• Title/Summary/Keyword: 유해물

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Effect of Municipal Sewage Sludge on Soil Chemical Properties and Growth of Rose (Rosa hybrida L.) (생활하수슬러지가 토양 화학성 및 장미의 생육에 미치는 영향)

  • Choi, Jyung;Lee, Dong-Hoon;Park, Man;Choi, Choong-Ryeol;Kim, Kwang-Seop
    • Korean Journal of Environmental Agriculture
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    • v.21 no.2
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    • pp.117-121
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    • 2002
  • This study was conducted to find out the effect of municipal sewage sludge on the growth and heavy metal content of rose and soil chemical properties. Municipal sewage sludge was applied to soil at rate of 0, 3, 5, 10 and 15 ton/10a, the plant height, flower number and stem size of rose were found to be increase in the treatments of sewage sludge. Contents of mineral nutrients in rose stem were determined to be higher at municipal sewage sludge application plots than those of no application. But, there were not any significant increases of heavy metal contents in soil and rose stem with the sludge applications. from the results of this study, it is apparent that the application of municipal sewage sludge would not increase available heavy metals in soil.

A Study on the Allowable Crack Width of RC Beam with Corrosive Environment (염해환경에서의 RC보의 허용 균열폭 산정에 관한 연구)

  • Kim, Dongbaek;Kwon, Soondong;An, Kwanghee
    • Journal of the Society of Disaster Information
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    • v.11 no.2
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    • pp.253-261
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    • 2015
  • Deterioration of reinforced concrete structures in corrosive environment is tend to be accelerated due to ingress of aggressive ion such as chloride ion. Chloride-induced corrosion is affected by various factors such as cover concrete qualities, width of existing cracks, and cover depth of concrete. However, the allowable crack width of RC structure in design code does not consider the concrete material properties and conditions of construction except the cover depth. In this paper, an equation for allowable crack width is proposed to consider the cover concrete quality, crack width, and cover depth. Crack width, cover depth, and water-cement ratio of concrete are selected as influencing factors on corrosion of reinforcement for rapid chloride tests. From test results, the relationships between the factors and corrosion are derived. Finally, the equation for allowable crack width is derived in terms of concrete compressive strength and cover depth. The presented equation is verified by comparative calculations with design code variables.

Waste Minimization Technology Trends in Semiconductor Industries (반도체 제조 공정에서의 환경 유해성 배출물 절감 기술 동향)

  • Lee, Hyunjoo;Yi, Jongheop
    • Clean Technology
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    • v.4 no.1
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    • pp.6-23
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    • 1998
  • Recently, semiconductor industry has grown rapidly because of the large demand for electronic devices and equipment. The semiconductor industries have also played an important role on the economic growth in Korea. As the environmental regulations become strict, the proper environmental management and the well-developed waste minimization technologies in semiconductor industries are two of urgent problems to be solved. The semiconductor manufacturing process consists of a series of continuous chemical processes, such as cleaning, oxidation, diffusion, photolithography, etching and film deposition. During the processes, various environmentally hazardous wastes are produced. The wastes may be classified as wastewater, gaseous pollutants, and solid wastes. For waste minimization, the substitution of raw materials and process optimization techniques are used, while the selective destruction technologies of toxic chemicals contained in the wastes have been reported. Also, new technologies have been developed for source reduction and waste reduction, such as reduction of toxic chemical use and substitution of hazardous liquids with gaseous reactants or solvent.

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Development and Characteristic Study of a Portable Gas Chromatography (소형 GC 모듈의 개발 및 특성)

  • Lee, Myeong-Gi;Oh, Jun-Sik;Jung, Kwang-Woo
    • Journal of the Korean Chemical Society
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    • v.55 no.2
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    • pp.157-162
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    • 2011
  • In the present study, we developed a portable GC module for real-time, quantitative determinations of gas mixtures in air sample. Capillary or packed column was coiled together with a heater wire and thermocouple in a small case. Together with the small and light weight sensors and valves as well as the rechargeable carrier gas canister, which permits collection and separation of samples, this system can determine the components of complex mixtures of air contaminants at low concentrations with a duty cycle of 10 min. When measured the various samples with a FID and TCD, the system showed, for a capillary column, a good resolution (R=8.3), high sensitivity, reproducibility, and linear dynamic range greater than three orders of magnitude. These results indicate that the portable GC module is expected to be used for a wide range of applications, particularly for in situ environmental monitoring, chemical processes, and regulation of contaminant emission.

