• Title/Summary/Keyword: 유해가스

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선박배기가스 유해물질 저감을 위한 선박용 SCR 시스템 요소기술에 관한 소개

  • Park, Yun-Yong;Song, Ha-Cheol;Sim, Cheon-Sik;An, Gi-Ju;Park, Gi-Yeong
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2015.10a
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    • pp.77-78
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    • 2015
  • 산업화로 인하여 토지의 사막화, 물부족, 오존층 파괴, 지구 온난화 등 많은 환경문제가 발생되었으며 아직 진행 중에 있다. 이에 UN에서는 환경 규제를 강화하였으며 국제해사기구(IMO:International Maritime Organization)에서는 선박의 배기가스 규제 강화를 위하여 NOx(질소산화물) 및 SOx(황산화물)의 배기량을 줄이도록 하고 있으며 2016년부터는 본격적으로 규제하려 하고 있다. 상기의 규제 물질 중 NOx를 제거하는 선택적환원촉매(SCR:Selectivity Catalytic Reduction) 시스템은 선박의 배기가스가 지나가는 통로에 요소수(Urea)를 분무하여 $260^{\circ}C$ 이상의 높은 온도에서 요소수에 있는 암모니아가 배기가스에 있는 NOx와 반응, 결합함으로서 NOx를 질소와 산소로 분리, 제거하는 방식이다. 하지만 선박의 경우 대부분 엔진이 2행정으로 배기가스 온도가 일반적으로 $180^{\circ}C{\sim}220^{\circ}C$이기 때문에 요소수에 있는 암모니아가 배기가스에 있는 NOx와 반응하지 않아 환원률이 높지 않다. 이에 우리는 초미세기포를 이용하여 낮은 온도에서도 반응할 수 있는 요소수 및 요소수 활성화 기기를 개발하여 상기의 문제점들을 최소화 할 수 있도록 하였다. 또한 SCR 시스템의 점성유동해석을 통하여 보다 효율적인 SCR 시스템의 개발을 할 수 있도록 기여하였다.

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Influence of Supplemental Dietary Yeast Culture on the Noxious Gas Emission in Broiler Houses and Performance of Broiler Chicks (효모배양물 첨가 사료가 계사내 유해가스 발생 및 육계의 생산성에 미치는 영향)

  • Park, J. H.;Ryu, M. S.;Kim, S. H.;Na, C. S.;Kim, J. S.;Ryu, K. S.
    • Journal of Animal Science and Technology
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    • v.45 no.1
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    • pp.41-48
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    • 2003
  • Two experiments were conducted to investigate the effect of dietary supplementation of yeast culture on the performance of broiler chicks and noxious gas emission in broiler houses. Two hundred forty and three hundred and twenty, one day old Cobb male broiler chicks in Expt 1 and Expt 2, respectively were alloted to four treatment levels of yeast culture (0, 0.1, 0.2, 0.4%). To each treatment, 60 birds were assigned in Expt 1 and 5 replicates of 16 birds each were assigned in Expt 2. Basal diets contained 21.5% and 19.0% CP, and 3,100kcal/kg ME for the starting and finishing periods, respectively. Ammonia and $CO_2$ gas emission were detected twice a day for seven days during the five week period of Expt 1. Weight gain, feed intake and feed efficiency were measured for five weeks in Expt 2. Intestinal microbes, blood cholesterol and ND antibody titer were examined at the end of Expt 2. In Expt 1, the concentration of $NH_3$ in the house of birds fed yeast culture tended to be lower than the control. It was significantly lower in the 0.4% yeast culture treatment than the control (P<0.05). $CO_2$ concentration was significantly lower in all yeast culture treatments regardless of its dietary supplemental level than the control (P<0.05). different from others. Feed efficiency (feed/gain), however, was significantly improved in all yeast culture treatments relative to that of the control for starting period (P<0.05) and that of 0.2% yeast culture treatment was significantly lower than those of the control and 0.4% for the overall period. Total number of E. coli in the ileum of birds fed yeast culture at 0.1 and 0.2% was significantly lower than those of the control and 0.4% in the ileum. The CFU of Lactobacillus spp. of birds fed yeast culture at 0.1% was higher in the cecum compared to other treatments (P<0.05). Total cholesterol level of chicks fed 0.1% yeast culture seemed to be lower compared to that of other treatments, whereas LDL-cholesterol level was significantly lower than those of the control and 0.4% treatment. ND antibody titer tended to be higher in the yeast culture treatments than the control, but was not significantly different. The results of these experiments indicated that 0.2% yeast culture may have a potential to reduce the noxious gas emission in broiler houses and maximize the performance of broiler chicks.

