• Title/Summary/Keyword: 이극자

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Studies on Crystallographic and Mossbauer Spectra of the LiFe0.9Mn0.1PO4 (LiFe0.9Mn0.1PO4 물질의 결정구조 및 뫼스바우어 분광 연구)

  • Kwon, Woo-Jun;Lee, In-Kyu;Rhee, Chan-Hyuk;Kim, Sam-Jin;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
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    • v.22 no.1
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    • pp.15-18
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    • 2012
  • The olivine structured $LiFe_{0.9}Mn_{0.1}PO_4$ material was prepared by solid state method, and was analyzed by x-ray diffractometer (XRD), superconducting quantum interference devices (SQUID) and Mossbauer spectroscopy. The crystal structure of $LiFe_{0.9}Mn_{0.1}PO_4$ was determined to be orthorhombic (space group: Pnma) by Rietveld refinement method. The value of N$\acute{e}$el temperature ($T_N$) for $LiFe_{0.9}Mn_{0.1}PO_4$ was determined 50 K. The temperature dependence of the magnetization curves showed magnetic phase transition from paramagnetic to antiferromagnetic at $T_N$ by SQUID measurement. M$\ddot{o}$ssbauer spectra of $LiFe_{0.9}Mn_{0.1}PO_4$ showed 2 absorption lines at temperatures above $T_N$ and showed asymmetric 8 absorption lines at temperatures below $T_N$. These spectra occurred due to the magnetic dipole and electric quardrupole interaction caused by strong crystalline field at asymmetric $FeO_6$ octahedral sites.

Dissociation Energies and Dipole Moments of Alkali Halides (할로겐화 알칼리 화합물의 해리에너지 및 이중극자 모멘트 계산)

  • Rhee, Chang Hwan
    • Journal of the Korean Chemical Society
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    • v.41 no.9
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    • pp.449-459
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    • 1997
  • The bonded state polarizabilities of ions in the alkali halides are estimated by using the Seitz and Ruffa (SR) energy level analysis relation. The effective number of electrons $(N_{eff})$ in the Slater-Kirkwood formula are used for all members of an isoelectronic sequence. The effective dispersion coefficients $(C_6^{eff})$ are calculated by the use of the empirical formula (J. Chem. Phys. 1991, 95, 1852) estimating $(N_{eff})$ values to reproduce the experimental $(C_6^{eff})$ for atom-atom (or molecule) interactions. In the framework of the T-Rittner model the model potential is constructed and used to calculate the values of dissociation energy and dipole moment. The results obtained in the present study are in good agreement with the experiment one.

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optical Simulation on EUV Reflectivity of Mo/Si Multilayer Structure (Mo/Si 다층박막의 극자외선 반사도에 대한 전산모사)

  • 이영태;강인용;정용재;이승윤;허성민
    • Journal of the Microelectronics and Packaging Society
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    • v.8 no.2
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    • pp.19-24
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    • 2001
  • The effect of thickness variation and inter-diffusion layer on the reflectivity of Mo/Si multilayer has been investigated. The reflectivity of the imperfect Mo/Si multilayer with thickness variation of 28% was found to be lowered by 10.8% compared to that of ideal Mo/Si multilayers with 40-periods. When the inter-diffusion layer is taken into account, the reflectivity is decreased by 4.7% additionally. We also fecund that the reflectivity continued to increase until the 25th-layer but it showed irregular tendencies about increment and decrement from the 26th-layer of Mo/Si multilayer structures.

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Development and characteristics investigation of new soft plasma ionization(SPI) source (새로운 소프트 플라스마 이온화(SPI) 장치의 개발 및 특성관찰)

  • Lee, Hiwwon;Park, Hyunkook;Lee, Sang Chun
    • Analytical Science and Technology
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    • v.22 no.2
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    • pp.152-158
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    • 2009
  • In this study, we made a new discharge source improving previous SPI source to ionize softly organic compounds. The new SPI source consists of two electrodes as a hollow mesh cathode of half cylindrical shape and a hollow anode. We optimized the geometrical parameter of the SPI source by investigating the I-V curves at the various distance between the cathode and the anode. As the results, we found stable conditions of the soft plasma on broad range of the current and the voltage. The new SPI source attached to quadrupole mass spectrometer (QMS), and we obtained the mass spectra of dichloromethane (DCM). The fragment patterns of DCM appeared similarly with the pattern of electron ionization (EI).

