• The Journal of Korean Academy of Prosthodontics
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• v.58 no.4
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• pp.275-281
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• 2020

Purpose: Development of a latent antimicrobial soft liner is strongly needed to overcome a possible inflammation related with its dimensional degrade or surface roughness. Modified tissue conditioner (TC) containing chitosan-doped silver nanoparticles (ChSN) complexes were synthesized and assessed for their characterizations. Materials and methods: ChSN were preliminarily synthesized from silver nitrate (AgNO₃), sodium borohydride (NaBH₄) as a reducing agent and chitosan biopolymer as a capping agent. Ultraviolet-visible and Fourier transform infrared spectroscopy were conducted to confirm the stable reduction of nanoparticles with chitosan. Modified TC blended with ChSN by 0 (control), 1.0, 3.0 and 5.0 % mass fraction were mechanically tested by ultimate tensile strength (UTS), silver ion elution and color stability (n=7). Results: At 24 hour and 7 day storage periods, UTS values were not significant (P>.05) as compared with pristine TC (control) and silver ion was detected with the dose-dependent values of ChSN incorporated. Color stability of TC were influenced by ChSN add, with the higher doses, the significantly greater color changes (P<.05). Conclusion: A stable synthesized ChSN was acquired and modified TC loading ChSN was characterized as silver ion releasing without detrimental physical property. For its clinical application, antimicrobial test, color control and multifactor investigations are still required.

• Journal of Korean Society of Forest Science
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• v.30 no.1
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• pp.19-29
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• 1976

The fiberboard and paper mills in this country are much affected by the price hikes and shortage of phenolic resins, since phenolic acid as a raw material depends on imported good. It is prerequisite to fiberboard industry to help replace with other sized and stabilize the prices and supply of them, improving the quality of boards. Thus, the present study was carried out to examine the effect of strength increasing sized such as urea formaldehyde resin (anion and cation type) and urea melamine copolymer resin, on the quality of the wet forming hardboard, and comparing them with two types of proprietary modified melamine resins, and ordinary size, phenol resin. The Asplund pulp was prepared from wood wastes mixed with 20 percent of lauan and 80 percent of pines as a fibrous material. After sizing agents were added at a pH of 4.5 for 10 minutes with alum in the beater, the stock was made in the form of wet sheet, prepared, and then performed by hot pressing cycle: $180^{\circ}C$, $50-6-5kg/cm^2$, 1-2-7 minutes. The properties of hardboard were examined after air conditioning. The results obtained are summarized as follows: 1. There is a significant difference in specific gravity among hardboards that were treated with strength increasing resins, but no difference is effected by the increase in the resin content. In the case of modified melamine resin, its specific gravity is highest. The middle group comprises cation type of urea resin, anion type of urea resin, and acid colloid of urea-melamine copolymer resin. The lowest is phenolic resin. 2. The difference of the moisture content of hardboard both by the resins and by the amount of each resin applied is significant. The moisture content of hardboard becomes lower along with the increase of each resin content, but there is no difference between 2 and 3 percent. 3. For water absorption, there is a significant difference both in the adhesives used and in the amount of paraffin wax emulsion. The water resistance becomes higher inn proportion to the content of the paraffin wax emulsion. To satisfy KS F standards of the water resistance, a proprietary modified melamine resin (p-6100) and modified cation type of urea resin (p-1500) do not require any paraffin wax emulsion, but in the case of anion type of urea resin, cation type of urea resin, and urea-melamine copolymer resin, 1 percent of paraffin wax emulsion is needed, and 2 percent of paraffin wax emulsion in the case of phenolic resin. 4. The difference of flexural strength of hardboard both by the resins and by the amount of each resin is significant. Modified melamine resin shows the highest degree of flexural strength. Among the middle group are urea-melamine copolymer resin, p-1500, anion type of urea resin, and cation type of urea resin. Phenolic resin is the lowest. The cause may be attributable to factors combined with the pressing temperature, sizing effect, and thermal efficiency of press platens heated electrically. 5. Considering the economic advantages and properties of hardboard, it is proposed that urea-melamine copolymer resin and cation type of urea resin be used for the development of the fiberboard industry. It is desirable to further develop the modified urea-melamine copolymer resin and cation type of urea resin through continuous study.

