• Economic and Environmental Geology
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• v.36 no.5
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• pp.349-356
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• 2003

As industrial activities are growing, pollutants found in the contaminated land are getting diverse. Some contaminated areas are subject to mixed wastes containing both organic and inorganic wastes such as hydrocarbon and heavy metals. This study concerns with the influence of the degradation of organic pollutants on the coexisting heavy metals, expecially for As. As mainly exists as two different oxidation state; As(III) and As(V) and the conversion between the two chemical forms may be induced by organic degradation in the soil contaminated by mixed wastes. We operated microcosm in an anaerobic chamber for 60 days, using sandy loam. The soils in the microcosm are artificially contaminated both by tetradecane and As, with different combination of As(III) and As(V); As(III):As(V) 1:1, As(III) only and As(V) only. Although not systematic, ratio of As(III)/As(Total) increase slightly at the later stage of experiment. Considering complicated geochemical reactions involving oxidation/reduction of organic materials, Mn/Fe oxides and As, the findings in the study seem to indicate the degradation of the organics is connected with the As speciation. That is to say, the As(V) can be reduced to As(III) either by direct or indirect influence induced by the organic degradation. Although Fe and Mn are good oxidising agent for the oxidation of As(III) to As(V), organic degradation may have suppressed reductive dissolution of the Fe and Mn oxides, causing the organic pollutants to retard the oxidation of As(III) to As(V) until the organic degradation ceases. The possible influence of organic degradation on the As speciation implies that the As in mixed wastes may be have elevated toxicity and mobility by partial conversion from As(V) to As(III).

• The Korean Journal of Malacology
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• v.31 no.3
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• pp.213-220
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• 2015

After oil outlow accident of Hebei spirit in December 7, 2007, the motality of manila clam, Ruditapes philippinarum in the west coast of South Korea, was significantly increased from 9.2% in April, 2007 to 22.4% in April 2008. Although the mortality was about 10% in the tidal flat of Geunso Bay and Cheonsu Bay, Incheon and Gyeonggi-do, the values was significantly high about 30% in water coast of Taean, Boryeong and Seosan in where the spilled oil was getting into fishery zone. However, the mortality in water coast of Taean, Boryeong and Seosan was decreased from 22.4% in 2008 to 6.0% in 2009. Also, we found that the mortality in contaminated and non-contaminated water zones was both slightly increased from 6.0 in 2009 to 8.6% in 2010, Therefore, these results are indicating that the significant high mortality observed in water coast of Taean, Boryeong and Seosan at April, 2008 was due to the crude oil accident outflow from tanks of Hebei spirit. Although the mortality of manila clam was significantly decreased in middle west coast of South Korea after the accident of Hebei spirit in December, 2007, the annual production of manila clam in South Korea was sustainedly from 27,459 ton in 2007, 36,302 ton in 2008, 40,392 ton in 2009, to 36,248 ton in 2010. In the production of manila clam by regional groups, the amount in sea coast of Chungnam, where was damaged by crude oil, was significantly decreased from 10,598 ton in 2007 to 5,048 ton in 2008, but then was significantly increased to 7,065 ton in 2009, and to 12,921 ton in 2010. However, in sea coast of Jeonnam that was not damaged by crude oil, the amount was significantly increased from 1,252 ton in 2007 to 12,248 ton in 2008, but then was significantly decreased to 9,566 ton in 2009, and to 2,770 ton in 2010. Therefore the results are suggesting that a increasing of the total annual production of manila clam in South Korea in 2008 when was 1 year after the oil accident of Hebei spirit was due to increasing of clam production in a coast of Jeonnam in where was not damaged by crude oil.

• Journal of Korea Soil Environment Society
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• v.4 no.2
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• pp.185-192
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• 1999

To assess the soil quality of Chonan City, soil analyses were conducted according to the 14 different sampling sites. The soil pH of the agricultural area near the expressway was lower than that of the other farming area, which indicated that this acidification was probably attributed to the acid rain caused by the traffic exhaust gas such as SOx and NOx. Acidification was more severe in the dry farming area than in the rice paddy area. All concentration of 6 different heavy metals (As, Cu, Cd, $Cr^{6+}$, Hg, Pb) and organic contaminants (cyanide, organic-p, PCBs, phenols) were found to be lower than the standard of soil pollution. The concentration of BTEX also lower than the standard of soil pollution. An assessment using the SPI (Soil Pollution Index). which was developed to estimate an overall soil quality, was performed. Each SPC (Soil Pollution Score) were evaluated with the results of the data from this study. The soil quality of most area of Chonan City was determined to Class 1 , which indicated that the soil was healthy.

• Journal of the Korean Society for Railway
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• v.12 no.5
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• pp.788-792
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• 2009

Railroad is well known for eco-friendly transportation system. But, for past few decades, there might be happened many contamination acts in railway facility sites. Industrial and municipal solid wastes produced to maintain and fix trains were dumped to underground of railroad depot area. To develop and reconstruct this area, we should remediate the contaminated soil and ground water. This study was conducted to evaluate the soil pollution status of railroad depot and propose the optimum remediation processes. Our investigation showed that main pollutants sources were TPH and some heavy metals from the dump site. The surveying results for the soil under rail track and crossing nose areas showed TPH contamination from crossing nose area causing lubricant agent. It could be use and rehabilitate the railroad facility areas to an intended purpose with an application of well designed in-situ and ex-situ remediation processes.

