• Title/Summary/Keyword: 오염물질수지

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A study on inspection methods for waste treatment facilities(I): Derivation of impact factor and mass·energy balance in waste treatment facilities (폐기물처리시설의 세부검사방법 마련연구(I): 공정별 주요인자 도출 및 물질·에너지수지 산정)

  • Pul-Eip Lee;Eunhye Kwon;Jun-Ik Son;Jun-Gu Kang;Taewan Jeon;Dong-Jin Lee
    • Journal of the Korea Organic Resources Recycling Association
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    • v.31 no.1
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    • pp.69-84
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    • 2023
  • Despite the continuous installation and regular inspection of waste treatment facilities, complaints about excessive incineration and illegal dumping stench continue to occur at on-site treatment facilities. In addition, field surveys were conducted on the waste treatment facilities currently in operation (6 type) to understand the waste treatment process for each field, to grasp the main operating factors applied to the inspection. In addition, we calculated the material·energy balance for each main process and confirmed the proper operation of the waste disposal facility. As a result of the site survey, in the case of heat treatment facilities such as incineration, cement kilns, and incineration heat recovery facilities, the main factors are maintenance of the temperature of the incinerator required for incineration and treatment of the generated air pollutants, and in the case of landfill facilities Retaining wall stability, closed landfill leachate and emission control emerged as major factors. In the case of sterilization and crushing facilities, the most important factor is whether or not sterilization is possible (apobacterium inspection).In the case of food distribution waste treatment facilities, retention time and odor control during fermentation (digestion, decomposed) are major factors. Calculation results of material balance and energy resin for each waste treatment facility In the case of incineration facilities, it was confirmed that the amount of flooring materials generated is about 14 % and the amount of scattering materials is about 3 % of the amount of waste input, and that the facility is being operated properly. In addition, among foodwaste facilities, in the case of an anaerobic digestion facility, the amount of biogas generated relative to the amount of inflow is about 17 %, and the biogas conversion efficiency is about 81 %, in the case of composting facility, about 11 % composting of the inflow waste was produced, and it was comfirmend that all were properly operated. As a result, in order to improve the inspection method for waste treatment facilities, it is necessary not only to accumulate quantitative standards for detailed inspection methods, but also to collect operational data for one year at the time of regular inspections of each facility, Grasping the flow and judging whether or not the treatment facility is properly operated. It is then determined that the operation and management efficiency of the treatment facility will increase.

Operating Status and Improvement Plans of Ten Wetlands Constructed in Dam Reservoirs in Korea (국내 10개 댐저수지 인공습지의 운영현황 및 개선방안)

  • Choi, Kwangsoon;Kim, Sea Won;Kim, Dong Sup;Lee, Yosang
    • Journal of Wetlands Research
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    • v.16 no.3
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    • pp.431-440
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    • 2014
  • To propose the improvement and management plans to strengthen the pollutant removal efficiency of dam reservoir's constructed wetlands(CWs), the operation status and configuration of CWs (including water depth, operational flow, water flow distribution, residence time, and pollutant removal efficiency, aspect ratio, open water/vegetation ratio etc.) were analyzed in 10 major wetlands constructed in dam reservoirs. The pollutant concentrations in the inflows of the studied CWs were lower than those of American and European constructed wetlands. Especially, organic matter concentrations in all of inflows were below 3 mg/L(as BOD) due to advanced treatment of sewage disposal plant and an intake of low concentration water during dry and normal seasons. The average removal efficiency of total nitrogen(TN) and total phosphorus(TP) for 10 CWs ranged from 7.6~67.6%(mean 24.9%) and -4.9~74.5%(mean 23.7%), respectively, showing high in wetlands treating municipal wastewater. On the other hand, the removal efficiency of BOD was generally low or negative with ranging from -133.3 to 41.7%. From the analysis of the operation status and configuration of CWs, it is suggested that the low removal efficiency of dam reservoir's CWs were caused by both structural (inappropriate aspect ratio, excessive open water area) and operational (neglecting water-level management, lack of facilities and operation for first flush treatment, lake of monitoring during rainy events) problems. Therefore, to enable to play a role as a reduction facility of non-point source(NPS) pollutants, an appropriate design and operation manuals for dam reservoir's CW is urgently needed. In addition, the monitoring during rainy events, when NPS runoff occur, must be included in operation manual of CW, and then the data obtained from the monitoring is considered in estimation of the pollutant removal efficiency by dam reservoir's CW.