Preparation and Bonding Properties of Natural Garlic Adhesives for Wallpaper (벽지용 천연마늘접착제의 제조 및 접착성능)

  • Roh, Jeongkwan;Lee, Jinwha
    • Journal of Adhesion and Interface
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    • v.12 no.4
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    • pp.125-132
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    • 2011
  • As the enhancement of indoor air quality is increasingly compelling the use of natural materials without any emission, this study reports the preparation and performance of natural garlic adhesives for wallpaper. The natural garlic adhesives were successfully prepared by the extraction of the clove of raw garlic with water to isolate carbohydrates and proteins. Properties of the prepared garlic adhesives such as the non volatile solids content, viscosity, density, and pH were 62%, 2,789 mPa.s, $1.3g/cm^3$, and 6.6, respectively. The non-volatile solids content has a great impact on the adhesion performance of the prepared garlic adhesives, which was adequate about 60%. Bonding strength of prepared garlic adhesives was greater than the requirement of a Korean standard for wallpaper. In addition, the garlic adhesives showed antibacterial activity inheriting from the garlic. It is expected that the prepared garlic adhesives could be used as safe and natural adhesives without emitting any volatile organic compounds and formaldehyde gas.

Source term estimation using least squares method in a radiological emergency (원자력 비상시 최소자승법을 이용한 선원항의 추정)

  • Jeong, Hyo-Joon;Kim, Eun-Han;Suh, Kyung-Suk;Hwang, Won-Tae;Han, Moon-Hee
    • Journal of Radiation Protection and Research
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    • v.29 no.3
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    • pp.157-163
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    • 2004
  • Atmospheric dispersion modelling has been widely used to predict the fate and transport of radioactive or toxic materials released from nuclear facilities which is an unlikely accidental event. To improve the forecasting performance of the dispersion model, it is required that source rate and dispersion characteristics must be defined appropriately. Generally, source term of the radioactive materials is much uncertain at the early phase of an accidental event. In this study, we computed the source rate with the experimental field data monitored at the Yeoung-Kwang nuclear site and obtained the optimal source rate to minimize the errors between the measured concentrations and the computed ones by the Gaussian plume model. Computed source term showed a good result within 24% of the artificially released source rate.

Development of a test system for analysis of air bubble behavior (에어버블 거동 분석을 위한 실험장치 개발)

