• Title/Summary/Keyword: 염하수로

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경상분지 남동부 일광광산에 산출하는 전기석 기원과 그 중요성에 관한 예비연구

  • 장주연;양경희;이준동
    • Proceedings of the Mineralogical Society of Korea Conference
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    • 2001.06a
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    • pp.58-59
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    • 2001
  • 부산에서 북동쪽으로 대략 25km 떨어진 지점에 위치하고 있는 일광광산 부근의 지질은 백악기 화산암ㆍ퇴적암 그리고 이를 관입한 화강암류와 이 암주 내에 발달하는 구리-중석을 함유하고 있는 각력파이프광상으로 이루어져 있다. 일광광산의 화강암류는 거의 타원형으로 felsic한 중앙부와 mafic한 양상의 주변부로 나뉘어지며, 암주 내에 수직적인 원통형의 각력파이프가 광화대를 이루고 있고, 그 주변에는 모암변질대가 발달되어 있다. 각력파이프를 충진하고 있는 vein과 화강암의 중앙부에는 전기석이 풍부하게 산출되고 있다. 일광광산에서 산출되는 전기석은 야외 관찰시 각력파이프 중심에서부터 외곽부쪽으로 전기석의 풍부함이 감소하며 산출형태도 달라진다. 파이프에서 대략반경 150m내에서 전기석은 침상형 의 방사상 모양 내지 rosettes형으로 풍부하게 산출되며, 화강암내의 mafic한 암편을 치환한 형태로 산출되기도 한다. 암주의 중앙부 주변부에서는 거의 미세한 구상형으로 산재되어 나타나고 있다. 전기석은 복잡한 화학식 {(Na, Ca)(Fe, Mg)$_3$(Al, Li)$_{6}$(BO$_3$)$_3$Si$_{6}$O$_{18}$ (OH, F)$_4$}을 갖는 붕산 규산염광물이다. 이러 한 다양한 성분은 마그마의 진화과정, 모암의 특성, 온도, 압력, 성분과 같은 물리ㆍ화학적 성질에 따라 전기석의 성분이 체계적으로 변하기 때문에 모암과 전기석 기원과의 상관관계를 파악할 수 있다. 파이프 부근의 화강암류는 현미 경상에서 전기석이 석류석과 같이 풍부하게 나타나며 장석들은 변질받은 상태로 세리사이트, 녹렴석으로 나타나고, 흑운모와 각섬석은 녹니석화되어 변질된 상태를 보이고 있다. 파이프 중심에서 외곽부로 갈수록 전기석의 함량은 줄어들고 있고 장석들이 알바이트ㆍ칼스베드 쌍정을 보이며, 흑운모가 각섬석보다는 우세하게 나타나고 있다. 전기석은 주상 결정, 자형 내지 반자형의 입자로 다색성을 보이며, 결정 중심에서 가장자리로 갈수록 파란색과 황갈색의 광학적 누대구조를 관찰할 수 있다. 일광광산에서 산출되는 전기석에 대한 현미경 관찰은 열수기원임을 지시하고 있다. 야외조사와 현미경 관찰의 예비조사에 의하면 일광광산의 전기석이 형성된 환경은 다른2가지 화학적인 저장소의 혼합 효과의 결과로 생성되어진 것으로 예상된다. 일광의 화강암류를 만든 마그마는 전기석을 형성할 만큼의 Fe-Mg성분이 충분하지 않았을 것이다. 화강암 내에 흑운모와 각섬석의 결정작용에 의해 마그마의 Fe-Mg성분이 고갈되어지고 이로 인해 그 함량이 감소하며 상대적으로 마그마 내에 남은 붕소(B$_2$O$_3$)는 열수로 용리되고 흑운모, 각섬석과 평형을 유지하며 열수에 남아있게 된다. 잔류용융체에 남은 붕소의 함량은 전기석을 만들기에 충분함에도 불구하고, Fe-Mg 함량이 부족하여 마그마 기원의 전기석 결정을 만들 수가 없다가 광맥이 형성된 시기에 또 다른 열수가 공급되면서 이전의 평형이 깨지고 기존의 흑운모와 같은 염기성 광물이 붕소(B)를 함유한 새로운 열수와 반응하여 전기석을 형성한 것으로 예상한다. 앞으로 전암과 광물에 대해 지화학적 연구를 통해 화강암류와 전기석과의 지화학적 연관성, 주성분 원소와 열수의 특성과의 상관관계, 전기석의 기원(마그마 기원인지 열수기원인지)이 보다 정확하게 파악될 것이다. 마그마 진화에 따른 전기석의 성분변화와 기원을 이용하여 일광광산의 동광화대를 형성한 마그마 계에서 열수계로 이어지는 지질학적 과정을 이해할 수 있을 것이며, 암석 성인론적 지시자로서 어떠한 중요성을 갖는지 논의되어질 수 있다.