Analysis of the Contribution of Biomass Burning Emissions in East Asia to the PM10 and Radiation Energy Budget in Korea (동아시아의 생체연소 배출물에 대한 한국의 미세먼지 기여도 및 복사 에너지 수지 분석)

  • Lee, Ji-Hee;Cho, Jae-Hee;Kim, Hak-Sung
    • Journal of the Korean earth science society
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    • v.43 no.2
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    • pp.265-282
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    • 2022
  • This study analyzes the impact of long-range transport of biomass burning emissions from northeastern China on the concentration of particulate matter of diameter less than 10 ㎛ (PM10) in Korea using the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem). Korea was impacted by anthropogenic emissions from eastern China, dust storms from northern China and Mongolia, and biomass burning emissions from northeast China between April 4-and 7, 2020. The contributions of long-range PM10 transport were calculated by separating biomass burning emissions from mixed air pollutants with anthropogenic emissions and dust storms using the zeroing-out method. Further, the radiation energy budget over land and sea around the Korean Peninsula was analyzed according to the distribution of biomass burning emissions. Based on the WRF-Chem simulation during April 5-6, 2020, the contribution of long-range transport of biomass burning emissions was calculated as 60% of the daily PM10 average in Korea. The net heat flux around the Korean Peninsula was in a negative phase due to the influence of the large-scale biomass burning emissions. However, the contribution of biomass burning emissions was analyzed to be <45% during April 7-8, 2020, when the anthropogenic emissions from eastern China were added to biomass burning emissions, and PM10 concentration increased compared with the concentration recorded during April 5-6, 2020 in Korea. Furthermore, the net heat flux around the Korean Peninsula increased to a positive phase with the decreasing influence of biomass burning emissions.

Dynamic Water Quality Simulation Considering Nonpoint Sources in Nakdong River (비점오염해석과 연계한 낙동강에서의 동적 수질모의)

