• Title/Summary/Keyword: 외부혼합

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A Feasibility Study on the Deep Soil Mixing Barrier to Control Contaminated Groundwater (오염지하수의 확산방지를 위한 대체 혼합차수재의 적용에 관한 연구)

  • 김윤희;임동희;이재영
    • Journal of Soil and Groundwater Environment
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    • v.6 no.3
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    • pp.53-59
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    • 2001
  • There is a lot of method to manage the insanitary landfill but vertical cutoff walls have been widespreadly used and were installed into the subsurface to act as a barrier to horizontal groundwater flow, The stabilized material such as specialized cement or mixed soil with additives has been generally applied for the materials of the deep soil mixing barrier in korea. The amount of the stabilized material is dependent on the field conditions, because the mixing ratio of the material and the field soil should achieve a requirement in the coefficient of permeability, lower than 1.0$\times$$10^{7}$cm/sec. This study determined the quantity and optimized function ratio of the stabilized material in the formation process of the mixed barrier that was added with stabilized material on the field soil classified into SW-SC under USCS (Unified Soil Classification System). After that the fly ash and lime were selected as an additives an that could improve the function of the stabilized material and then the method to improve the functional progress in the usage of putting into the stabilized material as an appropriate ratio was studied and reviewed. The author used the flexible-wall permeameter for measuring the permeability and unconfined compressive strength tester for compressive strength, and in the view of environmental engineering the absorption test of heavy metals and leaching test regulated by Korean Waste Management Act were performed. As the results, the suitable mixing ratio of the stabilized material in the deep soil mixing barrier was determined as 13 percent. To make workability easy, the ratio of stabilized material and water was proven to be 1 : 1.5. With the results, the range of the portion of the additives(fly ash : lime= 70 : 30) was proven to be 20-40% for improving the function of the stabilized material, lowering of permeability. In heavy metal absorption assessment of the mixing barrier system with the additives, the result of heavy metal absorption was proved to be almost same with the case of the original stabilized material; high removal efficiency of heavy metals. In addition, the leaching concentration of heavy metals from the leaching test for the environmental hazard assessment showed lower than the regulated criteria.

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Dispersion Characteristics of Carbon Black Particles in a High Viscous Simulated Solution (고점성 모사용액 내 Carbon Black 입자의 분산특성)

  • Jeong, Kyung-Chai;Eom, Sung-Ho;Kim, Yeon-Ku;Cho, Moon Sung
    • Applied Chemistry for Engineering
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    • v.24 no.2
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    • pp.165-170
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    • 2013
  • An external gelation method in place of an internal gelation method applied to the fabrication process of an intermediated compound of Uranium Oxy-Carbide (UCO) kernel spheres for Very High Temperature Reactor (VHTR) fuel preparation is under development in Korea. For the preliminary experiments of the UCO kernel sphere preparation using an external gelation method, the carbon black dispersion experiments were carried out using a simulated broth solution. From the selection experiments of various kinds of carbon black through dispersion experiments in a viscous metal salt solution, Cabot G carbon black was selected owing to its dispersion stability, and the homogeneous dispersing state of carbon black particles in our system. For the effective dispersion of nano-size aggregated carbon black particles in a high viscous liquid, the carbon black particles in a metal salt solution were first de-aggregated with ultrasonic force. The mixed solution was then dispersed secondly by the use of the extremely high-speed agitation with a mechanical mixer of 6000 rpm after feeding the Poly Vinyl Alcohol (PVA) in the solution. This results in the broth solution with good stability and homogeneity alongside no further changes in physical properties.

An Investigative Study on the Characterization of Cefaclor Decomposition in UV/H$_2$O$_2$ Process (UV/H$_2$O$_2$공정에 의한 Cefaclor 분해 특성에 관한 기초연구)

