• 제목/요약/키워드: 염화불화탄화수소

검색결과 10건 처리시간 0.029초

CFCs 자동연속측정시스템 구축 (On the Continuous Monitoring System of CFCs in the Ambient Air)

  • 한진석;강창국;노혜란;이덕희;최양일
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 1999년도 추계학술대회 논문집
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    • pp.94-95
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    • 1999
  • 불소나 염소가 수소대신에 치환 되어있는 활로겐화 화합물인 염화불화탄화수소(CFCs chlorofluoro carbons)는 오존층 파괴물질 그리고 지구온난화 기체물질로 널리 알려져있다. 이러한 CFCs는 Mauna Loa, Niwot Ridge, South Pole과 같은 지구배경농도지역에서 70년대 후반부터 지속적으로 측정되어 오고 있다. 대기중 CFCs농도는 일반적으로 수백 ppt 수준으로 매우낮아 측정이 매우 어려운 것으로 알려져왔다.(중략)

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고밀도 열교환기를 이용한 $NH_3$냉동장치의 성능 특성 연구 (The Study on Performance Characteristics of NH3 Refrigeration System Using Optimum Heat Exchanger)

  • 이승재;전상신;권일욱;이종인;하옥남
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 추계학술대회
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    • pp.1276-1281
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    • 2004
  • Nowadays CFCs and HCFCs refrigerants are restricted because it cause depletion of ozone layer. Accordingly, this experiment apply the ammonia gas and not CFCs and HCFCs for refrigerant to study the performance characteristic from the superheat control and improve the energy efficiency from the high performance. The condensing pressure of refrigeration system is increased from 15.0bar to 16bar by 0.5bar and superheat temperature is increased from $0^{\circ}C$ to $10^{\circ}C$ by $1^{\circ}C$ at each condensing pressure. As the result of experiment, when the superheat temperature is $0^{\circ}C$ at each condensing pressure, the refrigeration system has the high performance.

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과열도 변화에 의한 $NH_3$ 냉동장치의 성능특성 연구 (The Study on Performance Characteristics due to the Superheat Temperature of $NH_3$ Refrigeration System)

  • 전상신;권일욱;하옥남
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 춘계학술대회
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    • pp.1334-1339
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    • 2004
  • Nowadays CFCs and HCFCs refrigerants are restricted because it cause depletion of ozone layer. Accordingly, this experiment apply the $NH_3$ gas and not CFCs and HCFCs for refrigerant to study the performance characteristic from the superheat control and improve the energy efficiency from the high performance. The condensing pressure of refrigeration system is increased from 14.5bar to 16bar by 0.5bar and superheat temperature is increased from $0^{\circ}C$ to $10^{\circ}C$ by $1^{\circ}C$ at each condensing pressure. As the result of experiment, when the superheat temperature is $1^{\circ}C$ at each condensing pressure, the refrigeration system has the high performance.

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CFC 대체 산업세정제로의 HFEs의 적용가능성 연구 (A Study on Applicability of Hydrofluoroethers as CFC-Alternative Cleaning Agents)

