Optimum conditions for UV-radiated photopolymerization of unsaturated polyester that could be used as protecting layer of large diameter pipe were investigated in this paper. UV photopolymerization method was selected to solve the problems, arising when thermal polymerization by organic peroxide was used, such as the instability of peroxide initiator, the evolution of volatile organic compound, and thermal deformation of product. Two of the photo-initiators (Irgacure 819 and Darocure 1173) well known for its penetrating ability deep into the polymer layer were selected, and the optimum conditions for photopolymerization (1.5 phr initiator content, 1:1.2 initiator ratio, Ga lamp for UV source) were found from the thermal and mechanical test results of the resultant UP polymers. In addition, composite materials containing UP polymer and glass fiber were tested for hardness, impact strength, and flexural strength to find that the impact strength of composite significantly improved.
Antidotal efficacy of combinational prophylactics composed of physostigmine plus procyclidine, alone or in combination with antidotes such as atropine plus 2-pralidoxime or atropine plus HI-6, was evaluated in rats. Physostigmine (0.1 mg/kg) plus procyclidine (3 mg/kg), pretreated subcutaneously 30 min prior to subcutaneous exposure to organophosphates of militarily importance, exerted protection ratios of 7.2, 6.5, 4.0, 2.9 and 8.0 fold for tabun, saris, soman, cyclosarin and V-agent, respectively. In comparison, low effects (1.7 fold for soman and 1.3 fold for cyclosarin) were achieved with the traditional antidotes atropine (17.4 mg/kg) plus 2-pralidoxime (30 mg/kg) administered intramuscularly immediately after organophosphate, in contrast to high effects (5.5 fold for soman and 160.0 fold for cyclosarin) with atropine (17.4 mg/kg) plus HI-6 (125 mg/kg), although the protection ratio markedly decreased when treatment of antidotes was delayed. Note- worthy, the combinational prophylactics markedly potentiated the effects of antidotes to higher than 5.0 fold in all cases. In addition, the combinational prophylactics fully prevented the seizures and excitotoxic brain injuries induced by a high dose (100 mg/kg, 1.3 LD$_{50}$) of soman. Taken together, it is suggested that the prophylactics composed of physostigmine and procyclidine, in combination with posttreatment antidotes, could be a promising regimen for the prevention of lethality, seizures and brain injuries induced by organophosphates possessing diverse properties.s.
Journal of agricultural medicine and community health
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v.8
no.1
/
pp.19-27
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1983
This study was carried out to obtain the basic data for the prevention of chronic poisoning by organic phosphorous pesticides and to estimate the normal range of plasma cholinesterase activity level for Korean agricultural workers. The 285 agricultural workers were randomly selected for the study in Jungup Gun, Jeonbug Province, 135 persons of them were tested in the period of pre-exposure of organophosphorous pesticides (April 1981) and rest of them were tested after exposure(August 1981). Cholinesterase activity levels were measured by the Micro-method of Takahashi Hiroshi. Major findings are as following: 1) There is significant difference in plasma cholinesterase activity levels between the pro-exposed and post exposed group(p > 0.01). Mean values of plasma cholinesterase activity levels were $7.60{\pm}1.74{\mu}M/20{\mu}{\ell}$/hr. in the pre-exposed group and $6.23{\pm}1.59{\mu}M/20{\mu}{\ell}$/hr. in the post-exposed group. 2) Plasma cholinesterase activity in Korean agricultural worker could be estimated $7.30-7.90{\mu}M/20{\mu}{\ell}$/hr. with 95% confidence interval.
There experiment were carried out to analyze for pesticide residues in 4 kinds of dried fruits collected in northern area of Seoul in 2007~2009. Total of 213 samples were analyzed. According to the results, 20 kinds of residual pesticides were detected. Residual pesticides were detected in 66 samples (31.0%) and 8 samples (3.8%) exceeded maximum residue limits (MRL). Cypermethrin, fenvalerate, endosulfan, chlorpyrifos, bifenthrin were detected frequently. The Pesticide types which were detected in dried furits were revealed in order of pyrethroid > organophosphate > organochloride > dicarboximide. Detection rates of dried fruits were dried chinese matrimony vein (53.0%), dried jujube (34.9%), dried rubi fructus (7.6%) and dried maximowiczia chinensis (4.6%). Based on these results, we investigated the risk assessment from amount of residual pesticide in dried jujube. Range of %ADI were 0.0001~0.0081%, but the value has not effected on human health.
