• Proceedings of the Materials Research Society of Korea Conference
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• 2003.11a
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• pp.156-156
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• 2003

수평 전기로에서 ZnIn$_2$S$_4$ 다결정을 합성하여 HWE(Hot Wall Epitaxy)방법으로 2nIn2S4단결정 박막을 반절연성 GaAs(100)기판 위에 성장시켰다. ZnIn2S4 단결정 박막은 증발원의 온도를 610 $^{\circ}C$, 기판의 온도를 450 $^{\circ}C$로 성장시켰고 성장 속도는 0.5 $\mu\textrm{m}$/hr로 확인되었다. ZrIn2S4 단결정 박막의 결정성의 조사에서 10 K에서 광발광(photoluminescence) 스펙트럼이 433 nm (2.8633eV)에서 exciton emission스펙트럼이 가장 강하게 나타났으며, 또한 이중결정 X-선 요동곡선(DCRC)의 반폭치(FWHM)도 133 arcsec로 가장 작아 최적 성장 조건임을 알 수 있었다. Hall 효과는 van der Pauw방법에 의해 측정되었으며, 온도에 의존하는 운반자 농도와 이동도는 293K에서 각각 8.51$\times$$10^{17}$ electron/$cm^{-3}$ 291 $\textrm{cm}^2$/v-s였다. ZnIn2S4 단결정 박막의 광전류 단파장대 봉우리들로부터 10 K에서 측정된 $\Delta$Cr(crystal field splitting)은 0.1678 eV, $\Delta$So(spin orbit coupling)는 0.0148 eV였다. 10 K의 광발광 측정으로부터 고품질의 결정에서 볼 수 있는 free exciton 과 매우 강한 세기의 중성 주개 bound exciton등의 피크가 관찰되었다. 이때 중성 주개 bound exciton의 반치폭과 결합 에너지는 각각 9 meV와 26 meV 였다. 또한 Haynes rule에 의해 구한 불순물의 활성화 에너지는 130 meV 였다.다.

• Applied Chemistry for Engineering
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• v.10 no.4
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• pp.586-591
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• 1999

Mixed-firing of a bituminous and an anthracite coal carried out in a batch fluidized bed combustor(0.109 m-I.D., 0.9 m-height). Effect of particle size an mixing fraction of anthracite and bituminous coal combustion characteristics were studied. The temperature profiles and pressure fluctuation properties were measured to interpret the combustion characteristics in a batch fluidized bed combustor. The used domestic anthracite coal has heating value of 2010 kcal/kg and the imported high-calorific bituminous coal has heating value of 6520 kcal/kg. The combustion characteristics in a batch fluidized bed combustor could be interpreted by using pressure fluctuation properties and temperature increasing rates. It was found that the optimum anthracite mixing percentage could be predicted analyzing the combustion rate and fluidization characteristics, The optimum mixing fraction was about 30 %. The different burning region of fluidized bed combustor was measured by temperature increasing rates.

• Korean Chemical Engineering Research
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• v.58 no.2
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• pp.319-324
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• 2020

Electroconvective instability is a non-linear transport phenomenon which can be found in ion-selective transport system such as electrodialysis, Galvanic cell and electrolytic cell. The instability is triggered by the fluctuation of space charge layer in adjacent of ion-selective surface, leading to increase of mass transport rate. Thus, in the aspect of mass transport, the instability has an important meaning. Although recent experimental techniques have opened up an avenue to direct visualize the instability, fundamental investigations have been conducted in limited area due to several experimental limitations. In this work, the electroconvective instability under potentiostatic mode was solved by numerical method in order to demonstrate correlation between current-time curve and the instability behavior. By rigorous time-resolved analysis, the transition behaviors can be divided into three stages; formation of space charge layer - growth of electroconvective instability - steady state. Furthermore, scaling laws of transition time were numerically obtained according to applied voltage as well.

• Proceedings of the Korean Nuclear Society Conference
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• 1998.05a
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• pp.603-608
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• 1998

