• Title/Summary/Keyword: 유기물함량

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농약류 (1,2-dichlorobenzene, hexachlorocyclohexane)의 토양 흡착 특성 규명

  • 정현정;이민희;도원홍
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.338-341
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    • 2003
  • 유기염소계 농약 중 대표적인 살충제 $\delta$-BHC(hexachlorocyclohexane)와 1, 2-DCB (1, 2-dichlorobenzene)에 대한 논, 밭 토양 및 풍화 토에 흡착 배치실험을 통하여 토양 특성과 유기오염물간의 흡착 관계를 규명하였다. 13개의 토양시료에 대하여 pH, CEC, 유기물 함량, 비표면적, 입도분석, 원소조성분석을 통하여 토양의 물리ㆍ화학적 특징이 토양 흡착에 미치는 영향을 규명하고자 하였다. 유기염소계 농약의 흡착량을 Freundlich isotherm으로 나타내어 흡착분배계수(K$_{d}$)를 산출하였다. $\delta$-BHC는 유기물 함량이 높은 soil-4$_{d}$에서 가장 높은 $K_{d}$ 값을 보였으며, 1,2-DCB의 경우 CEC, 비표면적이 가장 낮은 soil-5에서 낮은 $K_{d}$ 값을 보여 토양 내 유기물 함량과 비표면적이 유기오염물 흡착량에 중요한 요소로 작용함을 알 수 있었다.

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토양 특성에 따른 Trichloroethylene (TCE:) 흡착능 비교

  • 정현정;이민희
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.362-365
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    • 2002
  • 토양의 물리/화학적 특성에 따른 토양의 유기오염물 흡착능 변화를 규명하기 위하여, 토양 내 clay 함량 및 유기물 함량변화, 수용액 내 TCE 농도변화에 따른 TCE 의 토양내 흡착량 변화를 측정하였다. 수용액의 pH와 실내온도는 일정하게 유지시켰으며 clay는 표면적이 다른 Ca-montmorillonite, Na-montmorillonite, kaolin을 이용하였고, 유기물질로는 활성탄을 사용하였다. 일정한 토양성분과 실제토양에 대해 수용액 내 TCE의 농도를 변화시켜 농도변화에 따른 흡착량 변화를 측정하였다. 실험결과 유기물과 점토함량의 증가에 따라 흡착량은 모두 증가하였으나 활성탄에 의한 TCE 흡착량이 점토에 비해 매우 높았으므로 유기물에 의한 TCE 흡착영향이 점토에 의한 흡착 영향보다 큰 것으로 나타났다. TCE 농도변화에 따른 흡착결과는 실제토양과 모사토양에서 모두 농도가 증가함에 따라 흡착 증가율이 증가하다가 감소하는 Langmuir isotherm 형태를 보여 주었다.

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Soil Chemical Properties of Peach Orchard and Nutrient Content of Peach Leaves In Gyeongbuk Area (경북지역 복숭아 과수원 토양 화학성 및 복숭아 엽의 양분함량 조사)

  • Seo, Young-Jin;Kim, Jong-Su;Kim, Jae-Kyu;Cho, Jae-Uk;Kwon, Tae-Young;Lee, Jae-Seog
    • Korean Journal of Soil Science and Fertilizer
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    • v.35 no.3
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    • pp.175-184
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    • 2002
  • Soil chemical parameters of peach orchards and the concentration of nutrients in peach leaves were investigated. Results of soil analysis showed that pH value and content of exchangeable calcium was quite low, required to adjust soil acidity in many investigated soils. Nitrogen and phosphorous contents in leaves were founded to be excessive comparing to RDA's optimal levels(N $29.3{\sim}35.9g\;kg^{-1}$, P $1.7{\sim}2.2g\;kg^{-1}$), while calcium contents were lower than optimal levels($11.2{\sim}21.0g\;kg^{-1}$) in many sites and Potassium content was higher in peach cultivars than nectarine cultivars. Correlation analysis revealed that organic matter contents in subsoils and exchangeable calcium content in soils(top and subsoil) were increased with cultivation year, but available phosphate contents in subsoils were decreased. Organic matter and exchangeable magnesium contents in top soils were positively correlated with potassium and magnesium contents in leaves, whereas were negatively correlated with calcium contents in leaves, impling antagonistic absorption of calcium against potassium and magnesium. The findings indicated that most of soils ought to managed to adjust soil acidity and application amount of nitrogen, phosphorous fertilizer and compost should be controlled properly.

