• Composites Research
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• v.27 no.4
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• pp.123-129
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• 2014

Ceramic matrix composites (CMCs) consist of such reinforcements as carbides, nitrides, borides and oxides, which have high melting points, low density, high modulus and high strength, for the purpose of increasing toughness. These materials are used for heat shielding systems for aerospace vehicles, high-temperature gas turbine combustion chambers, turbine blades, stator vane parts, etc. Oxide CMCs are used for the components of burner and flame holder and the high-temperature gas duct. CMCs are also applied to brake disks, which are subjected to severe thermal shock, and slide bearing parts under heavy loads. The research and development of the CMC are progressed for the strategic purpose in defense and energy industry; for instance, for aerospace applications in the U.S., and for hyper-speed aircraft, gas turbines, and atomic fissions in U.S., Japan, and Europe.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.16 no.3
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• pp.291-299
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• 2018

Under a pyro-processing concept, an electrolytic reduction process has been developed to reduce uranium oxide in molten salt by electrochemical means as a part of spent fuel treatment process development. Accordingly, a model based on electrochemical theory is required to design a reactor for the electrolytic reduction process. In this study, a 1D model based on the phase-field theory, which explains phase separation behaviors was developed to simulate electrolytic reduction of uranium oxide. By adopting parameters for diffusion of oxygen elements in a pellet and electrochemical reaction rate at the surface of the pellet, the model described the behavior of inward reduction well and revealed that the current depends on the internal diffusion of the oxygen element. The model for the electrolytic reduction is expected to be used to determine the optimum conditions for large scale reactor design. It is also expected that the model will be applied to simulate the integration of pyro-processing.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.37 no.9
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• pp.837-845
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• 2013

An airlift pump can be used to pump liquids and sediments within itself, which cannot easily be pumped up by a conventional method, by using the airlift effect. This characteristic of the airlift pump can be exploited in a DCFC (Direct Carbon Fuel Cell) so that molten fuel with high temperature may be carried or transported. The basic characteristics of airlift are investigated. A simple system is constructed, where the reservoir is filled with water, a tube is inserted, and air is supplied from the bottom of the tube. Then, water is lifted and its flow rate is measured. Bubble patterns in the tube are observed in a range of air flow rates with the parameters of the tube diameter and submergence ratio, leading to four distinct regimes. The pumping performance is predicted, and the correlation between the supplied gas flow rate and the induced flow rate of water is found.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2011.04a
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• pp.334-339
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• 2011

이 연구에서는 내화천장구조 재료의 고온 열특성을 파악하여, 건축물 화재시 천장구조에 대한 보다 정확한 화재성상예측을 위한 실험적 자료로 제시하고자 한다. 건축물의 화재성상 예측은 내화설계 시 반드시 필요하며, 화재성상예측을 위해서는 화재하중, 작용외력, 안전계수 및 설계용 정수의 합리적인 설정이 중요하다. 화재하중 및 작용외력 등은 건축물의 부재가 지니는 하중조건에 대한 화재시의 부재 안정성 예측에 관계되는 부분이며, 설계 시 필요한 데이터 중 내화천장구조 재료의 고온 열특성 값은 화재발생 구획의 화재온도가 주요 구조부재에 전달되는 정도를 예측할 수 있는 인자로 볼 수 있다. 따라서 내화천장구조 재료의 고온 열특성 값 설정은 화재발생 공간의 온도범위($20{\sim}1000^{\circ}C$)에 걸쳐 평가 및 분석되어야만 정확하고 신뢰성 있는 화재발생 예상 공간의 부재 온도 및 안전성 분석이 가능하다. 이에 국내 건축구조물에 사용되고 있는 대표적인 내화피복 재료인 방화석고보드, 텍스, 암면에 대해서 $20^{\circ}C{\sim}900^{\circ}C$까지의 열전도율을 측정하였다. 실험결과 방화석고보드와 텍스의 경우 약 0.15 W/m K까지 일정하게 증가하였다. 암면의 경우 약 $700^{\circ}C$까지는 방화석고보드나 텍스에 비해 열전도율이 낮게 나타났지만, $800^{\circ}C$ 지점부터 용융 및 탄화가 진행되면서 열전도율이 급격히 상승하는 것으로 나타났다.

