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Research Trends in Coating Strategies for Residual Lithium Control in High-Nickel Li(NixCoyMn1-x-y)O2 Cathodes (고니켈 삼원계 층상구조 양극 물질의 잔류 리튬 제어를 위한 코팅 기술 연구 동향)

  • Ui Yeoun Song;Eun Ji Lee;Ji Eun Lee
    • Applied Chemistry for Engineering
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    • v.35 no.3
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    • pp.182-191
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    • 2024
  • Li(NixCoyMn1-x-y)O2 (NCM) is the intensively developed cathode material for expanding the electric vehicle market and developing lithium-ion batteries that meet higher capacity, longer life, and lower cost. High-nickel NCM increases the nickel content to 80% or more, securing price competitiveness by improving performance with high energy density and reducing the cost of cobalt. However, the high-nickel NCM materials have a residual lithium problem, leading to issues in battery performance degradation and stability. While various methods exist for removing residual lithium, such as washing, doping, and coating, this paper focuses on recent research trends in coatings aimed at enhancing NCM performance and stability by removing residual lithium.

Effective Coastal Water Quality Management and Marine Environmental Impact Assessment (연안의 효율적 수질관리 방향과 해양환경영향평가)

  • Lee, Dae-In;Eom, Ki-Hyuk;Kim, Gui-Young;Hong, Sok-Jin;Lee, Won-Chan;Jang, Ju-Hyoung
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.14 no.1
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    • pp.29-37
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    • 2008
  • This study examined principles and techniques of efficient water quality management as well as total coastal pollutant loads and the relevant examples in the advanced countries from the viewpoints of water quality improvement and pollution control in coastal areas. The problems and improvements in an estimation of the current total pollutant loads were also pointed out. In addition, discussion was made on the relationship between total pollutant loads and environmental capacity as well as particulars requiring extensive examination on access to and study on water quality model used as prediction tool for marine environment. Furthermore, this study proposed details of and improvement plans for water quality control to be reflected and absorbed into systems and policies related to coastal water quality. In coastal areas, which are subject to total coastal pollutant loads, it is necessary to calculate pollutant loads reduction and allocation, to propose them in detail in statement in relations to new pollution sources for the corresponding projects or plans in environmental impact assessment and prior environmental review system. Also, in relations to regional plans for coastal management, the local government concerned must focus more on environmental management plan to implement data on pollution sources and pollutant loads flown into sea areas under basic jurisdiction, therefore it is required to actively respond to expansion and introduction of total coastal pollutant loads system in the future. Total coastal pollutant loads system must be expanded and executed by considering characteristics of sea area and changes in the environment of land. For pollution sources in land, the competent authorities in charge of coastal environment will need to initiatively administer supervision, monitoring activities and achieve integration and operation of the related laws by preparing legal bases for management system or adjusting the related laws.

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Concurrent Chemoradiation in Patients with Cancer of the Esophagus (식도암에서의 동시화학방사선요법)

  • Lee Kang Kyoo;Park Kyung Ran;Lee Jong Young;Shin Hyun Soo;Lee Chong In;Chang Woo Ick;Shim Young Hak
    • Radiation Oncology Journal
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    • v.16 no.1
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    • pp.7-16
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    • 1998
  • Purpose : To evaluate survival rate and prognostic factors affecting survival of patients with esophageal cancer treated with concurrent chemoradiation. Materials and Methods : Eligibility included biopsy proven invasive carcinoma of the cervical or thoracic esophagus, confined to esophagus and mediastinum with or without regional lymph node and supraclavicular lymph node, and ECOG Performance status $H_0-H_2$. Patients received radiation therapy with 5940cGy over 7 weeks and chemotherapy, consisted of 5-FU(1000 $mg/m^2/day$ in continuous infusion for 5 days, days 1 to 5 and days 29 to 33) and mitomycin C($8mg/m^2$ intravenous bolus at day 1). After concurrent chemoradiation, maintenance chemotherapy was followed with 5-FU(1000 $mg/m^2/day$ in continuous infusion for 5 days at 9th, 13th, and 17th weeks) and cisplatin($80mg/m^2$ intravenous bolus at the first day of each cycle). Results : From November 1989 to November 1995, 44 patients were entered in this study. After treatment, complete response rate and partial response rate were $59\%$ and $41\%$. Overall 1, 2, and 5-year survivals were $59\%$, $38\%$, and $9.6\%$(median 17 months), Prognostic factors affecting survival were response to treatment and T-stage. Among 26 complete responders, there were 6 local recurrences, 3 distant recurrences, 1 local and distant recurrence, and 2 unknown site recurrences Acute and chronic complication rates with grade 3 or more were $20\%$ and $13.0\%$ and there was no treatment-related mortality. Conclusion : Concurrent chemoradiation, compared with historical control groups that treated with radiation alone, improved median survival and did not significantly increase treatment-related complications. Complete responders had longer survival duration than partial responders. Predominant failure pattern was local failure. So, efforts to improve local control should be proposed.

