• Title/Summary/Keyword: 오염물질

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Long-term Trend Analysis of Key Criteria Air Pollutants over Air Quality Control Regions in South Korea using Observation Data and Air Quality Simulation (관측자료와 대기질 모사를 이용한 주요 기준성 대기오염물질의 권역별 장기변화 분석)

  • Ju, Hyeji;Kim, Hyun Cheol;Kim, Byeong-Uk;Ghim, Young Sung;Shin, Hye Jung;Kim, Soontae
    • Journal of Korean Society for Atmospheric Environment
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    • v.34 no.1
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    • pp.101-119
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    • 2018
  • In this study, we analyzed long-term measurements and air quality simulation results of four criteria air pollutants ($PM_{10}$, $O_3$, $NO_2$, and $SO_2$) for 10 years, from 2006 to 2015, with emphasis on trends of annual variabilities. With the observation data, we conducted spatial interpolation using the Kriging method to estimate spatial distribution of pollutant concentrations. We also performed air quality simulations using the CMAQ model to consider the nonlinearity of the secondary air pollutants such as $O_3$ and the influence of long-range transport. In addition, these simulations are used to deduce the effect of long-term meteorological variations on trends of air quality changes because we fixed the emissions inventory while changing meteorological inputs. The nation-wide inter-annual variability of modeled $PM_{10}$ concentrations was $-0.11{\mu}g/m^3/yr$, while that of observed concentrations was $-0.84{\mu}g/m^3/yr$. For the Seoul Metropolitan Area, the inter-annual variability of observed $PM_{10}$ concentrations was $-1.64{\mu}g/m^3/yr$ that is two times rapid improvement compared to other regions. On the other hand, the inter-annual variability of observed $O_3$ concentrations is 0.62 ppb/yr which is larger than the simulated result of 0.13 ppb/yr. Magnitudes of differences between the modeled and observed inter-annual variabilities indicated that decreasing trend of $PM_{10}$ and increasing trend of $O_3$ are more influenced by emissions and oxidation states than meteorological conditions. We also found similar patterns in $NO_2$. However, $NO_2$ trends showed greater regional and seasonal differences than other pollutants. The analytic approach used in this study can be applicable to estimate changes in factors determining air quality such as emissions, weather, and surrounding conditions over a long term. Then analysis results can be used as important data for air quality management planning and evaluation of the chronic impact of air quality.

Long-term Trend Analysis of Korean Air Quality and Its Implication to Current Air Quality Policy on Ozone and PM10 (국내 기준성 대기오염물질의 권역별 장기 추이 및 원인 분석: PM10과 오존을 중심으로)

  • Kim, Jeonghwan;Ghim, Young Sung;Han, Jin-Seok;Park, Seung-Myung;Shin, Hye-Jung;Lee, Sang-Bo;Kim, Jeongsoo;Lee, Gangwoong
    • Journal of Korean Society for Atmospheric Environment
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    • v.34 no.1
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    • pp.1-15
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    • 2018
  • Nation-wide systematic and comprehensive measurements of air quality criteria species have been made over 340 sites currently in Korea since 1990. Using these data, temporal and spatial trends of $SO_2$, $PM_{10}$, $NO_2$, $O_3$, CO and $O_x(NO_2+O_3)$ were analyzed to characterize and evaluate implementing efficiency of air quality policy and regulations. Due to strict and effective policy to use cleaner fuels in late 1980s and 1990s, the primary pollutants, such as $SO_2$, CO, and $PM_{10}$ decreased sharply by early 2000s in all parts of Korea. After this period, their concentrations declined with much lower rates in most parts of Korea. In addition, isolated but noticeable numbers of places, especially in major ports, newly developing towns and industrial parks, sustained high levels or even showed further degradation. Despite series of emission control strategies were enforced since early 1990s, $NO_2$ concentrations haven't changed much till 2005, due to significant increase in number of automobiles. Nevertheless, we confirmed that the staggering levels of $NO_2$ and $PM_{10}$ improved evidently after 2005, especially in Seoul Metropolitan Area (SMA), where enhanced regulations for $NO_2$ and $PM_{10}$ emissions was imposed to automobiles and large emission sources. However, their decreasing trends were much lessened in recent years again as current air quality improvement strategies has been challenged to revise further. In contrast to these primary species, annual $O_3$, which is secondary product from $NO_2$ and volatile organic compounds (VOCs), has increased consistently with about 0.6 ppbv per year in every urban part of Korea, while yearly average of daily maximum 8-hour $O_3$ in summer season had a much higher rate of 1.2 ppbv per year. Increase of $O_3$ can be explained mainly by reductions of NO emission. Rising background $O_3$ in the Northeast Asia and increasing oxidizing capacity by changing photochemistry were likely causes of observed $O_3$ increase. The future air quality policy should consider more effective ways to lower alarming level of $O_3$ and $PM_{10}$.