• Applied Chemistry for Engineering
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• v.10 no.8
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• pp.1136-1140
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• 1999

Melt blends of polymide 6(PA6) and polypropylene grafted maleic anhydride(PP-g-MA) were prepared to study the influence of chemical reaction between the two polymer components. The tensile, flexural, izod impact, dynamic mechanical properties and phase structure were investigated for this blend system. Tensile strength and modulus of the blends showed synergetic effect upon blending of two polymer components. Flexural properties maintained the value of numerical mean calculated from the weight ratio of two components. Also, notched izod impact strengths showed maximum in th PA6/PP-g-MA 50/50 wt % blend. From the change of tan ${\delta}$ observed, we confirmed the increase of miscibility in this blend system by chemical reaction between PA6 and PP-g-MA. Blends of good impact resistance could be obtained when the PP-g-MA particles of $2{\mu}m$ was dispersed in the PA6 matrix.

• Applied Chemistry for Engineering
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• v.5 no.4
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• pp.669-680
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• 1994

DMA-co-DAMA were synthesized from 2-diethylaminoethyl metacrylate and dodecyl-metacrylate containing long chain hydrocarbon group with hydrophilic and hydrophobic radicals. To facilitate water emulsification,acrylic copolymer was cationized by acetic acid to produce acetated acrylic copolymer. The structures of the synthesized copolymer and acetated copolymers were confirmed by IR, NMR, and molecular weight was measured by GPC, and C. H. N elemental analysis. Acetated acrylic copolymers were perfectly emulsified in water and showed increased emulsion stability. Polymer dispersion for cement modifier(PDCM-PDD) was prepared by blending of the guaternized acrylic copolymer synthesized above sodium silicate sodium gluconate oleic acid and triethanol amine. The result with prepared polymer dispersion of cement modfier was examined, and it was found that excellent waterproffing effect; Water permeability ratio is 0.44 under the water pressure of $100g/cm^2$ and 0.55 under $3kg/cm^2$, and water absorption ratio is 0.36~0.47 and 1.02 compressive strength ratio at mixed ratio of water/PDCM-PDD is 45 times.

• Proceedings of the Materials Research Society of Korea Conference
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• 2012.05a
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• pp.57.1-57.1
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• 2012

금속을 용해 응고시킬 때 생성되는 소위, 주조 결함이나 소결금속 내의 기공은 재료의 성능이나 강도를 현저하게 낮추는 결함으로서 예전부터 기피되어 왔다. 또한, 재료공정에 있어서도 여하의 기공이나 기포가 없는 치밀한 고강도 및 고기능성 재료를 개발하는 것에 최대한의 주의와 관심을 기울여 왔다. 반면에 자연계의 천연물이나 인공물을 둘러보면 그 대부분이 다공질임을 쉽게 눈치챌 수 있다. 예를 들어 목재, 지엽 등의 생물을 시작해서 콘크리트 등의 인공물, 우리 체내의 뼈도 전형적인 다공질구조로 구성되어 있다. 이러한 구조로부터 재료의 재질제어 이외에 구조제어라는 새로운 어프로치를 고려할 수 있고, 최근 들어, 금속재료에 있어서도 이러한 다공질 구조에 관한 연구가 활성화되어 충격흡수재, 생체재료, 베어링재료 등의 다양한 응용이 전개되고 있다. 원주상의 방향성 기공을 갖는 로터스 금속의 제조 원리는 용융금속의 높은 가스용해도와 고체금속의 낮은 가스고용도의 차이를 이용하여 응고할 때 고용되지 않는 가스원자가 기포를 형성시키는 것이다. 수소용해도는 모든 금속에 있어서 온도상승에 따라 증가하지만 융점에 있어서 용해도의 불연속적 증가를 나타내며 응고할 때 고액계면에서 다량의 가스를 방출하고 기공 생성을 야기한다. 특히, 고 액상에 있어서 수소용해도 차가 큰 마그네슘, 니켈, 철, 동 등은 기포를 생성하기 쉽다. 또한 기공의 배열구조를 제어하기 위해 일방향응고법를 이용하여 기공에 방향성을 부여한다. 외관상 기공구조가 연근뿌리를 닮은 것으로 부터 로터스 금속이라는 명칭이 널리 알려져 있다. 이와 같은 제조방법에 의해 로터스 금속은 기공 방향, 기공크기, 기공률을 자유롭게 제어할 수 있고 우수한 기계적 성질이 기존의 발포금속, 소결금속과 전혀 다른 특성을 가지고 있다. 이러한 기공구조는 용해온도, 응고속도, 분위기 가스압, 불활성가스와의 혼합체적비 등의 제어를 통해서 조절할 수 있다. 이와 같이 제조한 방향성 다공질금속은 BT (인플란트, 생체적합성, 저탄성, 경량), ST (초음속기엔진부품, 경량), IT (고성능수냉모듈), ET(고온촉매, 필터)의 분야로의 응용을 기대한다.