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Improvement of Energy Density in Supercapacitor by Ion Doping Control for Energy Storage System (에너지 저장장치용 슈퍼커패시터 이온 도핑 제어를 통한 에너지 밀도 향상 연구)

  • Park, Byung-jun;Yoo, SeonMi;Yang, SeongEun;Han, SangChul;No, TaeMoo;Lee, Young Hee;Han, YoungHee
    • KEPCO Journal on Electric Power and Energy
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    • v.5 no.3
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    • pp.209-213
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    • 2019
  • Recently, demand for high energy density and long cycling stability of energy storage system has increased for application using with frequency regulation (F/R) in power grid. Supercapacitor have long lifetime and high charge and discharge rate, it is very adaptable to apply a frequency regulation in power grid. Supercapacitor can complement batteries to reduce the size and installation of batteries. Because their utilization in a system can potentially eliminate the need for short-term frequent replacement as required by batteries, hence, saving the resources invested in the upkeep of the whole system or extension of lifecycle of batteries in the long run of power grid. However, low energy density in supercapacitor is critical weakness to utilization for huge energy storage system of power grid. So, it is still far from being able to replace batteries and struggle in meeting the demand for a high energy density. But, today, LIC (Lithium Ion Capacitor) considered as an attractive structure to improve energy density much more than EDLC (Electric double layer capacitor) because LIC has high voltage range up to 3.8 V. But, many aspects of the electrochemical performance of LIC still need to be examined closely in order to apply for commercial use. In this study, in order to improve the capacitance of LIC related with energy density, we designed new method of pre-doping in anode electrode. The electrode in cathode were fabricated in dry room which has a relative humidity under 0.1% and constant electrode thickness over $100{\mu}m$ was manufactured for stable mechanical strength and anode doping. To minimize of contact resistance, fabricated electrode was conducted hot compression process from room temperature to $65^{\circ}C$. We designed various pre-doping method for LIC structure and analyzing the doping mechanism issues. Finally, we suggest new pre-doping method to improve the capacitance and electrochemical stability for LIC.

Characteristics and Control of Microthrix Parvicella Bulking in Biological Nutrient Removal Plant (생물학적 영양소제거공정에서 Microthrix Parvicella에 의한 Bulking 특성 및 제어)

  • Lee, H.;Ahn, K.
    • Journal of Korean Society on Water Environment
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    • v.22 no.6
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    • pp.1101-1106
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    • 2006
  • Many BNR (Biological Nutrient Removal) plants have experienced a bulking problem, mainly due to the growth of filamentous organisms, particularly during the winter months. This study investigated the problem of bulking due to the growth of M. parvicella both at a full-scale municipal wastewater treatment plant and a pilot scale plant located in the C city. The full-scale facility was operated at a flow rate of $51,000m^3/d$, an F/M (Food-to-Microorganism) ratio of 0.12 kgBOD/kgMLVSS/d and an SRT (Solids Retention Time) higher than 25 days, respectively. This plant experienced bulking and foaming problems at low temperatures below $15^{\circ}C$ since it was retrofitted with the BNR system in 2003. The pilot plant employed had an identical process configuration as the full scale one and used the same wastewater source. It was operated at a flow rate of $3.8m^3/d$, temperatures between 10 to $25^{\circ}C$ and SRTs between 10 and 25 days. At full scale, the M. parvicella growth and SVI (Sludge Volume Index) patterns were studied in conjunction with temperature variations. At pilot scale, DO and SRT variations were also explored, in addition to the filamentous bacteria growth and SVI patterns. During the full-scale investigation, over a 3 year period, it was noted that the SVI was maintained within acceptable operational values (i.e. under 160) during the summer months. Moreover settling in the secondary clarifiers was good and was not affected by the presence of M. parvicella. In contrast, at low mean temperatures during winter, the SVI increased to over 300. Overall, as the temperature decreased, the predominance of M. parvicella became apparent. According to this study, M. parvicella growth could be controlled and SVI could drop under 160 by a change in operational conditions which involved an increase in DO concentration between 2 and 4 mg/L and a decrease in SRT to less than 20 days.