  • Cho, Chun-Ki;Han, Ihn-Sup
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.10
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    • pp.1039-1046
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    • 2008
  • The combining process of UV irradiation and H$_2$O$_2$ was used to investigate characteristics of cefaclor decomposition in the aquatic environment. The separate mixing tank was used to minimize the decreasing effective of contact area caused by sampling. Four baffles were installed inside the UV reactor for the complete mixing of the sample and outside of the reactor was wrapped with aluminum foil to protect the emission of photon energy. Production of OH radical was measured using pCBA(p-Chlorobenzoic acid) indirectly and rate constants were withdrawn pseudo-frist order reaction. Optimum condition for the maximum production of OH radical was found to be pH 3, hydrogen peroxide of 5 mmol/L and recirculation rate of 400 mL/min. Pseudo-frist order reaction rate constant was 0.1051 min$^{-1}$. In the optimum condition, cefaclor was completely decomposed within 40 min and rate constant was 0.093 min$^{-1}$. Decomposition by OH radical producted intermediate anions such as chloride, nitrate, sulfite and acetic acid and phenylglycine. After 6 hr most cefaclor was decomposed by UV/H$_2$O$_2$ process and converted to CO$_2$ and H$_2$O, resulting of operation in the decrease of TOC and acetic acid and the disappearance of phenylglycine.

Effect of Topical Application of Intercellular Lipids on Sodium Lauryl Sulphate-Damaged Skin Barrier Function in Dogs (개에서 sodium lauryl sulphate에 의한 손상 피부에 대한 각질세포간 지질의 국소적용 효과)

  • Hwang, Sun-Jin;Oh, Won-Seok;Ku, Sae-Kwang;Lee, Keun-Woo;Oh, Tae-Ho
    • Journal of Veterinary Clinics
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    • v.25 no.5
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    • pp.330-339
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    • 2008
  • Ceramide, cholesterol and free fatty acids are the major intercellular lipids, maintaining the integrity of the skin barrier. However, the roles of these lipids in canine skin barrier function are little known. The aim of this study was to evaluate the repairing effects of 2% ceramide (CER), 2% cholesterol (CHO), 2% linoleic acid (LIN) and 2% intercellular lipid mixture (ILM) on damaged canine skin barrier by 1.25% sodium lauryl sulphate (SLS). Transepidermal water loss (TEWL), skin hydration, skin pH and skin thickness were assessed. Histological profiles and transmission electron microscopic (TEM) profiles were assessed on day 12. SLS effectively induced the canine skin barrier damage. TEWL was significantly decreased by topical application of CER and ILM in SLS and vehicle-treated skin on day 8 and 12, respectively (p < 0.05, p < 0.0 I). By end of the experiment all lipids significantly decreased the TEWL as compared with SLS and vehicle control, but CER and ILM more significantly decreased the TEWL than UN and CHO, respectively (p < 0.01). Skin hydration was significantly increased by CER and ILM during experimental periods (p < 0.01). Skin pH was significantly decreased by CER, LIN and ILM. In histological profiles, the thickness of the stratum corneum (SC) was significantly increased by the SC lipids as compared with vehicle and SLS (p < 0.01). Especially, CER and ILM showed more prominent improvement of barrier recovery. In TEM of the SC, SLS induced exfoliations of corneodesmosomes in the SC, and CER and ILM effectively protected exfoliations of corneodesmosomes on SLS-damaged canine skin. These results indicated that topical application of CER and ILM dramatically improved damaged-skin barrier function by SLS. Also, it was considered that the use of CER or ILM was recommended for the management of skin barrier dysfunction by irritant and inflammatory skin disorders such as atopic dermatitis.

Analysis of the Characteristics of Water Quality Difference Occurring between High Tide and Low Tide in Masan Bay (만조와 간조시 마산만 수질의 농도차 발생 특성의 분석)

  • Yoo, Youngjin;Kim, Sung Jae
    • Journal of Wetlands Research
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    • v.21 no.2
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    • pp.102-113
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    • 2019
  • Slack-tide sampling was carried out at 6 stations at high and low tide for a tidal cycle during spring tide of the early summer (June) and summer (July, August) of 2016 to determine the difference of water quality according to tide in Masan Bay, Korea. The mixing regime of all the water quality components investigated was well explained through the correlation with SAL. In the early summer and summer, TURB, DSi and NNN which mainly flow into the bay from the streams and SS, COD, AMN and $H_2S$ which mainly indicate the internal sink and source materials have a property of conservative mixing and non-conservative mixing, respectively. The conservative mixing showed a good linear relationship of the water quality between high and low tide, and the non-conservative mixing showed a variation of different pattern each other. Factor analysis performed on the concentration difference data sets between high and low tide helped in identifying the principal latent variables for them. In early summer, multiple effects (tidal action, natural influx and internal sinks and sources etc.) acted in combination for the differences to be distributed evenly in four factors (VF1~4), since there were few allochthonous inputs as a low-water season. On the contrary, in summer, the parameters showing large concentration difference at ST-1 affected by stream water were concentrated in one factor (VF1) and clearly distinguished from the parameters affected by the internal sinks and sources. In fact, there is no estuary (bay) that always maintains steady state flow conditions. The mixing regime of an estuary might be changed at any time due to the change of flushing time, and furthermore the change of end-member conditions due to the internal sinks and sources makes the occurrence of concentration difference inevitable. Therefore, when investigating the water quality of the estuary, it is necessary to take a sampling method considering the tide to obtain average water quality data.