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Removal of Heavy Metals from Acid Mine Drainage using AFMR Process (AFMR 공정을 이용한 광산폐수의 중금속 제거)

  • Paik, Byeong Cheon;Kim, Gwangbok
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.2
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    • pp.313-321
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    • 2000
  • This research is to remove heavy metals from AMD(Acid Mine Drainage) using AFMR(Anaerobic Floating Media Reactor) process. Two AFMR were operated at HRT(hydraulic retention time) of 3 days. COD/sulfate ratio from 0.3 to 0.8, temperature from $30^{\circ}C$ to $35^{\circ}C$, and alkalinity of 1.000mg/l(as $CaCO_3$). At COD/sulfate($SO{_4}^{2-}$) ratio of 0.5 and temperature of $35^{\circ}C$, the ratio of reduced sulfate($SO{_4}^{2-}$)/removed COD(mg/mg) kept about 1 and the reactor achieved 99.99% of Cr, Pb anee Fe, 98% of Cd, and 90% of Mn removal efficiencies, respectively. Decreasing temperature to $30^{\circ}C$ increased the ratio of reduced sulfate($SO{_4}^{2-}$)/removed COD(mg/mg) to 1.37. Amount of sulfate reduction maximized at the temperature of $30^{\circ}C$ and the COD/sulfate ratio of 0.4 in the influent and then removal efficiencies of heavy metals were 99.99% of Fe, 99.99% of Pb, 99,99% of Cr, 97.3% of Mn, 99.9% of Zn, 99.9% of Cd and 99.9% of Cu.

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Characteristics of Removal and Precipitation of Heavy Metals with pH change of Artificial Acid Mine Drainage (인공 산성광산배수의 pH변화에 의한 중금속 제거 및 침전 특성 연구)

  • Lee, Min Hyeon;Kim, Young Hun;Kim, Jeong Jin
    • Economic and Environmental Geology
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    • v.52 no.6
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    • pp.529-539
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    • 2019
  • In this study, heavy metal removal and precipitation characteristics with pH change were studied for artificial acid mine drainage. Artificial acid mine drainage was prepared using sulfates of iron, aluminum, copper, zinc, manganese which contained in acid mine drainage from abandoned mines. The single and mixed five heavy metal samples of Fe, Al, Cu, Zn, and Mn were prepared at initial concentrations of 30 and 70 mg/L. Fe and Al were mostly removed at pH 4.0 and 5.0, respectively, and other heavy metals gradually decreased with increasing pH. Concentration changes with increasing pH show generally similar trend for single and mixed heavy metal samples. The effect of removing heavy metals from aqueous solutions is not related to the initial concentration and depends on the pH change. XRD were used for mineral identification of precipitates and crystallinity of the mineral tended to increase with increasing pH. The precipitates that produced by decreasing the concentration of heavy metals in the aqueous solution composed of Fe-goethite(FeOOH), Al-basaluminite(Al4(SO4)(OH)10·4H2O), Cu-connellite(Cu19(OH)32(SO4)Cl4·3H2O) and tenorite(CuO), Zn-zincite(ZnO), and Mn-hausmannite(Mn3O4).

Isolation of Phytase Producing Pseudomonas fragi and Optimization of its Phytase Production (Acid Phytase를 생산하는 Pseudomonas fragi의 분리와 phytase의 생산조건)

  • Kim, Young-Jin;Jang, Eun-Seok;In, Man-Jin;Oh, Nam-Soon
    • Applied Biological Chemistry
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    • v.46 no.4
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    • pp.291-298
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    • 2003
  • A bacterial strain producing a high level of an extracellular phytase was isolated from livestock waste water, identified as a strain of Pseudomonas fragi and designated as Pseudomonas fragi Y9451. Under the phytase production medium, the activity of phytase reached the highest level after 120 hours of incubation. On the effect of carbon sources on the phytase production, the most favorable carbon source for phytase production was fructose. As for the effect of nitrogen sources, high levels of phytase activity were detected in the medium containing nutrient broth as the nitrogen source. Free $PO_4^{3-}$ inhibited phytase production with increasing concentration of $KE_2PO_4$ and phytate in the media. The addition of $CaCl_2$ and $MgSO_4$ also resulted in the inhibition of phytase production. To investigate the effect of aeration on the phytase production, different volumes of culture broth in Erlenmeyer flasks were incubated in rotary shaker at the speed of 200 rpm. As a result, a high level of phytase activity was detected at small volume of culture broth as compared to larger volume because of its more aerobic condition.