• Clinical and Experimental Reproductive Medicine
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• v.9 no.1_2
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• pp.69-77
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• 1982

암모니움 썰페이트 분획분리법. 초미량여과. DEAE - 셀루로오즈 및 젤 여과 크로마토그라피법 등을 사용하여 사람의 정액에서 베타 글룩유로니다아제를 분리하였다. 이 효소는 pH4.4와 온도 50${\sim}$$54^{\circ}C$에서 최고의 활동도를 나타내었다. 파라-나이트로페닐-디-글룩유로나이드를 기질로 사용하였을때 Km치는 0.59mM이었다. 또한 이 효소는 수은이온, 구리이온, 은이온에 의해 활동도가 방해되고 반면에 망간이온 및 코발트 이온에 의해서 효소의 활동도가 증가되었다. 세파댁스 G-200 젤여과법에 의해 측정된 사람의 정액 베타글룩유로니다아제의 분자량은 400,000 이었다. 이렇게 정제된 효소는 수정과정 중에서 카페시태시션의 연구에 도움을 주리라고 본다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.07b
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• pp.790-793
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• 2004

이중의 망간 perovskite 블록을 가진 Ruddlesden-Popper 상(R-P phase) $Sr_3Mn_2O_7$ 은 공기중에서 불안정하다. 본 연구에서는 망간 이온 자리에 철 이온을 소량 치환 함으로써 R-P 상을 안정화 시켰으며 이들의 결정구조는 X-선회절 데이터를 이용하여 Rietveld 법으로 정밀화하였다. 안정화에 필요한 Fe 이온의 양은 약 x=0.15로 나타났으며 Fe이온의 양이 증가함에 따라 쉽게 안정화 되었다. 자화율 측정결과 x=0.20 시료는 120K에서 paramgnetic-antiferromagnetic 전이를 나타내었고 이 전이 온도는 치환되는 Fe이온의 양이 증가함에 따라 감소하는 경향을 나타내었다.

• Proceedings of the Korean Vacuum Society Conference
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• 1999.07a
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• pp.142-142
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• 1999

열역학적 평형하에서 금(Au)은 사파이어(Sapphire: 다결정 Al203)와 반응을 하지 않으므로 접합성이 약하나 사파이어표면을 Ar 이온으로 에칭한후 금박막을 증착하였을 때 후 열처리 없이도 대단히 강한 접합(>70MPa)이 얻어졌다. 접합기구를 규명하기 위해 고 해상도 Auger 전자광분광기로 금/사파이어 쌍의 입계에 Ai-Al-O 화합물이 1-2 원자층 범위내에서 형성되어 있고 7KeV의 Ar 이온에너지로 3분간 조사하을 때 사파이어표면에 환원으로 인한 금속알루미늄이 형성되어 있음이 발견되었다. 이 이온조사로 인한 환원은 선택적 에칭으로 인한 것으로 TRIM 계산결과와도 일치하는 것이다. 따라서 금박막과 이온조사된 사파이어 사이의 강한 접합은 이온조사로 인한 사파이어 표면에 충돌할 때의 운동 에너지가 구동력이 되어 Au-Al-O 화합물의 형성으로 결론될 수 있다.

• Proceedings of the Korean Society of Machine Tool Engineers Conference
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• 2005.05a
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• pp.360-363
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• 2005

본 연구에서는 인듐 액체금속이온원을 제작하여 빔 특성에 대해 연구를 하였으며, 기존의 연구를 하였던 갈륨 액체금속 이온원의 빔특성과 비교분석 하였다. 빔특성 분석을 위해 빔 안정도, 전류-전압특성곡선, 에너지 퍼짐을 측정하였다. 액체금속이온원에 사용되는 액체금속 저장소 및 바늘전극(tip)은 $500{\mu}m$의 직경을 갖는 텅스텐을 사용하였으며, 국내에서 제작된 제품을 사용하였다. 액체금속 저장소의 구조는 이전에 구상하여 연구가 이루어진 6개의 pre-etching된 텅스텐와이어(wire)가 묶여진 형태를 사용하였다.

• Proceeding of EDISON Challenge
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• 2016.03a
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• pp.1-7
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• 2016