  • Han, Kun-Yeun;Choi, Hyun-Gu;Kim, Ji-Sung;Yun, Young-Sam
    • Proceedings of the Korea Water Resources Association Conference
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    • 2007.05a
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    • pp.433-437
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    • 2007
  • 최근 환경부에서는 낙동강 유역의 오염총량관리제도의 시행에 따라 이제까지의 배출구 수질기준으로부터 총량수질기준을 통한 수질관리를 실시하고 있다. 오염총량관리를 실행하기 위해서는 주요지천 및 폐수처리장에서의 수질개선 및 비점오염원 관리가 선행되어야 하는데 이를 효율적으로 제어하기 위해서 낙동강 유역에 적합한 최적 수질해석 모델의 개발이 요구되는 상황이다. 수질모델의 가장 큰 목적은 유역으로부터 발생한 오염물이 하천으로 유입되었을 때 하천 수질 및 생태계의 수학적 표현을 통해 장래의 수질을 예측하고, 예측된 결과에 따라 합리적인 수질관리대책을 수립하는 것이다. 낙동강은 대표적인 수지상 하천망의 형태로서 댐 방류량 및 지류유입량은 본류 수계에 직접적인 영향을 미치며, 수질해석의 기본이 되는 수리계산에 매우 중요한 변수가 된다. 또한 대구, 구미, 왜관, 김천 등에서의 오염부하가 금호강, 남강 등의 주요 지류를 통하여 본류부로 유입되고 있으며, 하류부 칠서, 원동, 매리, 물금 등에서는 대량의 하천수를 취수하여 부산, 울산, 마산, 창원 지역 등의 생활 및 공업용수의 원수로 사용하고 있다. 다시 말해서 댐 방류량, 낙동강 하구언의 수위조절, 지류 유입량, 비점원 유입량 등 계산영역 경계에서의 비정상상태의 수리조건과 수질관리 계획에 의해 일률적으로 오염이 부하되는 정상상태의 수질조건이 공존하고 있는 실정이다. 본 연구에서는 낙동강 유역에 적합한 동적 수질모델을 개발하였다. 본 연구에서 개발된 수치모형은 갈수저수조건 및 불규칙한 하도단면을 반영하고, 동적 상태의 댐 방류량, 낙동강 하구언의 수위조절 영향, 지류 유입량 등 다양한 하천조건에서 발생하는 동적 흐름을 안정적으로 해석하여 낙동강 수질해석의 신뢰도를 향상시킴으로서 낙동강에 유입된 오염물질이 수계에 미치는 영향을 정확히 분석하고자 하였다. 동적수질해석에 의한 모의결과는 유량의 경우 상류부분은 모의치와 실측치가 잘 일치하지만, 중류 이후 지류의 유입이 많아지면서 지류의 변화를 정확히 입력하지 못해 모의치와 실측치의 차이가 발생한다. BOD의 경우는 수질이 양호한 상류지역은 모의치와 실측치가 잘 일치하지만, 오염원의 유입이 많은 중류지역부터는 실측치와 차이를 나타내다가 하류지역에서 다시 비교적 일치함을 알 수 있다. TN의 경우는 전반적으로 실측치보다 높게 모의되었고, TP는 전반적으로 실측치와 비교하여 잘 모의되었다. 본 연구에서 구축한 동적 수리해석모형 및 동적 수질해석모형은 낙동강 유역에 대해 유량 및 수질 등의 실제 하천의 경향에 비교적 잘 반영하므로 오염물총량규제에 따른 합리적인 하천 수질관리대책을 수립하는데 크게 기여할 수 있을 것으로 기대된다.

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Ecological Importance of Water Budget and Synergistic Effects of Water Stress of Plants due to Air Pollution and Soil Acidification in Korea (한국에서 수분수지의 생태적 중요성과 대기오염 및 토양 산성화로 인한 식물의 수분스트레스 증대 효과)

  • 이창석;이안나
    • The Korean Journal of Ecology
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    • v.26 no.3
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    • pp.143-150
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    • 2003
  • Korea has plentiful precipitation but rainfall events concentrate on several months of rainy season in her weather condition. Korea, therefore, experiences drought for a given period every year. Moreover the soil has usually low water holding capacity, as it is composed coarse particles originated from the granite. Response of several oaks and the Korean red pine (Pinus densiflora) on water stress showed that water budget was significant factor determining vegetation distribution. In addition, dehydration level due to cold resistance mechanism of several evergreen plants during the winter season was closely related to their distribution in natural condition. Experimental result under water stress showed that the Korean red pine was very tolerant to desiccation but the seedlings showed high mortality during the dry season. The mortality tended to proportionate to soil moisture content of each site. A comparison between soil moisture content during June when it is severe dry season and moisture content of the culture soil when the pine seedlings reached the permanent wilting point due to water withheld proved that high mortality during the dry season was due to water deficit. Water potential of sample plants measured during the exposure experiment to the air pollutant showed a probability that water related factors would dominate the occurrence of visible damage and the tolerance level of sample plants. In both field survey and laboratory experiment, plants exposed to air pollution showed more rapid transpiration than those grown in the unpolluted condition. The result would due to injury of leaf surface by air pollutants. Aluminum (Al/sup 3+/) increased in the acid soil not only inhibits root growth but also leads to abnormal distribution of root system and thereby caused water stress. The water stresses due to air pollution and soil acidification showed a possibility that they play dominating roles in inducing forest decline additionally to the existing water deficit due to weather and soil conditions in Korea. Sludge, which can contribute to improve field capacity, as it is almost composed of organic matter, showed an effect ameliorating the retarded growth of plant in the acidified soil. The effect was not less than that of dolomite known in widely as such a soil ameliorator. Litter extract contributed also to mitigate the water stress due to toxic Al/sup 3+/. We prepared a model showing the potential interaction of multiple stresses, which can cause forest decline in Korea by synthesizing those results. Furthermore, we suggested restoration plans, which can mitigate such forest decline in terms of soil amelioration and vegetation restoration.

