• Korean Chemical Engineering Research
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• v.54 no.3
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• pp.299-304
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• 2016

Characteristics of self-propagating reaction for the preparation of ZnO powder from precursors composed of nitrate and citrate compounds were examined. The ratio of C/N was maintained in range of 0.7~0.8 to initiate the self-propagating reaction between the reducing citrate and oxidizing nitrate groups. The samples were decomposed thermally by using TGA. The sudden decomposition occurred in the range of X > 0.5 in a very short time with a very sharp decrease of mass, indicating that the self-propagating reaction would occur. Friedman, Ozawa-Flynn-Wall and Vyazovkin methods were employed to predict the activation energy, reaction order and frequency factor of the reaction rate in the rate determining step of X < 0.5 range. The activation energy increased with increasing fractional conversion in the range of 46~130 (kJ/min). The reaction order decreased in the range of 2.9~0.9, while the frequency factor increased in the range of 85~278 ($min^{-1}$), respectively, with increasing the rate of temperature increase.

• Korean Chemical Engineering Research
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• v.48 no.1
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• pp.58-67
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• 2010

Combustion of the Korean Anthracite and wood-pellet was characterized in air atmosphere with variation of heating rate(5, 10, 20 and $30^{\circ}C/min$) in TGA. The results of TGA have shown that the combustion of the wood-pellet occurred in the temperature range of $200{\sim}620^{\circ}C$ which is much lower than that of Korean anthracite. Activation energies of the wood-pellet and Korean anthracite, determined by using Friedman method were 44.12, 21.45 kcal/mol respectively. Also, their reaction orders(n) and pre-exponential factors(A) were 5.153, 0.7453 and $4.01{\times}10^{16}$, $1.39{\times}10^6(s^{-1})$ respectively. In order to find out the combustion mechanism of the wood-pellet and Korean anthracite, twelve solidstate mechanisms defined by Coats Redfern Method were tested. The solid state combustion mechanisms of the woodpellet and Korean anthracite were found to be sigmoidal curve A3 type and a deceleration curve F1 type respectively. Also, from iso-thermal combustion($300{\sim}900^{\circ}C$) of their char, the combustion characteristics of their char was found. Activation energies of the their char were 27.5, 51.2 kcal/mol respectively. Also, pre-exponential factors(A) were $2.55{\times}10^{12}$, $1.49{\times}10^{10}(s^{-1})$ respectively. Due to the high combustion reactivity of wood-pellet compared with Korean anthracite, combustion atmosphere will be improved by co-combustion with Korean anthracite and wood-pellet.

• Korean Business Review
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• v.19 no.1
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• pp.157-174
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• 2006

In the past, because Korean private venture capital firms could get government support and subsidies, they could be survived in the market without having required management capabilities, advanced venture investment techniques, and professional supporting agencies and institutions. However, business environments have changed a lot recently. Now, only through identifying the optimal financial structures(the ratio of debt to equity), Korean private venture capital firms can minimize investment risks and ensure higher profits. Since Modigliani and Miller(1958) criticized the existence of the optimal financial structure, there have been numerous studies on the optimal financial structure of firms. However, there is no empirical study investigating the financial structure of venture capital firms. The purpose of this article is to analyze the relationship between firm characteristics, financial security indies, and financial profit indices of korean private venture capital firms. We gathered the data from various sources, including the web pages and the financial statements for 2003 and 2004. By using the student's t-test and the correlation analysis, we showed that there are differences in the current ratio and the ratio of net profit to net sales between new and old korean private venture capital firms. Even though it is known that korean private venture capital firms does not have enough knowledge and investment technique to compete with global venture capital firms, our result show that old korean private venture capital firms have already built some knowledge and understanding of venture capital investing.

• Journal of the Korean Geotechnical Society
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• v.16 no.4
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• pp.17-30
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• 2000

The objective of this study is to evaluate the lateral earth pressure and the stability of small scale retaining wall with waste foundry sand(WFS) mixtures as a controlled low strength materials (CLSM). Three different types of WFS, like Green WFS, Hurane WFS and Coated WFS, were used in this study, and fly ash of Class F type was adopted. To evaluate the lateral earth pressure and the stability of retaining wall, two different samll scale retaining wall tests, which are called an artificially controlled strain method and a natural strain method, were carried out. In case of an artificially controlled strain method, the coefficient of lateral earth pressure, just after backfilling of WF mixtures, was around 0.8 to 1.0, and most of earth pressure was dissipated within 12 hours. In case of a natural strain method, two steps of stage constructions were employed. The mixtures of Hurane WFS and Coated WFS showed fast decrease of earth pressure due to a relatively good drainage. Judging from the sta bility of retaining wall for overturning and sliding, two steps of stage construction for 2 days were enough to finish the backfill of 6-m height of retaining wall. Also, considering the curling effect of WFS mixtures, the stability of retaining wall increased as curling time increased.

• Korean Chemical Engineering Research
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• v.50 no.6
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• pp.994-1001
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• 2012

The Effects of operating variables on reactivity of two $CO_2$ absorbents (PKM1-SU and P4-600) for SEWGS process were investigated in a pressurized fluidized bed reactor. For both $CO_2$ absorbents, $CO_2$ sorption capacity decreased as the number of absorption-regeneration cycles increased. PKM1-SU absorbent represented higher $CO_2$ sorption capacity than that of P4-600 absorbent. However, P4-600 absorbent represented better performance than PKM1-SU absorbent from the view points of regeneration temperature and regeneration rate. For PKM1-SU absorbent, $CO_2$ sorption capacity increased as the steam concentration increased. However, $CO_2$ sorption capacity increased initially as the steam concentration increased from 5% to 10%, but maintained thereafter for P4-600 absorbent. For both $CO_2$ absorbents, $CO_2$ sorption capacity increased as the final regeneration temperature increased. For PKM1-SU absorbent, $CO_2$ sorption capacity increased as the pressure increased and the increment tendency was drastic at higher pressure than 15 bar.

