechanical strength and compressive strength increased by 44 %.

Separation of $CO_2$ from Syngas Using Gas Hydrate Formation (가스 하이드레이트 동공점유특성을 이용한 합성가스로부터의 $CO_2$ 분리 공정)

  • Park, Sungmin;Lee, Seungmin;Lee, Youngjun;Kim, Bomhui;Seo, Yongwon
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.121.2-121.2
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    • 2011
  • 석탄가스화복합발전과 연계하여 사용할 수 있는 $CO_2$분리법으로 연소 전 탈탄소화는 연료가 연소되기 전에 $CO_2$를 회수하는 방법으로 현재 여러가지 분리법이 사용되고 있다. 본 연구에서는 가스 하이드레이트의 다양한 응용 분야 중 이산화탄소 격리분야에서 합성가스로부터 $CO_2$롤 효과적으로 분리/회수하기 위하여 가스 고형화법에 관한 연구를 진행하였다. 가스 하이드레이트 형성과정에서의 반응 특성을 살펴보기 위하여 순수계와 촉진제 첨가계(TBAB, TBAF, THF)에 대하여 반응시간에 따른 가스소모량 및 기상의 $CO_2$ 조성 변화를 측정하였다. 그 결과 하이드레이트 상에 고농도의 $CO_2$가 포집되는 것을 확인 할 수 있었다. 순수계와 THF 첨가계의 경우 가스 소모량이 다른 계에 비하여 높게 나타났다. 이는 순수계의 경우 구조-I의 큰 동공과 작은 동공에 모두 기체가 점유되기 때문이며, THF 첨가계의 경우 구조-II의 큰 동공에만 기체가 점유되지만 THF의 첨가로 인해 전환율이 증가되기 때문이다. 반면, TBAF와 TBAB 첨가계의 경우에는 상재적으로 낮은 가스 소모량을 보였다. 기체 소모량이 큰 경우 최종 기상의 $CO_2$ 조성이 낮게 나타났다. 그리고 모든 실험조건에서 1시간 이내에 하이드레이트 형성반응이 종결되는 것을 확인할 수 있었다. 또한, 촉진제 첨가에 의한 하이드레이트의 구조적인 변화를 확인하기 위하여 Raman 분광법과 $^1H$-NMR을 이용하여 혼합가스 하이드레이트를 분석하였다. 본 실험으로 얻어진 결과는 가스 고형화법을 이용한 합성가스 분리 공정 설계 및 개발에 중요한 기초자료가 될 것으로 사료된다.

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Estimation of Aboveground Biomass Carbon Stock Using Landsat TM and Ratio Images - $k$NN algorithm and Regression Model Priority (Landsat TM 위성영상과 비율영상을 적용한 지상부 탄소 저장량 추정 - $k$NN 알고리즘 및 회귀 모델을 중점적으로)

  • Yoo, Su-Hong;Heo, Joon;Jung, Jae-Hoon;Han, Soo-Hee;Kim, Kyoung-Min
    • Journal of Korean Society for Geospatial Information Science
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    • v.19 no.2
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    • pp.39-48
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    • 2011
  • Global warming causes the climate change and makes severe damage to ecosystem and civilization Carbon dioxide greatly contributes to global warming, thus many studies have been conducted to estimate the forest biomass carbon stock as an important carbon storage. However, more studies are required for the selection and use of technique and remotely sensed data suitable for the carbon stock estimation in Korea In this study, the aboveground forest biomass carbon stocks of Danyang-Gun in South Korea was estimated using $k$NN($k$-Nearest Neighbor) algorithm and regression model, then the results were compared. The Landsat TM and 5th NFI(National Forest Inventory) data were prepared, and ratio images, which are effective in topographic effect correction and distinction of forest biomass, were also used. Consequently, it was found that $k$NN algorithm was better than regression model to estimate the forest carbon stocks in Danyang-Gun, and there was no significant improvement in terms of accuracy for the use of ratio images.