The study was planned to detect resistance levels of striped rice borers (Chilo suppressalis Walker) and green rice leafhoppers(Nephotettix cincticeps Uhler) from different localities to organophosphate and carbamate insecticides using topical application. Strains of overwintering striped rice borers were collected from 7 different areas in Gyeonggi Province and they were kept under conditions of about $25^{\circ}C$ for 10 days. Overwintered and reared larvae of striped rice borers were compared for response to insecticides. The strains of green rice leafhopper were collected from Iri, Milyang, Pyongtaek, Echeon and Suweon. Insects were multiplied in the lab. All insecticides tested were organphosphates(MPP, MEP and Diazinon) and carbamate (NAC), which have been used in control of rice insect pests for over past 10 years. The results obtained were as follows; a. With MPP compound, resistant levels of the Joam, Suweon, and Echeon strains of C. suppressalis were from 2 to 4 times as compared with the Yangpyong strain. b. With MEP insecticide, resistant levels of the Kimpo, Pyongtaek, Yongin, Echeon, Suweon, and Joam strains of C. suppressalis were from 2 to 6 times as compared with the Yangpyong strain. c. With Diazinon, resistant levels of the Suweon strain of C. suppressalis were 3 times greater than the Yangpyong strain; but the resistant levels of Kimpo, Pyongtaek, Yongin, and Echeon strains approximated the later. 4. The overwintered larvae of C. suppressalis were more tolerant to the insecticides than the larvae reared in the lab. e. With MEP, resistant levels of the Iri, Milyang, and Pyongtaek strains of N. cincticeps to the Suweon strain showed 13, 8, 7 and4 times, respectively. f. With MPP, resistant levels of the Iri and Pyongtaek strains of N. cincticeps were 7 and 4 times as compared with the Suweon strain, respectively. g. With NAC, resistant levels of the several strains of if. cincticeps showed no difference, and seemed not to have developed resistance yet.
The study involved determination of resistance levels of spider mites ta argano-phosphates using topical application and slide dip techniques; laboratory serening tests of alternative acaricides using an O/P resistant strain and a field trial of the screened materials. 1. Strains of Tetranychus were from Timaru(TR), Havelock Narth (HNR), Lincaln (LN). Germany (GR, GN). Comparisons of the resistant strains and normal strains at the LD50 and LC50 levels were as follows : (a) Using the topical application tochnique; with Parathian. resistant levels of the GR. TR and HNR strains of T. urticae were respeativuly, 1035. 484 and 452 times as resistant' as the LN strain. (b) Using the slide dip technique; with Phosdrin, resistant of GR, TR and HNR strains of T. urticae were 635, 274 and 266 times greater respeativuly, than the GN strain. 2. The laboratory sereaning tests were carried out far their contact plus stomach and residual effect to assess the toxicities of eleven alternative materials which would be used far control of O/P resistant strain of T. urticae. The acaricide groups represented were 3 organo-chlorines (Spidex, Kelthane and C 8514), 2 nitrophenyls (UC 19786 and Morocide), 2 cyclic carbonates(Eradex and Morestan). I carbamate (UC2004 7A), 1 mixture of carbamate and orano-chlorine and 2 other chemicals (C 8677 and M2527). From all acaricide tested. Kelthane and Morocide were the most effective, folowed by Spidex and M2527. Morestan, C8514. C8677 and RS 143 were intermediate, but Eradex, UC 19786 and UC 20046A were poor. 3, The number of sapmles required for estimation of the population in the field evaluation of acaricidal effects was one giving the highest practical precision. It was decided, after preliminary sampling trials. to use samples of 30 leaves per replicate which gave a $5.7\%$ standard error. 4. In the field trials, Morocide applied at the $0.05\%\;and\; 0.04\%$ a. i. conc. to black currant trees gave excellent control of O/P resistant population of T. urticae for about 12 days, but Morocide 0.025 and Kel thane $0.02\%$ a. i. cone. gave efficient control for about 6 days. In other words. first applications of Kel thane ane Moroeide gave very high degrees of control of O/P resistant population of the two-spotted spider mite. However, the results indicate that secondary application would sometimes be necessary. There was no foliage damage of black Currants and strawberries by either acaricides at the concentrations used. Acknowledgment ... The authors are grateful to: Dr. R. P. pottinger, Senior Lecturer in Agricultural Zoology. Lincoln college. New Zealand. for his helpful assistance in aiding with the organization of thd field work. Department of agriculture officers for mite colonies. Mr. D. A. Slade, Technical Advisor. Fruitgrowers' Federation (now at Massey University) for his assistance and provision of mites for testing. Mr T. McRae of Timaru for permission to use his crops for field tests. The following chemical companies and I or their New Zealand agents for so readily supplying samples of acarides; Ivan Watkins-Dow Limited. Fruitgrowers Chemical Company Limited. Henry H. York & company (New Zealand). Shell Oil (New Zealand) Limited.
