• Title/Summary/Keyword: 유리

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Non-destructive Analysis on the Chemical Properties of Glass Beads (비파괴 분석을 통한 유리구슬의 화학적 특성 연구)

  • Park, Jae Hyung;Chung, Kwang Yong;Cho, Sun Heum
    • 보존과학연구
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    • s.35
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    • pp.5-23
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    • 2014
  • The possibility of non-destructive inspection glass beads for verification. Conduct a comparative analysis of the Chungcheong area with glass beads excavated Age-specific characteristics of the glass beads shall be classified by region. Trace amounts of ingredients such as CaO, $Al_2O_3$ (stabilizer), MgO, the difference is negligible. $SiO_2$ (subjects), $Na_2O$ (flux) analysis and the difference between the values was greater than in the other ingredients. Composition differences occurred rough surface to a non-uniform cross-section analysis is considered. Minimize the error value, such as the surface of carbon-coated Study, there are additional requirements. Produced at the time of the social and cultural characteristics of ancient glass and important archaeological materials, and to inform the process of cultural exchange between each region in the production of glass technology era according to the level of science and technology, arts and crafts, can be identified.

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Properties of Glass-Ceramic in ${Nd_2}{O_3}-{Al_2}{O_3}-{SiO_2}$System (${Nd_2}{O_3}-{Al_2}{O_3}-{SiO_2}$ 계의 결정화유리의 물성)

  • Choi, Woo-Hyeong;Kim, Hyeong-Sun
    • Korean Journal of Materials Research
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    • v.11 no.7
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    • pp.545-549
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    • 2001
  • Glass-ceramics were prepared and evaluated for the properties to expand the scope of application of the rare earth aluminosilicate glasses, A glass-ceramic added with $TiO_2$as a nucleating agent, which was crystallized internally and it was characterized for physical, thermal and mechanical properties of crystal and residual glass in the glass-ceramic, X-ray diffractometer reveals an unknown crystal as $Nd_{4.6}Si_{7.6}Al_{4.0}Ti_{2.4}O_{32}$ which was found in surface and internal crystals dependent on composition and heat treatments. The thermal expansion coefficients of glass-ceramics were $5.4~6.2{\times}10^{-6}/^{\circ}C$, which increased with increasing crystal growth. Considering that the hardness and the elastic constant of crystal in glass-ceramics are 12GPa and 220GPa, respectively, the application of the glass-ceramics would be applicable for structural materials at elevated temperature.

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Activation of Cytosolic Phospholipase $A_2$ by Methyl Mercury($CH_3$HgCl) in Madin Darby Canine Kidney (MDCK) cells

  • Kang, Mi-sun;Seo, Ji-Heui;Huh, Don-Hang;Kim, Dae-Kyong
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 1997.04a
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    • pp.79-79
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    • 1997
  • 자연계에 존재하는 수은중 유기수은은 생태계 먹이사슬을 통하여 체내의 여러장기에 축적되어 조직손상을 일으키는 것으로 잘 알려져 있다. 그러나 이러한 세포독성에 대한 정확한 생화학적 기전에 대해서는 자세히 알려진 바가 없다. 포스포리파아제 $A_2$(PLA$_2$)는 세포막의 인지질로부터 Arachidonic acid (AA)와 Lysophospholipid를 유리시키는 효소로 최근 세포손상과 관련하여 그 역할이 주목되고 있으며, 극히 최근, 일차배양 소뇌신경세포를 이용한 연구에서 메칠수은처리에 의해 세포독성의 지표인 Lactate dehydrogenase (LDH)의 유리와 함께 AA 유리가 증가되는 것이 관찰되었으나 여러형태의 PLA$_2$중 어느형태의 효소가 관련되어 있는지, 또한, 그 자세한 기전에 대해서는 불분명한 점이 많다. 본 연구에서는 신장세포의 일종인 MDCK세포를 이용하여 메칠수은의 처리에 의한 PLA$_2$의 활성화 및 그 생화학적인 기전을 구명하고자 하였다. [$^3$H]AA를 MDCK세포의 배양액에 첨가하여 라벨링한 후 메칠수은을 처리하였을때 [$^3$H]AA가 대조군에 비해 농도의존적 및 경시적으로 현저하게 증가하였으며 동시에 LDH의 유리도 함께 관찰되었다. 이러한 [$^3$H]AA의 유리 증가는 세포질 PLA$_2$에 특이적인 저해제로 알려진 AACOCF$_3$의 전처리에 의해 거의 완전히 억제되었으나 LDH의 유리는 오히려 증가하였다. 또한, 글루타치온(GSH)의 전구체인 NAC (N-Acetyl Cysteine)에 의해 [$^3$H]AA의 유리는 부분적으로 감소하였으나, LDH의 유리는 변함이 없었다. 돼지비장이나 MDCK 세포에서 얻어진 세포질 PLA$_2$에 메칠수은을 직접 처리하였을때는 오히려 PLA$_2$의 활성은 감소되었다. 위의 결과들로부터 메칠수은에 의한 [$^3$H]AA의 유리 증가는 세포질 PLA$_2$효소에 대한 직접적인 작용이 아니라 세포내 -SH기의 차단이나 Oxidative Stress에 의해 간접적으로 활성화되는 것으로 예상되며, 세포질 PLA$_2$에 의해 유리된 AA의 세포독설과 관련된 세포내의 역할에 대해 의문이 제기되었다.