  • Lee, Hyo Sang;Chang, Hyung Joon;Lee, Ho Jin
    • Proceedings of the Korea Water Resources Association Conference
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    • 2016.05a
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    • pp.475-475
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    • 2016
  • 생활의 편의를 위하여 인간은 여러 종류의 시설을 만들고 있으며, 이에 필요한 전기를 공급하기 위하여 여러 종류의 발전소를 건설 운영하고 있다. 특히, 원자력 발전은 2014년을 기준으로 전체 전력생산량의 약 30%를 담당하고 있으며, 늘어나는 전력 수요를 감당하기 위하여 다수의 원자력 발전소 건설계획을 수립하고 있다. 원자력 발전소는 발전과정에서 생성되는 고열을 냉각시키기 위하여 다량의 물을 필요로 하기 때문에 연안에 위치한다. 물을 안정적으로 취수하는 것은 원자력 발전소의 안정성 확보에 큰 영향을 미치는 요소이다. 하지만, 유류 등의 오염 물질 또는 해파리 등의 생물체에 의하여 취수구가 마비되어 냉각수를 공급하지 못하는 사고가 종종 발생하고 있다. 원자력 발전소가 발전 중단이 되면 하루 약 10억원의 경제적 손실이 발생할 수 있고, 동일본 대지진의 예에서 확인할 수 있는 바와 같이 2차 피해가 발생하여 엄청난 재앙을 초래할 수 있다. 취수구로 유입되는 유류 등의 오염물질과 생물체를 차단하기 위하여 물리적인 방법과 생물학적 방법을 이용한 여러 가지 장치 및 기법이 고안되고 있지만, 생물학적인 방법은 개체군과 종류의 변화로 그 적용이 곤란하여 물리학적인 방법을 이용한 연구가 주를 이루고 있다. 대표적인 물리학적 장치는 해파리 제거용 그물이 있으나, 포집되는 해파리의 지속적인 제거를 위한 비용적인 문제와, 잠수부의 안전 문제가 발생하고 있다. 이와 같은 문제를 해결하기 위해서 최근 가장 주목받고 있는 방법은 에어버블을 이용하여, 유해 물질과 생물체를 차단하는 방법이다. 에어버블은 수심조건에 영향을 받지 않고, 취수구가 설치된 영역으로 유해물질의 유입 자체를 방어할 수 있어 몇 몇 선진국에서는 실용화 단계에 접어들고 있다. 본 연구에서는 에어버블 거동을 특성을 파악하기 위해서는 에어버블의 상승속도, 특성, 압력 및 수심조건 등을 고려할 수 있는 실험 장치를 개발하는 것을 목적으로 하였다. 이를 위하여 선행연구결과 및 현장조건을 고려하여, 취급이 간단하고, 실험조건 조절이 용이한 원통형 실험 장치를 개발하였다.

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Analysis of Parameter Sensitivity of 2D Numerical Model for Simulation of Toxic Contaminants Transport in Stream (하천에서 독성물질의 혼합거동모의를 위한 2차원 수치모형의 매개변수 민감도 분석)

  • Shin, Dongbin;Seo, Il Won
    • Proceedings of the Korea Water Resources Association Conference
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    • 2019.05a
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    • pp.106-106
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    • 2019
  • 많은 도심의 하천들은 오염물질의 유입에 취약하다. 최근 신소재 공학 등 첨단산업이 발전하게 되면서 유해화학물질의 유입문제는 더욱 대두되고 있으며, 실제로 최근 유해화학물질 유입사고 발생건수가 늘어나고 있다. 특히 국내 취수량의 90%는 지표수에서 취수하고 있어, 하천오염사고는 직접적인 피해로 이어지게 된다. 따라서 이러한 사고에 대응하기 위하여 수환경에 유입된 유해물질의 거동 매커니즘을 반영한 수질해석이 필요하다. 수체 내에 유입된 유해화학물질은 기본적으로 흐름에 따른 이송 확산을 하며 흡 탈착, 휘발, 침전 부유, 생화학 반응과 같은 다양한 반응과 함께 혼합거동을 한다. 특히 소수성물질의 경우 용해된 상태뿐만 아니라, 유사에 흡착된 상태로 수체에 존재하게 된다. 결국 유해화학물질의 거동을 해석하기 위해서는 유체의 흐름 해석뿐만 아니라 수체에 존재하는 유사의 이송 또한 해석해야한다. 본 연구에서는 흐름해석을 위하여 서울대에서 개발한 흐름모형(HDM-2D)을 사용하였으며, 부유사 거동모의를 위해 부유사거동모형(STM-2D)을 개발하였다. 또한 유해화학물질의 거동모의를 위해 서울대에서 개발한 수질모형(CTM-2D)에 생성/소멸항을 추가하였으며 흐름모형과 부유사모형과의 연계를 통해 유해화학물질의 혼합거동 수치모형을 개발하였다. 각 반응항(흡 탈착, 휘발, 침전 부유, 생화학 반응)을 수치모형에 반영 시에는 보통 두 계(물-토양, 물-공기) 사이의 선형 물질교환으로 이해된다. 따라서 물질의 각 반응 별 평형농도와 물질교환속도계수를 추정식을 통해 산정하여 사용하게 된다. 하지만 각 기작이 반영유무에 따라 계산시간 및 필요입력변수가 늘어나게 되므로, 유해화학물질 유입사고와 같은 빠른 대처가 필요한 경우 각 반응 텀의 유의성을 판단하여 모형에 반영여부를 결정을 통해 경제적인 모의를 할 수 있어야 한다. 이에 따라 본 연구에서는 개발된 모형의 각 매개변수들의 민감도를 분석하고, 흐름조건 및 물질의 특성에 따른 반응항의 유의성을 판단하였다. 본 연구에서는 개발된 모형(부유사거동모형, 유해화학물질의 혼합거동모형)은 해석해 및 현장 데이터와 비교검증을 통해 개발을 완료하였으며, 각 반응항의 민감도 분석을 통해 매개변수의 임계값을 결정하였다.

