• Title/Summary/Keyword: 염화물 확산성

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A Method on the Rapid Assessment of Resistance to Chloride Ion Penetration for Mortar and Concrete with Mineral Admixtures (혼화재를 사용한 모르타르 및 콘크리트의 염소이온 침투 저항성 평가)

  • Park Jung-Jun;Kim Sung-Wook;Koh Kyung-Taek;Lee Jong-Suk;Lee Jang-Hwa
    • Journal of the Korea Concrete Institute
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    • v.16 no.4 s.82
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    • pp.485-492
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    • 2004
  • In this study, ASTM C 1202 which is most commonly used for evaluating the penetration resistance into the concrete is reviewed. The test results by ASTM C 1202 showed that the passed charge could be underestimated as the $OH^-$ ion concentration in the concrete is lowered when the concrete is mixed with the admixtures. Therefore, the modified method using the distilled water was proposed in the paper. According to the test results, the modified method is not susceptible to $OH^-$ ion and temperature rise. In addition, the long term emersion test for the concrete mixed with the admixtures in the NaCl solution showed that the chloride diffusion coefficient tested by the modified method have higher correlation compared to the conventional ASTM method.

Evaluation of anti-rust properties of mortar with functionality anti-rust agent (기능성 방청혼화제 혼입율 변화에 따른 모르타르의 방청성능 평가)

  • Kim, Sang-Sup;Lee, Myung-Ho;Yoon, Won-Geun;Jang, Deok-Bae;Han, Min Cheol;Han, Cheon Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.05a
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    • pp.104-105
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    • 2014
  • In this study, fundamental properties of mortar with the variation of dosage of anti-rust agent has been tested to evaluate the effect of the anti-rust agent. Dosage of anti-rust agent was fixed as 0,3,6,9%, respectively. The variation of the flow, compressive strength and diffusion speed of chloride ion has been tested to evaluate the effect of the anti-rust agent. Results showed that flow has been smally increased. For the compressive strength, compressive strength increased with the increase of dosage of agent. For the diffusion speed of chloride, the speed decreased with the increase of dosage of the anti-rust agent. For the overall consideration, it could be identified that when the dosage of anti-rust agent was fixed as 3-6%, the mortar showed the optimum performances.

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Numerical Analysis for Impurity Effects on Diffusive-convection Flow Fields by Physical Vapor Transport under Terrestrial and Microgravity Conditions: Applications to Mercurous Chloride (지상 및 미소중력 환경에서 물리적 승화법 공정에 미치는 불순물의 영향 분석: 염화제일수은에 대한 응용성)

  • Kim, Geug Tae;Kwon, Moo Hyun
    • Applied Chemistry for Engineering
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    • v.27 no.3
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    • pp.335-341
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    • 2016
  • In this study, impurity effects on diffusive-convection flow fields by physical vapor transport under terrestrial and microgravity conditions were numerically analyzed for the mixture of $Hg_2Cl_2-I_2$ system. The numerical analysis provides the essence of diffusive-convection flow as well as heat and mass transfer in the vapor phase during the physical vapor transport through velocity vector flow fields, streamlines, temperature, and concentration profiles. The total molar fluxes at the crystal regions were found to be much more sensitive to both the gravitational acceleration and the partial pressure of component $I_2$ as an impurity. Our results showed that the solutal effect tended to stabilize the diffusive-convection flow with increasing the partial pressure of component $I_2$. Under microgravity conditions below $10^{-3}g_0$, the flow fields showed a one-dimensional parabolic flow structure indicating a diffusion-dominant mode. In other words, at the gravitational levels less than $10^{-3}g_0$, the effects of convection would be negligible.