Effects of Concentration and Size of Porous Calcium Silicate (PCS) in Broiler Feeds on Performances, Fly Generation and Malodorous Gas Emission (Porous Calcium Silicate(PCS)의 급여수준 및 PCS 입자 크기가 육계의 성장, 파리 및 악취 발생에 미치는 영향)

  • Jeon, B.S.;Song, J.I.;Jeon, J.H.;Kwag, J.H.;Kang, H.S.;Choi, H.C.;Kim, T.I.;Lee, E.S.;Nahm, K.H.
    • Journal of Animal Environmental Science
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    • v.15 no.2
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    • pp.115-130
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    • 2009
  • Three experiments on the addition of Porous Calcium Silicate (PCS) to broiler feed were conducted at different time periods in the same house. Each treatment had 4 replicates with 12 chicks in each treatment. Weight gain and feed intake were higher ($P{\le}0.05$) in the control groups. Feed conversions' were better ($P{\le}0.05$) in the PCS group, 3.0% PCS and 20 mesh size of PCS than the control group from 21 to 49 days, and for the overall period. $NH_3$ and $H_2S$. gas production were decreased ($P{\le}0.05$) when zeolite was added in broiler feeds. 1.5% or 3.0% PCS in broiler feed was better ($P{\le}0.05$) than the 4% PCS. More than 90 mesh size PCS was better ($P{\le}0.05$) in controlling $CO_2$ production in the 5th period than the 20 or 50 mesh size or control groups. The control and PCS groups produced more flies ($P{\le}0.05$) than zeolite group during the 2nd and 3rd weeks. The 3.0% or 4.5% PCS or 50 or 90 mesh size of PCS in broiler feed produced more flies than the 20 mesh size or control groups although 50 or 90 mesh size of PCS during 5th week tended to have lower fly production than the 20 mesh size of PCS and control group.

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A study on the Internal Flow Analysis of Gas Cylinder Cabinet for Specialty Gas of Semiconductor (반도체용 특수가스 공급을 위한 가스캐비닛 내부 유동해석에 관한 연구)

  • Kim, Jung-Duck;Han, Seung-A;Yang, Won-Baek;Rhim, Jong-Guk
    • Journal of the Korean Institute of Gas
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    • v.24 no.5
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    • pp.74-81
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    • 2020
  • In general, when manufacturing a semiconductor, a number of hazardous and dangerous substances such as flammability, toxic, and corrosiveness are used. In particular, semiconductors are manufactured using specialty gas in processes such as CVD and etching. The specialty gas is filled in a container in the state of compressed or liquefied gas, and a gas cylinder cabinet is used as a facility for supplying this specialty gas to the semiconductor manufacturing process. When a accident occurs in the gas supply system, gas is released through a pressure release device installed in the gas cylinder to secure the safety of the supply system. In this case, the gas released inside the gas cabinet, there is a risk of leaking to the outside. After that, by analyzing the gas flow in the gas cabinet, it is intended to identify the risk associated with leak and to provide measures to prevent accidents.