유체내의 물체 주위에서 유동박리로 인해 생성되는 와류쉐딩은 열전달이나 물질전달을 촉진시키는 이점이 있으나, 항력을 증가시키거나 유동 및 온도의 요동에 의해 구조물을 손상시키는 단점이 있다. 특히 물체와 주위 유동 사이에 공진이 일어나면 항력값이 증가하면서 항력과 양력의 진폭이 급격히 증가하여 물체에 심각한 손상을 초래할 수 있다. 본 연구에서는 레이놀즈수 200 이하의 층류유동에서 공진시 물체 주위의 유동현상과 이로 인한 양력과 항력의 변화들을 수치해석방법을 통하여 분석하였다 수치해석은 일반좌표계에서 유한체적법을 적용하여 Navier-Stokes 방정식을 차분화하였다. 이때 방정식의 종속변수로는 공변속도를 채택하였으며, 이산화된 방정식은 분리단계법을 이용하여 수치해를 구하였다. 입구유속의 강제진동에 의한 사각실린더 주위의 와류쉐딩시 공진이 발생하는 강제진동수의 범위는 원통실린더의 경우와 유사하였으나 상대적으로 폭이 더 좁았다 그리고 공진이 발생하는 강제진동수의 범위는 진폭이 증가할수록 증가하였다. 쉐딩 진동수가 일정하면서 입구유속의 진폭이 증가하면 이에 비례하여 실린더 주위의 유속이 상대적으로 증가하게 되어 와도가 강해지면서 입추유속 진폭에 비례하여 항력의 평균값 뿐 아니라 항력과 양력의 진폭도 증가하였다. 그리고 실린더 뒷면의 와류 생성영역은 진폭에 비례하여 감소하였다. 진폭의 변화에 따라 상변화가 서로 상이한 것은 실린더 뒤쪽의 와류들이 상하면의 합력차이를 변화시켰고 이것이 진폭변화에 따라 상변화를 상이하게 나타나게 한 원인으로 진폭이 클수록 실린더 뒤쪽에서 압력변화가 심하게 변하면서 실린더 앞쪽까지 더 많은 영향을 미쳤기 때문이다.선원의 사용자에게 제공되는 최종방사능을 평가하는데 유용하게 사용될 수 있다.r의 분포를 보였다.cting the effect of earthquake on structures. This paper is based on the presented paper at the Bertero Symposium held in January 31an4 February 1 at Berkeley, California, USA which was entitled "Needs to Evaluate Real Seismic Performance of Buildings-Lessons from 1995 Hyogoken-Nambu Earthquake-". The lessons for buildings from the damage due to the Hyogoken-Nambu Earthquake are necessity to develop more rational seismic design codes based upon a performance-based design concept, and to evaluate seismic performance of existing buildings. In my keynote lecture at the Korean Association for Computational Structural Engineering, the history of seismic design and use of structural analysis in Japan, the lessons for buildings from the Hyogoken-Nambu Earthquake, the

• Smart Media Journal
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• v.8 no.4
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• pp.38-45
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• 2019

When there is a spray flow such as from a pesticide nozzle, winds affect the droplet flow of a rotary-wing drone accompanied by a strong wake, with a severe oscillation. Especially, during forwarding flights or when winds come from the side, compare to a simple hovering flight as the droplet is in the effect of aerodynamic drag force, the effect of spraying region becomes even larger. For this reason, the spraying of pesticides using drones may cause a greater risk of scattering or a difference in droplet dispersion between locations, resulting in a decrease in efficiency. Therefore, through proper numerical modeling and its applied simulation, an indication tool is required applicable for the various flight and atmospheric conditions. In this research, we completed both experiment and numerical analysis for the strong downwash from the rotor and flight velocity of the drone by comparing the probability density function of droplet distribution to build a spraying system that can improve the efficiency when spraying droplets in the pesticide spray drone.

• Applied Chemistry for Engineering
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• v.16 no.5
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• pp.603-608
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• 2005

This study was conducted to investigate particle attrition characteristics in a gas desulfurization using zinc titanate sorbent in a 0.035 m i.d. by 1.34 m height gas fluidized bed reactor. Gas jetting from the distributor and bubbling in the gas fluidized bed were found to be the main causes of particle attrition. The experiment was carried out under a slow attrition rate condition to compare the performance of the batch reactor to that of a continuous reactor. The attrition index (AI) and corrected attrition index (CAI) were measured at various the gas velocity, temperature, pressure, and bed weight, in the gas fluidized bed, during the dexulfurization process. The AI (5) and CAI (5) decreased as the bed weight increased. Particle destruction occurred when the particles started to experience physical fatigue under specific impacts over several iterations. AI (5) and CAI (5) also increased as relative humidity, gas velocity and pressure increased, and as temperature decreased. Particle attrition was mainly affected by gas jetting from the distributor, and abrasion resulted in smaller particles than fragmentation did.