Simple Material Budget Modeling for a River-Type Reservoir (하천형 저수지의 단순 물질수지 모델링)

  • Yoon, Seong-Kyu;Kong, Dong-Soo;Bae, Wookeun
    • Journal of Korean Society on Water Environment
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    • v.26 no.3
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    • pp.420-431
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    • 2010
  • Simple material budget models were developed to predict the dry season water quality for a river-type reservoir in Paldang, Republic of Korea. Of specific interest were the total phosphorus (TP), chlorophyll ${\alpha}$ (Chl. ${\alpha}$), 5-day biochemical oxygen demand (BOD), and chemical oxygen demand (COD). The models fit quite well with field data collected for 20 years and have enabled the identification of the origins of organic materials in the reservoir. The critical hydraulic load that determines the usability of phosphorus for algal production appeared to be about $1.5m\;d^{-1}$. When a hydraulic load was smaller than the critical value, the concentrations of $Chl.{\alpha}$, COD, and BOD in the reservoir water became sensitive to internal algal reactions such as growth, degradation, and settling. In spite of the recent intensive efforts for organic pollutant removal from major point sources by central and local governments, the water quality in the reservoir had not been improved. Instead, the concentration of COD increased. The model analysis indicated that this finding could be attributed to the continuing increase of the algal production in the reservoir and the allochthonous load from non-point sources. In particular, the concentrations of COD and BOD of algal origin during 2000~2007, each of which is comprised of approximately one half of the total, were approximately 2.5 times higher than those observed during 1988~1994 and approximately 1.3 times higher than those between 1995~1999. The results of this study suggested that it is necessary to reduce the algal bloom so as to improve the water quality of the reservoir.

A study on the functional coatings using silicone resin of Architectural membrane structures products (건축용 막구조 제품의 실리콘 기능성 코팅에 관한 연구)

  • Choi, Yun-Sung;Lee, Jang-Hun;Yoon, Nam-Sik;Kim, Su-Hong;Yoo, Gu-Geun
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2012.03a
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    • pp.106-106
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    • 2012
  • 막구조(Membrane structure)란 건축분야에서 "fabric structure" 또는 tension structure"와 같이 사용되는 용어로 코팅된 직물(coated fabrics)을 주재료로 사용하는 구조를 말한다. 특히 구조체로서 연성의 막을 이용 이것에 초기 장력을 주어 강성을 늘림으로서 외부하중에 대하여 안정된 형태를 유지하는 장점을 갖고 있다. 초기 창안된 독일의 온화한 기후에 적용되는 반면 한국이나 일본에는 60m/sec를 넘나드는 태풍의 피해와 많은 적설량을 보이는 기후적 제약으로 발달되지 못하였다. 그러나 최근 새로운 소재의 막구조 제품 개발과 구조해석 방법 및 시공기술 등이 개발되어 보편화되어지고 있는 실정이다. 막구조용 재료로 사용되는 섬유소재는 주로 Polyester직물을 기재로 한 PVC 코팅 제품으로 일반 PVC 막재는 장력이 약하고, 광선에 의한 물성이 쉽게 변화되어 내구연한이 5~15년에 불과하다. 유리섬유나 아라미드섬유 등으로 제직한 기재에 고내열 실리콘이나 PTFE 수지를 코팅한 제품은 약품에 대한 내구성이 높고 자외선에 대해서는 매우 큰 저항성을 가지기 때문에 내구연한이 10년에서 30년 까지도 향상된다. 그러나 실리콘 코팅막은 세계적으로 가장 좋은 막재로 알려졌으나 자정능력(Self Cleaning)에 문제가 발생되어 사용량이 감소 추세라고 할 수 있다. 일반적인 코팅 가공의 경우 MEK, Toluene, DMF 등과 같은 유기용제를 다량 사용함에 따라 작업환경 및 대기오염, 화재 위험 등의 문제점이 있으며 특히 가공시 잔류되는 유기용제의 심각성이 대두되고 있는 상황이다. 이와 같이 코팅 가공제 자체를 친환경적인 물질로 대체하여 각종 환경규제에 대응하고 유해 폐기물의 발생을 줄일 수 있는 코팅 가공제 및 가공기술 개발이 절실하다. 이에 본 연구에서는 Glass-Fiber, Aramid 등의 슈퍼 섬유와 고 강력 섬유 등을 이용하여 PTFE 코팅제품과 비슷한 수준의 성능을 부여하는 무용제형 실리콘 코팅 수지를 개발하고 내구성능 향상, Self Cleaning성, 난연성, 자외선 차단, 인장강도 및 인열 강도의 향상 등 다양한 기능성을 부여하는 최적의 환경 친화적 코팅 공정 기술을 개발하여 차세대 건축용 막구조 제품을 개발하고자 한다.

