• Title/Summary/Keyword: 은

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Studies on Distributions and Morphological Characteristics of Calanthe discolor, C. sieboldii, and C. bicolor Native to Cheju Province (제주 자생 새우란, 금새우란, 왕새우란의 분포와 외형적 특성에 관한 연구)

  • Hyun, Myung-Ryuk;Choi, Ji-Yong;Suh, Jung-Nam;So, In-Sup;Lee, Jong-Suk
    • Horticultural Science & Technology
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    • v.17 no.4
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    • pp.497-499
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    • 1999
  • Distribution analysis on natural habitats for the genus Calanthe in Mt. Halla of Cheju province revealed that C. discolor and C. sieboldii were found mostly in the range of 120~400 m and 300~600 m above the sea level, respectively. C. bicolor was found in 300~400 m where both C. discolor and C. sieboldii were overlapped. The present morphological assessments showed that C. discolor had the smallest sizes of leaves and floral parts, C. had the largest, while C. bicolor had the intermediate between the above mentioned two species. Flower colors of C. discolor were brownish red and simple white, and that of C. sieboldii was merely golden yellow, whereas C. bicolor had a diverse mixed colors originated from the other two species. The specific distribution of natural habitats and morphological characteristics of three Calanthe species led the suggestion that C. bicolor can be regarded as new species derived originally from natural hybridization between C. discolor and C. sieboldii.

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Study on chemical properties of Pinus koraiensis Sieb. et Zucc. resin (잣나무 송지(松脂)의 화학적(化學的) 성상(性狀)에 관(關)한 연구(硏究))

  • Kang, Ha-Young;Hwang, Byung-Ho
    • Journal of the Korean Wood Science and Technology
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    • v.4 no.1
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    • pp.3-7
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    • 1976
  • This is to reveal the chemical properties of resin of Pinus koraiensis Sieb. et Zvcc, and to give the basic data to resin chemistry and resin processing field. Its results are given; 1) Acid value was shown as 134.12 2) Saponification value was shown as 172.72 3) Iodine value was shown as 109.93 and therefore, it is considered as semi-boiled oil. 4) Ester value was shown as 41.60 5) Moisture content was shown as 11.28% 6) The impurities of resin was shown as 0.09% 7) The amount of turpentine oil was shown as 23.29% 8) Rosin content was shown as 76.74% 9) The amount of resin acid was shown as 72.33% 10) Unsaponification matter was shown as 4.41% 11) The refractive index of resin was shown as 1.5045 at $N^{20}_D$.

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The Optimization of Silver Leaching from the Samjo Mine Concentrate by Thiourea (티오요소를 이용한 삼조광업 정광으로부터 은 용출 최적화)

  • Yang, Gwon-Seung;Kim, Bong-Ju;Choi, Nag-Choul;Park, Cheon-Young
    • Journal of the Mineralogical Society of Korea
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    • v.26 no.1
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    • pp.1-8
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    • 2013
  • This study was carried out to test the possibility of using an environmentally friendly method of leaching silver concentrate from the Samjo mine. The Samjo mine ore contained minerals such as pyrite, chalcopyrite, galena, arsenopyrite, and sphalerite. The concentrate samples tested with the thiourea solution were roasted at $750^{\circ}C$. The results of different experimental conditions showed that the highest silver leaching rate was obtained when the concentration of thiourea was at 0.8 g with ferric sulfate at 0.425 g and the leaching temperature at $60^{\circ}C$. The Ag leaching rate obtained was 91.5% at a pulp density of 10%. However, in the XRD analysis, peaks of pyrite, galena, and hematite were still found in the leached solid residues in which the Ag leaching rate was the highest. it is expected that the unrecovered silver in the solid residue can be lost.

Preparation of Silver/Polystyrene Nanocomposites by Radical Polymerization Using Silver Carbamate Complex (은 카바메이트 복합체를 이용한 라디칼 중합에 의한 은/폴리스티렌 나노복합체의 제조)

  • Park, Heon-Su;Park, Hyung-Seok;Gong, Myoung-Seon
    • Polymer(Korea)
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    • v.34 no.2
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    • pp.144-149
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    • 2010
  • Ag/polystyrene(PS) nanocomposites were prepared by in situ reduction of silver 2-ethylhexylcarbamate (Ag-CB) complex and follwing radical polymerization only by heating at 110 $^{\circ}C$. In contrast to this conventional heating method, the microwave irradiation afforded well-dispersed silver nanoparticles(NPs) in styrene monomer without polymerization. The synthesis of Ag NPs proceeded uniformly throughout the reaction vessel only under microwave irradiation, completing the reaction simultaneously in the whole reaction solution. Successive polymerization of the monomer containing the resultant NPs has successfully produced a hybrid of the silver NPs dispersed in PS matrix. Ag/PS (0.1/100) nanocomposites were prepared successfully by melt-mixing process using Ag/PS(4.0/100) as a master-batch. UV-VIS spectroscopy, TEM, and X-ray diffraction techniques were used to investigate the process of formation of Ag/PS nanocomposites.