Formation and Preservative Effectiveness of Inorganic Substances in Wood Treated with Potassium Carbonate and Calcium Chloride (탄산칼륨과 염화칼슘을 이용한 무기질 복합화 목재 중에 있어서 무기염의 생성과 방부효력)

  • Yoon, Sun-Mi;Lee, Jong-Shin
    • Journal of the Korean Wood Science and Technology
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    • v.29 no.2
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    • pp.126-132
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    • 2001
  • This research is carried out to investigate the formation and preservative effectiveness of inorganic substance, calcium carbonate($CaCO_3$), in wood. The specimens were prepared by the impregnation with saturated solutions of potassium carbonate($K_2CO_3$) into the wood followed by precipitation in saturated solutions of calcium chloride($CaCl_2$) for 24h, 72h and 120h, and then they were leached in instrument flowing with water for 24h. The weight percent gains of $K_2CO_3$ solution impregnated specimens reached approximately a maximum value (108.1%) by 72h precipitation in $CaCl_2$ solutions. Inorganic substances were observed to he produced in the lumina of tracheids of specimens. From these inorganic substances filling in the tracheids, characteristic X-rays of calcium(Ca-$K_{\alpha}$) were detected by energy dispersive X-ray analyzer. Moreover, it was shown from a leaching treatment that these substances could not he leached easily from the specimens. Therefore, they were could he considered to be insoluble calcium carbonates. The weight losses of the prepared specimens were hardly occurred by test fungi attacks. Thus inorganic substances in specimens can be said to have preservative effectiveness.

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Estimation on the Durability of High-Strength Concrete using Metakaolin (Metakaolin 혼합 고강도 콘크리트의 내구특성 예측)

  • Lee, Sang-Ho;Moon, Han-Young
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.9 no.2
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    • pp.173-180
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    • 2005
  • Metakaolin is a cementitious material for producing high-strength concrete. This material is now used as substitute for silica-fume. In this paper, we did the mechanical and durability test such as compressive/tensile/flexural strength test, chloride ion diffusion, chemical attack and repeated freezing and thawing, carbonation test. In the mechanical tests, 10~15% for binder is optimum substitute rate. And, in the chloride ion diffusion test, according to the increase of substitute of metakaolin & silica-fume for binder, the diffusion coefficient was more reduced. In the chemical attack test, by the filler effect of fine powder such metakaolin and silica-fume, the resistance is more excellent than normal concrete. In the other durability test, the concrete using metakaolin also compared with those of silica-fume substitute concrete. Through these tests, we recognized that metakaolin can be used as a substitute for silica-fume.

Mechanical Properties And Chlorde Penetration Resistance of Shotcrete according to Mineral Admixture Types and Supplemental Ratio (광물성 혼화재료의 종류 및 혼입율에 따른 숏크리트의 역학적 특성 및 염해 저항성)

  • Han, Seung-Yeon;Yun, Kyong-Ku;Nam, Kyeong-Gung;Lee, Kyeo-Re;Eum, Young-Do
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.7
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    • pp.4960-4968
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    • 2015
  • In this study to improve the chloride durability of the shotcrete structure depending on types and contents of mineral admixture chloride resistance was evaluated by NT BUILD 492 of european test standards. It was also evaluated with the mechanical properties such as static strength and chloride penetration resistance. For shotcrete mixed crushed stone aggregate of the maximum size 10mm of coarse aggregates was produced. Based on 28days compression strength the variable mixed with 15% silica fume showed the highest strength in 67.55MPa. As the content of fly ash and blast furnace slag increased, the strength lowered. In the chloride penetration resistance test, OPC showed "high grade" and In the case of admixture, the penetration resistance tended to increase in all variables except the fly ash. In order to evaluate the service life, the accelerated chloride penetration test was conducted by the standards of KCL, ACI, FIB. Test results were obtained with the lowest spreading factor in a variable mixed with silica fume of 15%. At the KCI standards, It was found to have a service life of about 65 years and at the FIB standards, It was found to have a service life of 131 years. Among standards, the service life of KCI standard in all of the variables was evaluated as the lowest.

Study on the Water Penetration in Mortar by Water Pressure (수압에 따른 모르타르내 수분침투에 관한 연구)

  • Yoo, Jo-Hyeong;Lee, Han-Seung;Cho, Hyeong-Kyu
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.505-508
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    • 2008
  • Concrete is a type of porous materials and is physically and chemically damaged due to exposure to various environments from the placing to the service life. These reactions affect the corrosionof steel bars applied in concrete and that decreases the durability life and strength of such steel bars. Thus, it is very important to insert rust inhibitors into steel bars in the case of a deterioration element that exceeds the critical amount of corrosion in the location of steel bars. However, it is very difficult to guarantee corrosion resistance at the location of steel bars using conventional technology that applies corrosion inhibitors only on the surface of concrete. This study attempts to develop a method that penetrates corrosion inhibitors up to the location of steel bars and investigate the penetration depth of corrosion inhibitors by verifying moisture migration in concrete under an applied pressure.

