• Title/Summary/Keyword: 유해화학물질 배출

Search Result 76, Processing Time 0.024 seconds

미생물을 이용한 폐수처리

  • 안준상
    • The Microorganisms and Industry
    • /
    • v.16 no.3
    • /
    • pp.56-62
    • /
    • 1990
  • 일반적으로 산업폐수및 생활하수의 생물학적 처리에 관계하는 미생물의 종류는 약1,000-2,000종에 이르는 것으로 추정된다. 이와 같은 미생물의 범위는 매우 넓어서 세균, 균류는 물론이고, 조류, 원생동물, 후생동물까지 포함한다. 19세기 이전에 미생물을 이용한 폐하수 처리는 생활하수와 같이 쉽게 분해하는 물질로만 구성되어 있기 때문에 간단한 처리 공정으로도 충분히 운영되었으나, 산업혁명 이후 새로운 화학물질이 합성되어 폐하수로 배출되므로 처리효율을 달성하는데 더욱 어렵게 되므로 미생물을 전공한 전문인력의 역할이 가일층 높아지게 되었다. 특히 1970년대 이후에는 생물공학 기법을 이용하여 독성 유해물질을 무해화(Detoxification) 하고, 광물화(Mineralization)할 수 있는 미생물 균류를 연구 개발하여 폐수나 폐기물을 처리하는데 활용코자하는 노력이 활발히 진행되고 있으며 일부는 큰 결실을 맺은 것도 있지만 아직도 연구가 진행 중인 분야가 더 많은 편이다. 그러므로 본 고에서는 지금까지 연구 보고된 결과와 앞으로 미생물을 전공한 우리들이 나아갈 방향을 제시코자 한다.

  • PDF

A Case Study on Operation of Off-Gas Treatment System of Radioactive Waste Vitrification Facility (방사성폐기물 유리화설비의 배기가스 처리계통 운영 사례 연구)

  • Lee, Hye Hyun;Park, Kyu Won
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.38 no.5
    • /
    • pp.249-254
    • /
    • 2016
  • In this study, we investigated the main characteristics of off-gas generated from melting process and off-gas treatment system operation example to provide some primary data for commercial vitrification facility design. The purpose of vitrification facility operation is to treat hazardous materials in the radioactive wastes and harmful off-gas containing a variety of chemical species generated in the glass melting process. Constructing and operating vitrification facility essentially need to be licensed through safety analysis; it is very important to treat radionuclide and hazardous materials below the legal environment emissions regulation level. We must accurately understand the characteristics of off-gas and apply an appropriate off-gas treatment process accordingly. Thus, to design the appropriate off-gas treatment there must be a wide range of elements taken into account such as characteristics of waste and melter, regulation guidance of off-gas, characteristics of generated off-gas and off-gas treatment system performance assessment.

Water Budget Analysis of Nak-Dong River basin based on K-WEAP (K-WEAP을 이용한 낙동강 수계 물수지 분석)