  • 민혜진;신진호;배재흠;김홍곤;이현주
    • 청정기술
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    • 제14권3호
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    • pp.184-192
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    • 2008
  • 불소계 화합물인 삼불화에탄올(2,2,2-trifluoroethanol, TFEA)와 수소화불화에테르(hydrofluoroether, HFE)는 성층권의 오존층을 파괴하지 않으며, 수소화불화탄소(hydrofluorocarbon, HFC) 및 수소화염화불화 탄소(hydrochlorofluorocarbon, HCFC)계 세정제에 비하여 지구온난화 영향력도 낮다. 특히, 인화점이 없는 HFE계 세정제는 낮은 인화점을 갖는 탄화수소계 세정제보다 취급에 안전하고 침투력이 우수하여 차세대 염화불화탄소(chlorofluorocarbon, CFC) 대체세정제로 주목받고 있다. 본 연구에서는 불소계 세정제인 TFEL HFE-7100, HFE-7200, HFE-476mec, HFE-449mec-f, AE-3000, AE-3100E와 실리콘계 세정제인 트리플 루로에톡시트리메틸실란(trifluoroetoxytrimethylsilane, TFES)와 헥사메틸디실라잔 (hexamethyldisilazane, HMDS)의 물성과 세정력을 오존파괴 물질인 CFC-113, 삼염화에탄(1,1,1-trichloroethane)와 유해물질인 이염화탄소(methylene chloride, MC) 등의 염소계 세정제, 그리고 현재 대체세정제로 많이 사용하고 있는 이소프로필알코올(isopropyl alcohol, IPA) 등과 비교 평가하였다. 그 결과 TFEA와 HFEs는 일반적으로 발생하는 다양한 오염물질들에 대하여 염소계 세정제에 비하여 낮은 세정능력을 보여주었지만, 불소를 함유한 불소계 오염물의 제거에는 우수한 세정력을 보였다. 그리고 실리콘계 세정제인 TFES와 HMDS도 실리콘계 오염물에 대한 세정력이 우수함을 보여주었다.

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$NH_3$ 냉동장치의 과열도에 관한 성능 특성 연구(III) -열교환기 타입별 비교- (The Study on the Performance Characteristics due to the Degree of Superheat in $NH_3$ Refrigeration System (III) -The Comparison of Heat Exchanger Types-)

  • 이종인;김양현;박찬수;하옥남
    • 설비공학논문집
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    • 제17권12호
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    • pp.1132-1138
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    • 2005
  • Recently, production and use of freon substances are restrained due to depletion of ozone layer and global warming. In this aspect of environmental problems, the best solution is to use the natural refrigerant such as ammonia. Thus, this study is to find the optimal operating conditions by comparing the performance between the shell and tube type and shell and disk type heat exchangers using the ammonia refrigerant, and to verify the superiority of the shell and disk type heat exchanger that is not used in field of refrigeration and air conditioning. Finally, this study shows that the shell and disk type heat exchanger is applicable to the ammonia refrigeration system, and this system minimizes the refrigerant charge and installation space.

$NH_3$ 냉동장치의 과열도 변화에 의한 성능 특성 연구 (The Study on Performance Characteristics of Superheating the Suction Vapor in $NH_3$ Refrigeration System)

  • 권일욱;하옥남
    • 설비공학논문집
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    • 제16권8호
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    • pp.756-761
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    • 2004
  • Since the use of CFC and HCFC refrigerants are to be restricted due to the depletion of ozone layer, this experiment applies the NH$_3$ gas to study the performance characteristics from the superheat control for improving the energy efficiency. The experiments are carried out for the condensing pressure of refrigeration system from 14.5 bar to 16.0 bar by 0.5 bar and for superheat temperature from $0^{\circ}C$ to 1$0^{\circ}C$ by 1$^{\circ}C$ at each condensing pressure. As a result of experiment, when the superheat temperature is 1$^{\circ}C$ at each condensing pressure, the refrigeration system has the highest performance.

폴리우레탄 폼의 물성과 Cell Morphology에 대한 촉매와 발포제의 영향 (Effects of Catalysts and Blowing Agents on the Physical Properties and Cell Morphology of Polyurethane Foams)

