• Title/Summary/Keyword: 유기 점토

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Polyester Nanocomposite Fibers with Organoclay; Thermo-Mechanical Properties and Morphology of PBT, PET, and PTT (유기화 점토를 이용한 폴리에스테르 나노복합체 섬유; PBT, PET, 그리고 PTT의 열적-기계적 성질 및 모폴로지)

  • Kim Sung Jong;Mun Mu Kyung;Chang Jin-Hae
    • Polymer(Korea)
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    • v.29 no.2
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    • pp.190-197
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    • 2005
  • Nanocomposites of three different polyesters with dodecyltriphenylphosphonium-montmorillonite $(C_{12}PPh-MMT)$ as an organoclay are compared with their thermal properties, mechanical properties, and morphologies. Poly (butylene terephthalate) (PBT), poly(ethylene terephthalate) (PET), and poly(trimethylene terephthalate) (PTT) were used as matrix polymers in the fabrication of polyester nanocomposite fibers. The variations of their properties with organoclay content in the polymer matrix and draw ratio (DR) are discussed. Transmission electron microscopy (TEM) micrographs show that some of the clay layers are dispersed homogeneously within the polymer matrix on the nano-scale, although some clay particles are agglomerated. We also found that the addition of only a small amount of organoclay is enough to improve the thermal stabilities and mechanical properties of the polyester nanocomposite fibers. Even polymers with low organoclay contents $(<5\;wt\%)$ were found to exhibit much higher strength and modulus values than pure polyester fibers. In the cases of all polyester hybrid fibers, the values of the tensile mechanical properties were found to decrease linearly with increasing DR. However, the initial tensile modulus of the PTT hybrid fibers were found to be independent of DR.

Organically Modified Vermiculite-Poly(Ethylene Terephthalate) Nanocomposites (유기물로 개질한 나노점토-폴리(에틸렌 테레프탈레이트) 복합재료의 기계적 특성)

  • Hai Anh Thi Le;Yong Tae Park
    • Composites Research
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    • v.36 no.4
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    • pp.275-280
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    • 2023
  • Because polymer-based composites are lightweight and have excellent properties, their demand is growing rapidly as a way to fulfill properties that are difficult to achieve with a single material. As a result, there has been a lot of research on polymer nanocomposites, which are made by dispersing particles with a size of 1-100 nm in a polymer matrix. In addition, many nanocomposites using thermoplastic resins as matrix materials are being studied. In this study, poly(ethylene terephthalate) (PET)-based nanocomposites containing organic nanoclays modified with cetyltrimethylammonium bromide (CTAB) as interlayer materials were prepared. Among various nanoclays, vermiculite (VMT) has been studied to increase the mechanical and thermal properties of polymeric materials due to its low cost, abundant reserves and unique properties. However, the strong interlayer bonding of VMT has limited its utilization due to its poor exfoliation and dispersion performance within polymer matrices. In this study, the mechanical properties of the VMT content were confirmed by tensile tests, the dispersion of VMT particles in the PET matrix was evaluated by TEM cross-sectional images, and the nitrogen gas barrier properties were evaluated.

Comparison of the Properties of Poly(lactic acid) Nanocomposites with Various Fillers: Organoclay, Functionalized Graphene, or Organoclay/Functionalized Graphene Complex (유기화 점토, 작용기화 그래핀 및 유기화 점토/작용기화 그래핀 복합체 등의 필러를 사용한 Poly(lactic acid) 나노 복합체의 물성 비교)