Magnetic Properties and Mossbauer Studies of $Cu_{1-x}Ge_{1-y}Fe_{x+y}O_3$System ($Cu_{1-x}Ge_{1-y}Fe_{x+y}O_3$계의 자기적 및 Mossbauer 분광학적 연구)

  • 채광표;권우현
    • Journal of the Korean Magnetics Society
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    • v.9 no.3
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    • pp.143-148
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    • 1999
  • Magnetic properties and crystallographic properties of $Cu_{1-x}Ge_{1-y}Fe_{x+y}O_3$ system were studied by using x-ray diffraction, superconducting quantum interference device (SQUID) and Mossbauer spectroscopy. All the samples have orthorhombic structure and the lattice constants some decreased as the substituted iron contents increasing. The spin-Peierls (SP) transition temperature of our samples are about 12.5 K and these temperatures lowered as increasing substituted iron contents. The Mossbauer spectra consisted with two Zeeman sextets and one doublet due to $Fe^{3+}$ ions. The jump up of magnetic hyperfine field of 2nd Zeeman sextet and the increasing of the values of quadrapole splitting and isomer shift of doublet below SP transition temperature could be interpreted with the variation of the superexchange interaction, the symmetry of lattice sites and the covalency of bonds due to the atomic displacements.

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A comparison study of 76Se, 77Se and 78Se isotope spikes in isotope dilution method for Se (셀레늄의 동위원소 희석분석법에서 첨가 스파이크 동위원소 76Se, 77Se 및 78Se들의 비교분석)

  • Kim, Leewon;Lee, Seoyoung;Pak, Yong-Nam
    • Analytical Science and Technology
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    • v.29 no.4
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    • pp.170-178
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    • 2016
  • Accuracy and precision of ID methods for different spike isotopes of 76Se, 77Se, and 78Se were compared for the analysis of Selenium using quadrupole ICP/MS equipped with Octopole reaction cell. From the analysis of Se inorganic standard solution, all of three spikes showed less than 1 % error and 1 % RSD for both short-term (a day) and long-term (several months) periods. They showed similar results with each other and 78Se showed was a bit better than 76Se and 77Se. However, different spikes showed different results when NIST SRM 1568a and SRM 2967 were analyzed because of the several interferences on the m/z measured and calculated. Interferences due to the generation of SeH from ORC was considered as well as As and Br in matrix. The results showed similar accuracy and precisions against SRM 1568a, which has a simple background matrix, for all three spikes and the recovery rate was about 80% with steadiness. The %RSD was a bit higher than inorganic standard (1.8 %, 8.6 %, and 6.3 % for 78Se, 76Se and 77Se, respectively) but low enough to conclude that this experiment is reliable. However, mussel tissue has a complex matrix showed inaccurate results in case of 78Se isotope spike (over 100 % RSD). 76Se and 77Se showd relatively good results of around 98.6 % and 104.2 % recovery rate. The errors were less than 5 % but the precision was a bit higher value of 15 % RSD. This clearly shows that Br interferences are so large that a simple mathematical calibration is not enough for a complex-matrixed sample. In conclusion, all three spikes show similar results when matrix is simple. However, 78Se should be avoided when large amount of Br exists in matrix. Either 76Se or 77Se would provide accurate results.

A Study on the Properties of Fe-Se-Te System (Fe-Se-Te계의 특성 연구)

  • Choe, Seung-Han
    • Korean Journal of Materials Research
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    • v.9 no.8
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    • pp.854-857
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    • 1999
  • The properties of Fe-Se-Te system(FeSe(sub)1-xTe(sub)x, x=0.2, 0.5, 0.8) have been studied by means of the X-ray diffraction method and Mossbauer spectroscopy. The results of X-ray diffraction patterns show that three samples have the ixed structure of tetragonal PbO and a small amount of hexagonal NiAs structure respectively. For x=0.5 the lattice parameters of tetragonal PbO structure are a=3.795$\AA$, c=5.896$\AA$ and c/a=1.55. The Mossbauer spectra were obtained with the various temperature variation and than they do not exhibit magnetic hyperfine structure but show a strong doublet. The values of observed isomer shift and quadrupole splitting suggest that the irons of all samples exist in the +2 oxidation state with a major covalent contribution. The temperature dependence of isomer shift values for x=0.8 seems to be originated from the second order Doppler effect.

