• Title/Summary/Keyword: 이방성필러

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하이브리드 탄소소재가 에폭시 복합체의 열전도도에 미치는 영향

  • An, Yu-Jin;Park, Ji-Seon;Sin, Gwon-U;Kim, Yun-Jin;Seo, Eun-Ha;Lee, Cheol-Seung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.187.2-187.2
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    • 2014
  • 최근 다양한 카본 나노소재들이 열 전도성 필러로써 고분자 복합체의 열전도도 향상을 위해 연구되고 있다. 그러나 구조적 이방성을 갖는 탄소나노튜브(CNT) 혹은 그래핀나노플레이트(Graphene Nanoplatelet)를 복합체에 적용할 경우, 복합체의 수직 방향과 수평 방향에서의 열전도도가 3배 이상 차이가 나는 문제가 있다. 따라서 본 연구에서는 2차원의 GNP 표면 위에 1차원의 CNT를 직접 성장시킨 하이브리드 탄소소재를 이용하여 이러한 열전도도 이방성을 개선하고자 하였다. 하이브리드 탄소소재는 무전해 도금법과 열기상법으로 제조하였다. 합성된 하이브리드 탄소소재 및 CNT를 단독 혹은 혼합하여 필러를 만들고 이를 에폭시 기지 내에 분산시켜 복합체를 제작하였다. 필러 함량별, 필러 비율별로 제작된 복합체의 열전도도를 레이저 플래시 법으로 측정 비교하였다. 결과적으로 기존의 단일 필러들보다 열전도도 이방성이 1.5배 이상 개선된 방열용 에폭시 복합체를 제작할 수 있었다. 한편 하이브리드 탄소와 2% 이하의 CNT 배합에서 단독 필러 투입에 비해 45% 이상의 열전도율 향상을 확인하였다. 이는 미세구조 분석 및 성분 분석 결과, 필러 분산 정도가 열전도도 향상의 주요 인자로 작용하는 것을 확인하였고 기지 내 CNT가 열전도도 경로로 작용하기보다는 하이브리드 탄소소재의 균일한 분산에 영향을 준 것으로 사료된다.

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Manipulating Anisotropic Filler Structure in Polymer Composite for Heat Dissipating Materials: A Mini Review (방열소재로의 응용을 위한 고분자 복합소재 내 이방성 필러 구조 제어 연구동향)

  • Seong-Bae, Min;Chae Bin, Kim
    • Composites Research
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    • v.35 no.6
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    • pp.431-438
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    • 2022
  • Efficient heat dissipation in current electronics is crucial to ensure the best performance and lifespan of the devices along with the users' safety. Materials with high thermal conductivity are often used to dissipate the generated heat from the electronics to the surroundings. For this purpose, polymer composites have been attracted much attention as they possess advantages rooted from both polymer matrix and thermally conductive filler. In order to meet the thermal conductivity required by relevant industries, composites with high filler loadings (i.e., >60 vol%) have been fabricated. At such high filler loadings, however, composites lose benefits originated from the polymer matrix. To achieve high thermal conductivity at a relatively low filler loading, therefore, constructing the heat conduction pathway by controlling filler structure within the composites may represent a judicious strategy. To this end, this review introduces several recent approaches to manufacturing heat dissipating materials with high thermal conductivity by manipulating thermally conductive filler structures in polymer composites.

Influence of Pillar Width on the Stability of Twin Tunnels Using Scaled Model Tests (쌍굴터널 간 이격거리가 터널 안정성에 미치는 영향에 관한 모형실험 연구)

  • Kim, Jong-Woo
    • Tunnel and Underground Space
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    • v.25 no.5
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    • pp.423-434
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    • 2015
  • Scaled model tests were performed to investigate the influence of pillar width, rock strength and isotropy/anisotropy on the stability of twin tunnels. Test models had respectively different pillar widths, uniaxial compressive strengths of modelling materials and model types, where both the deformation behaviors around tunnels and the biaxial pressure data at a time of pillar cracking were analysed. The cracking pressures of the higher strength models were higher than the lower strength models, whereas the percentage of cracking pressure to uniaxial compressive strength of modelling materials showed an opposite tendency. The cracking pressures of the shallower pillar width models were lower than the thicker models, moreover the percentage of that showed a same tendency. It has been found that the pillar width was one of the main factors influencing on the stability of twin tunnels. Model types such as isotropy/anisotropy also influenced on the stability of twin tunnels. The anisotropic models showed lower values of both cracking pressures and the percentage of that than the isotropic models, where the pillar cracks of anisotropic models were generated with regard to the pre-existing joint planes.

