• Economic and Environmental Geology
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• v.39 no.1 s.176
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• pp.63-74
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• 2006

In order to identify the Pb pollution and its sources in continental shelf and slope areas, Pb concentration and Pb isotope ratios ($^{207}Pb/^{206}Pb\;and\;^{208}Pb/^{206}Pb$) were determined far 6 box corer sediments collected from the southern East/japan Sea. Pb concentration, and $^{207}Pb/^{206}Pb\;and\;^{208}Pb/^{206}Pb$ ratios were constant at around $25\pm5 ppm$ and 0.842 and 2.092 from 1700 to 1930 year, respectively and increased steadily up to $40\pm5 ppm$ and 0.867 and 2.123 at the beginning of 1990s', respectively. The increase of concentration and isotope ratios in the labile fraction (leached by 2M HC1+0.5M $HNO_3$) explains their increase in bulk sediments, while Pb concentration and isotope ratios in the residual fraction were nearly constant during 300yrs. Temporal variation of Pb isotope ratios was explained by simple two end-members mixing of geo-genic and anthropogenic sources because isotope ratios and the inverse of Pb concentration showed the good linear relationships. Using Pb isotope ratios, we can constrain two Pb sources in the study area. The one is atmospheric particulates, compared with mean values of isotope ratios in atmospheric particulates collected at Jeju and Oki ;stands, based on the history of Pb emmission in Korea and China, and judged by oceanographic processes capable of homogenizing many sources. The other is local sources related to iron mills, refineries of Pb ore and of petroleum located at the coast of the study area. Isotope ratios of anthropogenic Pb can be estimated using two end-members mixing equation and were $0.879\pm0.005\;and\;2.144\pm0.008$ before 1950s' while they increased up to $0.900\pm0.008\;and\;2.162\pm0.011$ after 1980s', respectively.

• Korean Journal of Remote Sensing
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• v.36 no.2_1
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• pp.121-137
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• 2020

Data from the Ozone Monitoring Instrument (OMI) satellite and national emission inventories were used in this study to analyze air quality in East Asia and estimate the impact of domestic and foreign emissions on South Korea's air quality, based on which future emissions were predicted. The concentration trends of nitrogen dioxide (NO₂) and sulfur dioxide (SO₂) in East Asia from 2005 to 2015 showed that both substances were highest in North East China (NEC), followed by South East China (SEC) and Seoul Metropolitan Area (SMA). The average SO₂ concentration was 1.63 times higher in NEC than in SMA. Analysis on the ratios of NO₂/SO₂ and NO_x/SO_x provides an indirect picture of the effect of transboundary air pollutants on atmospheric composition in Korea. The concentration ratio of NO₂/SO₂ in all study areas peaked in 2013 and SMA's emission ratio of NO_x/SO_x increased in 2015 by over 22% from 2013. Despite the reduction in domestic emissions, the concentration-to-emission ratios (NO₂/NO_x, SO₂/SO_x) rose gradually, which implies that other factors besides domestic emissions (e.g., foreign sources, lifetime, etc.) influence air quality in SMA. We estimated future emissions of NO_x and SO_x in SMA to be 296.2 and 39.0 ktons in 2025 and 284.4 and 33.8 ktons in 2035, respectively. Application of the inter-comparison techniques of this study to the data from the Geostationary Environment Monitoring Instrument (GEMS) is expected to provide concrete information which can be used to improve national emission inventories and figure out factors and sources that affect domestic air quality.

• Korean Journal of Environmental Agriculture
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• v.26 no.3
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• pp.233-238
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• 2007

To assess pollutant loads in Nakdong river from highland agriculture in Kyungbuk province we. analyzed water qualities such as BOD, COD, T-N, T-P and SS in year 2005. BOD values in rainy period (June and July) were relatively higher than those in dry period, and those in 4 sites among 17 sites ranged from 10.71-19.25 mg/L which exceeded water criteria (8 mg/L) for agricultural use. COD values showed similar trends like BOD values. These trends might be caused by outflow of nutrients applied in agricultural lands. T-N content ranged from 0.1 to 14 mg/L. Those in lower reaches of stream were greater in those in upper stream. Compared to T-N contents during non-farming season, T-N content in farming season were higher. These phenomenon could be due to continuous input of nutrients from small watercourses. Averaged T-P content in lower stream during farming season was 0.4 mg/L, which was eight times higher than the limiting level for algae occurrence (0.05 mg/L). BOD, T-P, T-N loads from alpine agricultural practices were 12.25 $kg/km^2{\cdot}day$, 0.55 $kg/km^2{\cdot}day$ and 32.35 $kg/km^2{\cdot}day$, respectively. These values were greater than those from forestry. Therefore, Best management Practices (BMP) for alpine agricultural field are needed to reduce pollutant loads in Nakdong river.