  • 권현;이수헌;김상범;방문수;김연철
    • 공업화학
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    • 제16권3호
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    • pp.379-384
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    • 2005
  • Polymeric 4,4'-diphenylmethane diisocyanate (PMDI), 여러 관능기와 OH 값을 가지는 7종의 폴리올, 실리콘 계면활성제, 두 종류의 촉매 그리고 세 종류의 발포제를 사용하여 폴리우레탄폼(PUF)을 제조하였다. 발포제로는 염화불화탄소(CFC-11), 염화불화탄화수소(HCFC-141b)와 불화탄화수소(HFC-365mfc)가 이용되었다. HCFC-141b를 사용한 PUF의 기초특성과 cell 구조에 대한 겔화촉매와 blowing 촉매의 영향을 조사하였다. Cell 크기는 촉매의 양에 따라 감소하였다. 겔화촉매의 경우에 밀도 변화는 거의 없지만 압축강도는 촉매양이 0에서 2 pph로 증가함에 따라 11.9에서 $12.66kg_f/cm^2$로 증가하였다. 3 종의 발포제를 이용한 PUF의 겔화시간, 밀도와 압축강도를 측정하였으며, 물리적 특성에 있어서는 큰 차이를 나타내지 않았다. 그러나 다른 두 종류의 발포계와 비교했을 때 HCFC-141b를 사용한 PUF의 cell 구조는 불균일함을 알 수 있었다.

$NH_3$ 냉동장치의 과열도 변화에 의한 성능 특성 연구 II -열교환기 타입 변경- (The Study on Performance Characteristics of $NH_3$ Refrigeration System for Various Degree of Superheat - Part II : The Change of Heat Exchanger Type -)

  • 하옥남;권일욱;전상신;이승재;정송태;하경수;윤갑식;이종인;홍경한
    • 설비공학논문집
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    • 제17권4호
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    • pp.297-302
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    • 2005
  • Since the use of CFC and HCFC refrigerants are to be restricted due to the depletion of ozone layer, this experiment applies the $NH_3$ gas to study the performance characteristics of $NH_3$ refrigeration system by the superheat control for improving the energy efficiency. The experiments are carried out for the condensing pressure of refrigeration system from 1,500 kPa to 1,600 kPa and for degree of superheat from $0^{\circ}C\;to\;10^{\circ}C$ at each condensing pressure. As a result of experiment, when the degree of superheat is $0^{\circ}C$ at each condensing pressure, the refrigeration system has the highest performance.

냉매 R717과 R22를 작동유체로 이용한 냉동장치의 성능특성에 관한 연구 (The Study on Performance Characteristics in Refrigeration System using R717 and R22 as working fluid)

  • 김진현;김재근;김종길;김양현;홍석주;하옥남
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2006년도 하계학술발표대회 논문집
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    • pp.495-500
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    • 2006
  • Nowadays HCFCs refrigerant are restricted because it cause depletion of ozone layer. However, natural gases such as ammonia as an organic compound, propane and propylene as hydrocarbon are easy and cheap to obtain as well as environmental. Accordingly, this experiment apply the $NH_3$ and R22 to study the performance characteristic from the superheat control and compare the energy efficiency of two refrigerants from the high performance. The condensing pressure of refrigeration system is increased from 15bar to 16bar and degree of superheat is increased from 0 to $10^{\circ}C$ at each condensing pressure. As the result of experiment, when comparing the each COP, we knew the $NH_3$ is suitable as the alternative refrigerant of the R22.

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$NH_3$와 R22를 사용한 냉동장치의 성능특성 비교 (The Comparison of Performance Characteristics in Refrigeration System using $NH_3$ and R22)

  • 하옥남;이규태;하경수;정송태;김진현;홍성인;윤갑식;김양현;권일욱;이종일
    • 설비공학논문집
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    • 제18권5호
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    • pp.377-383
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    • 2006
  • Recently, production and use of Freon substances are restrained due to destruction of ozone layer and grobal warming. In this aspect of environmental problems, the best solution is to use the natural refrigerant such as ammonia. Thus, this study apply the $NH_3$ and R22 to study the performance characteristic from the superheat control and compare the energy efficiency of two refrigerants from the high performance. The condensing pressure of refrigeration system is increased from 1,500 kPa to 1,600 kPa and degree of superheat is increased from 0 to $10^{\circ}C$ at each condensing pressure. As the result of experiment, when comparing the each COP, we knew the $NH_3$ is suitable as the alternative refrigerant of the R22.