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Long-term Durability Characteristics of Fly ash Concrete Containing Lightly Burnt MgO Powder (저온 소성한 MgO 분말을 함유한 플라이애시 콘크리트의 장기재령에서의 내구특성)

  • Jang, Bong-Seok;Choi, Seul-Woo;Lee, Kwang-Myong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.33 no.3
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    • pp.909-916
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    • 2013
  • Concrete containing lightly burnt MgO has long term expansibility. It also could compensate for the thermal shrinkage of mass concrete, because the hydration of MgO proceeds at a slow pace to long-term age. Thus, lightly burnt MgO has been applied to the construction of mass concrete such as dams. Recently, the expansion characteristics of MgO concrete with fly ash that could be applied to mass concrete for the reduction of hydration heat have been studied and however, limited studies on its durability. This study investigates the long-term durability characteristics of fly ash concrete with lightly burnt MgO. The durability tests on carbonation, freezing-thawing, diffusion of chloride, and resistance to sulfate attack were carried out for MgO concrete with curing for 360 days in submerged condition with different temperature of 20 and $50^{\circ}C$. The results reveal that MgO concrete shows a greater resistance of carbonation, diffusion of chloride, and resistance to sulfate attack. On the other hand the resistance of freezing-thawing was little influenced by MgO powder.

Validation of Test Methods for Chloride Penetration Durability of Alkali Activated Slag (알칼리 활성 슬래그의 염해 내구성 평가 시험 방법 유효성)

  • Lim, Min-Hyuk;Lee, Do-Keun;Shin, Kyung-Joon;Song, Keum-Il;Song, Jin-Kyu
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.1
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    • pp.1-7
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    • 2019
  • Recently, studies on alkali activated slag(AAS) binders that do not use cement have been actively conducted. It is known that AAS concrete is highly resistant to chloride damage based on the test method used for ordinary concrete. However, it is fully not understood whether the test method used for concrete can be applied to AAS mixtures. Therefore, in this study, we verified the consistency of NT Build 492 and ASTM C 1202 test methods by applying various experimental variables. According to the experimental results, the two tests yielded opposite results. Therefore, the chloride durability of AAS mortar can be different depending on the evaluation method.

Time Dependent Chloride Transport Evaluation of Concrete Structures Exposed to Marine Environment (해안 환경 하에 있는 콘크리트 구조물의 시간의존적 염화물침투 평가)

  • Song, Ha-Won;Pack, Seung-Woo;Ann, Ki-Yong
    • Journal of the Korea Concrete Institute
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    • v.19 no.5
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    • pp.585-593
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    • 2007
  • This paper presents a model for durability evaluation of concrete structures exposed to marine environment, considering mainly a build-up of surface chloride $(C_s)$ as well as diffusion coefficient (D) and chloride threshold level $(C_{lim})$. In this study, time dependency of $C_s$ and D were extensively studied for more accurate evaluation of service life of concrete structures. An analytical solution to the Fick's second law was presented for prediction of chloride ingress for time varying $C_s$. For the time varying $C_s$, a refined model using a logarithm function for time dependent $C_s$ was proposed by the regression analysis, and averaging integrated values of the D with time over exposed duration were calculated and then used for prediction of the chloride ingress to consider time dependency of D. Durability design was also carried out for railway concrete structures exposed to marine environment to ensure 100 years of service life by using the proposed models along with the standard specification on durability in Korea. The proposed model was verified by the so-called performance-based durability design, which is widely used in Europe. Results show that the standard specification underestimates durability performances of concrete structures exposed to marine environment, so the cover depth design using current durability evaluation in the standard specifications is very much conservative. Therefore, it is found that utilizing proposed models considering time dependent characteristics of $C_s$ and D can evaluate service lift of concrete structures in marine environment more accurately.