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Development of Human Exposure and Risk Assessment System for Chemicals in Fish and Fishery Products (수산생물 중 유해물질의 인체 노출 및 위해평가 시스템 개발)

  • Lee, Jaewon;Lee, Seungwoo;Choi, Minkyu;Lee, Hunjoo
    • Journal of Environmental Health Sciences
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    • v.47 no.5
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    • pp.454-461
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    • 2021
  • Background: Fish and fishery products (FFPs) unintentionally contaminated with various environmental pollutants are major exposure pathways for humans. To protect human health from the consumption of contaminated FFPs, it is essential to develop a systematic tool for evaluating exposure and risks. Objectives: To regularly, accurately, and quickly evaluate adverse health outcomes due to FFPs contamination, we developed an automated dietary exposure and risk assessment system called HERA (the Human Exposure and Risk Assessment system for chemicals in FFPs). The aim of this study was to develop an overall architecture design and demonstrate the major features of the HERA system. Methods: For the HERA system, the architecture framework consisted of multi-layer stacks from infrastructure to fish exposure and risk assessment layers. To compile different contamination levels and types of seafood consumption datasets, the data models were designed for the classification codes of FFP items, contaminants, and health-based guidance values (HBGVs). A systematic data pipeline for summarizing exposure factors was constructed through down-scaling and preprocessing the 24-hour dietary recalls raw dataset from the Korea National Health and Nutrition Examination Survey (KNAHES). Results: According to the designed data models for the classification codes, we standardized 167 seafood items and 2,741 contaminants. Subsequently, we implemented two major functional workflows: 1) preparation and 2) main process. The HERA system was developed to enable risk assessors to accumulate the concentration databases sustainably and estimate exposure levels for several populations linked to seafood consumption data in KNAHES in a user-friendly manner and in a local PC environment. Conclusions: The HERA system will support policy-makers in making risk management decisions based on a nation-wide risk assessment for FFPs.

Study on Solidification and Strength of Soft Soils by Using Waste Magnesia-Carbon Powder (폐 Magnesia-Carbon Powder를 이용한 연약지반 고형화 및 강도 증진에 대한연구)

  • Choi, Hun;Song, Myong Shin;Kang, Hyung Ju;Jung, Eui Dam;Kim, Ju Seng
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.1
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    • pp.35-40
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    • 2011
  • Magnesia-carbon brick is used to refractory material in Converter and/or Ladle furnace for molten steel manufacturing. The rapid growth of steel making industry, molten steel industry is increased. Therefore, growth of molten steel industry lead to make waste magnesia-carbon brick by repair of Converter and/or Ladle furnace. These waste magnesia-carbon brick is abandoned all. Besides, as it is loosely composed of silt and clay including sand falling according to the type of gangue, rainwater inflows and outflows relatively easily, but silt or clay particles absorb water for a long period, weakening ground. This study tried to show that when colluvial soil is solidified using waste magnesia-carbon brick powder as a way to solidify strengthen the rigidity of colluvial soil.