• Title/Summary/Keyword: 유사농도분포

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Design of the Fixed-Bed Catalytic Reactor for the Maleic Anhydride Production (무수마레인산 생산을 위한 고정층 촉매 반응기 설계)

  • Yoon, Young Sam;Koo, Eun Hwa;Park, Pan Wook
    • Applied Chemistry for Engineering
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    • v.10 no.3
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    • pp.467-476
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    • 1999
  • This paper analyzed the behavior of fixed-bed catalytic reactor (FBCR) which synthesizing maleic anhydride(MA) from the selective oxidation of n-butane. The behavior of FBCR describing convection-diffusion-reaction mechanism is examined by using two-dimensional pseudohomogeneous plug-flow transient model, with the kinetics of Langmuir-Hinshelwood type. Prediction model is composed by optimum parameter estimation from temperature profile, yield and conversion of single FBCR on operating condition variations of Sharma's pilot-plant experiment. A double FBCR with same yield and conversion for single FBCR generated a $8.96^{\circ}C$ lower hot spot temperature than a single FBCR. We could predict parametric sensitivity according to the variation of possible operating condition (temperature, concentration, volumetric flow of feed reactant and coolant flow rate) of single and double FBCR. Double FBCR showed the behavior of more operating range than single FBCR. Double FBCR with nonuniform activities could assure safety operation condition for the possible variation of operating condition. Also, double FBCR had slightly higher than the single FBCR in conversion and yield.

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Oxygen Transport in Axisymmetric Thrombosed Aneurysm (혈전이 있는 축대칭 동맥류에서의 산소전달현상)

  • 김한일;태기식;김영호
    • Journal of Biomedical Engineering Research
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    • v.23 no.4
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    • pp.295-300
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    • 2002
  • Localized hypoxia, due to the diminished $O_2$supply, is reported to cause necrosis of the arterial cell and to significantly decrease resistances to physiologic distending pressures. In the present study, in order to understand the mechanism of localized hypoxia which might result in the rupture of the aneurysm. $O_2$ transport phenomena across intraluminal thrombus in axisymmetric aneurysms under steady laminar flow condition were numerically analyzed using the Fick's law and the analogy with the fluid-solid heat transfer. For computational models, varying the thickness of intraluminal thrombus, numerical results showed that for the axisymmetric aneurysm with intraluminal thrombus. $O_2$ concentration became minimal at the aneurysm wall. With increased thickness of the intraluminal thrombus in the aneurysm. regions of low $O_2$ concentration were widely distributed near the aneurysm wall, which resulted in the possibility of localized hypoxia. The present study verifis that intraluminal thrombus influences $O_2$ transport to the aneurysm wall. depending on its size and structure.

Allergic risk assessment of genetically modified cucumber mosaic virus resistant pepper (유전자변형 바이러스 저항성 고추의 알레르기 안전성)

  • Son, Dae-Yeul
    • Food Science and Preservation
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    • v.22 no.6
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    • pp.901-907
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    • 2015
  • Genetically modified (GM) pepper H15 containing the gene for cucumber mosaic virus (CMV) coat protein (CP) and its control line non-GM pepper P2377 were investigated for their allergic risk. Amino acid sequence of the inserted gene product CMV-CP was compared with those of known allergens. No known allergen had greater than 35% amino acid sequence homology over an 80 amino acid window or more than 8 consecutive identical amino acids. Protein patterns of GM and non-GM pepper extracts were evaluated by SDS-PAGE, which showed similar distribution of protein bands for both GM and non-GM pepper. Antigen-antibody reactions were compared between GM and its non-transgenic parental control. ELISA and immunoblot analysis of sera from allergic patients showed some IgE reactivity; however, no differences were observed between GM pepper H15 and P2377. We therefore conclude that CMV-CP is less likely to be an allergen; the protein composition and allergenicity of the GM pepper H15 is not different from that of P2377 and safe as a commercial host.

Geochemical Characteristics of Mineral Phases in the Mantle Xenoliths from Sunheul-ri, Jeju Island (제주도 선흘리 일대에 분포하는 맨틀포획암 내의 광물의 지화학적 특성 연구)

  • Kil, Young-Woo;Shin, Hong-Ja;Yun, Sung-Hyo;Koh, Jeong-Seon;Ahn, Ung-San
    • Journal of the Mineralogical Society of Korea
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    • v.21 no.4
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    • pp.373-382
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    • 2008
  • First reported geochemical characteristics of mantle xneoliths (spinel peridotites) from Sunheul-ri, Jeju Island, provide important clues for understanding the lithosphere composition, equilibrium temperature, and the period of entrainment and transport of the xenoliths in the host magma. Core and rim of mineral phases in the xenoliths are constant chemical compositions as $Fo_{89-90}$ of olivines. The ranges of equilibrium temperature, obtained by two pyroxenes geothermometer, are about $951{\sim}1035^{\circ}C$ for Sunheul-ri spinel peridotite xenoliths and are similar to the range of equilibrium temperatures for the xenoliths from other sites in Jeju island. The period of entrainment and transport of the xenoliths in the host magma of Sunheul-ri mantle xenoliths is about 42 days.