Eutrophication and Water Pollution Characteristics of the Kyongan Stream to Paltang Reservoir (경안천${\sim}$팔당호의 부영양화와 수질오염 특성)

  • Cho, Joo-Lae;Hwang, Soon-Jin;Cho, Kyung-Je;Shin, Jae-Ki
    • Korean Journal of Ecology and Environment
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    • v.33 no.4 s.92
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    • pp.387-394
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    • 2000
  • Water pollution characteristics were investigated in the Kyongan stream and major inlet parts of Paltang Reservoir from April to July, 2000. Water quality in the Kyongan stream was extremly deteriorated by treated wastewater discharge at near sewage wastewater treatment plant (SWTP) located in the upstream, and it is likely to influence eutrophication of the lower part of the stream. Water quality of the Kyongan stream showed a typical hypertrophic condition. Influxed concentrations with $NH_4$ and SRP into the main stream from SWTP were declined precipitously as water flowed toward the lower part of the stream, and chlorophyll- a explosively increased in the midstream. Average concentrations of $NH_4$, SRP and chlorophyll-a in the main stream were $1,343\;{\mu}g\;N/l$, $1,779\;{\mu}g\;P/l$ and $188\;{\mu}g\;l$, respectively. Particularly, phosphorus load was very high, and its influence on the algal growth stimulation was remarkable. In comparison with the water quality inflowing into Paltang Resevoir, pollution status of the Kyongan stream was more worse than that in the Pukhan River and the Namhan River. The results of this study indicate that the management of point source, SWTP effluent, is urgent to mitigate eutrophication of Paltang Reservoir, and requires further necessary controls of inorganic phosphorus loading.

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Quality Characteristics of Mul-kimchi Prepared Using Eastern Deep Seawater Added with Chitosan-Ascorbate (Chitosan-Ascorbate 함유 동해심해수로 담근 물김치의 품질특성)

  • Lee, Ye-Kyung;Shin, Kyung-Ok;No, Hong-Kyoon;Kim, Soon-Dong
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.34 no.9
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    • pp.1450-1458
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    • 2005
  • Quality characteristics of mul-kimchi prepared using eastern deep seawater added with $0.1\%$ chitosan-ascorbate (CA) were investigated during fermentation for 12 days at $10^{\circ}C$, in an effort to effectively utilize the eastern deep seawater in Korea. Four water sources were considered for preparation of mul-kimchi; (1)distilled water added with $1\%$ mineral salt (DW), (2) eastern deep seawater (containing $6\%$ salt) diluted to $1\%$ salt concentration with distilled water (ED), (3) DW+CA (DW-CA), and (4) ED+CA (ED-CA). Juice of mul-kimchi prepared with ED-CA as a water source showed higher PH and antioxidant activity, and lower acidity, total microbe numbers, turbidity and alcohol insoluble substance compared with those Prepared with other three water sources. The former also showed higher overall acceptability compared with the latter. This study demonstrated the possibility of use of eastern deep seawater added with chitosan-ascorbate as a water source for extension of shelf-life of mul-kimchi.

Diagnosis and Treatment of Feline Inflammatory Polyp with Video Otoscopy : A Case Report (고양이에서 비디오 이경검사법을 이용한 염증성 폴립의 진단 및 치료 1례)

  • Park, Se-Jin;Lee, Seung-Yong;Kim, Young-Ki;Seok, Seong-Hoon;Hwang, Jae-Min;Jeong, Dong-Hyuk;Lee, Hee-Chun;Yeon, Seong-Chan
    • Journal of Veterinary Clinics
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    • v.30 no.4
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    • pp.301-304
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    • 2013
  • Otic mass removal was performed in a 19-month-old, castrated domestic shorthair cat. The patient had 1- year history of recurrent otitis externa, and then otic mass in the right ear canal was found. Under general anesthesia, 2.7 mm rigid endoscope was inserted to the right ear canal with the irrigation system. The ovoid-shaped, 4.9 mm in diameter red otic mass located in the right ear canal was removed via traction-avulsion. Then, rupture of the tympanic membrane was revealed and otic flushing was performed with sterile isotonic (0.9%) saline to remove exudates. Histologically, the removed polyp was diagnosed as granulation tissue with severe ulceration. The patient didn't reveal any remarkable abnormality after surgery, and no recurrence were found after 5 months follow up. The video otoscopy seems to offer a useful option for treatment of a feline inflammatory polyp.