• Journal of the Korean Electrochemical Society
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• v.2 no.2
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• pp.98-105
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• 1999

In the present study, buoyant force and its stabilizing effects in an electrostatic field were examined systematically in order to reduce the effect of natural convection with thermal stratification in a horizontal fluid-saturated porous layer. The correlation of ionic mass transport induced by double-diffusive convection in a horizontal porous layer has been derived theoretically. And the theoretical model was examined by electrochemical experiments. The theoretical correlation for mass transport which is satisfying Forchheimer's flow equation and based on the micro-turbulence model is derived as a function of soltual Darcy-Rayleigh number, thermal Darcy-Rayleigh number and Lewis number. In the experiment, the mass transport of copper ions in $CuSO_4-H_2SO_4$ solution is measured by electrochemical technique. By assembling theoretical correlation and experimental results, the mass transport correlation induced by double-diffusive convection is proposed as $$Sh=\frac{0.03054(Rs_D-LeRa_D)^{1/2}}{1-3.8788(Rs_D-LeRa_D)^{-1/10}}$$ The present correlation looks flirty reasonable with comparing experimental results, and very promising for the applications of its prototype into various systems involving heat transfer as well as mass transfer, in order to control the effects of natural convection effectively.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.40 no.2
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• pp.69-73
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• 2016

Recently, automotive engineers have paid much attention to waste heat recovery technology as a possible means to improve the thermal efficiency of an automotive engine. A large displacement gasoline engine is generally a V-type engine. It is not cost effective to install two superheaters at each exhaust manifold for the heat recovery purposes. A single superheater could be installed as close to the exhaust manifold as possible for the higher recovery efficiency; however, only half of exhaust gas can be used for heat recovery. On the contrary, the exhaust temperature is decreased for the case where the superheater is installed at a junction of two exhaust tail pipes. With the fact in mind, the optimum position of a single superheater was investigated using simulation models developed from a commercial software package (i.e. AMESim). It was found that installing the superheater near the exhaust manifold could recover 3.8 kW more from the engine exhaust despite utilizing only half of the exhaust mass flow. Based on this result, the optimum layout of an automotive waste heat recovery system was developed and proposed in this paper.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.36 no.10
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• pp.1267-1274
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• 2012

A guide vane plays a key role in controlling the flow rate of water supplied to the turbine of a hydropower plant. It has been reported that guide vane bearing bushings are subjected to considerable wear, which requires them to be maintained. An ancillary service such as frequency control and black start causes cyclic low opening operation of the guide vanes. It is empirically well known that such operation increases the wear rate of the guide vane bearing bushing. In this study, the effect of low opening operation on the increasing wear of the guide vane bearing bushing is quantitatively assessed via finite element flow analysis, finite element stress analysis, and relative wear evaluation. As a result of the assessment, it is identified that the pressure applied on the guide vane surface increases and the contact length between the outer surface of the guide vane stem and the inner surface of the bearing bushing decreases with a decrease in the opening of the guide vane. In addition, low opening of the guide vanes results in an increase in the relative wear owing to the generation of high contact pressure on the bearing bushing surfaces.

• Journal of Bio-Environment Control
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• v.19 no.4
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• pp.195-202
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• 2010

Cooling air-conditioning of APC (Agricultural Products processing Center) workplace is important to improve the working environment in the summer season. As existing cooling systems for air-conditioning of whole workplace are inefficient because of their high equipment operating costs, relatively inexpensive cooling system is required. The objectives of this study were to simulate the thermal flow fields in APC workplace having the positive and negative pressure type fan and pad systems and spot cooling system by using CFD software (FLUENT, 6.2) and estimate the cooling effectiveness of respective cooling systems. The results showed that the negative pressure type fan and pad system was inappropriate for the present APC workplace because of excessive outside air influx from open gateway and the positive pressure type fan and pad system created relatively low temperature field but non-uniform velocity field at worker positions. The spot cooling system could supply cool air to worker positions with relatively constant air velocity and temperature.

• Journal of Bio-Environment Control
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• v.17 no.2
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• pp.83-89
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• 2008

A wind tunnel test was conducted at Protected Horticulture Experiment Station of National Horticultural Research Institute in Busan to find the aerodynamic resistance and quadratic resistance coefficient of chrysanthemum in greenhouse. The internal plants of the CFD model has been designed as a porous media because of the complexity of its physical shapes. Then the aerodynamic resistance value should be input for analyzing CFD model that crop is considered while the value varies by crops. In this study, the aerodynamic resistance value of chrysanthemum canopy was preliminarily found through wind tunnel test. The static pressure at windward increased as wind velocity and planting density increased. The static pressure at leeward decreased as wind velocity increased but was not significantly affected by planting density. The difference of static pressure between windward and leeward increased as wind velocity and planting density increased. The aerodynamic resistance value of chrysanthemum canopy was found to be 0.22 which will be used later as the input data of Fluent CFD model. When the planting distances were $9{\times}9\;cm$, $11{\times}11\;cm$, and $13{\times}13\;cm$, the quadratic resistance coefficients of porous media were found to be 2.22, 1.81, and 1.07, respectively. These values will be used later as the input data of CFX CFD model.