Triphenylsulfonium 양이온(TPS)은 잘 알려진 광산 생성자(photoacid generator, PAG)중 하나로 양이온성 중합반응(cationic polymerization)의 개시제로 널리 사용됐으며, 유기발광다이오드의 활성층, 폴리머 발광다이오드의 전자주입층을 구성하는 재료로도 사용되고 있다. TPS는 200nm 주변의 빛을 흡수하면 탄소-황 결합이 끊어져 페닐 라디칼과 diphenylsulfonium 양이온 라디칼로 분해되는 것이 알려져 있다. 본 연구에서는 밀도범함수이론과 시간의존 밀도범함수이론을 이용 triphenylsulfonium 이온의 광학적 특성을 조사하였다. 가장 안정한 구조를 기준으로 자외선 흡광 스펙트럼을 계산하였고, 실험값에 잘 맞는 것을 확인하였다. TPS의 빛에 의한 해리 과정을 알아보기 위해 페닐-황 결합 길이를 변화시키며 TPS의 흡광 스펙트럼을 계산, 여기상태 포텐셜 에너지 곡선을 구할 수 있었다. 결합의 분해에 이용되는 상태들은 주로 점유 분자 오비탈에서 최저준위 비점유 분자 오비탈(LUMO)로 들뜨는 성분을 가지고 있었는데, 이는 LUMO가 반결합성 오비탈이기 때문이다.

• Korean Journal of Soil Science and Fertilizer
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• v.27 no.1
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• pp.15-20
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• 1994

Lysimeter experiments were conducted to elucidate the behavior of $NO_3-N$ derived from urea applied at different rates and accompanying cations in soils and to further provide fundamental information of rational nitrogen-fertilizer management. Urea was applied at rates of 0, 7, 14, 21, 28 and 35kg N/10a to sandy loam pakced into PVC cylindrical lysimeter(vol. : $0.187m^2$, area $0.43m^2$). Leachates from the lysimeter with or without grass grown were collected periodically and analyzed for $NO_3$ and cations. Grass growth and yield responses to N fertilization were also examined. Dry matter yield and nitrogen uptake increased with the urea application rate. The amount of leachate from the lysimeter was negatively correlated with urea application ratesl($r=-0.95^{**}$). The nitrate leaching loss with grass grown was 230 g N/10a at the maximum rate of 35kg N/10a, but the highest leaching loss was observed as 1,607 g N/10a from the bare plot. Increase in urea application rates decreased significantly leaching losses of Ca, Mg, K and Na(>0.01). The highest leaching loss from the bare plot was observed for Ca but only 6.5% of exchangeable form and 14.0% for K from the grass plot respectively. Equivalent ratio of cations to nitrate leached were 3.2 % for the bare plot and the ratio for the grass plot increased with the urea application rate, ranging from 18.6 to 32.7%.

• Journal of the Korean Chemical Society
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• v.55 no.1
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• pp.63-69
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• 2011

This work discusses the fabrication, development and potential response behaviors of $Ag^+$ ion-selective electrodes ($Ag^+$-ISE) based on N,N'-bis(2-hydroxybenzyl)-1,3-diaminopropane (L1) and N,N'-bis(2-hydroxybenzyl)-2,2-dimethyl-1,3-diaminopropane (L2) as carriers. The observations indicated that the resulting electrode based on L1 toward $Ag^+$ showed stable near-Nernst slope approaching 58.7 mV/dec and the optimum potential response characteristics in a linear range at least five orders of magnitude with a detection limit of $1.0{\times}10^{-6}M$. The proposed electrode displayed the preferential selectivity to $Ag^+$ against other tested cations. The excellent potential analytical characteristics could lead to the successful applications of silver assay in significant real samples, indicating that the proposed $Ag^+$-ISE showed a significant advancement of measurement capabilities. But for the electrode based on L2, the poor potential response characteristics were observed in total experiment process.

• Korean Journal of Environmental Biology
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• v.39 no.4
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• pp.550-558
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• 2021

In a radiotracer study, the bioaccumulation and efflux of metals in earthworms (Eisenia fetida) exposed to soil spiked with ZnO and Ag nanoparticles (AgNP) were compared to those exposed to soil spiked with ionic Zn and Ag. Additionally, the bioavailability and chemical mobility of nano- and ionic metals in the soil were estimated using the sequential extraction method and compared to the bioaccumulation factor(BAF). The BAF for ZnO (0.06) was 31 times lower than that for Zn ions (1.86), suggesting that ZnO was less bioavailable than the ionic form in contaminated soil. In contrast, the BAFs for two types of AgNPs coated with polyvinylpyrrolidone (0.12) or citrate (0.11) were comparable to those of ionic Ag (0.17). The sequential extraction of metals from the soil suggests that the chemically mobile fractions in the Zn ion treatment were higher(35%) than those (<20%) in the Ag ion treatment, which was consistent with the greater BAFs in the former than the latter. However, the chemical mobility in the ZnO treatments did not predict bioavailability. The efflux rates of Ag (3.2-3.8% d^-1) in the worms were 2-3×those(1.2-1.7% d^-1) for Zn.