• Applied Chemistry for Engineering
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• v.23 no.2
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• pp.232-240
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• 2012

Bio-diesel (BD) is the mono alkyl esters of long chain fatty acids derived from renewable feed stocks like vegetable oils or animal fats. Bio-diesel shows poorer fuel properties than that of diesel fuel in a cold condition. For the diesel fuel, many cold flow improvers have been developed; however, since primary ingredients of bio-diesel are different from those of the diesel fuel, there is a limit to the cold flow improvement when the same cold flow improvers are added to bio diesel. In this study, to improve low temperature properties of bio-diesel, we developed a cold flow improver using an alkyl methacrylate monomer, prepared via ester reaction, and maleic anhydride and also conducted a ring opening reaction using amine. We characterized the products using $^1H-NMR$, FT-IR and GPC methods. In addition, the cold flow improvements of the products in Soybean BD and Palm BD in the concentration rage of 1000~10000 ppm were investigated. It was found that the addition of LMA2SMA6MA2-C8A in Soybean BD improved the pour point by $12.5\;^{\circ}C$.

• Journal of the Korea Institute of Building Construction
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• v.22 no.5
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• pp.441-450
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• 2022

In this study, the fluidity and strength characteristics of NSC mortar according to the type and rate of addition of superplasticizer were analyzed to secure the fluidity of NSC composed of only slag and ash. Through the flow test, it was found that the fluidity of NSC was related to the basicity according to the binder condition, and the lower the reactivity, the higher the fluidity. When polycarboxylate is added, NSC mortar is considered to be more advantageous than plain mortar in terms of securing fluidity. As a result of the strength tests of NSC mortar containing Lignin or Polycarboxylate superplasticizer, it was found that the strength tends to increase as the basicity increases. In addition, when polycarboxylate is added, it is judged that the NSC mortar can secure adequate fluidity and strength at the same time. Through this experiment, an appropriate binder condition that satisfies the flowability while securing the strength was derived.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.1
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• pp.68-75
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• 2017

The study investigates the effects of the content and using method of chemical admixtures such as superplasticizer and viscosity modifying admixture on the fluidity, bleeding ratio, volumetric change and compressive strength of the grout in order to provide basic data for the development of high-quality grout for prestressed concrete. It appeared that the combination of superplasticizer and viscosity modifying admixture decreased the fluidity of grout with small content of superplasticizer. On the contrary, Grout used more than 0.1% of superplasticizer appeared to have significant effect on the improvement of the fluidity. On the other hand, bleeding of grout reduced according to increasing the content of viscosity modifying admixture. Superplasticizer with less than 0.05% had practically no effect on the reduction of bleeding, whereas superplasticizer with more than 0.1% appear to have significant effect on the reduction of bleeding. Also the combination of superplasticizer with 0.15% and viscosity modifying admixture with 0.15% resulted in satisfactory fluidity accompanied with fair reduction of bleeding and shrinkage of the grout.

• Magazine of the Korea Concrete Institute
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• v.9 no.3
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• pp.149-156
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• 1997

In order to improve compressive strength of cement mortar, powder admixture(FAS) was mmufactured by mixing fly ash. Il-anhydite and silica hume, and superplasticizer was used for the control of fluidity reduction with the use of this admixture. Cement was substituted by 10, 20wt% of FAS respectively. At W/S = 0.40, the fluidity of' cement paste substituted by PAS was decreased. NSF and NT-2 were very effective fbr the control of fluidity reduction. As the particle size of U -anhydrite was fine, the fluidity of cement mortar was increased. The fluidity reduction of cement mortar substituted by 10wt% of FAS was controlled. The compressive strength of cement mortar substituted by 10wt% of FAS showed higher. value than that of 20wt%, expecially specimen(C1) substituted by 10wt% of $\gamma$ had the highest compressive strength value.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.24 no.1
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• pp.130-135
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• 2010

In this study, the performance improvement of epoxy resin system had been tried by the improvement of particle size distribution and globularization of filler using polymerization method. From the results of particle size distribution measurement, the polydispersity value of reformed filler was 1.04 and that of silica flour before reformation was 2.6, it could be confirmed that the particle size uniformity of reformed filler had been improved greatly and the shape of particle was globular. Compatibility between monomer and silica was improved remarkably with the silanization pretreatment of silica flour. From the results of degree of crosslinking test, it could be confirmed that the binding structure of reformed filler was 3-dimensional net structure. And it could be also confirmed that the fluidness was improved at the casting of epoxy resin with reformed filler. From the above results, it could be concluded that the reformation of filler with the improvement of particle size distribution and globularization was very successful method to improve the performance of cast epoxy resin system.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.613-616
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• 2008

