• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.1 no.1
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• pp.65-72
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• 2003

Adsorption and desorption characteristics of methyl iodide at high temperature conditions up to 25$0^{\circ}C$ by TEDA-impregnated activated carbon and silver-ion exchanged zeolite(AgX-10), which are used for radioiodine retention in nuclear facility, were experimentally evaluated. In the range of temperature from 3$0^{\circ}C$ to 25$0^{\circ}C$, the adsorption capacity of base activated carbon decreased sharply with increasing temperature but that of TEDA-impregnated activated carbon showed higher value even at high temperature ranges. Especially, the residual amount of methyl iodide after desorption on TEDA-AC represented 30% lower value than that on AgX-10. However, it can be used as an adsorbent for the removal of methyl iodide up to 15$0^{\circ}C$ if it is preventing explosion by Ignition. The breakthrough curves of methyl iodide in the fixed bed packed with AgX-10 uP to 40$0^{\circ}C$ were compared upon the effects of bed temperatures, bed depth and input concentration of methyl iodide. Removal mechanism of methyl iodide on AgX-10 was proposed, based on the analysis of by-product gas generated from adsorption reaction.

• Journal of the Korean Society of Radiology
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• v.17 no.3
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• pp.449-457
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• 2023

Shielding for reducing exposure dose can make the diagnosis limited. The purpose of this study is to increase the efficiency of radiation protection and minimize the loss of image information by producing the shielding made of the water and the contrast medium which has different proportion and finding out the ideal proportion of them. Each shielding materials were made of water and water-soluble iodine contrast medium with the different proportion. The attenuation rate of absorbed dose was evaluated by the shielding materials in the plastic contents for measuring the efficiency of the radiation protection. As a result, the higher ratio of the contrast medium, the more efficient it is for radiation attenuation. The anatomical structure was observed most properly in case of the solution with 20 ml of the contrast medium and most difficultly in case of more than 60 ml of the contrast medium. In case of the signal intensity between skeleton and gas, the difference of average value had a significant as p < 0.001. Shielding with contrast medium attenuates less than the conventional shielding but in the examination for the sensitive part to radiation, it can be used to minimize the loss of the image information and reduce the exposure dose.

• Journal of the Korean Chemical Society
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• v.19 no.5
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• pp.339-342
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• 1975

The rates of consumption of iodine and gas evolution in hydrazine-iodine reaction in the presence of large excess of hydrazine have been studied in the pH range 0.5${\sim}$7. They are the same at very low pH and both increase to respective asymptotic values as pH is increased. The rate of iodine consumption is three orders of magnitude faster than the rate of gas evolution at higher pH. The results are explained by postulating that $N_2H_4$ but not protonated form reacts with iodine and an intermediate, probably $N_2H_2I_2$, is formed which decomposed by first order reaction of rate constant about 1.5${\times}10^{-3}sec^{-1}$ in neutral and weakly acidic solutions.

• Journal of the Korean Chemical Society
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• v.19 no.1
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• pp.43-49
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• 1975

Small amounts of iodine compound in mineral oils are usually effective in reducing friction of metallic surfaces. Such improvement in frictional behaviour of wear characteristics was explained by the formation of a diiodide layer lattice structure at the metallic contact surfaces. The lubrication mechanism, however, by which organoiodine compounds functions is not based on the formation of such lattice structure iodide. It was tested and shown, by a static surface chemical reactivity test, wear and EP tests, and a hot wire method, that compound such as N-iodopyridinium dichlorodate, a double charge transfer complex, reacted with metals as an interhalogen compound and that the resultant thin film product reduced appreciable the friction of metallic surfaces, more than compounds such as methyl iodide, diiodomethane, and iodoform. These results suggest that the action of iodine, included in organoiodine compounds, is not that of a classical layer structure iodide, and an entirely new mechanism may be derived from a further studies on charge transfer complex compounds of organoiodine compounds.

• Transactions of the Korean hydrogen and new energy society
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• v.23 no.1
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• pp.1-7
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• 2012

This study was performed to develop a low Pt content catalyst as a catalyst for HI decomposition in S-I process. Bimetallic catalysts added various amounts of Pt on a silica supported Ni catalyst were prepared by impregnation method. HI decomposition was carried out using a fixed bed reactor. As a result, Ni-Pt bimetallic catalyst showed enhanced catalytic activity compared with each monometallic catalyst. Deactivation of Ni-Pt catalyst was not observed while deactivation of Ni monometallic catalyst was rapidly occurred in HI decomposition. The HI conversion of Ni-Pt bimetallic catalyst was increased similar to Pt catalyst with increase of the reaction temperature over a temperature range 573K to 773K. From the TG analysis, it was shown that $NiI_2$ remained on the Ni(5.0)-Pt(0.5)/$SiO_2$ catalyst after the HI decomposition reaction was decomposed below 700K. It seems that small amount of Pt in bimetallic catalyst increase the decomposition of $NiI_2$ generated after the decomposition of HI. Consequently, it was considered that the activity of Ni-Pt bimetallic catalyst was kept during the HI decomposition reaction.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2003.11a
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• pp.632-635
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• 2003

