• Title/Summary/Keyword: 유기유동

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Geochemical and Geophysical Characteristics of Shallow Gases in the Deep Sea Sediments, Southwestern Ulleung Basin (울릉분지 남서부 심해저 퇴적층에 분포하는 천부 가스의 지화학 및 지구물리 특성)

  • 김일수;이영주;유동근;류병재
    • Economic and Environmental Geology
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    • v.36 no.3
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    • pp.149-157
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    • 2003
  • Deep sea core samples were taken in the southwestern part of the Ulleung Basin in order to characterize the properties of shallow gases in the sediment. Amount of shallow gases in the sediments were calculated by head space techniques, and chemical and isotopic compositions of hydrocarbon gases were analyzed. Geochemical analyses were carried out on the gas bearing sediments to find out relationship between natural gas contents and organic characteristics of the sediments. Seismic characteristics of shallow gases in the sediments were also examined in this study. The amount of the hydrocarbon gases in the sediments range from 0.01% to 11.25%. Calculation of volume of gas per volume of wet sediment varies from 0.1 to 82.0 ml HC/L wet sediment. Methane consists 98% of the total hydrocarbon gases except for two samples. Based on the methane content and isotopic composition$(\delta^{13}c)$: -94.31$\textperthousand$~-55.5$\textperthousand$), the hydrocarbon gases from the sediments are generated from bacterial activities of methanogenic microbes. Contents of hydrocarbon gases are variable from site to site. Volume of shallow gases in the sediments shows no apparent trends vs. either characteristics of organic matter or particle sizes of the sediments. Gas concentration is high in the area of seismic anomalies such as blanking zone or chimney structures in the section. Physicochemically the pore water and the formation water systems are saturated with gases in these areas. Concentration of hydrocarbon gases in the sediments in these area shows favorable condition for generation of gas hydrate, as far as the other conditions are satisfied.

Multiscale Modeling and Simulation of Direct Methanol Fuel Cell (직접메탄올 연료전지의 Multiscale 모델링 및 전산모사)

  • Kim, Min-Su;Lee, Young-Hee;Kim, Jung-Hwan;Kim, Hong-Sung;Lim, Tae-Hoon;Moon, Il
    • Membrane Journal
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    • v.20 no.1
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    • pp.29-39
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    • 2010
  • This study focuses on the modeling of DMFC to predict the characteristics and to improve its performance. This modeling requires deep understanding of the design and operating parameters that influence on the cell potential. Furthermore, the knowledge with reference to electrochemistry, transport phenomena and fluid dynamics should be employed for the duration of mathematical description of the given process. Considering the fact that MEA is the nucleus of DMFC, special attention was made to the development of mathematical model of MEA. Multiscale modeling is comprised of process modeling as well as a computational fluid dynamics (CFD) modeling. The CFD packages and process simulation tools are used in simulating the steady-state process. The process simulation tool calculates theelectrochemical kinetics as well as the change of fractions, and at the same time, CFD calculates various balance equations. The integrated simulation with multiscal modeling explains experimental observations of transparent DMFC.

The stillness-motion interface designing of the Web, Based on the e-advertisement concept. (웹 인터페이스의 정.동디자인에 관한 연구 -e광고 컨셉트별 정.동디자인 분석-)

  • 전기순
    • Archives of design research
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    • v.15 no.4
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    • pp.317-326
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    • 2002
  • The Web has taken a strong post as one of the media for advertisement for long time. The Internet has an advantage of an easy access to each of customers; the fractioning of the potential customers; the transcending of the time and space; and the utilizing of the multimedia. As such, the Web as a communication tool has not only all characteristics of the existing media but also the factors such as the sound, motion, and interaction. Therefore the Web designing should be much more flexible and open than any other medias. Nevertheless, most of the Webs being created currently appear to be simply perfunctory and functional. This is because a methodological aspect has not been rooted firmly as the Web design industry has been developed too rapidly, driven by the explosive demand. Therefore, this study is designed to demonstrate the approaching method to the Web-interface designing as an alternative for such methodological aspect. In other words, it is the very stillness-motion interface designing of the Web, based on the e-advertisement concept. The Web as one of the media for advertisement gives the heaviest weight to the users emotional aspects than any other media do. Therefore, it is very important to get the differentiation and impact in the Web-interface designing through the users emotional aspects.