Theoretical Investigation for the Adsorption of Various Gases (COx, NOx, SOx) on the BN and AlN Sheets (N과 AlN 시트에 다양한 기체(COx, NOx, SOx)의 흡착에 관한 이론 연구)

  • Kim, Sung-Hyun;Kim, Baek-Jin;Shin, Chang-Ho;Kim, Seung-Joon
    • Journal of the Korean Chemical Society
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    • v.61 no.1
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    • pp.16-24
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    • 2017
  • The adsorption of various atmospheric harmful gases ($CO_x$, $NO_x$, $SO_x$) on graphene-like boron nitride(BN) and aluminum nitride(AlN) sheets was theoretically investigated using density functional theory (DFT) and MP2 methods. The structures were fully optimized at the $B3LYP/6-31G^{**}$ and $CAM-B3LYP/6-31G^{**}$ levels of theory and confirmed to be a local minimum by the calculation of the harmonic vibrational frequencies. The MP2 single-point binding energies were computed at the $CAM-B3LYP/6-31G^{**}$ optimized geometries. Also the zero-point vibrational energy (ZPVE) and 50%-basis set superposition error (BSSE) corrections were included. The adsorptions of gases on the BN sheet were predicted to be a physisorption process and the adsorptions of gases on the AlN sheet were predicted to be a physisorption process for $CO_x$ and $NO_x$ but to be a chemisorption process for $SO_x$.

Effects of Dietary Rosemary Supplementation on Performance, Microflora Population in the cecum and Noxious Gas Emission from Litter in Broilers (Rosemary의 급여가 육계의 생산성, 맹장내 균총 및 깔짚 중 유해가스 발생량에 미치는 영향)

  • Son, Jang-Ho
    • Korean Journal of Organic Agriculture
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    • v.23 no.2
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    • pp.335-346
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    • 2015
  • The objective of this study was to evaluate the effect of dietary rosemary on performance, microflora population in cecum and noxious gas emission from litter of broiler. A total of 216 broiler chicks at 7 days old were fed the commercial diet (control), added 0.5% level of dried rosemary leaves (5 g/kg diet, T1) and 1.0% level of dried rosemary leaves (10 g/kg diet, T2) for 4 weeks. The body weight gain and feed conversion ratio were improved by feeding rosemary at 7 to 35 days of age (P<0.05), but there was no difference between T1 and T2. Amount of feed intake and mortality were not different among the three group. There was an increase in the microflora population of Lactobacillus (P<0.05) and decreased in E. coli and salmonella (P<0.05) in the cecum contents at 21 and 35 days of age. Emission of ammonia gas from litter was significantly decreased by supplementary rosemary at 21 to 35 days of age (P<0.05), but there was no difference between T1 and T2. These results indicated that feeding 0.5 to 1.0% level of dried rosemary leaves during broiler production improved in the body weight gain and feed conversion ratio because of increasing nutrient digestibility from feed, also increase in intestinal beneficial bacteria and decrease in harmful bacteria in the cecum contents, and decreasing emission of ammonia gas from litter.

The Study for Idle Fuel Consumption of a Hydrogen-Blended Natural Gas Engine (수소 혼합 천연가스 연료 엔진의 아이들 연비에 관한 연구)

  • Lee, Sun-Youp;Kim, Young-Min;Lee, Jang-Hee
    • Journal of Energy Engineering
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    • v.19 no.3
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    • pp.171-176
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    • 2010
  • Using a hydrogen blended compressed natural gas (HCNG) as a fuel for IC engines has a significant meaning in terms of achieving a reduction of automotive exhaust emissions as well as preparing for an upcoming hydrogen economy by constructing hydrogen infrastructure. In addition, a HCNG engine has higher thermal efficiency than a CNG engine, which is another advantage that makes HCNG fuel considered as a future alternative for natural gas. Therefore, in this study, idling operation of a 11 litre HCNG bus engine was investigated in terms of fuel consumption rate and emissions characteristics. The results show that fuel consumption rate was decreased more than 20% by use of HCNG and all the emissions were significantly reduced in idling condition.

