• Membrane Journal
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• v.33 no.6
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• pp.344-351
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• 2023

The membrane separation process for carbon dioxide capture from hydrogen reformer exhaust gas has been developed. Using a commercial membrane module, a multi-stage process was developed to achieve 90% of carbon dioxide purity and 90% of recovery rate for ternary mixed gas. Even if a membrane module with being well-known properties such as material selectivity and permeability, the process performance of purity and recovery widely varies depending on the stage-cut, the pressure at feed and permeate side. In this study, we verify the limits of capture efficiency at single-stage membrane process under various operating conditions and optimized the two-stage recovery process to simultaneously achieve high purity and recovery rate.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.12
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• pp.8870-8878
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• 2015

During the carbon-dioxide capture and storage(CCS) process, $CO_2$ is captured from large point source, and then injected and stored in stable geological structure for thousands and more years. Inside the captured $CO_2$ flow, various impurities, such as $N_2$, $O_2$, argon, etc, are included inevitably. These impurities affect on the CCS process on various aspects. In this study, we designed and built experimental facility to evaluate the various impurity effect on the $CO_2$ pipeline flow, and analyzed the effect of argon ratio and pressure variation on the pressure drop of $CO_2$ flow. By comparing experimental data with 4 kinds of pressure drop model, we figured out and recommended the Cicchitti's model since it showed most accurate result among compared models in this study.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.12
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• pp.938-943
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• 2018

Thin nano-sized fibres were prepared by an electrospinning method. The spinning appratus consisted of pump for polymer injection, nozzle and nozzle rotus, and an aluminum plate collected the polymer fibers. Its surface was chemically modified for selective improved adsorption of carbon monoxide at indoor level. The chemical activation enabled to form the fibres 250-350 nm in thickness with pore sizes distributed between 0.6 and 0.7 nm and an average specific surface area of $569m^2/g$. The adsorption capacities of pure (100%) and indoor (0.3%) $CO_2$, of which level frequently appears, at the ambient condition were improved from 1.08 and 0.013 to 2.2 and 0.144 mmol/g, respectively. It was found that the adsorption amount of $CO_2$ adsorbed by the chemically activated carbon nanofiber prepared through chemical activation would vary depending on the ratio of specific surface area and micropores. In particular, chemical interaction between adsorbent surface and gas molecules could enhance the selective capture of weak acidic $CO_2$.

• Journal of the Korean GEO-environmental Society
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• v.13 no.11
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• pp.11-17
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• 2012

This study focused on application of various $CO_2$ philic adsorbents with amine to improve $CO_2$ uptake in mortar. TGA, phenolphthalein method, FT-IR XRD, and FE-SEM analysis methods were used to evaluate $CO_2$ capture in mortar. When $CO_2$ philic adsorbents was used, $CO_2$absorption efficiency was improved maximum of 58.5%. Carbonation depth was increased 3 times compared with original mortar. Chemical reactions between bicarbonate ion, $CO_2$, $CO_2$ philic adsorbents aqueous solution, and $Ca^{2+}$ ions dissolved from cement formed $CaCO_3$ in the mortar. Therefore, impregnation of the $CO_2$ philic adsorbent on the surface of the mortar can increase the adsorbed $CO_2$.

• Proceedings of the KAIS Fall Conference
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• 2011.05a
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• pp.310-313
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• 2011

본 논문에서는 지구온난화의 주요원인 중의 하나인 이산화탄소를 포집하기 위한 새로운 흡수제를 연구하였다. 액상 흡수법에서 가장 중요한 핵심 기술요소는 성능과 경제성면에서 우수한 흡수제를 개발하는 것이다. 흡수평형장치인 VLE(Vapor-Liquid Equilibrium)장치를 사용하여 신규흡수제의 이산화탄소 흡수능을 평가하고 특성을 알아봄으로써 신 흡수제를 개발하고자 하였다. 기존 아민흡수제인 MEA(monoethanolamine), DEA(diethanolamine)와 비교한 결과 아미노산염 흡수제의 경우 MEA (1.108), DEA (1.105)의 이산화탄소 흡수능보다 0.15～0.2 (mol $CO_2$/mol absorbent) 더 높은 흡수능과 2.5～3배 더 빠른 겉보기 속도를 나타내는 것을 확인하였다. 본 연구를 통하여 개발된 아미노산염 흡수제가 경제적인 이산화탄소 포집공정을 구현할 수 있는 가능성을 확인하였다.