• Korean Chemical Engineering Research
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• v.49 no.5
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• pp.571-576
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• 2011

Characteristics of bubble driven wakes were investigated in a simulated GTL process(0.102 m ${\times}$ 1.5 m in height) with viscous liquid medium. Effects of gas velocity(0.04 ~ 0.12 m/s) and liquid viscosity(0.001 ~ 0.050 $Pa{\cdot}s$) on the wake characteristics such as rising velocity, frequency, size and holdup were determined by employing a resistivity probe method. The wake phase formed behind the rising multi-bubbles as well as single bubbles were detected effectively from the conductivity fluctuations measured by the probe. Compressed, filtered and regulated air and aqueous solutions of Carboxy Methyl Cellulose(CMC) were used as a dispersed gas phase and a continuous liquid medium, respectively. It was found that the rising velocity and size of wake phase increased with an increase in gas velocity or liquid viscosity. The holdup and frequency of wake phase increased with increasing gas velocity due to the increase of gas input into the process with increasing gas velocity. However, the values of holdup and frequency of wake phase decreased with increasing liquid viscosity, since the size of bubbles and thus that of wakes increased with increasing liquid viscosity. The ratio of wake holdup to that of gas phase, which was in the range of 0.25 ~ 0.48, increased with an increase in liquid viscosity but decreased with gas velocity. The wake characteristics were well correlated in terms of operating variables within this experimental conditions.

• Resources Recycling
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• v.17 no.2
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• pp.36-45
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• 2008

Pickling of oxidized 304 stainless steel has been investigated using rotating disk electrode in waste acid solutions generated from the etching process of silicon wafer in order to recycle them. The waste acid solution contained acetic, nitric, hydrofluoric acids, and silicon of $19.6g/L^{-1}$. Electrochemical behavior during the pickling was distinctively different between the original and silicon-removed acid solutions. Open circuit potential was continuously changed in the original solution, while it was discontinuously changed and fluctuated in the silicon-removed solution. Fast and abrupt removal of surface oxide layer with severe pitting was observed in the silicon-removed solution. It was found that solution temperature had the most influential effect on glossiness. Surface glossiness after pickling was decreased with solution temperature. At the same condition, the glossiness was higher in the original solution than in the silicon-removed solution.

• Korean Journal of Crystallography
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• v.12 no.4
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• pp.197-206
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• 2001

A stoichiometric mixture of evaporating materials for AgInS₂ single crystal thin films was prepared from horizontal electric furnace. To obtain the single crystal thin films. AgInS₂ mixed crystal was deposited on thoroughly etched semi-insulating GaAs(100) substrate by the Hot Wall Epitaxy(HWE)system. The source and substrate temperatures were 680℃ and 410℃, respectively. The crystalline structure of the single crystal thin films was investigated by the photoluminescence and double crystal X-ray diffraction(DCXD). The carrier density and mobility of AgInS₂ single crystal thin film mea-sured from Hall effect by van der Pauw method are 9.35×10/sup 16/㎤ and 294㎠/V·s at 293K respectively. The temperature dependence of the energy band gap of the AgInS₂ obtained from the absorption spectra was well described by the Varshni's relation , E/sub g/(T)=2.1365eV-(9.89×10/sup-3/eV/K/)T²(T+2930K). The crystal field and the spin-orbit splitting energies for the valence band of the AgInS₂ have been estimated to be 0.1541eV and 0.0129 eV, respectively, by means of the photocur-rent spectra and the Hopfield quasicubic model. These results indicate that the splitting of the Δso definitely exists in the Γ/sub 5/ states of the valence band of the AgInS₂ /GaAs epilayer. The three photo-current peaks ovserved at 10K are ascribed to the A₁-, B-₁and C₁-exction peaks for n=1.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.23 no.6
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• pp.283-290
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• 2013

A stoichiometric mixture of evaporating materials for $MgGa_2Se_4$ single crystal thin films was prepared from horizontal electric furnace. To obtain the single crystal thin films, $MgGa_2Se_4$ mixed crystal was deposited on thoroughly etched semi-insulating GaAs(100) substrate by the Hot Wall Epitaxy (HWE) system. The source and substrate temperatures were $610^{\circ}C$ and $400^{\circ}C$, respectively. The crystalline structure of the single crystal thin films was investigated by double crystal X-ray diffraction (DCXD). The temperature dependence of the energy band gap of the $MgGa_2Se_4$ obtained from the absorption spectra was well described by the Varshni's relation, $E_g(T)=2.34 eV-(8.81{\times}10^{-4}eV/K)T^2/(T+251K)$. The crystal field and the spin-orbit splitting energies for the valence band of the $MgGa_2Se_4$ have been estimated to be 190.6 meV and 118.8 meV, respectively, by means of the photocurrent spectra and the Hopfield quasicubic model. These results indicate that the splitting of the ${\Delta}so$ definitely exists in the ${\Gamma}_5$ states of the valence band of the $MgGa_2Se_4$/GaAs epilayer. The three photocurrent peaks observed at 10 K are ascribed to the $A_{1^-}$, $B_{1^-}$exciton for n = 1 and $C_{27}-exciton$ peaks for n = 27.