Many researches on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. Instead, the source of material such as fly ash and blast slag, that are rich in Silicon(Si) and Aluminium(Al), are activated by alkaline liquids to produce the binder. Hence concrete with no cement is effect reduction of CO$_2$ gas. In this study, we investigated the influence of the workability and compressive strength of mortar on water reducing agent, alkaline activator and curing method in oder to develop cementless blast slag based alkali-activated mortar. In view of the results, we found out that the flowability of mortar was lowered as increasing to mole concentration of NaOH, but not large the loss of flowability to 9M NaOH, most of water reducing agent was not effect. The compressive strength was improved as increasing to mole concentration of NaOH, was the most effect in 9M NaOH. The curing temperature and curing conditions on compressive strength of blast slag based alkali-activated mortar didn't influence.

• Journal of the Microelectronics and Packaging Society
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• v.6 no.4
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• pp.41-48
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• 1999

Silica is the most popular materials as a filler of EMC for microelectronic packaging. However, because of its low thermal conductivity, the use of silica is restricted to parts requiring high thermal dissipation. The superior fluidity of EMC can be achieved with a combination of filler size distribution. In this study, physical properties of EMC filled with the crystalline silica(13$\mu\textrm{m}$) which have high fluidity and low cost and the AlN(2 $\mu\textrm{m}$) which have high thermal conductivity and low coefficient of thermal expansion were evaluated by changing the AlN/silica ratios. As a result of the evaluation of physical properties of EMC, the optimum mixing ratio of AlN/crystalline silica was 0.3/0.7. In this condition, binary mixture(AlN/crystalline silica) filled EMC showed superior properties, i.e., in the thermal conductivity, CTE, dielectric constant, flexural strength, and thermal shock resistance without reduction of fluidity.

• Journal of the Korean Recycled Construction Resources Institute
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• v.3 no.1
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• pp.50-57
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• 2015

Portland cement production is under critical review due to high amount of $CO_2$ gas released to the atmosphere. Attempts to increase the utilization of a by-products such as fly ash and ground granulated blast-furnace slag to partially replace the cement in concrete are gathering momentum. Many researchs on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. Instead, the sources of material such as fly ash, that are rich in Silicon(Si) and Aluminium(Al), are activated by alkaline liquids to produce the binder. Hence concrete with no cement is effect reduction of $CO_2$ gas. In this study, we investigated the influence of the fluidity, air content and compressive strength of mortar on alkaline activator in order to develop cementless fly ash and ground granulated blast-furnace slag based alkali-activated mortar with superplasticizer. In view of the results, we found out that Pn of fluidity and compressive strength is the best in four type of superplasticizer, and PNS of powder type of fluidity is better than that of liquid type in the case of AA.

• Journal of the Korea Concrete Institute
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• v.14 no.3
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• pp.275-282
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• 2002

High fluidity concrete needs high dosage of superplasticizer to acquire sufficient fluidity and high contents of fine powder and viscosity agents to prevent segregation. But it requires high manufacturing cost and has difficult in quality control. Therefore, in this paper, determination of optimal mixture proportion of segregation type superplasticizer for high fluidity concrete and manufacturing high fluidity concrete by applying developed segregation reducing type superplasticizer are discussed using flowing concrete method. According to test results, as dosage of superplasticizer increases, it shows that fluidity and bleeding increase, while air contents and ratio of segregation resistance decrease. It also shows that adding viscosity agent into it reduce bleeding and improve segregation resistance. Dosage of AE agent into it containing viscosity agent recovers loss of air contents during flowing procedure. Combination of proper contents of superplasticizer, viscosity agent and AE agent make possible to develope segregation reducing type superplasticizer Compressive strength of high fluidity concrete applying flowing method with it is higher than that of base concrete. No differences of compressive strength between compacting methods are found.

• Journal of the Korean Institute of Gas
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• v.2 no.3
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• pp.1-11
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• 1998

To increase peel strength, low temperature properties and flowability of pressure sensitive adhesives(PSA) used in a heat shrinkable sheet, these properties were evaluated by changing each components in type and content. In this study, Isobutylene-co-Isoprene Rubber (IIR) which has good wetherability was selected as a base polymer. Instead of rosin ester, petroleum resin was selected as a tackifier because of superior peel strength. By decreasing petroleum resin contents, flowability of PSA was decreased. High molecular weight of polybutene was better than low molecular weight for the peel strength of PSA. Large particle size of carbon black showed better properties than small one in peel strength and brittleness temperature. By adding calcium carbonate, the cost of compound was able to be reduced. But it must be used with carbon black.