  • Kwon, Kidae;Chang, Jin-Hae
    • Polymer(Korea)
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    • v.38 no.2
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    • pp.232-239
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    • 2014
  • Poly(lactic acid)(PLA) nanocomposites containing various nanofillers were synthesized using the solution intercalation method. Organically modified bentonite clay (NSE), octadecylamine-graphene oxide (ODA-GO), and an NSE/ODA-GO complex were utilized as nanofillers in the fabrication of PLA hybrid films. PLA hybrid films with varying nanofiller contents in the range of 0-10 wt% were examined and compared in terms of their thermomechanical properties, morphologies, and oxygen permeabilities. Transmission electron microscopy (TEM) confirmed that most of the NSE and ODA-GO nanofillers were dispersed homogeneously throughout the PLA matrix on the nanoscale, although some agglomerate NSE/ODA-GO complex particles were also formed. Among the three nanofillers for PLA hybrid films, the NSE/ODA-GO complex showed the best improvement in film thermal stability. In contrast, NSE and ODA-GO exhibited the best improvement in tensile mechanical properties and oxygen barrier properties of the PLA hybrid films, respectively.

Effect of Metal Ion on the Bentonite Modified with Cationic Surfactant (양이온성 계면활성제를 이용한 유기 벤토나이트의 합성시 금속 이온의 첨가 영향)

  • Kim, Soo-Hong;Park, Jae-Woo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.6B
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    • pp.677-682
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    • 2006
  • Dodecyldimethylethylammonium (DDDEA), a cationic surfactant, and aluminum metal ions were used with bentonite to synthesize to synthesize an improved organo bentonite. Among three different synthesis procedure for organo bentonites, aluminium-pillared bentonite showed the highest DDDEA sorption, which indicated that aluminium-pillared organo bentonite would exhibit the highest sorption capacity for organic contaminants. Aluminium pillared organo bentonite also showed a high sorption capability for phosphorus, while it did not exhibit strong sorption for nitrate. In the meantime, more desorption was observed with aluminium-pillared organo bentonite than ordinary organo bentonites.

A Study on Contaminant Sorption Capacity of Soil Liner for Seashore Waste Landfill by Using Column Test Apparatus (주상시험장치를 이용한 해안 폐기물 매립장 지반토지 오염물 흡착능에 관한 연구)

  • Jang, Yeon-Su;Han, Seong-Gil;Kim, Su-Sam
    • Geotechnical Engineering
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    • v.13 no.4
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    • pp.75-84
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    • 1997
  • In this paper, the retardation capacity of marine clay and weathered soil of seashore waste landfill is analyzed by using a laboratory column apparatus for organic and inorganic components which can represent the components of the leachate of municipal waste landfill. The results show that sorption capacity marine clay for potassium is larger than that of weathered soil. Lead and cadmium are adsorbed completely at concentrations higher than the real concentrations developed in the landfill. The bottom soils of seashore landfill can also retard some nondegradable components of organics although their sorption capacities for organics were less than those for inorganics.

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Applied Mineralogy for the Conservation of Dinosaur Tracks in the Goseong Interchange Area (35번 고속도로 고성 교차로 지역 공룡발자국의 보존을 위한 응용광물학적 연구)

  • Jeong Gi Young;Kim Soo Jin
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.3
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    • pp.189-199
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    • 2004
  • Cretaceous sedimentary rocks bearing dinosaur tracks in the Goseong interchange area were studied for their conservation and public display in the aspect of applied mineralogy. Black clay layers alternate with silt layers in the sedimentary rocks. The verical and horizontal fissures are commonly filled with calcite veinlets, supergenetic iron and manganese oxides. The rocks are composed of quartz, albite, K-feldspar, calcite, chlorite, illite, muscovite, and biotite, with minor apatite and rutile. Silt layers are relatively rich in calcite and albite, whereas clay layers are abundant in quartz, illite, and chlorite. Al, Fe, Mg, K, Ti, and P are enriched in the clay layers, while Ca, Na, and Mn in silt. Most of trace elements including V, Cr, Co, Ni, Cs, Zr, REE, Th, and U are enriched in clay layers. Inorganic carbon are present in silt layers as calcite, while organic carbon in black clay layers. The black clay layers were partly altered to yellow clay layers along the fissures, simultaneously with the decrease of organic carbon. Selective exfoliation of clay-rich black and yellow clay layers, calcite matrix of silt layers and calcite infillings of fissures are estimated as the major weakness potentially promoting chemical and physical degradation of the track-bearing rock specimens.