A Study on Mechanical Characteristics of Fiber Modified Emulsified Asphalt Mixture as Environmentally-Friend Paving Material (섬유보강 친환경 상온아스팔트 혼합물의 역학적 특성에 관한 연구)

  • Rhee Suk-Keun;Park Kyung-Won
    • International Journal of Highway Engineering
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    • v.8 no.2 s.28
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    • pp.23-30
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    • 2006
  • Emulsified Asphalt Mixture(EAM) is more environmentally-friendly and cost-effective than typical Hot Mix Asphalt (HMA) because EAM does not produce carcinogenic substances, e.g., naphtha, kerosene, during the both of manufacturing and roadway construction process. Also, it does not require heating the aggregates and asphalt binder. However, EAM has some disadvantages. Generally EAM has a less load bearing capacity and more moisture susceptibility than conventional HMA. The study evaluated a Fiber modified EAM (FEAM) to increase load bearing capacity and to decrease moisture susceptibility of EAM. Modified Marshall mix design was developed to find Optimum Emulsion Contents (OEC), Optimum Water Contents (OWC), and Optimum Fiber Contents (OFC). A series of test were performed on the fabricated specimen with OBC, OWC, and OFC. Tests include Marshall Stability, Indirect Tensile Strength, and Resilient modulus test. Comparison analyses were performed among EAM, Fiber modified EAM (FEAM), and typical HMA to verify the applicability of EAM and FEAM in the field. Test results indicated that both of EAM and FEAM have an enough capability to resist medium traffic volume based on the Marshall mix design criteria. Also the study found that fiber modification is effective to increase the load bearing capacity and moisture damage resistance of EAM.

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Bacterial Productivity and Degradability of Organic Compounds in the Coastal Area of East Sea (동해 연안역의 박테리아 생산력과 유기물질의 분해능)

  • 이기성;고동규;김근호;이영근;최청일;최영길
    • Korean Journal of Environmental Biology
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    • v.17 no.1
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    • pp.59-69
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    • 1999
  • Bacterial population, signal compounds of pollution, bacterial productivity, heterotrophic activity and the activities of extracellular enzymes were analyzed four times from July 1994 to April 1995 at Daejin, Galnam, Pohang, and Ulsan in the coastal area of Bast Sea in order to investigate the state of eutrophication. The population of heavy metal resistant bacteria in Pohang was the highest among all stations. The bacterial populations which could utilize C -P compounds (phosphonate) showed the highest at Pohang that was expected for the industrial and agricultural effluents to inpour. It could be useful as an index of expectation about the influx of industrial sewages and agricultural effluents. The activities of extracellular enzymes for the degradation of organic matter were the highest in the Ulsan Chuyongam, but low in Daejin. These results showed positive relationship with the population of heterotrophic bacteria and bacterial productivity The ratio of poly-P and DNA in Pohang was the highest, and that in Ulsan, Galnam, and Daejin consecutively, corresponding with the distribution of heterotrophic bacteria. In case of the heterotrophic activities, each of the stations gives difference of seasonal variation in heterotrophic activities. Bacterial productivity seemed to be dependent on seasons; the highest in summer and the lowest in fall and winter. These seasonal variations of bacterial productivity seems to be similar with those of heterotrophic bacteria. It is suggested that the state of eutrophication could be evaluated by the criteria of the population sizes and the productivities of microorganisms, the amount of poly-P, heterotrophic activity, the activities of extracellular enzymes, etc.

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Study on Design Technology of Heat Pump Cycle for High Temperature Performance (고온 생산용 열펌프 사이클 설계)

  • Kim, Jong-Ryul;Kim, Seok-Young;Kim, Yong-Min;Lee, Kong-Hoon;Kim, Ook-Joong;Yi, Sung-Chul;Jung, Chi-Young;Kim, Jong-Ryeol
    • Journal of Energy Engineering
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    • v.19 no.4
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    • pp.228-233
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    • 2010
  • About 55% of total energy is consumed in the industrial division. The industrial heat pump application will show magnificent energy saving effect as well as higher cost efficiency because of larger energy consuming volume of each facility and longer operation hour and higher stability against seasonal temperature change. Over 90% of dryer for industrial usage has hot wind heat source and hot wind dryer is the representative type covering 68.7% while its 30 ~ 50% lower heat efficiency causes lots of energy loss by exhaust air. Re-usage of exhaust air can improve energy efficiency of dryer because 68% heat energy or 78% of hot air lose in exhaust air. Therefore, high temperature heat pump dryer can be the best alternative. Comparing to the existing dryer with 30% ~ 50% energy efficiency, newly developing high temperature heat pump dryer will enhance energy efficiency up to 60% ~ 80% efficiency. In this paper, heat pump system for high temperature was designed, constructed and tested. The results have shown that system COPh is estimated as 3.3.