For the disposal of low-level radwaste from nuclear power plant need the determination of levels of radio nuclides in radwaste. These nuclides include the difficult-to-measure nuclides, so indirect methodology for the determination of the difficult-to-measure nuclides have to be developed. In this work, for the determination of $^129I(t_{1/2}=1.57{\times}10^7 years)$ in low-level radwaste from nuclear power plant is investigated. Recovery of Iodide in simulated waste($UO_2$ pellet) as a soluble and radwaste(resin, woolen fabric)as a insoluble samples are measured. After pretreatment of sample, $I_2$ are extracted from aqueous solution with $CCl_4$. Then I are extracted from $CCl_4$ with 0.1M $NaHSO_3$ aqueous solution. iodide in aqueous solution are determined by ion chromatography. The overall recovery yield is 76.7 (RSD 1.7%) for mixed-acid digestion method. Incase of woolen fabrics, overall recovery yield is 74.3 (RSD 2.2%) and recovery of iodide in resin 56.5(RSD 5.6%) for alkaline fusion method.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2003.11a
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• pp.207-214
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• 2003

Removal efficiency of methyl iodide at high temperature process by TEDA-impregnated activated carbon used for radioiodine retention in nuclear facility was experimentally compared with that of silver ion-exchanged synthetic zeolite(AgX), In temperature ranges of$30^{\circ}C$ to $400^{\circ}C$, adsorption capacity of un-impregnated carbon was sharply decreased, but TEDA-impregnated carbon showed similar values of adsorption capacity of AgX even around $100^{\circ}C$. Especially, loading amount of methyl iodide on TEDA carbon up to$250^{\circ}C$ represented higher values compared to un-impregnated carbon. Breakthrough curves of methyl iodide in fixed bed packed with AgX and TEDA-impregnated carbon at high temperature was compared. Removal mechanism of methyl iodide on AgX was proposed, based on analysis of by-product gas generated from adsorption reaction.

• Journal of Dental Rehabilitation and Applied Science
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• v.30 no.1
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• pp.23-27
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• 2014

Purpose: The purpose of this study was to determine the dimensional stability of three rubber impression materials (polysulfide, polyvinylsiloxane, polyether) in an iodophor disinfectant. Materials and Methods: Seventy-two impressions were made with each material and divided into control, 10-minute, and 30-minute immersion groups using an iodophor as the disinfectant. A microscope was used to measure dimensional changes in the stone casts made from each group of impressions, and the percent change was analyzed using a two-way ANOVA (P = 0.05). Results: All dimensional changes after iodophor disinfection were small in 10 minute groups, however, showed significantly increased in 30 minute groups (P < 0.05). Conclusion: Clinically, it can be recommended to use iodophor disinfectant for rubber materials within 10 minute.

• The Journal of the Korea Contents Association
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• v.15 no.5
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• pp.436-443
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• 2015

The purpose of this study was to develop a self-diagnostic linearity quality control techniques of computed tomography (CT) by using measured CT number values from the various concentrations of iodine contrast media (CM) is diluted with distilled water under each condition of the tube voltage. The equipment was used for four-channel MDCT, the iodine concentration were using 300 mgI/ml, 350 mgI/ml, 370 mgI/ml and 400mgI/ml. Dilution of CM in distilled water was increased by each 5% until the maximum CT number values were measured. We applied the tube voltages for 90 kVp, 120 kVp, 140 kVp. As a result, we was obtained to the nearest linearity as 0.993 of correlation coefficient between the iodinated CM from 5% to 25% in 400 mgI/ml and the CT number values by 90 kVp. In conclusion, the proposed self-diagnostic linearity quality assurance technique by using iodine CM can be utilized to replace the AAPM CT performance phantom.

• Journal of the Korean Chemical Society
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• v.29 no.6
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• pp.575-581
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• 1985

Ultraviolet spectrophotometric investigations have been carried out on the systems of benzene, naphthalene and phenanthrene with iodine in carbon tetrachloride. The results reveal the formation of the one to one molecular complexes. The equilibrium constants were obtained in consideration of that absorption maxima due to the formation of the charge transfer complexes shift to blue with increasing temperature. Thermodynamic parameters for the formation of the charge transfer complexes were calculated from these values. These results indicate that the stabilities of the complexes formed between polynuclear aromatics and iodine increase with the number of aromatic rings. This may be a measure of the relative basicities of polynuclear aromatics toward iodine, which is explained in terms of the resonance of the interaction between aromatics and iodine. The results in this study were, additionally, compared with those of the polymethylbenzene series to be discussed the reason for them.