  • Han, Kun-Yeun;Choi, Hyun-Gu;Lee, Won-Ha;Lee, Hyun-Dong
    • Proceedings of the Korea Water Resources Association Conference
    • /
    • 2008.05a
    • /
    • pp.1713-1716
    • /
    • 2008
  • 최근 배출되는 미량유해물질로 1991년 페놀, 2004년 1,4-다이옥산, 2006년 퍼클로레이트 검출 등 빈번하게 원수수질 오염사고가 발생하고 새로운 미량유해 화학물질의 배출이 우려됨에 따라, 일부 시민단체, 시의회, 언론 등에서 깨끗하고 안전한 상수원수 확보를 위한 근본적인 대책을 요구하는 목소리가 커지고 있다. 이에 대한 대책의 일환으로 취수원 이전에 대한 타당성 등이 검토되고 있다. 이러한 요구를 바탕으로 본 연구에서는 K-WEAP 모형을 이용하여 낙동강수계 물수지 분석을 실시하였다. 관련된 기존자료를 이용하여 용수수요량을 산정하였으며, 갈수량시 물수지 분석을 실시하였다. 연구에 사용된 K-WEAP 모형은 SEI-B(Srockholm Environment Institute, Boston Center)에서 개발된 WEAP에 기반을 두고 우리나라에 특성에 맞게 모의형태를 개선하고 한글화한 모형으로 분석대상 지역으로서 도시지역과 농업지역, 단일 소유역이나 복잡한 하천유역의 물 수요-공급 시스템에 적용할 수 있다. 또한 K-WEAP 모형은 용수목적별 수요량 분석, 물 절약, 수리권과 배분 우선순위, 지하수와 하천유량 모의, 저수지 운영, 수력발전, 오염물질 추적, 생태계 필요수량 분석과 같은 광범위한 부문의 문제들까지 다룰 수 있다. 본 연구에서 물수지 분석에 사용된 대상구간은 낙동지점에서 고령교지점까지 약 120km이며, 낙동강에 유입되는 지류로는 감천과 금호강을 대상에 포함하였다. 대상구간에 대해서는 3가지의 시나리오를 바탕으로 모의를 진행하였다. 선정된 3가지 시나리오는 현재의 대구 인근지역의 취수와 방류를 고려하는 상태와 현실가능성이 있는 2가지의 대안에 대해서 분석을 실시해 보았다. 대안들은 각각의 대구 취수시설을 구미 상류로 이전하여 취수하는 상황과 구미지역 및 칠곡지역의 방류구 시설을 하류로 이전하여 방류하는 상황으로 가정하여 분석을 실시하였다. 분석결과 현재 상태의 시나리오에서만 갈수기시 만족할 만한 결과를 보여주었고 나머지 2가지의 시나리오에서는 유량이 부족함을 나타났다. 현재의 상태를 모의한 시나리오를 제외한 시나리오의 분석에서는 갈수기 시에 물 부족을 겪게 된다. 이는 낙동강 상류에서 추가방류가 없으면 해결되지 못하는 상황으로 다른 대안들(신규 댐 방류 등)에 대한 추가적인 시나리오 분석이 필요할 것으로 판단된다.

  • PDF

A Study on the VOC Decomposition Factors by Electron Beam Irradiation (전자빔 조사에 의한 VOC 분해 인자에 관한 연구)

  • Kim, Jo-Cheon;Kim, Gi-Jun;Jeon, Jin;Lee, Jae-Hyung;Park, Jong-Rae;Han, Beom-Su;Kim, Jin-Gyu
    • Proceedings of the Korea Air Pollution Research Association Conference
    • /
    • 2002.04a
    • /
    • pp.195-196
    • /
    • 2002
  • 휘발성 유기화합물(Volatile Organic Compounds; VOCs)은 용제를 사용하는 도장공정, 석유화학공정 등 각종 산업공정과 자동차로부터 배출되어 대기중에 광화학 산화물을 형성하거나 그 자체로 발암성 또는 악취성을 나타내는 물질로 인체에 유해한 영향을 미치며, 한편 간접적으로 온실가스의 역할을 하는 것으로 알려졌다. 가속기를 이용한 전자빔 처리공정의 경우 상온에서 운영되고 2차오염물 발생이 거의 없으며, 특히 유량이 매우 크고 저농도로 배출되는 VOCs의 처리의 경우에 기존의 처리법 보다 더욱 경제적이고 효율적으로 적용될수 있다. (중략)

  • PDF

A Study on the Removal Characteristics of VOCs Using the Hybrid Technique of E-beam and Adsorbent (전자빔과 흡착제의 Hybrid 기술을 이용한 휘발성유기화합물 제거특성 연구)

  • 김조천;김기준;한범수;이재형;선우영;임용재
    • Proceedings of the Korea Air Pollution Research Association Conference
    • /
    • 2003.11a
    • /
    • pp.67-68
    • /
    • 2003
  • 휘발성 유기화합물(Volatile Organic Compounds; VOCs)은 용제를 사용하는 도장공정, 석유화학공정 등 각종 산업공정과 자동차로부터 배출되어 대기중에 광화학 산화물을 형성하거나 그 자체로 발암성 또는 악취성을 나타내는 물질로서 인체에 유해한 영향을 미친다. VOCs 물질의 전자빔 처리공정의 경우 상온에서 운영되어 에너지의 소모량이 적고, 2차오염물 발생이 매우 적으며 다양한 종류의 VOCs에 적용이 가능하므로 기존 방지시설의 보완 및 대체시설로서는 최적인 것으로 평가되고 있다. (중략)