The characteristics of discharged non-point pollutants on Hwa-sung lake inflow streams on precipitation (화성호 유입하천의 강우시 비점오염물질 유출특성)

  • Lee, Sang Eun;Choi, I Song;Lee, In Ho;Hong, Dae Byuk;Oh, Jong Min
    • Journal of Environmental Impact Assessment
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    • v.20 no.5
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    • pp.651-661
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    • 2011
  • The purpose of this study is to estimate the characteristics and pollutant loadings of non-point pollutants that flowed in the streams on precipitation for pollutant loading reduction of Hwa-sung lake inflow streams. Although it has been made an effort to improve the water quality of Hwa-sung basin through the strategies for the preservation of water quality, it is shown that the water quality is not greatly improved. Because it has been industrialized and urbanized near Hwa-sung basin so that it is difficult to reduce the water pollution due to the increase in pollutant loadings of point and non-point sources. In this study, it is investigated the outflow characteristics of non-point pollutants that discharged with storm runoff and estimated the effect of runoff on Hwa-sung basin. The final goal of this study is to utilize the basic information for proper management and strategies of non-point sources on Hwa-sung basin. At the result of inflow streams, Ja-an stream that has the greatest pollutant loadings on precipitation is strongly influenced on the water quantity of Hwa-sung basin. On the other hand, it is shown that Nam-yang stream is strongly influenced on the SS concentration of Hwasung basin among them. Also, all streams; Nam-yang, Ja-ahn, Ah-eun stream; has the degree of slope more than or near 1 in the correlation results so that they have strong pollutant loading impact and the concentration of SS is the highest among other pollutants. So, specific studies on initial rain phenomena are more necessary to manage the pollutants economically. Also, the proper control of SS concentration is required to manage the effluent pollutants effectively on precipitation. So, it is necessary to consider the strategies for non-point pollutants as well as point pollutants when the new management is imposed to reduce the pollutant load for improvement of Hwa-sung basin.

A Review on the Current Methods for Extracting DNA from Soil and Sediment Environmental Samples (토양 및 퇴적토 환경 시료로부터 DNA 추출하는 방법에 대한 고찰)

  • Yoo, Keun-Je;Lee, Jae-Jin;Park, Joon-Hong
    • Journal of Soil and Groundwater Environment
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    • v.14 no.3
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    • pp.57-67
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    • 2009
  • In soil and sediment environment, microorganisms play major roles in biochemical cycles of ecological significant elements. Because of its ecological significance, microbial diversity and community structure information are useful as indexes for assessing the quality of subsurface ecological environment and bioremediation. To achieve more accurate assessment, it is requested to gain sufficient yield and purity of DNA extracted from various soil and sediment samples. Although there have been a large number of basic researches regarding soil and sediment DNA extraction methods, little guideline information is given in literature when choosing optimal DNA extraction methods for various purposes such as environmental ecology impact assessment and bioremediation capability evaluation. In this study, we performed a thorough literature review to compare the characteristics of the current DNA extraction methods from soil and sediment samples, and discussed about considerations when selecting and applying DNA extraction methods for environmental impact assessment and bioremediation capability evaluation. This review suggested that one approach is not enough to gain the suitable quantity and yield of DNA for assessing microbial diversity, community structure and population dynamics, and that a careful attention has to be paid for selecting an optimal method for individual environmental purpose.

