• Journal of the Korean institute of surface engineering
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• v.31 no.2
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• pp.101-108
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• 1998

The effect of oxidation-reduction heating conditions on coating adherence of hot-dip galvanized steel containing silicon has beeninvestigated. The presence of a stbke sillicon oxide formed on the steel surface has been shown to be very detrimenal to proper wetting by liquid zinc. When the steel has more than the critical sillicon content neeled to from a stable external oxide, the use of oxidation-reduction method has been found successful in obtaining a good quality, coated product with excellence adhreence. This can be explained by the formation of an iron oxide. The iron oxrtion of the scale is reduced, leaving the stable oxides dispersed in a fresh metallic iron surface layer. This reduced iron surface is easily wetted by the liquid zinc and excellent adherence is obtained.

• Journal of the Korean institute of surface engineering
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• v.30 no.5
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• pp.320-332
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• 1997

The development of colored surface on zinc coating by the oxidation of a melten alloy of zinc with a minor amount of oxygen-avid additive such as tianium has been studied. Using a galvanizing Zinc alloy containing 0.1 to 0.3wt%Ti, gold, purple or blue color was developed clearly and stably, depending upon the extent of oxidation, by air cooling after hot dipping in a bath at temperature of $550^{\circ}C$ to $600^{\circ}C$. The source of the color is light interference with surface oxide layer. THe final color depends on the thickness of the color depends on the thickness of $TiO_2$, played So compositing, temperature and time at elevated temperature after are all controlling variables. Since oxidation film such as $TiO_2$ played role of passivation film, the corrosion resistance in a colored galvanized steel sheet. It is also thought that surface oxide layer of $TiO_2$ inhibited dissolution of the coating layer.

• Journal of the Korean institute of surface engineering
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• v.48 no.1
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• pp.27-32
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• 2015

Advanced high strength steels undergo recrystallization annealing in reducing gas atmosphere before galvanizing to improve mechanical properties. The selective oxidations of elements such as Mn, Si, Cr and Al during annealing decrease wettability of liquid zinc, resulting in bare spots and other defects. In this work, Fe-3wt%Mn steel sheet was annealed at $780^{\circ}C$ for 1200 sec. in 5% $H_2-N_2$ atmosphere and then dipped into zinc bath held at $460^{\circ}C$, which contained 0.2wt% dissolved Al. MnO crystallines in the average size of 200 nm were formed on the surface after annealing. It is estimated that MnO has been detached into bath with the formation and growth of inhibition layer with longer immersion time during galvanizing. No evidence of aluminothermic reduction of MnO has been found in this study.

• Journal of the Korean institute of surface engineering
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• v.34 no.2
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• pp.115-124
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• 2001

Gas wiping process of continuously hot-dip galvanized coating on steel strip has noise and coating problems. To improve the qualify of product, characteristics of air flow on the steel surface must be investigated. In this paper, fluid dynamic model of the gas flow is setup and solved numerically using STAR-CD. The effects of edge baffle, distance between steel plane edge and baffle, inlet pressure, and gap between air knife and strip steel surface are investigated, and it is concluded that edge baffle can reduce over-coating and edge built-up.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2005.05a
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• pp.389-392
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• 2005

In the modern days, a galvannealed sheet steel(GA) instead of a cold rolled steel sheet has been widely used as an alternative to extend the life of automotive body. Accordingly, the mechanical properties of GA for automobiles were taken Into account and studied by comparing with the temperature variation on annealing in this study. To clarify the effect of surface features in the mechanical properties of GA, the several tests such as nanoindentation and FE-analysis were executed. For this goal use is made of the method of neural networks. The developed neural networks apply also to obtain reliable mechanical properties of the thin films. Load-displacement curve was computed by the analysis procedure and compared with experimental results.

• Proceedings of the KWS Conference
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• 1992.10a
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• pp.91-95
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• 1992

The resistance spot welding process has been extensively used for joining of sheet metals, which are subject to variation of many process variables. Many qualitive analyses of sampled process variables have been attempted to predict nugget size. In this paper, dynamic resistance and electrode movement signal which is a good indicative of the nugget size was examined by introducing an artificial neural network estimator. An artificial neural feedforward network with back-propagation of error was applied for the estimation of the nugget size. The prediction by the neural network is in good agreement with the actual nugget size for resistance spot welding of galvanized steel. The results are quite promising in that the quantitative estimation of the invisible nugget size can be achieved without conventional destructive testing of welds.

• Journal of the Korean institute of surface engineering
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• v.31 no.5
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• pp.286-296
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• 1998

Galvannealing is becomming the main stream of the coating technology applied to automobile outer and inner panels due to its low cost and easy application applied to automobile outer and inner panels due to its low cost and easy application in thick Zn coating, compared to electro galvanizing. Despite of filed up data with an experience in this field, galvannealing in thick Zn coating is getting more difficult because of the absence of Fe deposition in Zn coating. As a result, it exhibits, with different steel sheet and grain size there is a proper temperature range which is good for the tarket coating thickness of galvannealing. In case of 1,200mm wide and 0.77 mm thick extra low carbon steel with 20$mu extrm{m}$ grain size, its proper temperature range for galvannealing of one side 60g/$\textrm{m}^2$ is 470-$480^{\circ}C$.

• Journal of the Korean institute of surface engineering
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• v.32 no.1
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• pp.21-30
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• 1999

Coating adherance behavior of low carbon steels, produced by POSCO, Korea, was studied in order to study the characteristics of hot rolled galvanized iron(HGI) manufactured without pickling line and the development of its process. Galvanizing experiments were carried out in zinc pot with 0.2wt% Al after hot rolled plates with scale were reduced at $550~750^{\circ}C$ in 10~30% hydrogen gas atmosphere during 60~400seconds. The reduced plates and coated products were examined by SST, XRD, SEM and EPMA on their surfaces and cross sections. Coating layer of HGI manufactured with pickling line was composed of retained scale, Fe-Zn-Al compound, Fe-Zn compound ($\delta_1\;and\;\zeta$ Phase) and pure zinc. It was superior to HGI in coating adhesion. It seems to be due to forming of Fe-Zn-Al compound in interface of matrix and retained porous scale.

• Journal of the Korean institute of surface engineering
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• v.33 no.4
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• pp.233-240
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• 2000

A novel electrostatic spraying method to solidify molten zinc coating layer was studied by SEM and measurement of sample's temperature. The sprayed droplets also served as nucleation sites in the solidification reaction of molten zinc but might leave the pitting mark by impinging on its surface especially at high spray pressure. Our experimental results showed that electric field could change the sprayed particle trajectories and assist the fine droplets to attach on the surface. Thus, by reducing the spray pressure and by applying the electric voltage higher than -20 KV to charge the droplets electrostatically, we could produce the spangle free galvanized coating layer without pitting.

• Journal of the Korean institute of surface engineering
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• v.34 no.4
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• pp.297-302
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• 2001

As GA (Hot dip galvannealed steel sheet) has good corrosion resistance, weldability and paintability as well as excellent formability, it's demand is rapidly increasing for automotive panels. The GA coated layers are composed of several kinds of brittle Fe-Zn Metallic compounds which are susceptible to powdering during the press forming, however, very careful controls of manufacturing conditions such as galvannealing heat-treatment or bath composition are essential to meet with the required quality of automotive use. In this study the required characteristics of automotive panel are practically surveyed in detail and the appropriate manufacturing conditions of galvannealing or bath composition have experimentally investigated by using the various analyzing and simulating equipments. The result in this study indicated that the corrosion resistance at the cut edges was improved by increasing of coating weight and decreasing of thickness of sheet steels.