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Effect of the redox flow battery and electrode characteristics according to the heat treatment temperature of a carbon felt (탄소펠트의 열처리 온도에 따른 레독스흐름전지와 전극 특성에 미치는 영향)

  • Yoo, Hyosung;You, Hyunjin;Yu, Kihyun;Kang, Junyoung;Park, Hongsik;Choi, Woonghwi;Yoo, Dong Jin
    • Journal of Energy Engineering
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    • v.24 no.3
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    • pp.89-95
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    • 2015
  • Carbon felts manufactured by (Co)CNF were subjected to heat treatment under different temperatures to use for the electrode of a redox-flow battery. BET and weight loss were tested to investigate the physical properties of the carbon felt according to the heat treatment conditions. SEM and XPS were also analyzed to characterize their surface area. In addition, electrical resistance, CV (cyclic voltammetry) and RFB charge on the electrode properties were examined in accordance with the heat treatment conditions with the discharge performance. The changes of physical properties on the carbon felt surface was confirmed via SEM and BET analysis, The most addition of oxygen functional groups on the carbon felt surface was obtained when one hour heat treatment at $550^{\circ}C$ and it was confirmed by XPS analysis. After resulting the CV tests, the active area of the electrode was the largest at $550^{\circ}C$ heat treatment. The heat treatment experiment of vanadium redox flow battery using the carbon felts were tested at $400^{\circ}C$, $500^{\circ}C$ and $550^{\circ}C$. As a result, the charge-discharge energy efficiency of the heat treatment electrode was 72.9% and 79.8%, at $400^{\circ}C$ and $500^{\circ}C$, respectively. The efficiency of the heat treatment electrode at $550^{\circ}C$ was the best as 79.8% at $550^{\circ}C$.

Identification and Removal of Pigments in Blood-colored Grooves of Long Sword, Admiral Yi Sun-sin (Treasure No. 326) (보물 제326호 이순신 장검 혈조 내 안료의 규명 및 제거)

  • Kwon, Hyuk Nam;Youn, Hye Seong;Ryu, Dong Wan;Lee, Jeong Won;Lee, Jang Jon;Han, Min Soo
    • Journal of Conservation Science
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    • v.31 no.4
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    • pp.499-506
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    • 2015
  • The artifacts of Admiral Yi Sun-sin (Treasure No.326) consist of six items with two long swords, a jade decoration, a belt and two peach-shaped cups. In commemoration of the opening of Chungmugong Yi sun-sin Memorial Museum (April 28, 2011), there were conservation treatments for those artifacts at the beginning of 2011. At that time, from the result of non-destructive surface analysis on pigments in blood-colored grooves of the two long swords, it was presumed to be synthetic resin paints. This study shows the accurate identification on pigments which was presumed as synthetic resin paints and its removal. To identify pigments in blood-colored grooves, the optical microscope, scanning electron microscope, Micro-XRF, XRD and FT-IR were used for the analysis. The results turned out that the thickness of $10{\sim}90{\mu}m$ in a single layer was measured. And major components containing Pb and Cr and lead chromium molybdenum oxide were identified and to identify components of adhesives from the analysis by FT-IR, it turned out to be alkyd resin, which can be presumed that they were recently colored with synthetic paints. The synthetic paints easily react with most of the organic solvents. And it is so easy to handle without the effect on metal that it was removed with acetone. While removing synthetic paints, all of paints on it were collected for identifying whether there is traditional pigment but nothing was identified.