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Input, Output and Budget of Nitrogen and Sulphur in Forested Watershed Ecosystems (산림 소유역 생태계에서 질소와 황의 유입량, 유출량과 물질수지)

  • You, Young-Han;Kim, Joon-Ho;Mun, Hyeong-Tae;Lee, Chang-Seok
    • The Korean Journal of Ecology
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    • v.25 no.3 s.107
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    • pp.189-195
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    • 2002
  • In order to elucidate the budget and cycling of Nitrogen and Sulfur, essential elements and principal constituents of acid rain, their input through precipitation, and their output by streamflow were quantified in coniferous and deciduous forested watersheds, using combination of nutrient concentration and hydrological analysis, in Kwangnung Experimental Forest from July 1991 to December 1993. Amount of annual mean precipitation was $12,916\;ton{\cdot}ha^{-1}{\cdot}yr^{-1}$, annual mean runoff $5,094\;ton{\cdot}ha^{-1}{\cdot}yr^{-1}$(39%), $7,467\;ton{\cdot}ha^{-1}{\cdot}yr^{-1}$(59%) in coniferous and deciduous forest watersheds, respectively. Amounts of annual input of $N({NO_3}^-+{NH_4}^+)$ and ${SO_4}^{2-}$ through preciptation were 12.5, $81.72\;kg{\cdot}ha^{-1}{\cdot}yr^{-1}$, repectively. Annual output via runoff of $N({NO_3}^-+{NH_4}^+)$ and ${SO_4}^{2-}$ were 0.06, $39.23\;ton{\cdot}ha^{-1}{\cdot}yr^{-1}$ in the coniferous forest watershed ecosystem, and 0.15, $55.46\;ton{\cdot}ha^{-1}{\cdot}yr^{-1}$ in the deciduous one, respectively. On the basis of annual nutrient input and output, the annual budget of $N({NO_3}^-+{NH_4}^+)$ and ${SO_4}^{2-}$ were +12.46, $+42.49\;ton{\cdot}ha^{-1}{\cdot}yr^{-1}$ in the coniferous forest watershed, and +11.35, $+26.26\;ton{\cdot}ha^{-1}{\cdot}yr^{-1}$ in the deciduous one. Thus $N({NO_3}^-+{NH_4}^+)$ and ${SO_4}^{2-}$ were accumulated in both forested watershed ecosystems.