Preparation of Silver Nanoparticles with Various Morphology Using Amphiphilic Graft Copolymer Membranes (양쪽성 가지형 공중합막을 이용한 다양한 모양의 은 나노입자 제조)

  • Seo, Jin-Ah;Choi, Jin-Kyu;Ahn, Sung-Hoon;Yeon, Seung-Hyeon;Kim, Jong-Hak
    • Membrane Journal
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    • v.20 no.2
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    • pp.169-172
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    • 2010
  • Silver ions of poly(vinyl chloride)-g-poly(styrene sulfonic acid) (PVC-g-PSSA) graft copolymer were reduced to form silver nanoparticles under thermal condition ($80^{\circ}C$). We were successful in synthesizing silver nanoparticles with various morphologies by changing reaction time. At short reaction times (~1 h), silver nanoparticles with 5 nm in size were formed without disrupting a microphase-separated structure of graft copolymer. At medium reaction times (~5 h), silver nanoparticles were aggregated to form large clusters ranging 30~50 nm in size. At much longer reaction times (~18 h), hurricane-like silver clusters were observed due to strong particle aggregation.

A Novel Patterning Method for Silver Nanowire-based Transparent Electrode using UV-Curable Adhesive Tape (광경화 점착 테이프를 이용한 은 나노와이어 기반 투명전극 패터닝 공법)

  • Ju, Yun Hee;Shin, Yoo Bin;Kim, Jong-Woong
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.3
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    • pp.73-76
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    • 2020
  • Silver nanowires (AgNWs) intrinsically possess high conductivity, ductility, and network structure percolated in a low density, which have led to many advanced applications of transparent and flexible electronics. Most of these applications require patterning of AgNWs, for which photolithographic and printing-based techniques have been widely used. However, several drawbacks such as high cost and complexity of the process disturb its practical application with patterning AgNWs. Herein, we propose a novel method for the patterning of AgNWs by employing UV-curable adhesive tape with a structure of liner/adhesive layer/polyolefin (PO) film and UV irradiation to simplify the process. First, the UV-curable adhesive tape was attached to AgNWs/polyurethane (PU), and then selectively exposed to UV irradiation by using a photomask. Subsequently, the UV-curable adhesive tape was peeled off and consequently AgNWs were patterned on PU substrate. This facile method is expected to be applicable to the fabrication of a variety of low-cost, shape-deformable transparent and wearable devices.

Antibacterial Properties of Silver-alginate/PVP Nanofiber (은-알지네이트/PVP 나노섬유의 항균 특성)

  • Choi, Yoo-Sung;Min, Kyung-Du;Yoon, Doo-Soo
    • Applied Chemistry for Engineering
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    • v.24 no.4
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    • pp.416-422
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    • 2013
  • In order to incorporate silver ions into the alginate, silver-alginate was prepared with aqueous solutions of silver nitrate. In the study, the silver-alginate was prepared by blending with poly vinylpyrrolidone solutions and the electrospinning was performed by using this blend solution. Antibacterial properties of silver-alginate/PVP solutions were estimated for Escherichia coli and Staphylococcus aureus by the colony counting test. Electrospinning conditions of silver-alginate/PVP solution were the tip-to-collector distance of 22 cm, the flow rate of the solution at 0.01 mL/min, and the voltage at 26 kV. The form and size of silver-alginate/PVP nanofibers were estimated by SEM and Image J. The average diameter of the electrospun SA5P15 fibers was 124 nm and showed a narrow diameter distribution. The reduction of bacteria for SA5P15 exhibited 99.9% after 24 h.

Ultrathin Metal Films on Single Crystal Electrodes : Electrochemical & UHV Studies