Synthesis and Characterization of Allyl Ester Resin-Layered Silicate Nanocomposite (알릴 에스터 수지-층상 실리케이트 나노복합재료의 합성과 특성)

  • 팽세웅;김장엽;허완수;조길원;이상원
    • Polymer(Korea)
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    • v.28 no.2
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    • pp.177-184
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    • 2004
  • Polymer-clay nanocomposite containing the low amounts of clay shows improved physical, mechanical properties. In this study, allyl ester prepolymer was synthesised by reactions of the diallyl terephthalate monomers and the 1,3-butanediol monomers. Nanocomposites of allyl ester prepolymer and the two kinds of the organically layered silicate were prepared by using the intercalation method as well as the in-situ polymerization method using. By varying the amount of clay content, curing conditions, and feeding conditions. the nanocomposite was studied using X-ray diffraction. From XRD results, allyl ester-Cloisite 30 B nanocomposite made by the in-situ polymerization method shows better exfoliation behavior compared with the intercalation method. It can be said that the transesterification reaction between functional groups (-OH) of intercalant and monomers results in the increased gallery distance. Also mechanical and thermal properties indicate that the dispersity of clay is an important factor for improving physical properties of the nanocomposite.

Effects of Coupling Agents and Clay on the Physical Properties of Wood Flour/Polyethylene Composites (커플링제 및 점토가 목분/폴리에틸렌 복합체의 물성에 미치는 영향)

  • Park, Byung-Sub;Kim, Dae-Su
    • Polymer(Korea)
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    • v.35 no.2
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    • pp.124-129
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    • 2011
  • Wood plastic composites (WPCs) are attracting a lot of interest recently. In this study, wood flour/polyethylene (PE) composites panels comprised of a coupling agent and nanoclay were prepared by melt-blending followed by compression molding. Five maleic anhydride grafted polyethylene (MAPE) coupling agents were tested, and the best choice and its optimum content were determined. The mechanical properties of the WPCs were measured by UTM, and the thermal properties were measured by TGA, DMA, DSC, and TMA. Adding just a small amount (1 phr) of organoclay made the tensile and flexural strength and the crystallinity of the WPC somewhat increase and the storage modulus and dimensional stability of the WPC largely increase. SEM images showed that the coupling agent drastically improved wood flour/PE interfacial bonding. Selecting the best coupling agent optimized content and adding a small amount of organoclay resulted in a high performance wood flour/PE composite.

Characterizations of Lyocell and Its Blended Nanocomposite Film: Morphology and Mechanical Property (라이오셀 및 라이오셀 블렌드 나노복합체 필름의 특성 연구 : 모폴로지 및 기계적 성질)

  • Jang, Seo-Won;Chang, Jin-Hae
    • Polymer(Korea)
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    • v.31 no.3
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    • pp.221-227
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    • 2007
  • The mechanical properties and morphologies of lyocell and its blend we compared. Poly (vinyl alcohol) (PVA) was used as a filler in blends with lyocell produced through solution blending. The variations of their properties with polymer matrix filler content are discussed. The ultimate tensile strength of the PVA/lyocell blend is highest for a blend lyocell content of 30 wt%, and decreases as the lyocell content is increased up to 40 wt%. The variations in the initial moduli of the blends with filler content are similar. Lyocell and its blended hybrid films were prepared by the solution intercalation method, using dodecyltriphenylphosphonium-mica ($C_{12}PPh$-Mica) as the organoclay. The variations of the mechanical tensile properties of the hybrids with the organoclay content were examined. These properties were found to be optimal for an organoclay content of up to 5 wt%. However, the mechanical tensile properties of the PVA/Lyocell (w/w=30/70) blended hybrid films were found to decrease linearly with increases in organoclay content from 1 to 5 wt%.