• The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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• v.37 no.5
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• pp.22-28
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• 2008

바다에 유출된 기름으로 오염된 지역의 친환경적인 방제를 위하여 기름분해 미생물을 이용하는 생물정화기술을 소개하고, 해양환경관리법 시행('08.1.21)으로 방제약제에 새로 추가된 생물정화제제의 성능시험기준 및 검정기준 등 형식승인절차를 기술하였다.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 1999.04a
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• pp.31-32
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• 1999

• Resources Recycling
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• v.23 no.2
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• pp.46-52
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• 2014

This study was conducted to observe the removal efficiency of oil-contaminated soil by various tests using microwaves and high-temperature heating elements. The water content was measured with the treatment amount, which was lowered to 300g in a relatively short amount of time. The treatment rate of TPH(Total Petroleum Hydrocarbons) showed the highest value with 70.1% when the SiC-activated carbon heating element was at 4 kW/kg, compared to the SiC heating element used alone. In particular, the higher electric power became, the higher treatment rate became, except at 3 kW. In the case of the heating element made by the fusion of SiC and activated carbon, the internal temperature exceeded $300^{\circ}C$ and again fell when it was treated at 4 kW for about 2 minutes. Then, after about 8 minutes, it rose again. On the basis of such results, the energy content necessary for the sample was calculated according to the electric power of microwaves, and tthe constant of TPH treatment was measured by tests on the treatment characteristics of oil-contaminated soil.

• Journal of the Korean GEO-environmental Society
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• v.11 no.8
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• pp.25-32
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• 2010

Contamination of soil and groundwater by the compounds of hydrocarbon petroleum has been widely accepted as the main cause that harms the environments and health. To remove those pollutants, absorbing clothes, activated carbons, or oil-water separation devices with the gravity method are employed for treatment. However, those materials and devices cannot remove the emulsion pollutants despite of their efficiency for removing free products. Therefore, we investigated the problems which occur during the groundwater treatment for the highly concentrated suspended solid particles, which can be resulted from excavation, and to propose methods to remove TPH(Total Petroleum Hydrocarbon). After coagulation experiment with high molecular polymers, the concentration of SS(Suspended Solids) and COD(Chemical Oxygen Demand) turned to satisfy the groundwater quality criteria within 5 minutes while the concentration of TPH failed to meet the water quality standard of effluent. Consequently, the water quality criteria for effluent could not be met by single DAF(Dissolved Air Flotation) process. However all water quality criteria could be satisfied after 20 minutes when coagulation reactions are carried out simultaneously in the DAF reactor.

• Journal of Soil and Groundwater Environment
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• v.7 no.4
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• pp.48-58
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• 2002

As a pilot experiment for developing the monitoring system for oil spill from storage tank, previous approach of monitoring contaminated oil from mixed soil sample had the limitation that it cannot reflect the real situations of the contamination. In this study, more realistic contamination condition and water contents were considered. Fluorescence intensity was not affected by water contents. To acquire the stability of media, sand, Ca-bentonite, alumina, Fe-oxide, bead and silica were tested. Only sand was suitable to our system. These results should provide basic information for constructing reliable monitoring system.

• Korean Journal of Microbiology
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• v.39 no.1
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• pp.8-15
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• 2003

To evaluate the effects of slow release fertilizer and chemical dispersant on oil biodegradation, mesocosm studies were conducted on sand seashore. The rapid removal rates (85%) of aliphatic hydrocarbons and the simultaneous decreases of n-$C_{17}$/pristane (69%) and $n-C_{18}/phytane$ (61%) ratios by the addition of slow-release fertilizer (SRF) within 37 days of experiment indicated that SRF could enhance the oil degrading activity of indigenous microorganisms in sand mesocosm. Although the growth of heterotrophic bacteria and petroleumdegrading bacteria in the mesocosm treated with $Corexit 9527^{R}$ was stimulated, the biological oil removal based on the ratios of $Corexit 9527^{R}$ and $n-C_{18}/phytane$ was inhibited. Removal rates of aliphatic hydrocarbons (56%), and n-$C_{17}$/pristane (27%) and $n-C_{18}/phytane$ (17%) ratios by the addition of chemical dispersant $Corexit 9527^{R}$ were similar or lower than those values of control (50, 60, 46%), respectively. The biodegradation activity, however, when simultaneously treated with SRF and $Corexit 9527^{R}$, was not highly inhibited and even recovered after the elimination of chemical dispersant. From these results it could be concluded that the addition of SRF enhanced the oil removal rate in oligotrophic sand seashore and chemical dispersant possibly inhibit the oil biodegradation. Hence, in order to prevent the unrestrained usage of chemical dispersant in natural environments contaminated with oil, the National Contingency Plan of Oil Spill Response should be carefully revised in consideration of the application for bioremedaition techniques.