Level of Service of Signalized Intersections Considering both Delay and Accidents (지체와 사고를 고려한 신호교차로 서비스수준 산정에 관한 연구)

  • Park, Je-Jin;Park, Seong-Yong;Ha, Tae-Jun
    • Journal of Korean Society of Transportation
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    • v.26 no.3
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    • pp.169-178
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    • 2008
  • Level of Service (LOS) is one of ways to evaluate operational conditions. It is very important factor in evaluation especially for the facility of highways. However, some studies proved that ${\upsilon}/c$ ratio and accident rate is appeared like a second function which has a U-form. It means there is a gap between LOS and safety of highway facilities. Therefore, this study presents a method for evaluation of a signalized intersection which is considered both smooth traffic operation (delay) and traffic safety (accident). Firstly, as a result of our research, accident rates and EPDO are decreased when it has a big delay. In that reason, it is necessary to make a new Level of Service included traffic safety. Secondly, this study has developed a negative binominal regression model which is based on the relation between accident patterns and stream. Thirdly, standards of LOS are presented which is originated from calculation between annual delay costs and annual accident cost at each intersection. Lastly, worksheet form is presented as an expression to an estimation step of a signalized intersection with traffic accident prediction model and new LOS.

Development and Validation of Cryopanel Cooling System Using Liquid Helium for a Satellite Test (액체헬륨을 이용한 위성시험용 극저온패널 냉각시스템 개발 및 검증)

  • Cho, Hyok-Jin;Moon, Guee-Won;Seo, Hee-Jun;Lee, Sang-Hoon;Hong, Seok-Jong;Choi, Seok-Weon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.2
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    • pp.213-218
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    • 2010
  • A cooling system utilizing liquid helium to chill the cryopanel (800 mm $\times$ 700 mm dimensions) down to 4.2 K was designed, implemented, and tested to verify the role of the cryopanel as a heat sink for the payload of a spacecraft inside the large thermal vacuum chamber (effective dimensions : 8 m ($\Phi$) $\times$ 10 m (L)) of KARI (Korea Aerospace Research Institute). Two LHe (Liquid Helium) Dewars, one for the main supply and the other for refilling, were used to supply liquid helium or cold helium gas into this cryopanel, and flow control for the target temperature of the cryopanel within requirements was done through fine adjustment of the pressure inside the LHe Dewars. The return helium gas from the cryopanel was reused as a thermal barrier to minimize the heat influx on the core liquid helium supply pipe. The test verified a cooling time of around three hours from the ambient temperature to 40 K (combined standard uncertainty of 194 mK), the capacity for maintaining the cryopanel at intermediate temperatures, and a 1 K uniformity over the entire cryopanel surface at around 40 K with 20 W cooling power.

An Appraisal on the MAGPs for the EU's Fishing Industry (EU의 어업구조조정을 위한 다년도지도프로그램(MAGP)에 대한 평가)