Studies on the Processing and Utilization of Seaweeds - Studies on the Processing of Sea Mustard Jam- (해조류의 가공 및 이용에 관한 연구 -미역쨈의 제조에 관한 연구-)

  • CHA Yong-Jun;LEE Eung-Ho;PARK Du-Cheon
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.21 no.1
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    • pp.42-49
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    • 1988
  • In order to utilize sea mustard, Undaria pinnatifida, effectively. sea mustard jam was prepared by use of physical properties of polysaccharides, mainly alginic acid and then its chemical composition, nutritive qualifies and the stability of pigments were examined. Suitable processing condition for sea mustard jam was as fellows : as the first stage, fresh sea mustard was scalded for 20 sec at $85^{\circ}C$ and dried sea mustard was dipped for 20 min in cold water for rehydration, then both sea mustards were treated by draining and chopping. Next, after adding 4 fold of $0.5\%\;K_2HPO_4$ solution to weight of chopped sea mustards, the mixed solutions were agitated for 15 min at $95^{\circ}C$, and gelated sea mustards were filterated by pressing. Flow characteristics of those sea mustard jam were regarded mixed type having pseudoplastic type and yield stress. Judging from sensory evaluation, adding $0.375\%$ of saccharin, $2\%$ of sorbitol, $0.25\%$ of citric acid and $0.5\%$ of powder of roasted soybean to sea mustard jam were suitable for enhancing taste and flavor of product. Chemical composition of products were scarcely changed throughtout processing. Jam processed by fresh sea mustard was better than dried one in contents of chlorophyll and total carotenoid pigments. In fatty acid composition, polyenoic acids of $C_{18:3},\;C_{20:4},\;C_{20:5},\;C_{22:6}$ were held high contents as known to have lowering function of cholesterol contents. It was presumed that dominant contents in free amino acids such as lysine, alanine, glutamic acid and organic acids such as citric acid, oxalic acid, $\alpha-ketoglutaric$ acid, lactic acid and succinic acid held important role for the flavor of sea mustard jam.

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Effect of Dietary Yeast (Saccharomyces exiguus) on Growth Performance, Cecal Microflora and Fecal Ammonia Gas in Broiler Chickens (효모(Saccharomyces exiguus)의 급여가 육계 생산성, 맹장내 미생물 및 분내 암모니아 가스 발생에 미치는 영향)

  • Kim, D.W.;Jang, B.G.;Kim, J.H.;Yu, D.J.;Kang, K.H.;Kang, H.G.;Na, J.C.;Kim, S.H.;Lee, D.S.;Suh, O.S.
    • Korean Journal of Poultry Science
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    • v.34 no.2
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    • pp.137-141
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    • 2007
  • This experiment was conducted to investigate the effects of dietary yeast (Saccharomyces exguus) supplementation on growth performance, cecal microflora and fecal ammonia gas in broiler chicks. A total of two hundred seventy, 1-d-old male broiler chicks (Ross strain) were randomly allotted to nine pens (replicates), 30 birds per pen. There were three dietary treatments with three replicates. The treatments were control (virginiamycin 0.05%+salinomycin 0.03%), Saccharomyces exguus 0.5 and 1.0%. Total body weight gain were significantly higher in Saccharomyces exguus1 1.0% treatment than the control (P<0.05). Although not significant, the yeast supplementation tended to improve the feed conversion ratio. No significant differences were observed on the numbers of cecal E. coli, Salmonella and Lactobacillus in yeast treatments compared to those of control. The production of fecal ammonia gas was significantly lower in yeast treatments than the control (P<0.05). The concentrations of fecal short chain fatty acids and volatile organic compounds were not different among the groups. These results suggest the possibility that yeast (Saccharomyces exguus) could be used as the alternative of antibiotic growth promoters by improving the performance of broiler chicks. In addition, dietary yeast could improve the environment of broiler houses by reducing fecal ammonia production.

