• Title/Summary/Keyword: 용해율

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Soluble Characteristics of Deer Young Antler, Deer antler, Oystershell, Crabshell and Eggshell to Organic Acid (녹용.녹각.굴껍질.게껍질.달걀껍질의 유기산에 대한 용해 특성)

  • Ann, Yong-Geun
    • The Korean Journal of Food And Nutrition
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    • v.23 no.1
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    • pp.45-51
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    • 2010
  • The 2%, 3% of deer young antler, deer antler, oystershell, crabshell, eggshell were add into the 5%, 10%, 15% solution of glacial acetic acid and vinegar and after incubating it for 4 days at $30^{\circ}C$ respectively, solubility was analyzed. The result shows the difference was minute between glacial acetic acid and vinegar. In the 2% content of deer young antler, solubility was 42~47%, in the 3% content of it, solubility was 41~47%, with the acid concentration becoming higher, solubility increased slightly. In the 2% content of deer antler, solubility was 59~63%, in the 15% content of acid, solubility rather decreased. In the 2% content of oystershell, solubility was 85~96%, in the 3% content, solubility was 95~98%, in the 15% of acid density, it decreased. In the 2% content of crabshell, solubility was 79~88%, in the 3% content, solubility was 81~95%, and in case that acid density was high, solubility increased rather slightly. In the 2% content of eggshell, solubility was 84~96%, in the 3% content, solubility was 84~93%. When young deer antler and deer antler were heated for two hours at $100^{\circ}C$, solubility increased 19~24%, and in the case of crabshell, 10~11% increased. The above result and condition, and the result of pH and acidity don't have much influence on solubility. Thus, the 5% of acidity was enough to melt the 3% of sample. Highest were glacial acetic acid and vinegar in solubility to the various organic acid, and wax gourd vinegar melted the 85% of oystershell, the 78% of crabshell, the 28% of the deer young antler, and in the precipitation was made. Citric acid melted the 57% of deer antler, but it was precipitated with all other samples. Ascorbic acid melted the 92% of eggshell, and did the 37~54% of other samples.

A Study on the Dissolution of Aluminum Hydroxide with Mineral and Organic Acid (Aluminum Hydroxide의 유무기산(有無機酸)에 의한 용해특성(溶解特性) 연구(硏究))

  • Lee, Hwa-Young
    • Resources Recycling
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    • v.18 no.2
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    • pp.56-61
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    • 2009
  • The dissolution of domestic aluminum hydroxide of 99.7% purity has been performed with mineral and organic acid prior to the synthesis of aluminum compounds from aluminum solution. Mean particle size of aluminum hydroxide used in the work was $14.4{\mu}m$, $22.9{\mu}m$ and $62.3{\mu}m$, respectively and the effect of reaction temperature, concentration of acid and reaction time on the dissolution of aluminum hydroxide has been examined. As a result, the dissolution of aluminum hydroxide was increased with the concentration of HCl and more than 70% dissolution was obtained with 5 mole/l HCl at $70^{\circ}C$ for reaction time of 4 hr. As far as the dissolution of aluminum hydroxide with sulfuric acid was concerned, it was found that the optimum concentration of sulfuric acid was about 6 mole/l for the effective dissolution of aluminum hydroxide. When oxalic acid was used for the dissolution of aluminum hydroxide, nearly complete dissolution could be obtained by the dissolution for 16 hr with 1.0 mole/l oxalic acid at $90^{\circ}C$.

Determination of Forward Dissolution Rate of Glass by a Single-Pass Flow-Through Test (Single-Pass Flow-Through Test방법에 의한 유리의 정용해율 측정)

  • Kim Seung-Soo;Chun Kwan-Sik;Choi Jong-Won;Kim Sung-Ki;Hahn Pil-Soo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.3 no.4
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    • pp.335-340
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    • 2005
  • The forward dissolution rate of a borosilicate waste glass was determined as an interlaboratory study(ILS) testing program for the evaluation of precision in the measurement of the dissolution rate or a waste glass using a single-pass flow-through(SPFT) test, whose conducting practice has been written for standardization through American Society for Testing and Materials (ASTM). A simulated low-activity waste glass powder with a size of 100/200 mesh was dissolved by lithium buffer solution (pH=10) at 70? under Ar atmosphere. By plotting the dissolution rates as a function of silicon and boron concentration in eluate, the forward dissolution rate of the glass was obtained as about $2.7\times10^{-5}g{\cdot}m{\cdot}s^{-1}$ in our laboratory.

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Effect of Hydraulic Pressure on Bubble Dissolution Rate of Ejector Type Microbubble Generator (수압이 자흡식 마이크로버블 발생장치의 산소 용해율에 미치는 영향)

  • Kim, Hyun-Sik;Lim, Ji-Young;Park, Soo-Young;Kim, Jin-Han
    • Journal of the Korea Organic Resources Recycling Association
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    • v.25 no.2
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    • pp.27-31
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    • 2017
  • This study was performed to estimate bubble dissolution rate by change of hydraulic pressure according to increase of water depth. Experimental results showed that airflow rate was decreased by increase of hydraulic pressure. Because the force which acts on outlet of nozzle was increased by increase of hydraulic pressure. Mass-transfer coefficient decreased with decreasing airflow rate and increasing effective volume due to increase of hydraulic pressure as water depth increased. On the contrary, as the water depth increased, the bubble dissolution rate was increased because longer residence time of microbubble which was generated by ejector type microbubble generator. However it was thought that if water depth for capacity of ejector type microbubble generator is excessively increasing, bubble dissolution rate would be reduced due to low airflow rate and mass-transfer coefficient. Therefore, it is importance to consider the water depth when operating ejector type microbubble generator.