Comparison of Particle Size Analysis and Distribution of Heavy Metals in River and Lake Sediments (하천 및 호소 퇴적물 입도분석 방식의 비교와 입도에 따른 중금속물질의 분포경향)

  • Oh, Hyungsuk;Shin, Wonsik;Kim, Joonha;Hwang, Inseong;Hur, Jin;Shin, Hyunsang;Oh, Jeongeun;Huh, Inae;Kim, Younghun
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.5
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    • pp.15-23
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    • 2010
  • Dry sieving, wet sieving and photoscattering analyzer were tested as particle size analyzing methods for sediments from rivers and lakes of Han river, Nakdong river, Youngsan river, and Kumgang river area. Dry sieving showed a big error due to coagulating effect over drying process and this phenomena was severe for lake sediment. Wet sieving and PSA showed an accurate results though wet sieving needs more labor and complicate processes. Freeze-dry or freeze-dry after oxidation of organics with hydrogen peroxide showed improved results but gave lower portion of fine particles in comparing with wet sieving. Heavy metal contents and extractable metal contents were investigated for the sediments and high heavy metal content and extractable amount were obtained from fine particles as expected. Using of proper particle size analyzing method is important and the sediment management should be focused on the fine particles.

Stability of Nano-emulsions Containing Fatty Acid and Fatty Alcohol (지방산 및 지방알코올을 함유한 나노에멀젼의 안정성)

  • Cho, Wan Goo;Kim, Kyung Ah;Jang, Seon Il;Cho, Byoung Ok
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.43 no.4
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    • pp.273-279
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    • 2017
  • In this study, low viscous O/W (oil-in-water) nano-emulsion with fatty acid and fatty alcohol was prepared by phase inversion emulsification method using Tween 80 and Span 80 widely used in cosmetic products. The particle size of the nano-emulsion was increased as increasing the concentration of fatty alcohol in oil phase. Adjusting the HLB of mixed surfactants, a stable nano-emulsion with a narrow size distribution was produced. Similar change in viscosity and electrical conductivity in both systems containing fatty acid and fatty alcohol was shown in the vicinity of the phase inversion point. However, high viscosity was shown in a wide range of different aqueous fraction unlike the system consisting only oils and surfactants. The low viscous nano-emulsion with less than 100 nm droplet size was stable for one month or more at room temperature. O/W nano-emulsions with low viscosity containing fatty acid or fatty alcohol produced by low-energy emulsification method can be widely used as formulations of cosmetics.

Review of the Role of Land Surface in Global Climate Change (기후변화에서 지표환경의 역할에 대한 고찰)

  • Kim, Seong-Joong
    • The Korean Journal of Quaternary Research
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    • v.23 no.1
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    • pp.42-53
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    • 2009
  • In response to the abrupt climate change in recent years, atmosphere, ocean and cryosphere are reported to be altered. In addition to these changes, the land surface is also gradually changing and its impact on the global climate may not be negligible. The land surface change impacts the global climate via two ways, the biogeochemical and biophysical feedbacks. The biogeochemcial change in the land surface modifies the atmospheric trace-gas concentrations through a change in photo synthesis, while biophycal changes of the land surface alters the surface albedo, which influences the amount of the short wave radiative heat fluxes. There are many examples in the past that the change in land surface greatly influences the global climate change. The recent IPCC report has suggested that the climate change will occur rather abrubtly in the near future. In order to predict the future climate accurately, the impact of the land surface change is fully considered.

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Effect of Heavy Metals on Larvae of Barnacle, Balanus albicostatus (생태독성 검정을 위 한 고랑따개비 (Balanus albicostatus) 초기유생의 중금속에 대한 민감도 분석)