• Clean Technology
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• v.20 no.1
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• pp.88-94
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• 2014

During the past decades much attention has been paid to the desulfurization of diesel oil which is important as a source for the fuel cells to prevent the sulfur poisoning of both diesel steam reforming catalyst and electrode of fuel cell. Although alternative desulfurization techniques have been investigated, desulfurization for ultra-low sulfur diesel (ULSD) is still challenged. Therefore, this research focuses on the desulfurization of commercial ULSD for the application to molten carbonate fuel cell (MCFC). Herein, the performances of several kinds of commercial adsorbents based on activated carbons, zeolites, and metal oxides for desulfurization of ULSD were screened. The results showed that metal oxides based materials can feasibly reduce sulfur concentration in ULSD to a level of 0.1 ppmw while activated carbons and zeolites did not reach this level at current conditions.

• Journal of Adhesion and Interface
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• v.7 no.2
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• pp.32-38
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• 2006

In this study, we used a sericite which is a cheap price antibacterial agent and had excellent results. The particle size of sericite was fixed to $15{\mu}m$. The effect of the peel strength is not affected by several types of adhesives. Peel strength is increased with increasing adhesive content, and satisfied standard value of peel strength when adhesive content is $20g/m^2$. Laundering cotton fabric treated with antibacterial agent, the optimum content satisfying Korean Standard (KS) is 8%. Continuous processing conditions for antibacterial treatment on the footwear cotton fabrics are follows : melting temperature $120^{\circ}C$, cooling time 20 s, pressing temperature $130^{\circ}C$, pressing time 30 s.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.8
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• pp.338-343
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• 2017

In this study, blast furnace slag powder was used in concrete to help reduce carbon dioxide emissions and to recycle industrial waste. Blast furnace slag powder is a byproduct of smelting pig iron and is obtained by rapidly cooling molten high-temperature blast furnace slag. The powder has been used as an admixture for cement and concrete because of its high reactivity. Using fine blast furnace slag powders in concrete can reduce hydration heat, suppress temperature increases, improve long-term strength, improve durability by increasing watertightness, and inhibit corrosion of reinforcing bars by limiting chloride ion penetration. However, it has not been used much due to its low compressive strength at an early age. Therefore, this study evaluates the effects of steam curing for increasing the initial strength development of concrete made using slag powder. The relationship between compressive strength, SEM observations, and XRD measurements was also investigated. The concrete made with 30% powder showed the best performance. The steam curing seems to affect the compressive strength by destroying the coating on the powder and by producing hydrates such as ettringite and Calcium-Silicate-Hydrate gel.