The Design of Digital Audio Interpolation Filter for Integrating Off-Chip Analog Low-Pass Filter (칩 외부의 아날로그 저역통과 필터를 집적시키기 위한 디지털 오디오용 보간 필터 설계)

  • Shin, Yun-Tae;Lee, Jung-Woong;Shin, Gun-Soon
    • Journal of IKEEE
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    • v.3 no.1 s.4
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    • pp.11-21
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    • 1999
  • This paper has been proposed a structure composed of FIRs and IIR filters as digital interpolation filter to integrate the off-chip analog low-pass filter of audio DAC. The passband ripple (>$0.41{\times}fs$), passband attenuation(>at$0.41{\times}fs$) and stopband attenuation(<$0.59{\times}fs$) of the ${\Delta}{\Sigma}$ modulator output using the proposed digital interpolation filter had ${\pm}0.001[dB]$, -0.0025[dB] and -75[dB], respectively. Also the inband group delay was 30.07/fs[s] and the error of group delay was 0.1672%. Also, the attenuation of stopband has been increased -20[dB] approximately at 65[kHz], out-of-band. Therefore the RC products of analog low-pass filter on chip have been decreased compared with the conventional digital interpolation filter structure.

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A Comparison between Various CFD Solvers for Analysis on Thermal Load in Smart Farm(Fluent, Open-FOAM, Blender) (스마트팜 열부하 분석을 위한 CFD 해석 도구 비교)

  • Lee, Jun-Yeob;Oh, Jong-woo;Lee, DongHoon
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2017.04a
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    • pp.170-170
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    • 2017
  • 기후변화 따른 스마트팜 돈사 외부 환경의 변화에 대응하고, 사육 환경을 능동적으로 개선하기 위한 연구가 수행 중이다. 돈사 내 열전달 요소 간 상호 역학성 분석을 위해서 고려해야할 사항은 입기구, 보온 등, 열풍기, 단열제, 위치, 방향, 돈사의 연평균 온도, 습도, 연중 일사량, 가축의 열복사 등 상호 복잡하게 연관되어 있는 물리량이다. 돈사 전체 열손실, 자연발생 에너지량, 강제발생 에너지량, 난방용량 등을 고려한 순간 열부하 산정을 위한 여러 방법 중 우선적으로 CFD(Computational Fluid Dynamics)를 이용하였다. 순간 열부하 산정을 위한 해석 도구 선정에 있어서 다양한 유체 및 기체 전산 유체역학 Solver(Fluent, Open-FOAM, Blender)를 고려하였다. 공간 Mech를 수행하기 위한 도구로는 공개 소프트웨어 인 FreeFem++ 3.51-4 (http://www.freefem.org)를 이용하였다. 이 과정에서 일부 기체 (암모니아)의 농도를 난수로 변화시키는 기법을 적용하여 가상적으로 돈사의 환경을 Pseudo 시뮬레이션 하였다. 결과적으로 Fluent에 비하여 OpenFOAM을 이용하여 얻은 열유동의 방향(속도)과 크기 백터가 상대적으로 크게 나타났다. Fluent가 시계열 상에서 혼합 기체 물리량 변화를 무시할 수 있는 안정되고 균일한 환경에 적합하기 때문인 것으로 판단되었다. Blender의 경우 Lattice Boltzmann methods 과 Smoothed-particle hydrodynamics 방법을 이용한 유체/입자 동력학 모델링을 제공함에 있어 시각적 효과를 강조하는 기능에 중점을 두었다. Fluent와 Blender에서 제공하는 해석 연산 모듈의 정확성 검증을 위해선 공간 분해능을 높인 정밀 계측 시스템을 이용하여 검증할 필요가 있다. Open-FOAM를 이용한 열부하 분석 수행이 상대적으로 높은 절대값을 보이는 특성은 열부하 제어 시스템의 Overshoot를 유발할 가능성이 있으므로 이에 대한 해석 모델의 보정이 추가적으로 필요할 것이다. CFD의 한계인 시간 복잡도를 낮추고 상대적으로 높은 시계열 분해능을 확보할 경우 돈사 내 환기시스템에 맞는 소요 환기량 실시간 산정이 가능해지고 외부기상 및 돈사내부 복사열을 활용함과 동시에 돈군 순환에 상응하는 실시간 열부하 관리 시스템 도출이 가능할 것이다.