  • PDF

Determination of byproducts after treatment in PCBs-containing transformer oils (PCBs 함유 절연유의 처리 후 부산물 배출특성 연구)

  • Shin, Sun Kyoung;Park, Jin Soo;Kang, Young Yeul;Hwang, Seung Ryul;Kim, Young Sik
    • Analytical Science and Technology
    • /
    • v.21 no.3
    • /
    • pp.201-211
    • /
    • 2008
  • The treatment efficiency of PCBs containing wastes has been investigated. The samples treated by electron beam and de-chlorination method were analyzed to verify the byproducts before treatment and after treatment. In the treated samples by electron beam irradiation, PCBs were not detected by comparing the peak matching using the Korean official waste test method. On the other hand, PCBs congeners were detected by analyzing individual isotope method using HRGC/HRMS. Most of PCB congeners in waste were decomposed to 3-chlorobiphenyls, lower chlorinated congener produced during the treatment of electron beam. In the chemical dechlorination treatment, it was found that the concentrations of PCBs in treated samples were lower than those of regulation criteria in Waste & POPs management law and the after treatment concentration were satisfied to the regulation criteria. Also, dioxins were not observed after the physio-chemical treatment processes of PCBs containing wastes.

A Study on the Emission Changes in Reduction Chemical Substances in Korea (유해화학물질 배출량 변화에 관한 연구: 배출저감계획서 작성 대상물질 중심으로)

  • Im, JiYoung;Lee, MyeongJi;Kim, HyunJi;Ryu, JiSung;Yun, DaeSik;Jang, YongChul;Lee, ChungSoo
    • Journal of Environmental Health Sciences
    • /
    • v.46 no.2
    • /
    • pp.159-169
    • /
    • 2020
  • Objectives: The purpose of this study was to investigate changes among the nine kinds of reduction chemical substances in Korea over the period of 2008-2017. We will define basic data for improving the management methods for reducing chemical substances. Methods: A survey of hazardous pollutant emissions for 2008-2017 was conducted through the pollutant Release and Transfer Register homepage. Nine kinds of designated reduction chemical substances (Benzene, Vinyl chloride, Trichloro ethylene, 1,3-butadiene, Dichloro methane, Tetrachloro ethylene, N,N-dimethylformamide, Acrylo nitrile, and Chloroform) provided the study subjects. The emission of hazardous chemicals and health effects used the National Health Statistics and Integrated Chemicals Information System (ICIS) as a reference. Results: Hazardous pollutant emissions increased by 1.2 times over the past decade, and nine types of reduction chemical substances increased by 1.6 times. By region, the emissions of reduction chemical substances over the last 10 years were in the order of Chungbuk, Gyeonggi, and Gyeongbuk. Emissions of Dichloro methane was the highest in Chungbuk and Gyeongbuk. N,N-dimethylformamide was the highest in Gyeonggi. Carcinogen pollutant emissions showed a tendency to increase continuously. In addition, group 1 carcinogen emissions showed a tendency to decrease. Conclusion: In the last decade, the amount of hazardous chemical emissions has been continuously increasing. Hazardous chemical emissions require facility improvement for continuous emissions reduction. More research on reduction of emissions is needed.

Characterization of Heavy Metals Including Mercury and Fine Particulate Emitted from a Circulating Fluidized Bed Power Plant Firing Anthracite Coals (무연탄 순환유동층 발전소로부터 배출되는 수은을 포함한 중금속 및 미세분진의 배출 특성)