Seismic Stratigraphy and Depositional History of Holocene Transgressive Deposits in the Southeastern Continental Shelf, Korea (한국 남동해역 홀로세 해침퇴적층의 탄성파층서 및 퇴적역사)

  • Yoo, Dong-Geun;Kim, Seong-Pil;Lee, Chi-Won;Park, Soo-Chul
    • Economic and Environmental Geology
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    • v.44 no.4
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    • pp.303-312
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    • 2011
  • Analysis of high-resolution seismic profiles from the southeastern continental shelf of Korea reveals that the Holocene transgressive deposits consist of five sedimentary units characterized by retrograding or backstepping depositional arrangements. Unit I, forming a linear sediment body along the shelf margin, is an ancient beach/shoreface deposit formed during the early stage of transgression. During the transgression, the paleo-channels were backfilled with fluvial or coastal-plain sediments, forming Unit II as an incised-channel fill deposit. The near-surface sediment was reworked and eroded by shoreface erosion, forming a thin lag of sands (Unit III) on the midshelf. During the middle stage of the transgression, the shoreline may have stabilized at around 70 - 80 m below the present sea level for some period of time to allow the formation of sand ridge systems (Unit IV). Unit V in the inner shelf was deposited in an estuarine environment during the middle to late stage of transgression. Such transgressive stratigraphic architecture is controlled by a function of lateral changes in the balance among rates of relative sea-level rise, sediment input and marine processes at any given time.

Growth characteristics of different Barley cultivars grown on NaCl stress (NaCl stress에 의한 몇가지 보리 품종들의 생육시기별 생육 특성)

  • Cho, Jin-Woong;Park, Ki-Sun;Lee, Sok-Young
    • Korean Journal of Environmental Agriculture
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    • v.19 no.1
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    • pp.1-5
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    • 2000
  • This study was conducted to investigate the growth characteristics of four barley cultivars to NaCl stress of 100mM on 10 March (Tillering stage) and 10 April(Panicle formation stage). Plant grown in Wagner pot(1/5,000 a) with sand culture. Plant height, root length, leaf number and tillering number reduced by NaCl stress and tillering number was shorter than any other character. The reduction of those with NaCl treatment was more severe in 10 March treatment compared to in 10 April it. Leaf, root and straw weight were decreased with NaCl treatment and root weight was more sensitive than any others on 10 March and 10 April treatment. One hundred grain weight (g) in grain component was the most severe in 10 March treatment and panicle number per plant was the most severe in 10 April treatment. The result also varied depending on the cultivars and the time of NaCl stress. In terms of yield component, salt sensitivity was low in order of Bunong, Chalssalbori, Dongbori 1, and Neulssalbori in 10 March and Neulssalbori, Dongbori 1, Bunong and Chalssalbori in 10 April treatment by 100mM NaCl.

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Efficacy of Electrolyzed Water and Aqueous Chlorine Dioxide for Reducing Pathogenic Microorganism on Chinese Cabbage (전기분해수 및 이산화염소수 처리에 따른 배추의 미생물 제어 효과)

  • Park, Seong-Soon;Sung, Jung-Min;Jeong, Jin-Woong;Park, Kee-Jai;Lim, Jeong-Ho
    • Korean Journal of Food Science and Technology
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    • v.44 no.2
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    • pp.240-246
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    • 2012
  • This study evaluated the efficacy of strong acidic electrolyzed water (SAcEW), low alkaline electrolyzed water (LAlEW) and aqueous chlorine dioxide (ACD) for reducing pathogenic bacteria($Escherichia$ $coli$, $Bacillus$ $cereus$, $Salmonella$ Typhimurium, $Stapylococcus$ $aureus$) on Chinese cabbage. Artificially inoculated Chinese cabbage was immersed for 1, 5 and 10 min with TW, NaClO, EW and ACD. Generally, leaves showed more effective reduction than stems. Regarding the inhibitory effect, ACD treatment showed the highest effects rather than other treatments. When Chinese cabbage was immersed for 3 min in sterilized water, it was reduced to a minimum of 1.33 log CFU/g at LAlEW and a maximum of 4.70 log CFU/g at ACD. Compared to NaClO, ACD and LAlEW which showed a reduction of 3.2 log CFU/g ($Sal.$ Typhimurium) and 2.7 log CFU/g($B.$ $cereus$), respectively. Furthermore, the others had similar inhibitory effects compared to NaClO.