Automotive Echaust Gas and Its Preventive Measures (자동차 배출가스와 그 대책(1))

  • 이재순
    • Journal of the korean Society of Automotive Engineers
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    • v.6 no.1
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    • pp.21-26
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    • 1984
  • 내연기관은 일찍이 군용과 특수용도는 물론, 최근 서민생활에 직결되어 널리 사용되고 있으며, 일상생활의 필수기계가 되어 놀랄만한 수의 엔진이 생산, 사용되기에 이르렀다. 그러나 한편으 로는 그것을 사용함으로서 사람들에게 해를 준다는 문제가 발생하였다. 특히 주위 사람들의 건 강을 해칠 우려가 있는 유해성분을 포함한 가스의 배출, 또는 소음의 발생이 큰 사회적 문제가 되어 그 방지대책이 종래의 성능향상에 대신하여 지상명제로서 연구 개발되고 있다. 이에 대한 대책은 일반적으로 엔진의 가격과 성능을 희생시키는 것은 불가피하지만, 그것은 최근 세계적인 위기로 불리는 에너지와 기타 자원의 절약과 상용할 수 없으므로 이러한 공해와 자원이 양 립할 수 있는 방향으로의 새로운 내연기관 연구가 강력하게 요망되고 있는 것이 현상태이다. 엔진이 인체에 해를 줄 가능성이 있다는 것은 이전부터 알고 있던 바이다. 예를 들면 좁은 실 내나 터널중에서 운전하면 많은 량의 산소를 소비하기 때문에 단시간에 산소가 부족하게 될 뿐만 아니라, 일산화탄소 함유량이 많은 배기를 배출하게 되어 인체에 중대한 해를 준다. 그러나 이와 비슷한 일이 전도시적인 문제가 되어 법규제가 된 것은 최근의 일이고, 배출가스에 대하여서는 미구에 의하여 약 10년 전부터 자동차의 배기규제가 계획되어 금일 진행중이다. 또 소음에 대 하여서는 오히려 극히 초근부터 법규제화가 진행되고 있으나 어느 쪽도 사회의 요구를 완전히 만족시킬만한 대책기술은 용이하지 않다.

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수소 중성입자빔을 이용한 실리콘 에칭

  • Kim, Dae-Cheol;Hong, Seung-Pyo;Kim, Jong-Sik;Park, Jong-Bae;O, Gyeong-Suk;Kim, Yeong-U;Yun, Jeong-Sik;Lee, Bong-Ju;Yu, Seok-Jae
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.278-278
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    • 2011
  • 수소 중성입자빔을 이용한 silicon etching은 기존의 silicon etching 공정 가스(Fluorine이나 Chlorine 계열의 가스) 사용 시 배출되는 유해 가스로 인한 지구 온난화 방지 및 폐기물 처리에 추가적인 비용이 발생하지 않는 친환경 etching 공정이다. 본 연구에 사용된 수소 중성입자빔을 발생시키기 위한 플라즈마 소스는 낮은 압력에서 높은 플라즈마 밀도를 발생시킬 수 있는 ECR 플라즈마 소스를 사용하였으며 중성입자빔의 에너지를 조절할 수 있는 중성화판과 플라즈마로부터의 전하손상을 방지할 수 있어 charge free 공정을 가능하게 하는 Limiter로 구성되어 있다. 본 연구에서는 플라즈마 밀도, 공정 압력 그리고, 중성입자빔의 에너지를 조절하여 수소 중성입자빔을 이용한 poly-crystal silicon과 a-Si:H 간의 etch rate와 etching selectivity를 관찰하였다.

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A Study on the Coal Gasification Slag as Fine Aggregate for Concrete - Focus on Physical Properties and hazardous materials content characteristics - (콘크리트용 잔골재로서 석탄가스화복합발전 슬래그의 활용성 검토 - 물리적 성질 및 유해물질 함유량 특성을 중심으로 -)

  • Hyun, Seong-Yong;Han, Jun-Hui;Lee, Jae-Jin;Shin, Yong-Sub;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.56-57
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    • 2018
  • This study is a fundamental consideration for using CGS from the IGCC as a fine aggregate for concrete. For the review, the physical properties and hazardous materials content of KS F 2527 were considered. The results showed that KS F 2527 standard was generally satisfied, making it possible to confirm the possibility that it is a fine metal considering its physical properties and hazardous materials content characteristics.

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