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Manufacturing Process of Self-Luminous Glass Tube (SLGT) Utilizing Tritium Gas (I) (삼중수소 활용을 위한 자발광유리관 (SLGT) 제조기술)

  • Kim Kwangsin;Kim Kyeongsook;Chung Eun-Su;Son Soon Hwan;Nam Gi-Jung
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.11a
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    • pp.87-95
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    • 2005
  • Laser sealing/cutting technique, one of the 4 core technologies to manufacture self-luminous glass tubes (SLGTs) has been developed. Through the analysis of commercial products it is found that Pyrex Is used for SLGTs. A CO2 laser, which is commonly used for glass work was used for the study The factors affecting the sealing/cutting were laser intensity, duration. Irradiation method, and pressure inside the tube. The whole Process is composed of 2 stages. In the first stage. both ends of the tubes are sealed while tritium is insected in the tubes. And the tritium sealed tubes are cut in the desired size in the second stage. Defocused beam was used for seal ing and focused beam was used for cutting. After the sealing/cutting, the tubes were heat treated to prevent fracture due to the residual heat stress.

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Radioactive Wastes Vitrification Using Induction Cold Crucible Melter: Characteristics of Vitrified Form (유도 가열식 저온용융로를 이용한 방사성페기물 유리화: 유리 고화체 특성)

  • 김천우;박은정;최종락;지평국;최관식;맹성준;박종길;신상운;송명재
    • Journal of the Korean Ceramic Society
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    • v.39 no.6
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    • pp.576-581
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    • 2002
  • In order to simultaneously vitrify the ton Exchange Resin(IER) and Dry Active Waste(DAW) generated from the Nuclear Power Plants, a vitrification pilot test was conducted using an induction cold crucible melter. The PCT result evaluating the chemical durability of the vitrified from showed that the final glass was more durable than the benchmark glass. Liquidus temperature for the final vitrified form was 1048 K(775$\^{C}$) fur heat treatment experiments. The value of the compressive strength for the vitrified form was ninety times higher than the regulation limit, 34 kg/㎠. The glasses on bottom, middle and top of the CCM were homogeneous with no secondary phase. The precipitation of the magnetic metal phase was able to be avoided by simultaneously fEeding of DAW with IER containing strongly reducing organics. Volume reduction factor of 74 was achieved through the vitrification Pilot test for mixed waste.

Fracture Toughness of Glass Fiber Reinforced Laminated Timbers (유리섬유 보강적층재의 파괴인성 특성)

  • Kim, Keon-ho;Hong, Soon-Il
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.6
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    • pp.861-867
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    • 2015
  • The Compact Tension (CT) type test was performed in order to evaluate the fracture toughness performance of glass fiber-reinforced laminated timber. Glass fiber textile and sheet Glass fiber reinforced plastic were used as reinforcement. The reinforced laminated timber was formed by inserting and laminating the reinforcement between laminated woods. Compact tension samples are produced under ASTM D5045. The sample length was determined by taking account of the end distance of 7D, and bolt holes (12 mm, 16 mm, 20 mm) had been made at the end of artificial notches in advance. The fracture toughness load of sheet fiberglass reinforced plastic reinforced laminated timber was increased 33 % in comparison to unreinforced laminated timber while the glass fiber textile reinforced laminated timber was increased 152 %. According to Double Cantilever Beam theory, the stress intensity factor was 1.08~1.38 for sheet glass fiber reinforced plastic reinforced laminated timber and 1.38~1.86 for glass fiber textile reinforced laminated timber, respectively. That was because, for the glass fiber textile reinforced laminated timber, the fiber array direction of glass fiber and laminated wood orthogonal to each other suppressed the split propagation in the wood.

SEM-EDS Microanalysis of Glass Beads Excavated from Yangdong-ri Remains, Kimhae (SEM-EDS를 이용한 경남 김해 양동리 출토 유리구슬의 분석 고찰)

  • Kim, Gyu Ho;Huh, Woo Young;Kim, Dong Won
    • Journal of Conservation Science
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    • v.7 no.1
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    • pp.23-30
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    • 1998
  • The examination of scientific analysis could give many information on the object of ancient glass. It would be allowed to understand the cultural situation and a course of inflow that the data of glass composition was classified by raw materials, technique of making, period and regional groups. Quantitative analysis conditions for SEM-EDS were set for glass and glaze on the pottery and 62 samples of glass beads excavated from Yangdong-ri remains at Kimhae were analyzed and classified. It was found that the glass beads were made of all alkali-glass. In addition, it was postulated that the potash glass was appeared from the 1st century A.D. and soda glass was appeared from the late second or early 3rd century A.D. in this region. The colors of glass were closely related to the concentration of metallic elements such as copper, iron and manganese. It was confirmed that the composition of glass beads could be classified and characterized by raw materials, color, period and regional groups.