• Korean Journal of Microbiology
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• v.53 no.2
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• pp.83-96
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• 2017

A constructed sea stream in Yeongdo, Busan, Republic of Korea is mostly static due to the lifted stream bed and tidal characters, and receives domestic wastewater nearby, causing a consistent odor production and water quality degradation. Bioaugmentation of a microbial consortium was proposed as an effective and economical restoration technology to restore the polluted stream. The microbial consortium activated on site was augmented on a periodic basis (7~10 days) into the most polluted site (Site 2) which was chosen considering the pollution level and tidal movement. Physicochemical parameters of water qualities were monitored including pH, temperature, DO, ORP, SS, COD, T-N, and T-P. COD and microbial community analyses of the sediments were also performed. A significant reduction in SS, COD, T-N, and COD (sediment) at Site 2 occurred showing their removal rates 51%, 58% and 27% and 35%, respectively, in 13 months while T-P increased by 47%. In most of the test sites, population densities of sulfate reducing bacterial (SRB) groups (Desulfobacteraceae_uc_s, Desulfobacterales_uc_s, Desulfuromonadaceae_uc_s, Desulfuromonas_g1_uc, and Desulfobacter postgatei) and Anaerolinaeles was observed to generally decrease after the bioaugmentation while those of Gamma-proteobacteria (NOR5-6B_s and NOR5-6A_s), Bacteroidales_uc_s, and Flavobacteriales_uc_s appeared to generally increase. Aerobic microbial communities (Flavobacteriaceae_uc_s) were dominant in St. 4 that showed the highest level of DO and least level of COD. These microbial communities could be used as an indicator organism to monitor the restoration process. The alpha diversity indices (OTUs, Chao1, and Shannon) of microbial communities generally decreased after the augmentation. Fast uniFrac analysis of all the samples of different sites and dates showed that there was a similarity in the microbial community structures regardless of samples as the augmentation advanced in comparison with before- and early bioaugmentation event, indicating occurrence of changing of the indigenous microbial community structures. It was concluded that the bioaugmentation could improve the polluted water quality and simultaneously change the microbial community structures via their niche changes. This in situ remediation technology will contribute to an eco-friendly and economically cleaning up of polluted streams of brine water and freshwater.

• Clean Technology
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• v.17 no.4
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• pp.306-313
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• 2011

Flux or solder is used in soldering process for manufacturing electronic parts such as printed circuit boards (PCB). After soldering process, residual flux and solder paste on the parts should be removed since their residuals could cause performance degradation or failure of parts due to their corrosion and electric leakage. Ozone depletion substances such as 1,1,1- trichloroethane (TCE) and HCFC-141b have widely been using for removal of residual flux and solder paste after soldering process In manufacturing of electronic parts until now. In this study, non-aqueous cleaning agents without flash point were developed and applied to industrial field for replacement of cleaning agents with ozone depletion. In order to develop non-aqueous cleaning agents without ethers, esters, fluoride- type solvents. And their physical properties and cleaning abilities were evaluated, and they were applied to industrial fields for cleaning of flux and solder on the PCB. And vacuum distillation apparatus were operated to determine their operating conditions and recycling yields for recycling of used cleaning agents formulated in this study. As a result of physical properties measurement of our formulated cleaning agents, they were expected to have good wetting and penetrating power since their surface tensions were relatively low as 18.0~20.4 dyne/$cm^2$ and their wetting indices are relatively large. And some cleaning agents holding fluoride-type solvents as their components did not have any flash point and they seemed to be safe in their handling and storage. The cleaning experimental results showed that some cleaning agents were better in their cleaning of flux and solder paste than 1,1,1-TCE and HCFC-141b. And industrial application results of the formulated cleaning agents for cleaning PCB indicated that they can be applicable to industry due to their good cleaning capability in comparison with HCFC-141b. The recycling experiments of the used formulated cleaning agents through a vacuum distillation apparatus also showed that their 91.9~97.5% could be recycled with its proper operating conditions.

• Korean Journal of Soil Science and Fertilizer
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• v.29 no.4
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• pp.432-438
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• 1996

This study was carried out to prepare information for the establishment of countermeasures for an area contaminated with minewaste from an old zinc mine at Kahak-long in Kwangmyong. Minewaste and bottom sediments from the streams in this area were sampled and were analyzed for Cd, Cu, Pb, and Zn extracted with different solution. Total heavy metal contents in both minewaste and bottom sediments were fairly high. Cadmium and Zn contents in the minewaste and Cd, Cu, Pb, and Zn contents in the bottom sediments extracted with 0.1 N HCl showed a much higher level than those in the background level of paddy soils and in the soils around the other metal mines regardless of the distance from the mine. Sulfide/residue forms of Cd, Cu, Pb, and Zn covered the highest portions for the minewaste. For bottom sediments, sulfide/residue forms of Cu and Zn formed the highest portions, whereas the contents of both carbonate and sulfide/residue forms of Cd and Pb were significant. The lower the pH of the extracting solutions, the more heavy metals extracted from both minewaste and bottom sediments.