  • Shin Yong-Min;Lee Sang-Go
    • The Journal of Fisheries Business Administration
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    • v.37 no.1 s.70
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    • pp.121-142
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    • 2006
  • EU는 당면과제인 과잉 어획능력을 해소하기 위해 공동어업정책하 어업구조정책의 하나로 '다년도지도프로그램(Multi Annual Guidance Programmes: MAGPs)'을 시행해 왔다. 지난 1983년부터 2002년까지 시행된 MAGP는 EU의 어업구조정책의 핵심 요소이다. 이러한MAGP는 최초 EU의 공공원조계획을 위한 체제의 하나로 입안되었으며, 그 목적은 어선 톤수와 마력수에 대한 각 회원국 어선의 능력을 동결하고자 하는 것이었다. 회원국들은 $4{\sim}5$년 주기로 각 국의 어선개발에 대한 정밀한 계획을 세워야하며, 어선의 용량(총톤수와 엔진출력)과 어획노력에 관한 목표들을 달성하도록 되어 있다. 이러한 감소 목표들은 독립된 과학적 조사결과에 따라 EU 위원회에 제안되고, 공동체 선박등록부에 의거 각국의 프로그램에 대한 적정 실현여부를 감시받고 있다. 또한 각 회원국들은 매년 4월 1일까지 EU위원회에 당해 MAGP의 실현에 대한 진도보고서를 제출하는 식으로 운영되어 왔다. 현재까지 4개의 MAGP가 시행되었다. 제1세대 MAGP(1983-1986년)는 회원국들에 강제적인 것은 아닌 관계로 별다른 성과가 없었으나, 공동체 어선들간의 어획능력 증가 경쟁에 대한 제어의 표현으로 의미가 있었다. 제2세대 MAGP(1987-1991년)에서는 처음으로 진출입 제어를 위한 매우 제한된 법규정이 만들어졌으며, 제3세대 MAGP(1992-1996년)에서는 공동체 어선 감소의 실제목표를 수여하는 첫 번째 계획이었다. 그리고 이 계획은 약 15%정도의 매 우 실질적인 어획능력 감소를 이루었다. 가장 최근에 끝난 4세대 MAGP(1997-2002)는 공동어업정책의 개혁 시간을 주기 위하여 1년 연장되었으며, 이 시스템은 만약 어선의 어획구성상 감소되는 어족자원의 비율이 낮으면 그 자원을 보호하고자 하는 것이었으나, 그 성과는 매우 낮았다. 이 4세대 계획의 또 다른 중요한 혁신은 회원국이 그들의 어선의 활동규제와 크기를 결합시키거나, 또는 전적으로 표본어선의 수익성 분석을 통해 어획능력을 제거하고자 하는 것이다. 그러나 이 역시 관리와 통제의 곤란으로 별 다른 성과를 거두지 못한 것으로 평가받고 있다. 그러나 많은 어려움과 제도상 불완전함에도 불구하고 MAGP는 일정한 효과를 거둔 것으로 보고되고 있다. 즉 어획능력은 지난 20년동안 전체적으로 25% 가량 감소하였으며, 특히 오래되고 비효율적인 어선에 대한 감척으로 어획능력 감소에 기여한 것으로 평가되고 있다. 이들 프로그램은 특히 보조금을 통해 어선의 제3국 영구이전과 낡고 비효율적인 어선의 신조를 가속화시킨 것으로 보고되고 있다.

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A Study on the Call Admission Control with Overflow and Preemption at Adaptive Moving Boundary in Cellular Mobile Communications (셀룰러 이동통신망의 적응성 가변경계에서 Overflow와 Preemption을 갖는 호 접속제어 방안 연구)

  • 노희정
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.18 no.4
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    • pp.171-180
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    • 2004
  • CDP(handoff Call Dropping Probability) and CBP(new Call Blocking Probability) have been used as two important call level QoS parameters in cellular mobile communications. But, many methods to reduce CDP without considering CBP have been studied, and hand-off call priority scheme has been introduced. But the use of hand-off call priority scheme increases CBP and decreases channel utilization rate depending on the number of reserved channel for priority. In this paper, we propose a CAC(Call Admission Control) algorithm with overflow and preemption to solve the problem caused by considering CDP and CBP in calculation of the number of channel reserved. The problem is the increase of CDP as the traffic load increases. In our CAC algorithm, hand-off call is permitted to use(overflow) unreserved and unused channel if there is no reserved and unused channel, and new call is permitted to use(preemption) the channel overflowed by hand-off call if there is no unreserved and unused channel. This mechanism of calculation of the number of reserved channel and CAC algorithm is expected to increase channel utilization rate, and can be applied to media-based QoS provision in cellular mobile communications.

Performance Evaluation of Multi-User Detectors Employing Subtractive Interference Cancellation Schemes for a DS-CDMA System (감산형 간섭제거기법을 적용한 DS-CDMA 다중사용자 검파기의 성능분석)

  • Seo, Jung-Wook;Kim, Young-Chul;Oh, Chang-Heon;Ko, Bong-Jin;Cho, Sung-Joon
    • Journal of Advanced Navigation Technology
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    • v.6 no.1
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    • pp.17-26
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    • 2002
  • In this paper, we have analyzed the BER (Bit Error Rate) performance of multi-user detectors employing SIC(Successive Interference Cancellation) and PIC (Parallel Interference Cancellation) which are the representative schemes in the subtractive interference cancellation. We have considered the MUD structure employing HIC (Hybrid Interference Cancellation) which combines SIC with PIC scheme, and then analyzed the BER performance. We have evaluated the BER performance of SIC and HIC schemes which execute the soft decision to generate the tentative data bit for the purpose of the interference cancellation in MAI and noise environments. Through the numerical analysis and computer simulation, it is shown that HIC can remove the effect of MAI more efficiently than the others, that improve the BER performance and increase the capacity of DS-CDMA systems regardless of the power control conditions. The reason is that the SIC scheme in front of HIC can solve the near-far problem caused by the imperfect power control and PIC scheme in the rear of it can improve the performance much more.

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