1. This experiment was planned to compare the effectiveness of Diazinon granular and gammadol dust with the low toxic organophosphorus insecticides applied on the water-surface for the control of the rice stem borer, Chilo suppressalis Walker, in the 2 nd generation and to determine the proper timing of those insecticidal applications at Suwon, Korea, in 1964. 2. The hatching larvae from the eggs were inoculated on the rice plants in pots and insecticides were applied on the water-surface of pots at a given day intervals. The dose of insecticides used per pot was calculated from the 120g. as a actual ingredient per 10 a. The number of living larvae was observed at the 20 days later from the inoculation (as shown in Table 1.). 3. As shown in Table 2 and 3, there was highly significance between the chemicals and L.S.D. was 24.22. The best effectiveness was Diazinon granular and 2nd was gamma-dol dust. The organophosphorus emulsion concentrations used in this experiment were less effective than two other insecticides. Although there were some suspicious results according to the day intervals inoculated, the order of effectiveness was Diazinon>gamma-dol>Sumithion>EM>EPN> Cidial as the total moan. 4, As shown in Table 2 and 3, there was no significance between the timing of insecticidal applications, but, m the whole, Diazinon granular was most effective at a given day intervals in this experiment and gamma-dol also was effective at the day Plot inoculated. The proper timing of EPN, EM, and Cidial seemed to be at e day plot inoculated and that of Sumithion at the day plot before inoculation.
The distribution and habitat characteristics of Echinosophora koreensis (Nakai) Nakai were investigated to compile basic data for conservation and restoration. The species Echinosophora koreensis is distributed within fourteen regions of the Korean Province of Gangwon, including Yanggu-gun, Inje-gun, Cheorwon-gun, Chuncheon-si and Hongcheon-gun. Natural habitats were located at altitudes of 192-626 m, with inclinations of $1-45^{\circ}$. One hundred and fifty seven vascular plant taxa were identified from 42 quadrats in 14 habitats. Dominant species among the woody plants, based on importance value, were Pinus densiflora and Quercus dentata in the tree (T1) layer, Quercus variabilis, Pinus densiflora and Quercus mongolica in subtree (T2) layer, and Fraxinus rhynchophylla, Prunus sargentii, Zanthoxylum schinifilium, and Ulmus davidiana var. japonica in the shrub (S) layer. Importance values for members of the herb layer were: Echinosophora koreensis 28.34%; Polygonatum odoratum var. pluriflorum 10.21%; Spodiopogon sibiricus 7.60%; Atractylodes ovata 4.77% and Carex lanceolata 4.13%. The importance values of the last four species were high, so they were at affinity with Echinosophora koreensis in their habitats. Average species diversity was 1.03, and evenness and dominance were found to be 0.82 and 0.16, respectively. The soil types were sandy loam and loam. Average field capacity was 13.28%, and the organic matter and soil pH were 6.70% and 5.77, respectively.
Journal of Korean Society of Occupational and Environmental Hygiene
/
v.31
no.1
/
pp.73-82
/
2021
Objectives: This study aimed to investigate the public cognition and information acquisition route for heavy metals and organic solvents in the general population in order to provide information for the development of public relations materials. Methods: The study was carried out by questionnaire from January to March 2011 by an interview with trained surveyors. There were 700 participants, divided by gender and age. A questionnaire was issued consisting of subjective and objective cognition evaluation items and questions about information acquisition route and preferred information acquisition route for six heavy metals and five organic solvents. Data were expressed as a percentage using the SPSS 23.0 software package. Result: For heavy metals, subjective and objective cognition degrees were higher in the order of lead, mercury, cadmium, and arsenic. They were higher among males than females, and in adults compared to school-age subjects. For organic solvents, both cognition degrees were high in the order of acetone, benzene, and formaldehyde. However, cognition degree by gender and age showed a complex pattern. As a response to information acquisition route, broadcast media had the highest in all ages and genders, followed by word of mouth from neighbors in elementary school children, school education or expert lectures in middle and high school students up to people in their 30s, and print media among those in their 40s to over 60s. There was no difference in the order by gender. As a response to preference for information acquisition route, broadcast media also proved the highest in all ages and genders, followed by school education or professional lectures among those in elementary school and over their 60s, and the internet in other age groups. Females preferred school education or expert lectures and word of mouth from neighbors, while males preferred the internet. In the case of the internet, the ranking was higher for preferred information acquisition route compared with the ranking for information acquisition route. Conclusions: This data on cognition degree, information acquisition route, and preferred information acquisition route according to gender and age can provide basic data for the development of educational and promotional materials for heavy metals and organic solvents exposure management.
The Journal of the Convergence on Culture Technology
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v.8
no.5
/
pp.307-313
/
2022
In Korea, youth participation in economic activities and unemployment appear at the same time, which is a more serious problem, so a study on the labor market movement can be viewed as a study to overcome youth unemployment. The purpose of this study is to examine how labor movement between the employed and the unemployed is progressing through the survey data of the youth panel among the employment panel and to identify the factors affecting the movement path and movement of the employed and the unemployed. In the case of the employed, they possessed professional qualifications, and in the case of unstable occupational status, they attempted to move to a stable position after being employed. In the case of the unemployed, the probability of failing to find a job was higher as they had no job search experience, the longer the job search period, and the less effort they made. The fact that the home environment directly or indirectly influences the movement of the labor market remains unchanged. On the other hand, the higher the educational level, the more stable, and the most stable the metropolitan area. Therefore, more urgently than ever, a plan to revitalize the local labor market through the organic relationship between the government, local governments, local industry, and local universities and balanced regional development should be sought.
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