  • Kim, Jeong-Hun;Yoo, Jong-Ik;Seo, Yong-Chil
    • Korean Chemical Engineering Research
    • /
    • v.48 no.2
    • /
    • pp.268-274
    • /
    • 2010
  • Emission of heavy metals as hazardous air pollutants has been focused with tightening regulatory limits due to their hazardousness. Measurements and characteristic investigations of heavy metals emitted from a commercial power plant burning anthracite coal have been carried out. The plant consists of a circulating fluidized bed combustor, a cyclone, a boiler and an electrostatic precipitator(ESP) in series. Dust and gaseous samples were collected to measure main heavy metals including gaseous mercury before ESP and at stack. Dust emissions as total particulate matter (TPM), PM-10 and PM-2.5 at inlet of ESP were very high with 23,274, 9,555 and $7,790mg/Sm^3$, respectively, as expected, which is much higher than those from pulverized coal power plants. However TPM at stack was less than $0.16mg/Sm^3$, due to high dust removal efficiency by ESP. Similarly heavy metals emission showed high collection efficiency across ESP. From particle size distribution and metal enrichment in sizes, several metal concentrations could be correlated with particle size showing more enrichment in smaller particles. Mercury unlike other solid metals behaved differently by emitting as gaseous state due to high volatility. Removal of mercury was quite less than other metals due to it's volatility, which was 68% only. Across ESP, speciation change of mercury from elemental to oxidized was clearly shown so that elemental mercury was half of total mercury at stack unlike other coal power plants which equipped wet a scrubber.

Domestic Status for Acceptance of Various International Conventions relating to Marine Environment Management (해양환경관리 관련 각종 국제협약의 국내 수용 현황)

  • Kim, Kwang-Soo
    • Proceedings of KOSOMES biannual meeting
    • /
    • 2006.11a
    • /
    • pp.221-237
    • /
    • 2006
  • Domestic laws such as Korea Marine Pollution Prevention Law which has been made and amended according to the conclusions and amendments of various international conventions, especially by MARPOL 73/78, were reviewed and compared with major contents of international conventions, and several alternative measures for legislating new laws or amending existing laws such as Korea Marine Pollution Prevention Law in accordance with new contents and recent amendments of existing and new international conventions were proposed. Annex VI of MARPOL 73/78 has been recently accepted in Korea Marine Pollution Prevention Law which should be applied to ships which are the moving point sources of air pollution at Sea rather than in Korea Air Environment Conservation Law which should be applied to automobiles and industrial installations which are the line and/or point sources of air pollution in land. International Convention for Ship's Ballast Water/Sediment Management should be accepted in Korea Marine Pollution Prevention Law or by a new law in order to prevent domes marine ecosystem and costal environment from the invasion of harmful exotic species through the discharge of ship's ballast water. International Convention for the Control of Harmful Anti-Fouling Systems on the Ships should be accepted in Korea Marine Pollution Prevention Law which should be applied to ships which are navigating in open sea and coastal waters rather than in Korea Noxious Chemicals Management Law. Basel Convention which shall regulate and prohibit inter-nations movements of noxious chemical substances should be accepted in Korea Marine Pollution Prevention Law in order to prevent the movement and transfer of scrap-purpose tanker ships containing bilge water of oil/water mixtures and chemicals remained on board from advanced countries to developing and/or underdeveloped countries and to conserve global marine environment after all.

  • PDF

Effect of Specific Surface Area of Activated Carbon Fiber on Harmful Gas Adsorption and Electrochemical Responses (활성탄소섬유의 비표면적에 따른 유해가스 흡착 및 전기화학적 감응 특성)

  • Kang, Jin Kyun;Chung, Yong Sik;Bai, Byong Chol;Ryu, Ji Hyun
    • Journal of Adhesion and Interface
    • /
    • v.21 no.2
    • /
    • pp.51-57
    • /
    • 2020
  • Recently, there has been growing interest in the study of removal of harmful and hazardous pollutants emitted by industrial activities. In this study, we have developed porous activated carbon fibers prepared by a water vapor activation method and analyzed the adsorptions of the harmful gases with electrochemical responses of activated carbon fibers. To control the uniformity of pore structures, active reaction areas, and active sites, the reaction conditions of activation temperatures were varied from 750 to 850 ℃ with the predetermined reaction time intervals (30 to 240 min). The SO2 and NO gas adsorptions of activated carbon fibers prepared by various reaction conditions were analyzed and monitored by electrochemical sensor responses. In particular, the activated carbon fibers prepared at the reaction temperature of 850 ℃ and time of 45 min showed the highest specific surface area (1,041.9 ㎡/g) and pore characteristics (0.42 ㎤/g), and excellent adsorption capabilities of SO2 (1.061 mg/g) and NO (1.210 mg/g) gases, respectively.