• Title/Summary/Keyword: 이산화탄소와 물의 영향

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Structural Safety Evaluation for Fixed CO2 Extinguishing Systems Under Ship Motion (선박모션에 따른 고정식 CO2소화 장치 구조안전성 평가)

  • Kim, Seung Chan;Kang, Sang Hoon;Choi, Joo Hyoung;Kim, Jeong-Hwan;Park, Young Chul
    • Transactions of the KSME C: Technology and Education
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    • v.4 no.2
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    • pp.75-83
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    • 2016
  • Since fire is one of the most dangerous threats to the safety of the ship, from the safety device is installed on the vessel the digestive apparatus can be viewed as the most important safety device. The fire-extinguishing device to be mounted to the vessel structure affected the stability of the structure in accordance with the blue of the sea. In particular, the Rack part of the basic safety of a fixed fire extinguishing system in the absence of a $CO_2$ container. In this paper, by utilizing simulation techniques to apply the pressure data being ejected in each direction by ship motion and $CO_2$ containers Rack perform an analysis of the structural safety assessment was part of the digestive system accordingly.

A Study on the Catalytic Reduction of Carbon Dioxide by Methane (메탄에 의한 이산화탄소의 환원반응에 관한 연구)

  • Hong, Seong-Soo;Yang, Jin-Seop;Kim, Byung-Kee;Ju, Chang-Sik;Lee, Gun-Dae
    • Applied Chemistry for Engineering
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    • v.8 no.4
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    • pp.685-693
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    • 1997
  • We have studied the reforming of carbon dioxide with methane over various supported nickel catalysts. The nickel supported on natural zeolite showed the highest activity and the nickel on acidic support showed higher activity and slow deactivation compared to nickel on basic support. The activity of nickel on natural zeolite increased with increasing loading ratio and showed almost constant activity above 10wt.% loading of nickel. The conversion and yield of products were affected by the mole ratio of reactants and the highest yields of CO and $H_2$ were obtained at $CH_4/CO_2=1$. The deactivation of catalyst was caused by deposition of coke which was formed by the decomposition of methane. The shape of coke was shown to be whisker tripe carbon, and it brought out the slow deactivation of catalyst.

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Effects of natural calcium-coated package papers on the fruit quality and storage life of 'Hongro' apple. (수확 한 사과 '홍로'에서 천연칼슘이 코팅된 포장지 적용이 과실품질 및 저장성에 미치는 영향)

  • Moonm, B.W.;Lee, Y.C.;Jung, H.W.;Chung, T.S.
    • Journal of Practical Agriculture & Fisheries Research
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    • v.12 no.1
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    • pp.53-62
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    • 2010
  • This study was designed to examine whether 'Hongro' apples packaged with natural calcium-coated package papers was fresher maintained than fruit held in not-packaged tray, and whether postharvest physiology of the fruits was affected by calcium-coated papers, or not. The summarized results were as follows; Soluble solids contents and firmness of fruit were higher room temperature(20~25℃) after 4 week and 14 week in cold storage(0~1℃) by calcium-coated package papers. but total acid contents in juice and Hunter a value of peel were trended to decrease in room temperature and cold storage. Weight loss of fruit, decay fruit and CO2 evolution were decreased by calcium and wax-coated package papers in room temperature storage condition. Also, excellent fruits increased. Ethylene evolution in fruit were not different by package paper and storage condition.

Continuous Process for the Etching, Rinsing and Drying of MEMS Using Supercritical Carbon Dioxide (초임계 이산화탄소를 이용한 미세전자기계시스템의 식각, 세정, 건조 연속 공정)

  • Min, Seon Ki;Han, Gap Su;You, Seong-sik
    • Korean Chemical Engineering Research
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    • v.53 no.5
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    • pp.557-564
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    • 2015
  • The previous etching, rinsing and drying processes of wafers for MEMS (microelectromechanical system) using SC-$CO_2$ (supercritical-$CO_2$) consists of two steps. Firstly, MEMS-wafers are etched by organic solvent in a separate etching equipment from the high pressure dryer and then moved to the high pressure dryer to rinse and dry them using SC-$CO_2$. We found that the previous two step process could be applied to etch and dry wafers for MEMS but could not confirm the reproducibility through several experiments. We thought the cause of that was the stiction of structures occurring due to vaporization of the etching solvent during moving MEMS wafer to high pressure dryer after etching it outside. In order to improve the structure stiction problem, we designed a continuous process for etching, rinsing and drying MEMS-wafers using SC-$CO_2$ without moving them. And we also wanted to know relations of states of carbon dioxide (gas, liquid, supercritical fluid) to the structure stiction problem. In the case of using gas carbon dioxide (3 MPa, $25^{\circ}C$) as an etching solvent, we could obtain well-treated MEMS-wafers without stiction and confirm the reproducibility of experimental results. The quantity of rinsing solvent used could be also reduced compared with the previous technology. In the case of using liquid carbon dioxide (3 MPa, $5^{\circ}C$, we could not obtain well-treated MEMS-wafers without stiction due to the phase separation of between liquid carbon dioxide and etching co-solvent(acetone). In the case of using SC-$CO_2$ (7.5 Mpa, $40^{\circ}C$), we had as good results as those of the case using gas-$CO_2$. Besides the processing time was shortened compared with that of the case of using gas-$CO_2$.