• Transactions of the KSME C: Technology and Education
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• v.1 no.1
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• pp.123-128
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• 2013

Carbon dioxide Capture and Storage (CCS) is one of the key players in greenhouse gas (GHG) reduction portfolio for mitigating climate change. CCS makes it possible not only to reduce a huge amount of carbon dioxide directly from coal power plant but also to maintain the carbon concentrated-energy infrastructure. The objective of the present paper is to review and introduce R&D progress and large scale demonstration plan focused on marine geological storage in Republic of Korea.

• Tunnel and Underground Space
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• v.20 no.5
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• pp.309-317
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• 2010

CCS (Carbon dioxide Capture and Storage) is a means of mitigating the contribution of $CO_2$ to the Greenhouse gas, from large point sources such as power plants and steel companies. CCS is a process whereby $CO_2$ is captured from gases produced by fossil fuel combustion, compressed, transported and injected into deep geologic formations for permanent storage. CCS applied to a conventional power plant can reduce $CO_2$ emissions to the atmosphere by approximately 80~90% compared to a plant without CCS. The IPCC estimates that the economic potential of CCS will be between 10% and 55% of the total carbon mitigation effort by year 2100. In this paper, overseas sites where CCS technology is being applied and technical development trends for CCS are briefly reviewed.

• Korean Chemical Engineering Research
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• v.57 no.4
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• pp.539-546
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• 2019

Global warming has mentioned as one of the international problems and these researches have conducted. Carbon Capture, Utilization and Storage (CCUS) technology has improved due to increasing importance of reducing emission of carbon dioxide. Among of various CCUS technologies, mineral carbonation can converted $CO_2$ into high-cost materials with low energy. Existing researches has been used ions extracted solid wastes for mineral carbonation but the procedure is complicated. However, the procedure using seawater is simple because it contained high concentration of metal cation. This research is a basic study using seawater-based wastewater for mineral carbonation. 3 M Monoethanolamine (MEA) was used as $CO_2$ absorbent. Making various concentrations of seawater solution, simulated seawater powder was used. Precipitated metal carbonate salts were produced by mixing seawater solutions and $rich-CO_2$ absorbent solution. They were analyzed by X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), and Thermogravimetric Analysis (TGA) and studied characteristic of producing precipitated metal carbonate and possibility of reusing absorbent.

• Economic and Environmental Geology
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• v.50 no.5
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• pp.389-400
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• 2017

In December 2015, 195 nations agreed to cut green house gas emissions in the Paris Climate Convention, and all over the world showed their willingness to participate in greenhouse gas mitigation. Accordingly, various technologies related to greenhouse gas reduction are being considered, among which carbon dioxide capture, storage, utilization (CCUS) technologies are attracting attention as an unique technology capable of directly removing greenhouse gases. However, CCUS technologies are still costly and have low efficiency. It is still more important to analyze the level of CCUS technology before commercialization and to understand trends and to predict future direction of technology. Therefore, this study analyzes the patent trends of CCUS technology and derives implications for future directions. As a result of country analysis, the United States had the highest number of applications, and sectoral analysis shows that 64% of total patents are from capture sector. Companies such as Alstom technology, Toshiba Corp, and Mitsubishi Heavy are focusing on capturing carbon dioxide. In Korea, government research institutes have focused on storage and utilization technologies. In addition, since the late 2000s, patent applications have increased rapidly, and many countries have been interested in the development of the technology and have made efforts to reduce greenhouse gas.

• Journal of the Korean Society for Marine Environment & Energy
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• v.14 no.1
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• pp.51-64
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• 2011

Carbon dioxide Capture and Storage (CCS) is one of the key players in greenhouse gas (GHG) reduction portfolio for mitigating climate change. CCS makes simultaneously it possible not only to reduce a huge amount of carbon dioxide directly from the emission sources (e.g., coal power plant) but also to maintain the carbon concentrated-energy and/or industry infrastructure. Internationally, the United Nations Framework Convention on Climate Change (UNFCCC) is dealing the agenda for considering the possibility of including CCS project as one of Clean Development Mechanism (CDM) projects. Despite its usefulness, however, there are the controversies in including CCS as the CDM project, whose issues include i) non-permanence, including long-term permanence, ii) measuring, reporting and verification (MRV), iii) environmental impacts, iv) project activity boundaries, v) international law, vi) liability, vii) the potential for perverse outcomes, viii) safety, and ix) insurance coverage and compensation for damages caused due to seepage or leakage. In this paper, those issues in considering CCS as CDM are summarized and analyzed in order to suggest some considerations to policy makers in realizing the CCS project in Korea in the future.