• Journal of the Korean Chemical Society
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• v.48 no.6
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• pp.590-598
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• 2004

The preconcentration and determination of trace Cu(II) and Pb(II) on calcium alginate beads in aqueous solution were studied. A calcium alginate beads were prepared by adding an alginic acid to sample solution contained Ca(II). Some following conditions were optimized: the pH of sample solution, amount of alginic acid, and stirring time for effective adsorption; the type and concentration of acid, and sonication time in an ultrasonic vibrator for the perfect de-sorption. A sample solution was prepared with Cu(II) and Pb(II) in DI water. And Ca(II) and ethanol was added into the sample solution. The pH of the final sample solution was controlled with buffer solution. The alginic acid were dispersed in the sample solution by a magnetic stirrer. This mixture was stored in room temperature for 30 min to form a calcium alginate. After the beads were filtered and washed on a membrane filter, the analytes were redissolved from the beads by an ultrasonic vibration of 10 minutes in 1.0M $HNO_3$ solution. The effect of diverse ions on the adsorption of analytes were studied. This procedure was applied for the analysis of two real samples. The recoveries in spiked samples were $90.4{\sim}104.3%$ for analytes.

• 제어로봇시스템학회:학술대회논문집
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• 1996.10b
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• pp.792-795
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• 1996

In TIG welding of pipe, back bead size monitoring is important for weld quality assurance. Many researches have been performed on estimation of the back bead size by heat conduction analysis. However numerical conduction model based on many uncertain thermal parameters causes remarkable errors and thermomechanical phenomena in molten pool can not be considered. In this paper, filler wire feeding force in addition to weld current, wire feedrate, torch travel speed and orbital position angle is monitored to estimate back bead size in orbital TIG welding. Monitored welding process variables are fed into an artificial neural network estimator which has been trained with the monitored process variables (input patterns) and actual back bead size (output patterns). Experimental verification of the proposed estimation method was performed. The predicted results are in a good agreement with the actual back bead shape. The results are quite promising in that estimation of invisible back bead shape can be achieved by analyzing the welding parameters without any conventional NDT of welds.

• Journal of Welding and Joining
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• v.29 no.4
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• pp.80-84
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• 2011

In the 5xxx series Al-Mg alloy, magnesium addition can increase the strength of aluminum alloy by solid solution strengthening but it has a relatively low melting and boiling temperature. During full -penetration laser welding of the Al-Mg alloys, its low boiling point and high vapor pressure brings about the spiky humping bead on the bottom side. Under back-side shielding, the spiking of back bead can be reduced but it restraints the process flexibility. In this study, a square pulse waveform modulation was employed to stabilize keyhole and back bead surface without back-side shielding. By using an experimental design, the bead shapes were evaluated for various process parameters such as the focal position, welding velocity and waveform parameters and the smooth back bead shape could be achieved.

• Journal of Ocean Engineering and Technology
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• v.16 no.2
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• pp.53-59
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• 2002

This paper shows the experimental results controlling the height of surface and back bead in GMAW by analyzing the unexpected gaps between base metals produced in welding and by controlling welding velocity due to the variation of the gap between base metals in thin-plate welding. The back bead behavior and burn-through in I-type butt joint $CO_2$ welding of thin mild steel are analyzed in the views of short circuit time ratio and short circuit frequency. It is shown through experimental consideration that the short circuit time ratio method is more reasonable than the short circuit frequency method in analyzing the formulation of back bead under changing the gap between base metals. Based on the these results, welding manipulator is designed so as to satisfy the bead height control in real time by measuring the short circuit time ratio. To show the effectiveness of the developed bead formulation control system, the experiment is implemented under two welding conditions such as increasing gap from 0mm to 0.8mm and gradually increasing gap from 0mm to 1.2mm. The experimental results show that the bead formulation can be controlled uniformly in spite of the variation of the gap between base metals.