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Structure and chemical durability of borosilicate glass-ceramics containing EAF dust (EAF dust가 포함된 붕규산염계 결정화 유리의 구조 및 화학적 내구성)

  • Ahn, Y.S.;Kang, S.G.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.2
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    • pp.82-89
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    • 2007
  • Glass-ceramics were fabricated by heat-treating a glass at $700^{\circ}C$/10hr which was obtained by melting a glass frit mixed with $40{\sim}80 wt%$ EAF dust at $1300^{\circ}C$/1hr. Dependence of crystal phase and bonding state change upon a compositional change and heat treatment condition were studied and the results was connected to the toxic characterization leaching procedure (TCLP) test data to investigate a chemical durability of the specimens. Increasing dust in a glass shifted the peak around $1000cm^{-1}$ to the lower frequency which was composed of two vibration peaks for the nonbridging oxygen at $960cm^{-1}$ and the bridging oxygen at $1050{\sim}1060cm^{-1}$. Also, the $B_2O_3$ structure of boroxol ring changed to a tetrhedral-, trigonal- and di-borate with dust addition. The Fe-O peaks in the glass-ceramics were observed which is consitent with XRD results of spinel formation. The surface of glass after TCLP test was severely cracked while there was no cracks on a glass-ceramics after TCLP test so the chemical durability of the glass-ceramics is superior than that of glass. The leaching concentration of Fe for the glass-ceramics containing EAF dust 80 wt% is 1/15 times lower than that of glass. The Zn leaching concentration fur the glass-ceramics containing dust < 70 wt% was higher than that of glass but its trend was reversed for the specimen of dust content > 80 wt% which could be concluded as correlated with occurrence of willemite phase.

A study on the fabrication of heatable glass using conductive metal thin film on Low-e glass (로이유리의 전도성 금속박막을 이용한 발열유리 제작에 관한 연구)

  • Oh, Chaegon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.1
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    • pp.105-112
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    • 2018
  • This paper proposes a method for fabricating heatable glass using the conduction characteristics of metal thin films deposited on the surface of Low-e(Low emissivity) glass. The heating value of Low-e glass depends on the Joule heat caused by Low-e glass sheet resistance. Hence, its prediction and design are possible by measuring the sheet resistance of the material. In this study, silver electrodes were placed at 50 mm intervals on a soft Low-e glass sample with a low emissivity layer of 11 nm. This study measured the sheet resistance using a 4-point probe, predicted the power consumption and heating value of the Low-e glass, and confirmed the heating performance through fabrication and experience. There are two conventional methods for manufacturing heatable glass. One is a method of inserting nichrome heating wire into normal glass, and the other is a method of depositing a conductive transparent thin film on normal glass. The method of inserting nichrome heating wire is excellent in terms of the heating performance, but it damages the transparency of the glass. The method for depositing a conductive transparent thin film is good in terms of transparency, but its practicality is low because of its complicated process. This paper proposes a method for manufacturing heatable glass with the desired heating performance using Low-e glass, which is used mainly to improve the insulation performance of a building. That is by emitting a laser beam to the conductive metal film coated on the entire surface of the Low-e glass. The proposed method is superior in terms of transparency to the conventional method of inserting nichrome heating wire, and the manufacturing process is simpler than the method of depositing a conductive transparent thin film. In addition, the heat characteristics were compared according to the patterning of the surface thin film of the Low-e glass by an emitting laser and the laser output conditions suitable for Low-e glass.

Seasonal Occurrence Patterns of Synanthedon tenuis and S. bicingulata (Lepidoptera: Sesiidae) in Sweet Persimmon Orchards in the Southern Part of Korea (남부지방 단감원에서 애기유리나방과 복숭아유리나방의 발생소장)

  • Cho, Young-Sik;Kim, Junheon;Jang, Sin Ae;Park, Chung Gyoo
    • Korean journal of applied entomology
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    • v.55 no.3
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    • pp.297-301
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    • 2016
  • Seasonal occurrence patterns of Synanthedon tenuis and S. bicingulata (Lepidoptera: Sesiidae) were monitored in sweet (non-astringent) persimmon orchards in the southern part of Korea from 2013 to 2105, using sex pheromone traps of the respective species. The two species occurred twice a year. Peak occurrences of the $1^{st}$ and $2^{nd}$ generations of S. tenuis were observed in late May nd mid to late September, respectively, while those of S. bicingulata were in early May to early June and mid to late September, respectively. Pooled catches of S. tenuis during the three years from the three locations showed that the $1^{st}$ generation was 1.9 times larger than the $2^{nd}$ generation. In contrast, pooled catches of S. bicingulata showed that the $2^{nd}$ generation was 1.3 fold larger than as the $1^{st}$ generation. However, it remains unclear whether S. bicingulata damages persimmon tree or not.