The Influence of Environmental Variables on Macrobenthic Communities after Dike Construction in Asan Bay, Korea (방조제 건설이후 아산만 대형저서동물 군집 구조에 영향을 주는 환경요인)

  • Yu, Ok-Hwan;Lee, Hyung-Gon;Lee, Jae-Hac
    • Korean Journal of Environmental Biology
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    • v.29 no.4
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    • pp.326-344
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    • 2011
  • Although anthropogenic disturbance of 20 years duration affects benthic habitats, few studies have examined its effects on the macrobenthic communities of a bay. The aim of this study was to determine the influence of environmental variables on the macrobenthic communities after the construction of the Hwaong dike. Macrobenthos were collected at 22 sites using a Smith McIntyre grab (0.1 $m^2$) in August 2007 and February 2008. Total organic content was very low around the Hwaong dike. Sediment grain size increased from the Hwaong dike to the outer bay. In total, 317 species of macrobenthic fauna were collected and the mean density was 1,155 ind. $m^{-2}$, both of which were higher than the results of previous studies. The dominant species, $Hetermastus$ $filiformis$, known to be a potential pollution indicator, was more abundant near the Hwaong dike. Conversely, species sensitive to organic pollution, such as the polychaete $Ampharete$ $arctica$ and the ophiuroid $Amphioplus$ $squamata$, exhibited higher mean densities in areas distant from the dike. A cluster analysis indicated that the macrobenthic community was divided into two distinct groups: group I near the dike and group II in the outer bay, which were affected by sediment grain size and total organic content. This study suggests that variations in sediment grain size and organic content after dike construction are important factors controlling the macrobenthic community in Asan Bay.

Antioxidant Enzyme Activities and Soil Properties of Healthy and Declining Abies koreana (Wils.) in Mt. Halla (한라산 구상나무 건전개체와 쇠약개체의 항산화효소활성 및 토양특성)

  • Lim, Jong-Hwan;Woo, Su-Young;Kwon, Mi Jeong;Kim, Young Kul
    • Journal of Korean Society of Forest Science
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    • v.96 no.1
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    • pp.14-20
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    • 2007
  • In order to examine the differences in antioxidant enzyme activities which represent defence mechanism to stressful environments, and soil properties between healthy and declining (or unhealthy) trees, we selected three sites, Witseorum, Youngsil and Sungpanak (Jindallebat). Antioxidant enzymes including Ascorbate peroxidase (APX) and Glutathione Reductase (GR), forest soil properties including soil texture, soil pH, organic matter, total nitrogen, available phosphate, cation exchange capacity, exchangeable cation content and nutrient contents in leaves of Abies koreana (Korean fir) trees were analyzed. There were no significant differences between healthy and declining trees in GR activity. However, seasonal difference in antioxidant enzyme activity was observed. GR activity was lower in June and August than that of September. Soil chemical and physical properties of each site showed a tendency that organic content, total nitrogen content, available phosphorus, cation exchange capacity and cation content were lower at the site of declining trees than the site of healthy trees.