$Co{^2+}$ 이온으로 오염된 토양에 대한 EDTA 존재 하에서 pH변화에 따른 탈착반응 연구

  • 권회삼;원휘준;안병길;김계남;이병직;오원진;이계호
    • Proceedings of the Korean Nuclear Society Conference
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    • 1998.05b
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    • pp.808-813
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    • 1998
  • EDTA 의 농도 및 온도가 일정한 조건에서 수용액의 pH 를 변화시켜 가며, 토양으로부터 Co$^2$$^{+}$ 이온의 탈착특성을 살펴보았다. 실험범위에서, pH 4 일 때 $CO_2$$^{+}$ 이온의 탈착율이 가장 양호하였으며, pH 가 상승함에 따라 탈착율이 감소되는 것으로 나타났다. 또한, 반응중 철 성분이 용해되어 나오는데 이는 반응 초기 수소이온에 의한 용해와 반응중 탈착된 Co$^2$$^{+}$ 이온에 의한 용해로 설명하였다.

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Effect of Solution Temperature and Bath Concentration on the Kinetics with Dissolution Reaction of Zinc-Ferrite (Zinc-ferrite의 용해 속도론에 미치는 황산 용액의 온도와 농도의 영향)

  • Oh Iee-Sik;Kim Chun-Jo
    • Resources Recycling
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    • v.12 no.4
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    • pp.30-37
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    • 2003
  • A kinetics study on the dissolution reaction of zinc-ferrite has been made with aqueous sulfuric acid in various temperature and concentration. Fraction reacted(R) and apparent rate constant(K) increased with increasing temperature and concentration of sulfuric acid solution. The rate of dissolution is shown by $1-(1-K)^{1/3}=Kt$ for the initial stage of the reaction in aqueous sulfuric acid, where K is apparent rate constant, R is fraction reacted and t is reaction time, respectively. Activation energy associated with reaction was determined to be 16.3 kcal/mole. The dissolution of zinc-ferrite in sulfuric acid solution is dissolved by sto-ichiometric composition, but Fe and Zn did not dissolved, respectively.

A Study of the Metal Recovery from the Aluminium Scrap (Al 스크랩으로부터 금속회수에 관한 연구)

  • 김준수;임병모;윤의박
    • Resources Recycling
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    • v.4 no.1
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    • pp.25-30
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    • 1995
  • In the preparatIon of reclaimed aluminium lllgot from alumimum scrap, the aluminium recovery was studied a as a function of the preliminary treatment of samples, addition of flux and melting atmosphere. AI dross is produced by an oxidation reaction at the surface of liquid metal. The recovery of AI metal increases u up to maximum 95% by adding salt up to 7%, The recovery of AI metal in the compacted chip bale without oil removal mcrease about 14% compared io non-compacted chip. In the case of the AI seed melting process, the recovery of Al metal of the crushed and compacted chip hale is 97%, In meltmg of alumimum scrap under the atmosphere of carbon and nitrogen gas, the recovery of AI metal increase, but it is decreased when the mixture of salt and carbon powder is added excessively.

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Effect of Phytate on the Solubility and Digestibility of Rapeseed Protein Isolate (분리 유채단백의 용해도와 소화율에 미치는 Phytate의 영향)

  • Cho, Hee-Kyung;Yoon, Jae-Young;Lee, Su-Rae
    • Korean Journal of Food Science and Technology
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    • v.24 no.3
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    • pp.279-283
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    • 1992
  • This study was undertaken to investigate the effects of added phytate and pH on the solubility and in vitro digestibility of low-phytate rapeseed protein isolate. Phytate content of low-phytate rapeseed protein isolate was 1.5%, as a result of 66% removal from defatted rapeseed flour and the protein: phytate ratio was 58:1. Solubility of rapeseed protein isolate at pH 2.0 and pH 11.5 was much higher than near the isoelectric point, pH 5.0. It's solubility was lowered by adding an increased amount of phytate especially at pH 2.0. The inhibitory effect of phytate toward pepsin digestibility of rapeseed protein isolate decreased by the increasing amount of phytate added. It is suggested that the production of low-phytate rapeseed protein isolate is necessary to improve the functionality and nutritional value in order to utilize it as food material.

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The Effect of Pre-treatment on the Anaerobic Digestion of waste Activated Sludge (하수슬러지의 혐기적 소화효율 향상을 위한 전처리 효과)

  • Kang, Chang-Min;Kim, Bong-Keun;Kim, In-Su;Kim, Byung-Tae
    • Journal of the Korea Organic Resources Recycling Association
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    • v.9 no.1
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    • pp.90-98
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    • 2001
  • The slow degradation rate of sewage sludge in anaerobic digesters is due to the rate limiting step of sludge hydrolysis. Therefore, the pre-treatment process had been carried out using acidic(pH 1.5, 3, 4, 5) and alkaline(pH9, 10, 13), thermal(50, 100, 150, $200^{\circ}C$) and ultrasonic treatment(400W, 20kHz, 15, 20, 25, 30, 35, 40, 50, 60min). In the best conditions of each treatment, the SCOD ratio(%) of treated/untreared samples were increased 102% in acid(pH5), 986% in alkali(pH13), 959% in thermal($200^{\circ}C$) and 1123% in ultrasonic(35min) treatment. As the result, the ultrasonic treatment was most effective, followed by alkali, thermal, acidic treatment. In the effects of total gas productivity, the thermal($200^{\circ}C$) pretreatment was the highest, followed by thermal($150^{\circ}C$), ultrasonic(90min), alkaline(pH9) and ultrasonic(50min).

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