Effect of pH Adjustment by CO2 on Coagulation and Aluminum Elution in Water Treatment (CO2 주입에 의한 pH 조정이 정수장 응집효율 및 알루미늄 용출에 미치는 영향)

  • Lee, Gil-Seong;Kim, Min-Chai;Kwon, Jae-Kook;Seo, Gyu-Tae
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.1
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    • pp.17-22
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    • 2013
  • In this study, a pH control method by carbon dioxide ($CO_2$) was applied to coagulation process in water treatment plant (WTP) to investigate the coagulation efficiency and residual dissolved aluminum when high pH raw water is flowing into the plant during algal blooming. Existing coagulant dose (1 mg/L in raw water) resulted in the pH reduction of 0.0384 by LAS, 0.0254 by PAC, 0.0201 by A-PAC, and 0.0135 by PACS2, respectively. And then the concentration of dissolved aluminum was 0.02 mg/L at pH 7.44, 0.07 mg/L at pH 7.96, 0.12 mg/L at pH 8.16, 0.39 mg/L at pH 8.38 showing the concentration increase with pH in the coagulation process. It was noteworthy that rapid increase was observed at pH above 8.0 next the rapid mixing. Therefore it is necessarily required to control pH below 7.8 in the coagulation process in order to meet drinking water quality standard of aluminum for high pH raw water into WTP, $CO_2$ injection could control pH successfully at about 7.3 even for the raw water of high pH above 8.0. In addition it was found that the pH control by $CO_2$ injection was significantly effective for coagulation in terms of turbidity removal, coagulant dosage, and residual dissolved aluminum concentration.

Flow Characteristics and Wind Loads on the Solar Panel and Floating System of Floating Solar Generato (부유식 태양광 발전기의 패널과 부유체에 작용하는 풍하중과 유동특성)

  • Ryu, Dae-Gyeom;Lee, Kye-Bock
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.10
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    • pp.229-235
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    • 2019
  • A floating photovoltaic generation system is a new concept that combines existing photovoltaic generation technology with floating technology. This is installed in the water not on conventional land and a building. The system is designed as a unit module type that can be connected to other modules according to the power generation capacity, thereby forming a large-scale power generation facility. As a renewable energy source, it is composed of a floating structure, mooring device, photovoltaic power generation facility, and underwater cable. Because this system is installed outdoors, the effect of the wind load on the structure is very large. In this study, the wind loads most affected on the floating photovoltaic generation structure were obtained by computational fluid dynamic analysis. The flow characteristics and wind loads were analyzed for a range of wind orientations and angles of inclination. The analysis showed the position and magnitude of the maximum wind load to the wind direction and the flow characteristics around the solar panel and floating system. The wind load increased with increasing angle of inclination of the panel to the ground.

A Study on Carbonation Velocity for Concrete Structures (콘크리트 구조물의 탄산화속도에 관한 연구)

  • Kim, Jong Ho;Oh, Kwang Chin;Park, Seung Bum
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.12 no.2
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    • pp.163-170
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    • 2008
  • The carbonation velocity is produced an effect on carbon dioxide($CO_2$) density of surrounding near structures, the concrete quality and types of structures and this study was accomplished to draw a conclusion for estimated formula of carbonation velocity coefficient with various factors by the concrete quality on the base of the data of the durability surveyed in Korea. From the results of analysis of carbonation velocity, the followings were appeared. It is analyzed that carbonation velocity of the structures under urban area is 1.5 times faster than the rural area in the bridges case and it is 2.5 times faster than the rural area in the tunnels case. And the order of carbonation velocity of the structures under urban area is the buildings, the tunnels, the bridges and they are evaluated to progress about 2.7 times and 1.3 times faster than the bridges. In the rural area, the bridges are evaluated to progress about 1.3 times faster than the tunnels and it is analyzed that the carbonation velocity of the upper structures of the bridges under urban area is about 1.3 times faster than lower structures. The results which is compared to estimated formula of carbonation velocity coefficient of Kishitani equation which is generally applied for convert compressive strength into W/C ratios, most of those velocity of structures is faster than the results of Kishitani equation.