Adsorption Coefficients of Eight Pesticides for Citrus Orchard Soils with Different Soil Organic Matter (유기물함량이 다른 감귤원 토양에서 8 개 농약의 흡착상수)

  • Oh, Sang-Sil;Hyun, Hae-Nam;Moon, Doo-Khil
    • Korean Journal of Environmental Agriculture
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    • v.19 no.1
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    • pp.6-12
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    • 2000
  • This study was carried out to determine the adsorption characteristics of eight pesticides on thirty citrus orchard soil so soil samples were taken from nineteen soil series containing different fractions of organic carbon(Foc). The adsorption characteristics for eight pesticides fitted to Freundlich isotherms. The adsorption isotherms showed C-type for alachlor and chlorpyrifos, L-type for linuron and diniconazole. and S, C, and L-types for metribuzin, metolachlor, and alachlor with increasing Foc, respectively. In particular, the adsorption of chlorothalonil showed S, C, L, and H-types with increasing Foc. Distribution coefficient(Kd) values of metribuzin, metolachlor, and alachlor were below $10\;Lkg^{-1}$ and increased linearly with Foc. Kd values of linuron, diuron and chlorothalonil increased exponentially to 60, 200, and $400\;Lkg^{-1}$, respectively and those of diniconazole and chlorpyrifos increased logarithmically. Kf value. Freundlich adsorption coefficiient, increased with Kd in the same manner with Kd. Furthermore, the linearity of Kf value was larger than that of Kd value.

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Numerical Approach for Evaluation of Forest Soil Fertility (수치적(數値的) 접근방법(接近方法)에 의(依)한 산림토양(山林土壤)의 비옥도(肥沃度) 평가(評價))

  • Ma, Sang Kyu
    • Journal of Korean Society of Forest Science
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    • v.35 no.1
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    • pp.1-8
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    • 1977
  • Forest soil fertility was evaluated through the approach of numerical method. In this study, the soil chemical properties analyzed for 35 different soil series as table 2 were cited in numerical analysis. Minimum contents of essential nutrients in the surface soil for a satisfactory growth of tree in the plantation were evaluated by comparing with Wild's standard as table 1. Demanding level of fertilization were evaluated by using the formula 1 as table 5. Similar relation of soil chemical properties between soil series were calculated through formula 2, and then classified into 5 groups in soil chemical properties. 1. General chemical properties of surface soil in case of 35 soil series. About 40 percent of 35 different soil series are less than 2 percent in organic matter, 10 ppm in available phosphorus, 1.25m.e/l00g in exchangeable calcium and 0.5m.e/l00g in exchangeable magnesium. Generally, shortage of exchangeable potash are not found. CEC less than 10m.e/l00g are in two thirds and strong acid soil less than PH 5.5 are in about four fifths. 2. Soil series requested or not the fertilization are indirectly evaluated from the formula 1 using the relative figure of chemical components of CEC, OM and MgO. Through this analysis, 8 different soil series have very poor quality in soil chemical capacity so that demands highly the fertilization. On the other hand, other 13 different soil series group have not been thought to need the fertilization according to chemical guality. 3. By the results comparing the similarity of chemical properties of forest soil, it is thought to be suitable that the forest soil fertility are divided into 5 groups as follows: 1. Low CEC soil 1-1 Low organic matter soil less than 2 percent 1-2 Medium organic matter soil less than 4 percent 2. High CEC and organic matter soil 2-1 Low magnesium soil 2-2 High magnesium soil 3. High magnesium and calcium soil as lime stone.

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Development of Soil Organic Matter Measuring System (토양 유기물 센서 개발)