Review of CO2 Storage Projects and Driving Strategy of CO2 Storage Program in Korea (이산화탄소 지중저장 사업의 추진현황 검토 및 한국의 추진방향 제안)

  • Gwon, Lee-Gyun
    • KEPCO Journal on Electric Power and Energy
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    • v.2 no.2
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    • pp.167-185
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    • 2016
  • $CO_2$ 지중저장 기술은 가장 유력한 대용량 온실가스 감축기술의 하나이다. 이 기술을 적용하여 국제적으로 노르웨이, 알제리, 캐나다, 미국 등에서 이미 대규모 실증 및 상용화 사업이 수행되고 있으며, 호주, 일본, 네덜란드, 독일 등 그 밖의 여러 나라에서 다양한 내용과 규모를 갖는 중소규모 실증사업이 진행되고 있다. 한국도 소규모 육상 파일럿 저장 프로젝트와 중규모 해상 저장실증 프로젝트가 추진되어 착실하게 기술개발과 경험확보를 위해 노력하고 있다. $CO_2$ 지중저장 사업은 화석연료의 사용이 다른 에너지원으로 대체되기 전까지 지속적으로 확장될 것으로 예측되고 있으나, 온실가스 감축시장의 불안전성, 사업의 수익구조와 관련된 경제성, 누출에 대한 안전성 등의 위협요소를 갖고 있다. 따라서 이러한 위협을 극복하기 위해 많은 국가와 기업들이 저비용-고효율 지중저장 기술과 안전한 지중저장 기술의 확보를 목표로 연구개발 및 실증사업을 추진하고 있다. 한국의 경우에 저장소가 주요 포집원으로부터 상당한 거리를 갖고 있는 해저에 발달하고 있기 때문에 지중저장 사업의 경제성 확보가 매우 불리한 조건이다. 따라서 정부나 기업이 CCS 기술을 주요 온실가스 감축수단으로 채택하여 대규모 지중저장 사업을 본격적으로 착수하는 것을 주저하고 있다. 한국과 같은 불리한 조건을 갖는 국가의 경우에 특히 대규모 저장소의 확보를 포함한 저비용-고효율 지중저장 기술의 실용화가 절실하게 필요하다. 결론적으로 한국의 $CO_2$ 지중저장 사업의 성공적인 추진을 위해서는 대규모 저장소의 확보, 저비용-고효율 지중저장 기술의 개발과 실증을 통한 실용화, 중소규모 지중저장 실증사업으로 축적한 기술과 경험으로 대규모 지중저장 사업의 효율화 달성이 요구된다. 이를 위한 실천적인 로드맵과 프로그램의 작성과 착실한 이행 역시 중요하다. 이러한 기반이 착실하게 다져질 경우에 한국에서 대규모 CCS 통합실증과 $CO_2$ 지중저장 사업이 본격적으로 개시될 수 있을 것이다.

Analysis of the Influence of CO2 Capture on the Performance of IGCC Plants (가스화 복합화력발전 플랜트에서 CO2제거가 성능에 미치는 영향 해석)

  • Cha, Kyu-Sang;Kim, Young-Sik;Lee, Jong-Jun;Kim, Tong-Seop;Sohn, Jeong-L.;Joo, Yong-Jin
    • The KSFM Journal of Fluid Machinery
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    • v.13 no.1
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    • pp.9-16
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    • 2010
  • In the power generation industry, various efforts are needed to cope with tightening regulation on carbon dioxide emission. Integrated gasification combined cycle (IGCC) is a relatively environmentally friendly power generation method using coal. Moreover, pre-combustion $CO_2$ capture is possible in the IGCC system. Therefore, much effort is being made to develop advanced IGCC systems. However, removal of $CO_2$ prior to the gas turbine may affect the system performance and operation because the fuel flow, which is supplied to the gas turbine, is reduced in comparison with normal IGCC plants. This study predicts, through a parametric analysis, system performances of both an IGCC plant using normal syngas and a plant with $CO_2$ capture. Performance characteristics are compared and influence of $CO_2$ capture is discussed. By removing $CO_2$ from the syngas, the heating value of the fuel increases, and thus the required fuel flow to the gas turbine is reduced. The resulting reduction in turbine flow lowers the compressor pressure ratio, which alleviates the compressor surge problem. The performance of the bottoming cycle is not influenced much.