Case study for Stability Estimation of Subway Twin Tunnels Using Scaled Model Tests (축소모형실험을 통한 지하철 병설터널의 안정성평가 사례연구)

  • Kim, Jong-Woo
    • Tunnel and Underground Space
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    • v.29 no.6
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    • pp.425-438
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    • 2019
  • A scaled model test was performed to evaluate the stability of subway twin tunnels excavated in the sedimentary rocks with subhorizontal bedding planes. The size of studied tunnel was 6.2 m×6.8 m and pillar width was 4 m. The anisotropic model test specimen was manufactured with the modeling materials suitable for in-situ rocks by way of dimensional analysis. Fracture and deformation behaviors of tunnels according to applied loads were investigated through the biaxial compression test. As the load was increased on the model specimen, the first crack occurred in the middle part of the pillar across twin tunnels and the gradual fractures progressed at crown and floor of twin tunnels. All the cracks in pillar were generated along the existing bedding planes so that they were found to be the main cause of the pillar failure. In addition, the test results were verified by numerical analysis on the experimental conditions using FLAC ubiquitous joint model. The distribution of plastic regions obtained from numerical analysis were in general agreement with test results, confirming the reliability of the scaled model test conducted in this study.

Scale Model Studies for Stability Estimation of Twin Tunnels with Small Clearance (근접병설터널의 안정성 평가를 위한 모형실험 연구)

  • Kim, Pyoung Gi;Kim, Jong Woo
    • Tunnel and Underground Space
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    • v.23 no.2
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    • pp.130-140
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    • 2013
  • In this study, scaled model tests were performed to investigate the stability of twin tunnels with small clearance, where the pillar widths were 0.5D and 0.25D, respectively. The tunnels were supposed to be constructed in anisotropic weathered rocks with $30^{\circ}$ inclined bedding planes, and the model tests were conducted under the condition of lateral pressure ratio, 1. Six types of test models which had respectively different pillar widths and support conditions were experimented, where crack initiating pressures, maximum pressures, failure modes of pillar and deformation behaviors around tunnels were investigated. The models with wider pillar were cracked under higher pressure than the models with shallower pillar. The models with lining support were cracked under higher pressure and showed less tunnel convergence than the unsupported models. The models with both lining and pillar reinforcement were proved to be most stable among the tested models. In particular, as the model of 0.25D pillar width with only lining support showed shear failure of pillar according to the existing bedding planes, so both lining and pillar reinforcement were thought to be indispensable in that case of tunnel.

A Study for the Stability Investigation of Three Parallel Tunnels Using Scaled Model Tests (삼병렬 터널의 안정성 검토를 위한 모형실험 연구)

  • Kim, Jong-Woo;Bae, Woo-Seok
    • Tunnel and Underground Space
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    • v.18 no.4
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    • pp.300-311
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    • 2008
  • In this study, scaled model tests were performed to investigate the stability of three parallel tunnels. Seven types of test models which had respectively different pillar widths, tunnel sectional shapes, support conditions and ground conditions were experimented, where crack initiating pressures and deformation behaviors around tunnels were investigated. In order to evaluate the effect of pillar widths on stability, various models were experimented. As results, the models with shallower pillar widths proved to be unstable because of lower crack initiating pressures and more tunnel convergences than the models with thicker pillar widths. In order to find the effect of tunnel sectional shape on stability, the models with arched, semi-arched and rectangular tunnels were experimented. Among them rectangular tunnel model was the most unstable, where the arched tunnel model with small radius of roof curvature was more stable than semi-arched one. The model with rockbolt showed higher crack initiating pressure and less roof lowering than the unsupported model. The deformation behaviors of tunnels in the anisotropic ground model were quite different from those in the isotropic ground model. Futhermore, the results of FLAC analysis were qualitatively coincident with the experimental results.