  • ;A.Wieckowski
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.141-141
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    • 1999
  • 전기화학과 초고진공(ultra-high vacuum, UHV) 분광법을 이용하여 고체/액체의 계면에서 일어나는 현상을 분자단위에서 이해하고 조절하기 위한 연구를 수행하였다. 이들 중 전기화학으로 형성된 구리 및 은 금속(sub)monlayer 박막을 그 예로 선택하여 소개한다. 초박막 금속의 흡착량은 cyclic voltammogram과 새로 개발된 Auger electron spectroscopy (AES) 정량법을 통해 얻어졌고, 이 값들은 low energy electron diffraction (LEED) 및 in-situ atomic force microscopy (AFM)법을 이용한 구조 분석결과와 비교되어졌다. 또한 화학상태를 확인하기 위하여 core-level electron energyy loss spectroscopy (CEELS)를 사용하였다. 먼저 황산 전해질에서 금(111) 단결정 전극상에 전기화학적으로 형성된 굴의 계면특성을 조사하였다. 특정 전위값에서 2/3 ML의 구리와 1/3 ML의 음이온이 상호 흡착하여 ({{{{ SQRT { 3} }}$\times${{{{ SQRT { 3} }}) 격자 구조를 보였고, 전위값이 커지거나 줄어들면, 이 구조가 사라지는 현상이 관찰되었다. 즉 이 ({{{{ SQRT { 3} }}}}$\times${{{{ SQRT { 3} }}}}) 흡착구조는 첫 번째 UPD underpotential deposition) 피크에 특이하게 관련되어 있음을 알 수 있었다. 금속 초박막 형성에 미치는 음이온의 영향을 좀 더 확인하기 위해 초박막 은이 증착된 금 단결정 전극상의 황산 음이온에 관하여 연구하였다. 은의 증착이 일어날 수 없는 양전위값 영역에서 ({{{{ SQRT { 3} }}}}$\times${{{{ SQRT { 3} }}}})의 규칙적인 음이온의 구조를 보였다. 그리고 은의 장착은 세척 과정과 용액의 농도에 따라 p(3$\times$3)과 p(5$\times$5)의 규칙적인 두가지 구조를 가졌다. in-situ AFM에서는 p(3$\times$3)의 은 증착 구조만 나타났고, 음 전위값으로 옮겨가면 p(1$\times$1) 구조로 바뀌었다. ex-situ 초고진공 결과와 이 AFM의 in-situ 결과를 상호 비교 논의할 것이다. 음이온의 흡착이 없는 묽은 플로르산(HF) 전해질에서 은은 전위값을 음전위 쪽으로 이동해 감에 따라 p(3$\times$3), p(5$\times$5), (5$\times$5), (6$\times$6), 그리고 (1$\times$1)의 연속적 구조 변화를 보였다. 이 다양한 구조들을 AES로부터 얻어진 표면 흡착량과 연결시켰더니 정량적으로 잘 일치되는 결과를 보였다. 전기화학적인 증착에서는 기존의 진공 증착과 비교할 때 음이온의 공흡착이 금속 초박막 형성 메카니즘에 큰 영향을 미침을 알 수 있었다. 또한 은의 전기화학적 다층박막 성장은 MSM (monolayer-simultaneous-multilayer) 메카니즘을 따름을 확인하였다. 마지막으로 구조 및 양이 규칙적으로 조절되는 전극의 응용가능성이 간단히 논의될 것이다.

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Effects of NitrogenLeVel and Plant Populationon agronomic Chracterisitics and yield I silage Corn (질소시비와 제식밀도가 Silage 옥수수의 제형질 및 수량에 미치는 영향)

  • 강정훈;이호진;박병훈
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.6 no.1
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    • pp.44-48
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    • 1986
  • This field experiment was conducted to determine the optimum nitrogen level and plant population for silage and grain corn cv. Suweon No. 19 at Suweon from 1981 to 1982. The results obtained are summarized as follows: 1. Leaf Area Index (LAI), Loding Index (LI) and stalk diameter were increased by raising nitrogen level but ear height was decreased. And tasseling date and stalk height were not influenced by nitrogen level. 2. LAI, LI and ear height were increased by raising plant population but tasseling date, stalk height and stalk diameter were decreased. 3. Numbers of missing hill and barren plants were increased by raising nitrogen and dense plant population respectively. Grain yield and total digestible dry matter yield in 5,550 plants with 10kg of nitrogen fertilization per 10a were recommendable for grain and silage corn respectively.

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Effect of Proteolysis on the Functionalities of 7S and 11S Soy Proteins (대두(大豆) 7S 및 11S 단백질(蛋白質)의 기능성(機能性)에 대한 효소적(酵素的) 가수(加水)분해의 효과(效果))

  • Kang, Yeung-Joo;Lee, Ki-Chun;Park, Yeung-Ho
    • Korean Journal of Food Science and Technology
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    • v.20 no.3
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    • pp.344-349
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    • 1988
  • Proteolysis of 7S and 11S soy protein-rich fraction(PRF) with commercial proteases(alcalase and pronase) apperently increased protein solubility at pH 5, heat coagulation and calcium tolerence, while decreasing emulsifying capacity and foam stability regardless of the kind of protein and protease used. However, the proteolysis decreased the protein solubility of 7S PRF at pH 6 and 11S PRF at pH 4. The proteolysis of 11S PRF increased oil absorption and foam expansion, while slight decrease or almost no change was noted on 7S PRF. Heat stabilities of the emulsion and kinetic viscosities changed very little by the proteolysis.

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