Synthesis of mesoporous carbon supported CuO: a new sorbent for $CO_2$ Caapture (이산화탄소 포집용 CuO담지 메조포러스 탄소체 합성)

  • Kim, Dae-Kyung;Peng, Mei Mei;Lee, Joo-Bo;Jeong, Ui-Min;Back, Kyung-Ran;Song, Sung-Hwa;Aziz, Abidov;Jang, Hyun-Tae
    • Proceedings of the KAIS Fall Conference
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    • 2011.12a
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    • pp.196-199
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    • 2011
  • In this study we synthesized mesoporous carbon supported CuO by using mesoporous silica i.e. SBA-15 as the template and cupric nitrate trihydrate ($Cu(NO_3)_23H_2O$)as copper source. The porous CuO was characterized with XRD, TGA, SEM and BET. The result reveals porous CuO has good crystal structure with uniform size of spherical crystal particles. The surface are a ($S_{BET}$) of porous CuO was found to be $153.46m^2g^{-1}$ with a total pore volume ($V_p$)of$0.1516cm^3g^{-1}$ and average pore size of 3.9 nm which was much higher than that of commercial CuO ($S_{BET}$, $7.6m^2g^{-1}$; $V_p$, $0.01cm^3g^{-1}$). The obtained porous CuO was studied for adsorption of $CO_2$and the maximum $CO_2$ adsorption capacity was found to be 67.5 mg/g of the sorbent at $25^{\circ}C$.

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Joining Foil-typed Pd-Cu Membranes to Collect CO2 Gas (이산화탄소 포집용 극박형 Pd-Cu 멤브레인 접합)

  • Rhewy, Gyung-Woo;Wee, So-Young;Kim, Gyeom;Lee, Chang-Ha;Baik, Il-Hyun;Park, Jin-Woo
    • Korean Journal of Metals and Materials
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    • v.48 no.12
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    • pp.1056-1063
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    • 2010
  • We present a new joining method for Pd-Cu membrane foils used as permeation tubes to collect $CO_2$. Since foils have poor mechanical strength, joining should be done at low temperatures to reduce residual stresses and without joining pressure. This contradicts the well known conditions for good contact between base materials that determines joint qualities. We selected Sn-Ag-Cu alloys that are highly reactive with Pd and Cu as a filler metal. As the filler melts at joining temperatures as low as $220{\sim}280^{\circ}C$, Pd and Cu are dissolved into the melt and react with the filler elements, which raises the melting temperature of the filler based on eutectic structures among the elements. Then, isothermal solidification progresses for the rest of the joining time. Intermetallic compounds (IMC) in the joints, one of the main factors for brittle joints, are inevitably formed. However, by optimizing both joining time and temperature, we balanced the wettability with IMC. Sealing test results confirmed that the joints are mechanically reliable during operation.

Modeling and Simulation of Small and Medium-sized Ships for Fuel Reduction Rate Verification (연료 감소율 검증을 위한 중소형 선박의 모델링 및 시뮬레이션)

  • Kim, Sung-Dong;Kim, Nam-Ho
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.26 no.6
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    • pp.914-921
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    • 2022
  • The International Maritime Organization (IMO) has set a goal of reducing ship's carbon dioxide emissions by 70% and greenhouse gas emissions by 50% by 2050 compared to 2008. Shipowners and shipyards are promoting various R&D activities such as LNG propulsion, ammonia propulsion, electric propulsion, CO2 capture, and shaft generators as a way to satisfy this problem. The dual shaft generator has the advantage that it can be directly applied to an existing ship through remodeling. In this paper, the total fuel reduction rate that can be obtained by applying the shaft generator to the existing ship was verified through simulation. For this purpose, the size of the medium-sized ship was defined, and the governor, diesel engine, propeller, torque switch, generator for shaft generator, propulsion motor for shaft generator, and ship model were modeled and simulated.

A Study on Technology Status and Project of Hydrogen Production from Coal Gasificiation (석탄가스화를 이용한 수소생산 기술현황 및 프로젝트 분석)

  • Seungmo Ko;Hochang Jang
    • Journal of the Korean Institute of Gas
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    • v.27 no.1
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    • pp.1-12
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    • 2023
  • Coal gasification is a process of incomplete coal combustion to produce a syngas composed of hydrogen and carbon monoxide. It is one of methods to utilize coal cleanly because the process does not emits nitrogen oxides or sulfur oxides and particulate matters. In addition, chemicals can be produced using syngas. Coal gasification is classified as IGCC (Integrated Gasification Combined Cycle), Plasma coal gasification and UCG (Underground Coal Gasification). Recently, WGS (Water Gas Shift) reactor and carbon capture system have been combined to gasifier to produce hydrogen from coal. In this study, the coal gasification and method of hydrogen production from syngas was summarized, and the hydrogen production from coal gasification project was investigated.