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A Numerical Study on Aerodynamic Noise Characteristics of the Tandem Cylinders using DES and FW-H Acoustic Analogy (DES와 FW-H 음향상사법을 이용한 탠덤 실린더의 공력소음 특성 연구)

  • Kim, Manshik;Lee, Youn Kyu
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.46 no.11
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    • pp.883-891
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    • 2018
  • In this paper, aerodynamic noise simulation was conducted using DES (Detached Eddy Simulation) and FW-H (Ffowcs Williams and Hawkings) acoustic analogy for the tandem cylinders which have configuration similar to a landing gear of airplanes. Numerical simulation for the tandem cylinders whose centers are 3.7D apart was carried out and results were compared with the measured data such as flow characteristics, pressure coefficients on the cylinder surfaces and far-field noise characteristics. It was confirmed that periodically shedded vortices released at the upstream cylinder and impinged on the downstream cylinder surface are major sources of aerodynamic noise. After verifying the computational method of using DES and FW-H acoustic analogy for predicting aerodynamic noise of tandem cylinders, additional simulation was conducted to examine the effect of attaching a splitter plate at the rear of the upstream cylinder. It was confirmed that the noise level in specific frequency band decreased significantly because the splitter plate changed the vortex shedding features and reduced dipole noise source.

An Experimental Study on the Noise Reduction of Cooling Fans for Four-ton Forklift Machines (4톤급 지게차 냉각홴 소음 저감에 관한 실험적 연구)

  • Choi, Daesik;Kim, Seokwoo;Yeom, Taeyoung;Lee, Seungbae
    • Journal of Drive and Control
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    • v.18 no.1
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    • pp.1-8
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    • 2021
  • This paper presents research on methods for the reduction of forklifts' noise level for the increased comfort and safety of its operator. A cooling fan with a high air volume flow rate installed in the forklift acts as an important design parameter which efficiently cools the heat exchanger system, helping to transfer internal heat from the engine room to the outdoors with both transmitted and diffracted opening noises. The cooling fan contributes significantly to both the forklift's emitted sound power and the operator room's noise level, thereby necessitating research on the forklift's reduction of acoustic power level and transmission. A noise analysis for various fan models with a biomimetic design based on eagle-wing geometry was conducted. In addition to the acoustic power generation, the aerodynamic performance of the cooling blade is also strongly influenced by the design of airfoil distribution, thereby requiring optimization. The cooling fans were fabricated and installed in the forklift in order to check the efficacy of the forklift engine's cooling, and the final version of the fan was measured for its ability to lower acoustic power level and cool the engine room. This study explains the aerodynamic and acoustic features of the designed fans with the use of BEM analysis and forklift test results.

VALIDATION OF AURIC MODEL WITH EUV/FUV DAYGLOW OBSERVATION OF STP78-1 SATELLITE (STP78-1 위성의 극자외선/원자외선 낮대기광 관측자료를 이용한 AURIC 모델의 검증)

  • Kang, Mi-Ji;Kim, Jeong-Han;Kim, Yong-Ha
    • Journal of Astronomy and Space Sciences
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    • v.24 no.1
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    • pp.55-68
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    • 2007
  • We carried out a validation study on AURIC FUV/EUV dayglow calculation with $OII\;834{\AA},\;OI\;989{\AA},\;OI\;1027{\AA},\;NII\;1085{\AA},\;NI\;1134{\AA},\;NI\;1200{\AA},\;OI\;1304{\AA},\;OI\;1356{\AA}$ dayglows observed by STP78-1 satellite. Comparison between calculated and observed values indicates that they are in agreement within about 20% for dayglows of $OII\;834{\AA},\;OI\;1027{\AA},\;NI\;1200{\AA},\;OI\;1304{\AA}$. However, the calculated intensities of $OI\;989{\AA},\;NII\;1085{\AA},\;NI\;1134{\AA}$ are only 42, 74 and 45% of the observed values, respectively, showing serious differences from the observation. It was surmised that the differences in $OI\;989{\AA}\;and\;NI\;1134{\AA}$ are due to incomplete calculation of radiative transfer and uncertain photochemical processes in AURIC model, respectively. The difference in $NII\;1085{\AA}$ is conjectured to be due to variation of the input solar EUV flux rather than due to AURIC model itself. For up-looking dayglows from the satellite, the calculated values from AURIC are all less than those of STP78-1, which may imply that AURIC model does not include dayglow contribution from regions below the satellite altitude when it computes dayglows in up-looking direction. The differences are particularly serious for $OI\;989{\AA},\;NI\;1134{\AA},\;NI\;1200{\AA}$ dayglows. The calculated latitudinal variation of $OII\;834{\AA}$ dayglow is also significantly different from the observed one, especially at mid-latitude regions. This may be due to inability of MSISE-90 (in input of AURIC) to simulate oxygen atom densities at mid-latitudes during auroral storms at those days of STP78-1 observations. Our findings of the validation study should be resolved when AURIC model is revised in future.