• Journal of Wetlands Research
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• v.22 no.1
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• pp.49-58
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• 2020

The excessive use of fertilizer and compost in agricultural land increases the accumulation of nutrients in soil. The surplus nutrients in soil transported through surface and sub-surface flow can lead to water pollution problems and algal bloom. Moreover, nutrient accumulation and continuous crop cultivation changes the physical structure of the soil, which increases the potential of nutrient. The cultivation in the Daecheong Lake reservoir area may have a direct effect on the lake's water quality due to leaching and releasing of nutrients when water level rises. This research was carried out to analyze the physical and chemical properties of soil in the agricultural areas surrounding Daecheong Dam reservoir to provide basic data available for the establishment of Daecheong Lake water quality management measures. The soil of the Daecheong Lake reservoir was classified as sandy Loam, where surplus nutrients can be transported. Chemical compositions in the soil were found to be significantly affected by use of different fertilizer amounts. Nutrient outflow occurred during spring rainfall events from the rice paddy fields, whereas excess nutrients from summer to fall seasons originated from dry paddy fields. Nutrient outflow from dry paddy fields is mainly from sub-surface flow. Organic agricultural wastes from agricultural land and excessive vegetation inside the river was also evaluated to contribute to the increase in organic matter and nutrients of the river. The results can be used to select the priority management area designation and management techniques in the Daecheong Lake for water quality improvement.

• Journal of Soil and Groundwater Environment
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• v.6 no.2
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• pp.3-13
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• 2001

It has been known that nonlinear characteristics of sorption affect the transport behavior of water soluble pollutants in soils. However detailed experimental studies have not been performed to verify the effect of non-linearity of adsorption isotherm on transport of chemicals in porous media. In this research, the distortion of breakthrough curves of a cationic surfactant (cetylpyridinium chloride, CPC) in a engineered stainless steel column packed with glass beads were investigated. Glass beads with about 110 $\mu\textrm{m}$diameter coated with a thin n-decane film were used as the media providing the sorption surface for CPC. The CPC adsorption isotherm on the surface of n-decane from aqueous solution was a typical Langmuir type. The breakthrough curve of CPC using step Input showed a late breakthrough on the front side and early breakthrough on the back side accordance to the shape of the isotherm. The retardation factor of CPC was found to be a strong function of the input concentration, which also a manifestation of the non-linearity of the isotherm. The retardation factors for the CPC with step input agreed with those of pulse input that the maximum concentrations are controlled to be the same as the step input concentrations. This results support the validity of the unproven field practices of using hydrogeotracers with non-linear adsorption isotherms to determine the hydrogeological parameters, e.g., NAPL saturation, air-water or NAPL-water interfacial areas.

• Journal of Wetlands Research
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• v.21 no.spc
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• pp.1-8
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• 2019

River works for water utilization have substantially altered the natural flow regime, and it has resulted in deformation of healthy river ecosystems. In Korea, river restoration projects have conducted actively since 1990's. Major purposes of the river restoration are the rehabilitation of modified river channel, improvement of water quality, and creation of aquatic habitats as well as recreational spaces using natural material for river work. However, there have been little interests about the restoration of flow regime which influences to most aspects of river ecosystems. The restoration of natural flow regime has received much attention in preservation of aquatic ecosystems. It should be needed to explore the relationship between flow regime and river ecosystems, and the restoring flow regime is essential. This paper introduce the concept of environmental flow through the interrelation between flow regime and river ecosystem. It provides rolls of flow regime and addresses the method of establishing target flow regime using the RVA(Range of Variability Approach) that suggested by Richter et al.(1997) through analysis of altered flow pattern case of Han river basin.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.6
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• pp.626-633
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• 2006

Bucheon city has been rapidly urbanized and steadily enlarged. Also, the city depends on groundwater as an alternative water resource. The objective of this study is to characterize the hydrogeology in this city including the recharge of groundwater and hydraulic property of an aquifer in order to investigate the chemical characteristics and contamination of groundwater in the Bucheon area. Eleven groundwater wells in the Bucheon area were selected for applying certain hydraulic tests, such as pumping and recovery tests. Theis method and Theis recovery method were used to obtain hydraulic parameters, such as hydraulic conductivity, transmissivity by applying recovery tests. The playground of school and uncovered areas layed a major function of recharging areas. The groundwater well in these areas showed high recharge, transmissivity, and hydraulic conductivity. In a downtown area, groundwaier wells showed low pumping capacity and hydraulic parameters. Groundwater samples were collected from 48 different locations in the Bucheon area and that showed very various chemical composition in groundwater Their electrical conductivity showed various ranges from 70.4 to $1,287{\mu}S/cm$. The composition more significantly affected the groundwater due to the land use and urbanization than that of the aquifer rock type.