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Modeling and Theoretical Analysis of Thermodynamic Characteristic of Nano Vibration Absorber (나노 진동 흡수기의 모델링 및 열역학적 특성 해석에 대한 이론적 연구)

  • 문병영;정성원
    • Journal of the Earthquake Engineering Society of Korea
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    • v.7 no.6
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    • pp.93-99
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    • 2003
  • In this study, new shock absorbing system is proposed by using nano-technology based on the theoretical analysis. The new shock absorbing system is complementary to the hydraulic damper, having a cylinder-piston-orifice construction. Particularly for new shock absorbing system, the hydraulic oil is replaced by a colloidal suspension, which is composed of a porous matrix and a lyophobic fluid. The matrix of the suspension is consisted of porous micro-grains with a special architecture: they present nano-pores serially connected to micro-cavities. Until now, only experimentally qualitative studies of new shock absorbing system have been performed, but the mechanism of energy dissipation has not been clarified. This paper presents a modeling and theoretical analysis of the new shock absorbing system thermodynamics, nono-flows and energy dissipation. Compared with hydraulic system, the new shock absorbing system behaves more efficiently, which absorb a large amount of mechanical energy, without heating. The theoretical computations agree reasonably well with the experimental results. As a result. the proposed new shock absorbing system was proved to be an effective one, which can replace with the conventional one.

Kinetic Study on the Immobilized Penicillin Amidase in a Differential Column Reactor (Differential column reactor에 있어서 고정화페니실린 아미다제의 반응속도론에 관한 연구)

  • Park, Jong-Moon;Park, Cha-Yong;Seong, Baik-Lin;Han, Moon-Hi
    • Microbiology and Biotechnology Letters
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    • v.9 no.3
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    • pp.165-171
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    • 1981
  • The penicillin amidase from Escherichia coli (ATCC 9637) was immobilized by entrappment in gelatin and DEAE-cellulose mixture cross-linked with glutaraldehyde, and the kinetics in a differential column reactor was studied. The optimal operating condition of a differential reactor was reasonably met when the enzyme loading was 1g, and 30 mM substrate solution in 0.1 M phosphate buffer (pH 8.0) was fed at flow rate 4$m\ell$/min and 4$0^{\circ}C$. The optimal pH and temperature were found to be 8.0 and 55$^{\circ}C$, respectively. The Michaelis-Menten constant was 4.8 mM while the maximum velocity was 308 units/g of the immobilized enzyme under the condition of the differential reactor. The effect of substrate inhibition disappeared in the immobilized enzyme preparation. The differential reactor was proved to be good for studying the true kinetics since the pH drop and the external diffusional resistance could be eliminated.

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Simultaneous Determination of Tryptophan and Tyrosine by Spectrofluorimetry Using Multivariate Calibration Method (다변량 분석법을 이용한 Tryptophan과 Tyrosine의 형광분광법적 정량)

  • Lee, Sang-Hak;Park, Ju-Eun;Son, Beom-Mok
    • Journal of the Korean Chemical Society
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    • v.46 no.4
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    • pp.309-317
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    • 2002
  • A spectrofluorimetric method for the simultaneous determination of amino acids (tryptophan and tyrosine) based on the application of multivariate calibration method such as principal component regression and partial least squares (PLS) to luminescence measurements has been studied. Emission spectra of synthetic mixtures of two amino acids were obtained at excitation wavelength of 257 ㎚. The calibration model in PCR and PLS was obtained from the spectral data in the range of 280-500 ㎚ for each standard of a calibration set of 32 standards, each containing different amounts of two amino acids. The relative standard error of prediction ($RSEP_a$) was obtained to assess the model goodness in quantifying each analyte in a validation set. The overall relative standard error of prediction ($RSEP_m$) for the mixture obtained from the results of a validation set, formed by 6 independent mixtures was also used to validate the present method.