Development of 3D DMFC Model for Flow Field Design (직접 메탄올 연료전지 유로 설계를 위한 3차원 모델 개발)

  • Kim, Hongseong;Danilov, Valeri A.;Lim, Jongkoo;Moon, Il
    • Korean Chemical Engineering Research
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    • v.45 no.1
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    • pp.93-102
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    • 2007
  • The objective of this study is to develop a 3D DMFC model for modeling gas evolution and flow patterns to design optimal flow field for gas management. The gas management on the anode side is an important issue in DMFC design and it greatly influences the performance of the fuel cell. The flow field is tightly related to gas management and distribution. Since experiment for the optimal design of various flow fields is difficult and expensive due to high bipolar plate cost, computational fluid dynamics (CFD) is implemented to solve the problem. A two-fluid model was developed for CFD based flow field design. The CFD analysis is used to visualize and to analyze the flow pattern and to reduce the number of experiments. Case studies of typical flow field designs such as serpentine, zigzag, parallel and semi-serpentine type illustrate applications of the model. This study presents simulation results of velocity, pressure, methanol mole fraction and gas content distribution. The suggested model is verified to be useful for the optimal flow field design.

The Selective Oxidation of CO in Hydrogen Rich Stream over Alumina Supported Cu-Ce Catalyst (알루미나에 담지된 Cu-Ce 촉매상에서의 개질수소가스에 포함된 CO의 선택적 산화 반응에 관한 연구)

  • Park, J.W.;Jeong, J.H.;Yoon, W.R.;Lee, Y.W.
    • Transactions of the Korean hydrogen and new energy society
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    • v.14 no.2
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    • pp.155-170
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    • 2003
  • $Cu-Ce/{\gamma}-Al_2O_3$ based catalysts were prepared and tested for selective oxidation of CO in a $H_2$-rich stream(1% CO, 1% $O_2$, 60% $H_2$, $N_2$ as balance). The effects of Cu loading and weight ratio(=Cu/(Cu+Ce)) upon both activity and selectivity were investigated upon the change in temperatures, It was also examined how the activity and selectivity of catalysts were varied with the presence of $CO_2$ and $H_2O$ in the reactant feed. Among the various Cu-Ce catalysts with different catalytic metal composition, Cu-Ce(4 : 16 wf%) /${\gamma}-Al_2O_3$ catalyst showed the highest activity(>$T_{99}$) and selectivities(50-80%) under wide range of temperatures($175-220^{\circ}C$). However, in the Cu-Ce(4 : 16 wt%)/ ${\gamma}-Al_2O_3$, the presence of $CO_2$ and $H_2O$ in the reactant feed decreased the activity and the maximum activity(>$T_{99}$) in terms of reaction temperature moved by about $25^{\circ}C$ toward higher temperature, the $T_{>99}$ window was seen between $210-230^{\circ}C$ (selectivity 50-75%). From $CO_2-/H_2O-TPD$, it can be concluded that the main cause for the decrease in catalytic activity may be attributed to the blockage of the active sites by competitive adsorption of water vapor and $CO_2$ with the reactant at low temperatures.

Development of Land Fill Gas(LFG)-MGT Power Generation and Green House Design Technology (쓰레기 매립지 MGT 발전 및 유리온실 설계기술개발)

  • Hur, Kwang-Beom;Park, Jung-Keuk;Lee, Jung-Bin
    • Journal of Energy Engineering
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    • v.20 no.1
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    • pp.13-20
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    • 2011
  • The high fuel flexibility of Micro Gas Turbine(MGT) has boosted their use in a wide variety of applications. Recently, the demand for biogas generated from the digestion of organic wastes and landfill as a fuel for gas turbines has increased. We researched the influence of firing landfill gas(LFG) on the performance and operating characteristics of a micro gas turbine combined heat and power system. $CH_4$ and $CO_2$ simultaneous recovery process has been developed for field plant scale to provide an isothermal, low operating cost method for carrying out the contaminants removal in Land Fill Gas(LFG) by liquid phase catalyst for introduce into the green house for the purpose of $CO_2$ rich cultivation of the plants. Methane purification and carbon dioxide stripping by muti panel autocirculation bubble lift column reactor utilizing Fe-EDTA was conducted for evaluate optimum conditions for land fill gas. Based on inflow rate of LFG as 0.207 $m^3$/min, 5.5 kg/$cm^2$, we designed reactor system for 70% $CH_4$ and 27% $CO_2$ gas introduce into MGT system with $H_2S$ 99% removal efficiency. A green house designed for four different carbon dioxide concentration from ambient air to 1500 ppm by utilizing the exhaust gas and hot water from MGT system.