Water Quality Improvement of Pocheon Stream Using Freshwater Bivalves: Development and Operation of Continuous Removal of Organic Matter in Streams (S-CROM) (포천천 수질개선을 위한 패류의 이용 하천형 유기물 제어(S-CROM) 기술의 적용)

  • Kim, Baik-Ho;Lee, Ju-Hwan;Kim, Yong-Jae;Hwang, Su-Ok;Hwang, Soon-Jin
    • Korean Journal of Ecology and Environment
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    • v.42 no.3
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    • pp.317-330
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    • 2009
  • To diminish the levels of organic matters, a novel S-CROM (continuous removal of organic matters in the stream system using freshwater bivalve), was developed and applied to the polluted stream discharging from the wastewater treatment plant, Pocheon stream, Pocheon city (Korea). Major pollutants of the stream were human population and industrial wastewaters. The study was conducted at a small dam constructed within the stream, often called 'bo', and designed with four tanks; no mussels and no sediment (negative control), no mussels and sediment (positive control), 30 mussels and sediment (D1), and 60 mussels and sediment (D2). Physicochemical and biological parameters were measured at 12 hours interval (day and night) after mussel stocking. Results indicated that Anodonta woodiana Lea (D2) clearly removed approximately 72% of chl-$\alpha$ and 57% of suspended solids on second day, however, there were no differences in removal activities between animal densities (P>0.5). Dislike a laboratory CROM system, which previously developed, there were no huge release of nutrient ($NH_3$-N and SRP), due perhaps to the higher flow rate and the lower animal density. Therefore, we may suggest that if we can determine the relevant current and the animal density considering the stream state, an S-CROM system has a strong potential to water quality improvement of eutrophic streams. Some characteristics on both CROM and S-CROM were compared.

Quality Evaluations of Seasoning Chicken Containing Pine Needles During Cold Storage (솔잎 닭고기 양념육의 냉장동안 품질평가)

  • Kim, Chang-R.;Kim, Kwang-H.
    • Food Science of Animal Resources
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    • v.27 no.1
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    • pp.47-52
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    • 2007
  • Quality evaluations of seasoning chicken wing treated with pine needles during storage of 6 days at $4^{\circ}C$ were assessed. Seasoning chicken containing 0.5-1.3% (w/w) pine needle during storage at $4^{\circ}C$ was allowed to the growth of Staphylococcus aureus. pH values of seasoning chicken containing pine needles after 6 days of storage were not significantly different (p>0.05) than those of the controls. The rate of drip loss on seasoning chicken containing pine needles after 24 hr of storage was significantly different (p<0.05) than that of the controls. Sensory scores of seasoning chicken containing 0.8-1.3% pine needles for odor and flavor were in the "liked more" to typical category during storage of 6 days at $4^{\circ}C$. For odor and flavor scores, seasoning chicken containing 1.0-1.3% pine needles compared to the controls and other treatments increased during storage days due to fresh odor of pine needles. Seasoning chicken containing 0.5-1.3% pine needles after 6 days of storage were no significantly different levels (p>0.05) of Hunter color $L^*$ values compared to controls. Hunter color $a^*$ and $b^*$ values of seasoning chicken containing 0.5-1.3% pine needles after 6 days of storage were significantly different (p<0.05) than those of the controls.

Effect of Cadmium Treatment on the Total Thiol Groups, Glutathione and Phytochelatin Contents in Oenanthe javanica (카드늄을 처리한 미나리 (Oenanthe javanica)에서 전체 Thiol 잔기, 글루타치온, Phytochelatin의 농도 변화)

  • Min, Bok-Kee;Choi, Soon-Yong;Lee, Se-Yong
    • Applied Biological Chemistry
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    • v.40 no.3
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    • pp.243-248
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    • 1997
  • In order to evaluate the usefulness of O. javanica for the phytoremediation, it was grown for 1, 3, 7, 14, 21 days and was exposed to $50\;{\mu}M\;of\;CdCl_2$ in hydroponic medium after 3 weeks. Its biomass and contents of chlorophylls were analyzed. The growth of O. javanica showed little difference between cadmium treated and non-treated groups, while its contents of chlorophylls of Cd-treated group decreased up to 50% compared to the case of non-treated group. Its accumulated cadmium concentrations were 2.1, 7.3 and $113\;{\mu}moles\;Cd/g$ dry weight in the leaf, stem and root, respectively. The total contents of thiol increased 0.5, 1 and 7 times in the leaf, stem and root, respectively, while the contents of glutathione tended to decrease by 43%, 70% and 47% in the leaf, stem and root, respectively. Using HPLC analysis, the reasonable peaks of thiol compounds in shoot and root of Cd-treated sample were compared to those of non-treated sample in O. javanica, and found to be phytochelatins. In case of Nicotiana tabacum cv. Xanthi tested as control plant, the cadmium treatment for 3 weeks resulted in the decrease of both biomass and chlorophyll up to 70% and 75%, respectively. The roots of tobacco became rotten and eventually died. These results suggested that Oenanthe javanica is cadmium-tolerant hyperaccumulator.(Received December 20, 1996; accepted March 17, 1997)

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