Estimation of Rice Cultivation Impacts on Water Environment with Environmental Characteristics and Agricultural Practices by Nitrogen Balances (질소수지에 의한 환경특성과 영농방법별 벼농사의 수질영향 평가)

  • Roh, Kee-An;Kim, Min-Kyeong;Ko, Byong-Gu;Kim, Gun-Yeob;Shim, Kyo-Moon;Lee, Deog-Bae
    • Korean Journal of Soil Science and Fertilizer
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    • v.42 no.6
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    • pp.439-446
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    • 2009
  • Nitrogen balance in the regional scale which was calculated the difference between nitrogen input and output was estimated to assess the impact of rice cultivation on water environment. Nitrogen balances in Gyeonggi province, where nitrogen concentration in irrigation water was high and in Chungnam province, where nitrogen absorbtion by rice was high, were -5.4 and -8.3 kg $-8.3kg\;ha^{-1}\;yr^{-1}$, respectively. Nitrogen balances of paddy field in Gangwon province, where nitrogen output was small and irrigation water was clean, and in Gyeongnam province, where organic matter content of soil was high and rice yield was low, were 4.9 and $14.0kg\;ha^{-1}\;yr^{-1}$, respectively. Average nitrogen balance and total nitrogen absorption of paddy field in Korea were estimated to $-0.3kg\;ha^{-1}\;yr^{-1}$ and $-3,315Mg\;yr^{-1}$, respectively. When the nitrogen concentration in irrigation water was increased by $1mg \;L^{-1}$, nitrogen balance of rice paddy changed by $-2.91kg\;ha^{-1}\;yr^{-1}$. Also, when nitrogen fertilizer applied was decreased from 110 to $90kg\;ha^{-1}$ and the same harvest was maintained, the nitrogen absorption by rice paddy from irrigation water was estimated to increase by 10,600 Mg per year in Korea. However, in cases, the harvest was reduced to either 90% or 85%, nitrogen balances were changed from -11.7 to -2.3 and $2.4kg\;ha^{-1}$, respectively. These results suggest that the reduction of nitrogen fertilizer use may not always lead to a negative nitrogen balance and sustainable agriculture can achieve by not cutting down the use of fertilizer only but by reduction of fertilizer application concurrently by maintenance of harvest and by utilization of environmental characteristics such as nutrient contents in irrigation water and soils.

A Study on the Manufacture of Healing Textile Material with Characteristics of Dermatitis Symptom Relief (피부염 증상완화특성을 갖는 힐링섬유소재 제조에 관한 연구)

  • Son, Eun-Jong;Koo, Chang-Mo;Lee, Young-Mok
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2012.03a
    • /
    • pp.57-57
    • /
    • 2012
  • 피부염 증상 완화특성을 갖는 힐링섬유소재 제조를 연구하였다. 면소재, 폴리에스테스/나일론 소재에 피부염 증상완화특성이 있다고 알려진 기능성물질을 바인더, 수지 등의 혼합물 페이스트로 만들어 스크린프린팅법을 사용하여 실험을 시도하였다. 제조한 힐링섬유시편소재의 항균특성은 면소재의 경우 99.9% 의 우수한 항균특성을 나타냈다. 암모니아가스의 소취성능은 시간경과에 따라 최대 68%의 소취율을 보였다. 타소재와의 오염견뢰도는 평균 4.5 ~ 5등급, 변퇴세탁견뢰도는 5등급, 마찰견뢰도는 3 ~ 4.5 등급, 일광견뢰도는 5등급을 나타냈다. 의약품 등의 독성시험기준에 따른 힐링소재의 피부자극성을 평가하기 위해 NZW토끼의 피부에 24시간 동안 부착한 후 72시간 동안 사망률, 일반증상, 체중변화 및 피부자극성을 시험한 결과 사망토끼는 관찰되지 않았고, 모든 시험동물에서 특이할 만한 이상증상은 관찰되지 않았다. 체중측정결과 모든 동물에서 정상적인 체중증가를 보였다. 시험소재의 피부자극성을 관찰한 결과 피부자극성이 관찰되지 않아 비자극성(None Irritant)섬유소재로 판단되어 피부염증상완화 특성을 갖는 힐링섬유소재 제조의 실용화 가능성을 연구하였다.

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