  • Sung, Chan-Gyoung;Choi, Mi-Sun;Chun, Ho-Hwan;Lee, In-Won;Park, Hyun;Lee, Chang-Hoon
    • Environmental Analysis Health and Toxicology
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    • v.23 no.4
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    • pp.337-343
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    • 2008
  • 따개비류는 암반기질에 무리를 이루어 비교적 단단히 부착생활을 하며 전 세계적으로 분포하는 생물이다. 본 생물은 형태가 다른 두 단계의 플랑크톤 유생시기를 거쳐 기질에 부착하여 생활한다. 따개비류에 관한 국내연구는 순수 분류학적으로 몇 편의 연구가 이루어졌을 뿐이며 실험실 내 사육조건 및 유생의 민감도 등에 관한 연구는 제대로 수행되어 있지 않은 실정이다. 본 연구에서는 첫 번째 단계 유생을 대상으로 몇몇 중금속(Cd, Cr, Cu 그리고 Zn)에 대한 민감도를 조사하였고 타 연구결과와의 비교로 생태 독성학적 적용을 시도하였다. 네 가지 금속물질, 카드뮴, 크롬, 구리 그리고 아연에 대한 따개비 유생의 반수사망농도는 각각 0.43, 24.4, 0.22 그리고 1.74mg/L로 산정되었다. 외국의 생물검정용 따개비와 본 연구에 사용된 고랑따개비의 민감도는 아주 유사하게 나타났다. 따라서 국내산 고랑따개비의 유생은 해양 환경 평가에 일반적으로 이용되는 해양생물과 동반 검정의 수행에 자격을 갖추었다고 할 수 있다. 본 연구의 결과는 해양환경의 평가는 물론 방오물질개발 등에의 기초자료를 제공할 수 있을 것으로 사료된다.

A Simulation of Advanced Multi-dimensional Isotachophoretic Protein Separation for Optimal Lab-on-a-chip Design (최적화된 Lab-on-a-chip 설계를 위한 향상된 다차원 프로틴 등속영동 시뮬레이션)

  • Cho, Mi-Gyung
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.13 no.7
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    • pp.1475-1482
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    • 2009
  • In this paper, a computer simulation is developed for isotachophoretic protein separation in a serpentine micro channel for optimal lab on a chip design using 2D Finite Element Method. This 2D ITP model is composed of 5 components such as hydrochloric acid as Leader, caproic acid as terminator, acetic acid and benzoic acid as two proteins, and histindine as background electrolyte. The computer model is based on mass conservation equation for 5 components, charge conservation equation for electric potential, and electro neutrality condition for pH calculation. For the validation of the 2D spatial ITP model, the results are compared with the Simul5 developed by Bohuslav Gas Group. The simulation results are in a good agreement in a ID planar channel. This proves the precision of our model. The 2Dproteinseparation is conducted in a 2D curved channel for Lab on a chip design and dispersions of proteins are revealed during the electrophoretic process in a curved shape.

Characteristics of soil erosion from steep slope of sandy loam (사양토 급사면의 토양침식 특성)

  • Hwang, Yoonhee;Park, Sang Deog;Shin, Seung Sook;Yoon, Yun Minu
    • Proceedings of the Korea Water Resources Association Conference
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    • 2017.05a
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    • pp.137-137
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    • 2017
  • 우리나라는 산지가 64%를 차지하고 있기 때문에 토양침식 위험성이 큰 급경사지가 많다. 산지사면 토양은 대부분 사질토와 사양토로 이루어졌다. 급경사면에서의 토양침식이 많이 발생함에도 이에 대한 연구결과는 부족한 실정이다. 본 연구에서는 사양토로 구성된 나지사면에 대한 토양침식 특성을 파악하고자 강우모의 실험을 수행하였다. 강우모의 실험의 강우강도는 전국의 확률강우분포 3~200년 빈도의 30분 강우강도인 60mm/hr~130mm/hr의 범위였다. 사면경사는 급경사지 범위을 대표하는 $24^{\circ}$$28^{\circ}$에서 실험을 하였다. 실험은 발생하는 지표유출과 지표하유출를 수집하여 측정하였으며, 지표표면에 잉크를 뿌린 다음 실험을 동영상 촬영하여 속도를 측정하였다. 지표유출량을 건조로에 넣고 건조시켜 토양침식량을 측정하였다. 그리고 강우운동에너지는 광학디스트로메터(Pasivel)을 이용하여 측정하였다. 강우운동에너지를 측정한 결과 $800J/m^2{\sim}1700J/m^2$ 범위였다. 강우강도가 클수록 지표유출량과 토사유출량은 증가하였다. 경사가 증가함에 따라 지표유출량은 큰 변화가 없으나, 토양침식량은 크게 증가하였다. 지표하유출량은 강우강도와 경사가 증가하여도 큰 변화가 없었으며, 강우 발생이 멈추면 즉시 감소하였다. 사양토의 점토성분이 강우의 침투를 저해하고, 모래보다 많은 양의 물을 함유하는 있는 것으로 파악 되었다. 그러나 사질토보다 토양입자가 작은 사양토에서 상대적으로 많은 토양침식이 발생하였다. 강우에너지가 증가하면 유사농도는 감소하는 경향을 보였다. 이는 강우에너지가 증가함에 따라 지표유출량의 증가율에 비해 토양침식량의 증가율이 작기 때문인 것으로 판단된다.

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