The Characterizations of Tape Casting for Low Temperature Sintered Microwave Ceramics Composite (저온소성 마이크로파 유전체 세라믹스 복합체의 Tape Casting특성)

  • Lee, Woo-Suk;Kim, Chang-Hwan;Ha, Mun-Su;Jeong, Soon-Jong;Song, Jae-Sung;Ryu, Bong-Ki
    • Journal of the Korean Ceramic Society
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    • v.42 no.2 s.273
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    • pp.132-139
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    • 2005
  • Sintering behavior of $BaO-Nd_{2}O_3-TiO_2$ with a Pb-based glassceramics frit were investigated in order to understand an effect of glassceramics as a low temperature sintering agent on dielectric ceramics. A green sheet form was fabricated through tape casting method with the glassceramic fut added $BaO-Nd_{2}O_3-TiO_2$. The dispersion properties, rheological properties and final density of dielectric composit slurry as a function of amount and composition of organic additives was examined. The dispersants' addition was effective in controlling dispersion of the ceramics in solution. The addition of excessive dispersant showed adverse effect on dispersion. The prepared slurries, containing ceramic : powders, glass-ceramics and various kinds of organic viechles, exhibited typical shear thinning behavior. The best properties of tape casting appeared powder to solvent ratio 65 : 35 and amount of the binder 6 wt$\%$ and plasticizer 3 wt$\%$. The viscosity of the slurry was 677 cps and green/sintered density in the tape was $3.3 g/cm^3,\;5.56 g/cm^3$ respectively.

Research on Managing Incineration Facility according to Prediction of Change in Amount of Waste (폐기물 발생량 변화 예측에 따른 소각시설 운영에 관한 연구)

  • Ha, Sang An
    • Journal of the Korea Organic Resources Recycling Association
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    • v.20 no.1
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    • pp.23-30
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    • 2012
  • In the state that re-evaluation of calculating optimum amount of incineration in the future is needed, as considering the amount of waste, increase of heat value and change in floating population in each area in city B, the purpose of this research was to predict optimum available capacity in incineration plant and to study alternatives for the amount of disposal in each incineration plant based on the available capacity that was predicted. As a result of predicting the change in population based on progress of population in city B in the past, it is expected that an overall population is decreasing, but in some areas, population is concentrated due to increased apartment complexes, showing similar figures as the present. Moreover, when predicting the amount of waste through forecasting population, it is considered that the amount of waste by decreased population is also decreasing. However, the amount of combustible component among a total amount of waste is expected to increase, so it is predicted that the amount of incineration and combustible component will be reasonable except D incineration plant, Therefore, D incinerating plant showed 72.7% of rate of utilization of incineration facility compared to 59.1% of national rate. However, if shortfall of waste in the future can be used wisely in other areas, the use of renewable energy using burner useless heat can be maximized.

A Numerical Simulation of Three- Dimensional Nonlinear Free surface Flows (3차원 비선형 자유표면 유동의 수치해석)

  • Chang-Gu Kang;In-Young Gong
    • Journal of the Society of Naval Architects of Korea
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    • v.28 no.1
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    • pp.38-52
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    • 1991
  • In this paper, a semi-Lagrangian method is used to solve the nonlinear hydrodynamics of a three-dimensional body beneath the free surface in the time domain. The boundary value problem is solved by using the boundary integral method. The geometries of the body and the free surface are represented by the curved panels. The surfaces are discretized into the small surface elements using a bi-cubic B-spline algorithm. The boundary values of $\phi$ and $\frac{\partial{\phi}}{\partial{n}}$ are assumed to be bilinear on the subdivided surface. The singular part proportional to $\frac{1}{R}$ are subtracted off and are integrated analytically in the calculation of the induced potential by singularities. The far field flow away from the body is represented by a dipole at the origin of the coordinate system. The Runge-Kutta 4-th order algorithm is employed in the time stepping scheme. The three-dimensional form of the integral equation and the boundary conditions for the time derivative of the potential Is derived. By using these formulas, the free surface shape and the equations of motion are calculated simultaneously. The free surface shape and fille forces acting on a body oscillating sinusoidally with large amplitude are calculated and compared with published results. Nonlinear effects on a body near the free surface are investigated.

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