  • 성제훈;서상룡;정인규;이충근;이용범
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2003.07a
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    • pp.456-461
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    • 2003
  • 농작물 재배에서 토양 중의 양분을 일정 수준으로 유지하는 것은 매우 중요한 기술이다. 일반적으로 전년에 수확이후의 토양에 대해 토양중의 이화석 성분을 분석하여 일정한 시비 기준에 의해 시비처방전을 만들고 이에 따라 비배작업을 수행한다. 이러한 목적을 위해서는 토양 이화학성을 자주 측정해야 하는데, 기존의 토양유기물, 수분 및 전질소와 같은 이화학 성분 측정방법은 조작에 전문성이 필요하고 현장에서 결과 값을 알 수 없는 단점이 있었다 이러한 단점을 해결하고, 정밀농업형 기계에 맞는 실시간 처방을 위해서는 비접촉형 센서의 개발이 요구된다. 비접촉형 센서 개발을 위해 주로 사용되는 방법이 근적외선 반사를 분석하는 방법이다. 즉, 측정하고자 하는 토양에 전자파 에너지가 투입되고 반사될 때 생기는 에너지 차이를 수량화하여 토양 유기물 함량과의 상관관계로 토양 내 유기물 함량을 측정한다. 정밀농업형 센서는 일반 계측용 센서와 달리, 측정값을 몇 개의 그룹으로 구별하게 된다. 측정값이 어떠한 그룹에 속해 있는가에 따라 전문가 시스템에 의한 농작업 의사결정이 내려지고, 그 결정에 따라 변량형 농작업이 수행되게 된다. (중략)

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Effect of soil organic matter content on plant uptake factor of ginseng for endosulfan (토양유기물 함량이 인삼근의 endosulfan 흡수이행에 미치는 영향)

  • Oh, Kyeong-Yeol;Choi, Geun-Hyoung;Bae, Ji-Yeon;Lee, Deuk-Yeong;Lee, Sung-Woo;Kim, Jin-Hyo
    • Journal of Applied Biological Chemistry
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    • v.63 no.4
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    • pp.401-406
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    • 2020
  • The plant uptake of endosulfan, a new persistent organic pollutants from soil environment was investigated on ginseng through the field survey in Korea. The endosulfan residues in soil for this survey were ranged on 0.013-0.136 mg kg-1. The plant uptake factor (PUF) for endosulfan in ginseng was 0.243-1.708 and the highest PUF was found on 3-year-old ginseng. The PUF for endosulfan decreased in the longer cultivation period and it might be caused by the dilution effect of ginseng growth. In addition, the soil organic matter (SOM) content affected on the PUF negatively and Pearson correlation coefficient (r) between SOM and PUF was -0.7812 (p <0.05). Thus, higher SOM would positively affect to reduce the endosulfan residue in ginseng root.

낙동강 하구사주에서 갈대서식지역의 환경특성

  • Seong, Gi-Jun;Jang, Hye-Hyeon;Gwon, Hye-Ok;Jeong, Yong-Hyeon;Lee, Seok-Mo;Park, So-Yeong;Yeo, Un-Sang
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2007.05a
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    • pp.457-459
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    • 2007
  • 낙동강 하구의 맹금머리등, 백합등, 도요등의 세 개의 사주의 갈대분포와 관련된 토양 및 수질환경요인을 조사하였다. 대상지역의 갈대우점지역과 비우점지역에 대하여 토양 유기물 함량, 양이온 교환능력과 같은 토양 특성을 조사한 결과 이들 특성이 사주형성시기와 갈대의 분포유무와 관계있는 것으로 조사되었다. 유기물 함량은 갈대서식지역이 더 높게 나타났는데 이는 갈대의 성장으로 인한 토양의 유기물 축적 결과로 하구의 갈대가 사주의 토양환경에 영향을 미치고 있는 것으로 사료된다. 토양내 질소와 인 농도 역시 갈대우점지역에서 비우점지역에 비해 높게 나타났는데, 이는 토양 내 영양염류가 많은 곳을 갈대가 선호함과 동시에 갈대에 함유된 질소와 인성분이 토양에 집적된 두 가지 경우를 모두 고려할 수 있다. 수질조사 결과 현재 해수의 수질이 직접적으로 갈대의 분포에 영향을 주는 것은 아닌 것으로 나타났다. 하지만 토양양이온능력과 유기물 함량과 같은 토양특성 조사와 함께 고려하면 퇴적으로 인한 사주형성 및 토양유실과 갈대분포와 관련이 이는 사주에 형성된 식생이 사주의 영양물질 순환에 어떻게 영향을 미치는 가를 잘 설명해 주는 예라 할 수 있다.

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